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1.  Di­hydrogen phosphate mediated supra­molecular frameworks in 2- and 4-chloro­anilinium dihydrogen phosphate salts 
The title compounds, 2-chloro­anilinium dihydrogen phosphate (2CADHP) and 4-chloro­anilinium di­hydrogen phosphate (4CADHP), both C6H7NCl+·H2PO4 −, form two-dimensional supra­molecular organic–inorganic hybrid frameworks. In 2CADHP, the dihydrogen phosphate anions form a double-stranded anionic chain generated parallel to the [010] direction through O—H⋯O hydrogen bonds, whereas in 4CADHP they form a two-dimensional supra­molecular net extending parallel to the crystallographic (001) plane into which the cations are linked through strong N—H⋯O hydrogen bonds.
doi:10.1107/S0108270110001940
PMCID: PMC2855582  PMID: 20203405

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