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1.  (E)-4-(2-Hy­droxy-3-meth­oxy­benzyl­idene­amino)-6-methyl-3-sulfanyl­idene-3,4-dihydro-1,2,4-triazin-5(2H)-one 
In the title mol­ecule, C12H12N4O3S, there is an intra­molecular O—H⋯N hydrogen bond. The dihedral angle between the benzene and triazine rings is 65.9 (3)°. In the crystal, N—H⋯S and O—H⋯N hydrogen bonds link the mol­ecules into chains along [010]. In addition, there are weak π–π stacking inter­actions between symmetry-related triazine rings with a centroid–centroid distance of 3.560 (3)°.
doi:10.1107/S1600536812036756
PMCID: PMC3435839  PMID: 22969685
2.  N,N′-(4-Chloro­benzyl­idene)dipyrimidin-2-amine 
The title compound, C15H13ClN6, contains two pyrimidine rings and one benzene ring, where the dihedral angle between the planes through the pyrimidine rings is 81.57 (10)°, and those between the pyrimidine rings and the benzene ring are 84.02 (8) and 89.46 (7)°, indicating that the three rings are almost perpendicular. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into infinite chains along (100).
doi:10.1107/S1600536809045243
PMCID: PMC2971878  PMID: 21578719

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