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1.  4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate 
In the title compound, C23H18N6O5·C2H6O, all three benzene rings lie in an approximate plane [maximum deviation = 0.2688 (16) Å] that makes an angle of 53.56 (3)° with the plane of the pyrazolone ring. Intra­molecular N—H⋯O hydrogen bonds occur. In the crystal, the ethanol solvent mol­ecule links adjacent mol­ecules through N—H⋯O—H⋯O hydrogen bonds, leading to an infinite chain along the c-axis direction. The ethyl group of the ethanol solvent mol­ecule is disordered over two set of sites in a 0.762 (5):0.238 (5) ratio.
doi:10.1107/S1600536812044935
PMCID: PMC3588976  PMID: 23476212
2.  (2-Ethyl-2-oxazoline-κN)bis(N-ethyl-N-phenyl­dithio­carbamato-κ2 S,S′)cadmium 
In the title compound, [Cd(C9H10NS2)2(C5H9NO)], the CdII atom is five-coordinated in a distorted square-pyramidal geometry by four S atoms from two chelating N-ethyl-N-phenyl dithio­carbamate ligands and one N atom from a 2-ethyl-2-oxazoline ligand. Inter­molecular C—H⋯π inter­actions are observed in the crystal structure.
doi:10.1107/S1600536812038433
PMCID: PMC3470177  PMID: 23125621
3.  Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2 O,O′)bis­(ethanol-κO)cobalt(II) 
The title compound, [Co(C17H13N2O2)2(C2H5OH)2], is a CoII complex with two 4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olate (BMPP) ligands and two coordinating ethanol mol­ecules. In the asymmetric unit, there are two half mol­ecules, with the CoII atoms located on inversion centres. The two cobalt complexes have slightly different geometries and in one, the ethyl group of the ethanol is disordered over two sets of sites [occupancy ratio 0.757 (7):0.243 (7)]. Each BMPP ligand is deprotonated with the negative charge delocalized. The hy­droxy group of each ethanol mol­ecule forms hydrogen bonds with a pyrazole N atom in an adjacent BMPP ligand. Weaker C—H⋯O and C—H⋯N inter­actions link the mol­ecules into a three-dimensional structure.
doi:10.1107/S1600536812032837
PMCID: PMC3414155  PMID: 22904762
4.  4-[(4-Meth­oxy­benzyl­idene)amino]­benzene­sulfonamide 
The title Schiff base compound, C14H14N2O3S, is non-planar, with a dihedral angle of 24.16 (7)° between the benzene rings. In the crystal, N—H⋯O and N—H⋯N hydrogen bonds link the mol­ecules into a layer parallel to (011). Intra- and inter­layer C—H⋯O inter­actions and π–π inter­actions [centroid–centroid distances = 3.8900 (9) and 3.9355 (8) Å] are also present.
doi:10.1107/S1600536812018818
PMCID: PMC3379209  PMID: 22719407
5.  3-Methyl-1-phenyl-4-[(phen­yl)(2-phenyl­hydrazin-1-yl)meth­ylidene]-1H-pyrazol-5(4H)-one 
The title compound, C23H20N4O, is a heterocyclic phenyl­hydrazone Schiff base with a pyrazole moiety. In the crystal, a variety of inter­actions occur, including N—H⋯π and π–π stacking between the phenyl ring of the phenyl­hydrazinyl group and its symmetry-generated equivalent [centroid–centroid distance = 3.6512 (7) Å].
doi:10.1107/S1600536812013463
PMCID: PMC3344433  PMID: 22590195
6.  1,5-Bis(2-methyl­phen­yl)-3-nitro­formazan 
In the title compound, C15H15N5O2, the nitro O atoms are disordered over two sets of sites with an occupancy ratio of 0.75 (4):0.25 (4). Amine–imine tautomerism is observed in the formazan group. This was evident from the similar C—N bond distances in the formazan [1.319 (2) and 1.332 (3) Å], as well as the distribution of the imine proton in the Fourier difference map which refined to a 0.53 (3):0.47 (3) ratio. C—H⋯O and π–π inter­actions [centroid–centroid distances = 3.4813 (1) and 3.3976 (1) Å] are observed in the crystal packing.
doi:10.1107/S1600536812001171
PMCID: PMC3275183  PMID: 22347039
7.  (E)-1-[2-(Methyl­sulfan­yl)phen­yl]-2-({(E)-2-[2-(methyl­sulfan­yl)phen­yl]hydrazinyl­idene}(nitro)­meth­yl)diazene 
In the title compound, C15H15N5O2S2, the phenyl rings make dihedral angles of 4.03 (4) and 9.77 (5)° with the plane defined by the central N—N—C—N—N atoms (r.m.s. deviation = 0.010 Å). The C—S—C—C torsion angles of the methyl­sulfanyl groups with their respective phenyl rings are −7.47 (13) and −72.07 (13)°. The shortest centroid–centroid distance of 3.707 Å occurs between the two π-systems N—N—C—N—N and the benzene ring in the diazene 1-position. The H atom bound to the N atom is involved in intra­molecular N—H⋯N and N—H⋯S contacts, while the nitro O atoms are involved in inter­molecular C—H⋯O contacts.
doi:10.1107/S1600536811054080
PMCID: PMC3254534  PMID: 22259480

Results 1-7 (7)