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1.  2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone 
In the title compound, C15H9Cl2N3O, an intra­molecular C—H⋯O inter­action generates an S(7) ring motif. The cyclo­penta-1,3-diene ring forms dihedral angles of 1.93 (6) and 2.78 (6)° with its attached benzene rings. In the crystal, mol­ecules are linked by C—H⋯N and C—H⋯O hydrogen bonds, thereby forming layers lying parallel to the ac plane. The crystal also features a π–π inter­action with a centroid–centroid distance of 3.5612 (6) Å.
PMCID: PMC3201472  PMID: 22058777
2.  (E)-4-Phenyl­butan-2-one oxime 
In the title compound, C10H13NO, the C—C—C—C torsion angle formed between the benzene ring and the butan-2-one oxime unit is 73.7 (2)°, with the latter lying above the plane through the benzene ring. In the crystal, inter­molecular O—H⋯N hydrogen bonds link pairs of mol­ecules into dimers, forming R 2 2(6) ring motifs which are stacked along the a axis.
PMCID: PMC3200599  PMID: 22065139
3.  1-Isobutyl-4-meth­oxy-1H-imidazo[4,5-c]quinoline 
In the title compound, C15H17N3O, the 1H-imidazo[4,5-c]quinoline ring system is approximately planar, with a maximum deviation of 0.036 (1) Å. The C—N—C—C torsion angles formed between this ring system and the isobutyl unit are −99.77 (16) and 79.71 (17)°. In the crystal, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains along the c axis.
PMCID: PMC3200859  PMID: 22058955
4.  3-[(1-Isobutyl-1H-imidazo[4,5-c]quinolin-4-yl)amino]­benzoic acid 
In the title compound, C21H20N4O2, the statistically planar 1H-limidazole ring [maximum deviation = 0.003 (1) Å] makes dihedral angles of 1.33 (9) and 8.23 (7)°, respectively, with the essentially planar fused pyridine ring [maximum devation = 0.018 (1) Å] and the pendant benzene ring, which is attached to the pyridine ring by an —NH— group. An intra­molecular C—H⋯N inter­action, which generates an S(6) ring, helps to estalish the mol­ecular conformation. In the crystal, the mol­ecules are linked by N—H⋯O, C—H⋯O and O—H—N hydrogen bonds, which generate bifurcated R 1 2(6) and R 2 2(9) ring motifs, resulting in supra­molecular [001] chains. The crystal structure also features weak π–π stacking [centroid–centroid distance = 3.5943 (9) Å] and C—H⋯π inter­actions.
PMCID: PMC3213588  PMID: 22091165
5.  1-Isobutyl-N,N-dimethyl-1H-imidazo[4,5-c]quinolin-4-amine 
In the title compound, C16H20N4, the 1H-imidazo[4,5-c]quinoline ring system is approximately planar, with a maximum deviation of 0.0719 (15) Å. An intra­molecular C—H⋯N hydrogen bond contributes to the stabilization of the mol­ecule, forming an S(6) ring motif. In the crystal, the mol­ecules are stacked along the b axis through weak aromatic π–π inter­actions between benzene and imidazole and benzene and pyridine rings [centroid–centroid distances = 3.6055 (10) and 3.5342 (10) Å, respectively].
PMCID: PMC3051498  PMID: 21523077
6.  4-Chloro­benzaldehyde (1-isobutyl-1H-imidazo[4,5-c]quinolin-4-yl)hydrazone monohydrate 
In the title compound, C21H20ClN5·H2O, the 1H-imidazo[4,5-c]quinoline ring is approximately planar, with a maximum deviation of 0.0795 (7) Å, and it forms a dihedral angle of 7.65 (3)° with the chloro­phenyl ring. In the crystal, the components are linked into chains along the a axis via inter­molecular N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. One of the H atoms of the water mol­ecule is disordered over two positions with a site-occupancy ratio of 0.80 (4):0.20 (4).
PMCID: PMC3051724  PMID: 21523079
7.  4-Hydrazinyl-1-isobutyl-1H-imidazo[4,5-c]quinoline 
In the title compound, C14H17N5, the 1H-imidazo[4,5-c]quinoline ring system is essentially planar, with a maximum deviation of 0.0325 (7) Å. In the crystal, a pair of inter­molecular N—H⋯N hydrogen bonds link neighbouring mol­ecules, forming an inversion dimer and generate an R 2 2(10) ring motif. These dimers are further connected into a chain along the b axis via inter­molecular C—H⋯N hydrogen bonds, resulting in an R 2 2(14) ring motif.
PMCID: PMC3051739  PMID: 21523078

Results 1-7 (7)