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1.  N-Ferrocenylmethyl-2-nitro­aniline 
In the title compound, [Fe(C5H5)(C12H11N2O2)], the two cyclo­penta­dienyl (Cp) rings are nearly eclipsed and parallel to each other, the dihedral angle between their mean planes being 2.54 (1)°. One of the Cp rings is substituted by a nitro­benzenamine group, which is essentially perpendicular to the substituted cyclo­penta­dienyl ring, with an N—C(H2)—C—C torsion angle of 89.8 (2)°. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds occur. In the crystal, weak C—H⋯O hydrogen bonds link adjacent mol­ecules.
doi:10.1107/S1600536812039177
PMCID: PMC3470183  PMID: 23125627
2.  N-Ferrocenymethyl-N-phenyl­propionamide 
In the title compound, [Fe(C5H5)(C15H16NO)], the two cyclo­penta­dienyl (Cp) rings are nearly parallel to each other, forming a dihedral angle of 3.7 (1)°, and adopt a staggered conformation. The amide group is almost perpendicular to the plane of the substituted Cp ring, with a C—N—C—C torsion angle of 101.3 (2)°, and the N and O atoms in the ethanoyl group are coplanar, with a C—N—C—O torsion angle of −0.7 (3)°. Weak C—H⋯O hydrogen bonds link adjacent mol­ecules.
doi:10.1107/S1600536812016303
PMCID: PMC3344370  PMID: 22590136

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