The asymmetric unit of the title compound, C13H10F3NO3, contains two independent molecules with similar conformations. In the crystal, N—H⋯O hydrogen bonds link alternating independent molecules into chains in [-110]. In the chain, the quinoline planes of the independent molecules are almost perpendicular to each other, forming a dihedral angle of 89.8 (1)°. π–π interactions between the aromatic rings of quinoline bicycles related by inversion centres [for two independent centrosymmetric dimers, the shortest centroid–centroid distances are 3.495 (1) and 3.603 (1) Å] link the hydrogen-bonded chains into layers parallel to (110). Weak C—H⋯F and C—H⋯O interactions further consolidate the crystal packing.
doi:10.1107/S1600536812045321
PMCID: PMC3588845
PMID: 23468810
In the title compound, C23H15BrO3, the anthracene ring system is essentially planar [maximum deviation = 0.29 (2) Å] and makes a dihedral angle of 5.74 (8)° with the mean plane of the bromo-substituted benzene ring. An intramolecular C—H⋯O hydrogen bond generates an S(9) ring motif. In the crystal, molecules are linked by C—H⋯O interactions, forming a two-dimensional network parallel to the ac plane. π–π stacking interactions are observed between benzene rings [centroid–centroid distances = 3.5949 (14) and 3.5960 (13) Å].
doi:10.1107/S1600536812022684
PMCID: PMC3379439
PMID: 22719637
In the title compound, C16H13FO4, the aromatic rings enclose an angle of 73.68 (6)°. In the crystal, C—H⋯O and C—H⋯F contacts connect the molecules into a three-dimensional network. The shortest intercentroid distance between two aromatic π-systems is 3.6679 (7) Å and is apparent between the fluorinated phenyl groups.
doi:10.1107/S1600536812002577
PMCID: PMC3275257
PMID: 22347113
The title compound, C15H16F3NO4, is an N-substituted derivative of ortho-trifluoromethylaniline featuring a twofold Michael system. The least-squares planes defined by the atoms of the phenyl ring and the atoms of the Michael system enclose an angle of 15.52 (5)°. Apart from classical intramolecular N—H⋯O and N—H⋯F hydrogen bonds, intermolecular C—H⋯O contacts are observed, the latter connecting the molecules into chains along [110]. The shortest intercentroid distance between two aromatic systems is 3.6875 (9) Å.
doi:10.1107/S1600536812002590
PMCID: PMC3275258
PMID: 22347114
In the title compound, C16H13FO4, the dihedral angle between the benzene rings is 84.28 (8)°. In the crystal, C—H⋯F and C—H⋯O hydrogen bonds link the molecules to form a three-dimensional network. The crystal structure is consolidated by C—H⋯π interactions and short F⋯F contacts [2.7748 (14) Å] also occur.
doi:10.1107/S1600536811049233
PMCID: PMC3239086
PMID: 22199934
The title compound, C16H13BrO3, consists of a toluene ring and a bromobenzene ring which are linked together by a 2-oxopropyl acetate group. The dihedral angle formed between the toluene and bromobenzene rings is 80.70 (7)°. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into a three-dimensional network.
doi:10.1107/S1600536811045272
PMCID: PMC3238827
PMID: 22199680
In the title compound, C23H20F3N5O, the piperazine ring adopts a chair conformation. The quinoline ring makes dihedral angles of 56.61 (11), 49.94 (12) and 42.58 (14)° with the piperazine ring, the 1,3,4-oxadiazole ring and the benzene ring, respectively. An intramolecular C—H⋯O hydrogen bond generates an S(7) ring motif. In the crystal, molecules are linked into infinite chains along the b axis by C—H⋯N hydrogen bonds.
doi:10.1107/S1600536811044370
PMCID: PMC3247502
PMID: 22220120
In the title compound, C16H13BrO3, the dihedral angle formed between the bromo- and methyl-substituted benzene rings is 66.66 (8)°. In the crystal, molecules are linked by intermolecular C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the ac plane. The crystal packing is further consolidated by C—H⋯π interactions.
doi:10.1107/S1600536811044564
PMCID: PMC3247503
PMID: 22220121
The asymmetric unit of the title compound, C15H10BrClO3, consists of three crystallographically independent molecules. The dihedral angles between the benzene rings in the three molecules are 68.8 (2), 0.7 (3) and 66.1 (2)°. In the crystal, the three independent molecules are interconnected by C—H⋯O hydrogen bonds, leading to isolated trimers.
doi:10.1107/S1600536811022963
PMCID: PMC3151903
PMID: 21837113
In the title compound, C16H13ClO4, the two benzene rings make a dihedral angle of 86.38 (8)°. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules to form columns along the a axis. The molecules are also stabilized by a π–π stacking interaction, with a centroid–centroid distance of 3.7793 (10) Å between the inversion-related benzene rings.
doi:10.1107/S1600536811021246
PMCID: PMC3151969
PMID: 21837084
In the title molecule, C16H13BrO4, the dihedral angle between the benzene rings is 85.92 (10)°. In the crystal, molecules are linked into chains along [100] via weak intermolecular C—H⋯O hydrogen bonds.
doi:10.1107/S1600536811023002
PMCID: PMC3152007
PMID: 21837114
The asymmetric unit of title compound, C15H9ClF2O3, consists of two crystallographically independent molecules. The dihedral angle between the two terminal benzene rings in one molecule is 7.92 (14)°, while that in the other molecule is 73.50 (16)°. In the crystal, molecules are stacked into columns along the b axis by intermolecular C—H⋯O hydrogen bonds. A π–π interaction with a centroid-to-centroid distance of 3.747 (2) Å further stabilizes the crystal structure.
doi:10.1107/S1600536811020630
PMCID: PMC3151833
PMID: 21837007
In the title compound, C16H10ClF3O3, the two benzene rings are slightly twisted from each other, with a dihedral angle of 15.50 (8)° between the planes. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into a layer parallel to the bc plane.
doi:10.1107/S1600536811020629
PMCID: PMC3152104
PMID: 21837005
The asymmetric unit of the title compound, C15H10Br2O3, consists of three crystallographically independent molecules (A, B and C). The phenyl rings in molecules A, B and C make dihedral angles of 6.1 (3), 3.2 (2) and 54.6 (2)° to each other, respectively. In the crystal, molecules are linked into two-dimensional layers parallel to the ab plane by intermolecular C—H⋯O hydrogen bonds. The crystal structure is further stabilized by C—H⋯π interactions. The studied crystal is an inversion twin, the refined ratio of the twin components being 0.128 (8):0.872 (8).
doi:10.1107/S1600536811020654
PMCID: PMC3152043
PMID: 21836992
In the title compound, C16H13BrO4, the benzene rings are almost perpendicular to each other, making a dihedral angle of 84.07 (8)°. In the crystal, the molecules are linked into chains along the a axis via intermolecular C—H⋯O hydrogen bonds. A C—H⋯π interaction is also observed.
doi:10.1107/S1600536811018988
PMCID: PMC3120282
PMID: 21754889
In the title compound, C15H12O3, the terminal phenyl rings make a dihedral angle of 86.09 (9)° with each other. In the crystal, a pair of intermolecular C—H⋯O hydrogen bonds link the molecules, forming a dimer with an R
2
2(10) ring motif.
doi:10.1107/S1600536811018976
PMCID: PMC3120516
PMID: 21754888