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1.  [2-Cyclo­propyl-4-(4-fluoro­phenyl)quinolin-3-yl]methanol 
The title compound, C19H16FNO, crystallizes with two independent mol­ecules in the asymmetric unit. In the two mol­ecules, the dihedral angles between the benzene and quinoline rings are 72.6 (5) and 76.2 (5)°, between the cyclo­propane and quinoline rings they are 65.2 (5) and 66.0 (5)°, and between the benzene and cyclo­propane rings they are 25.9 (5) and 33.9 (5)°. There are inter­molecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, as well as intra­molecular C—H⋯O hydrogen bonds, which may be effective in stabilizing the crystal structure.
doi:10.1107/S1600536810043588
PMCID: PMC3009308  PMID: 21589152
2.  (E)-5-(2-Nitro­prop-1-en­yl)-2,3-dihydro-1-benzofuran 
The asymmetric unit of the title compound, C11H11NO3, contains two crystallographically independent mol­ecules. The aromatic rings are oriented at a dihedral angle of 56.17 (5)°. The furan rings adopt envelope conformations. Intra­molecular C—H⋯N inter­actions results in the formation of two six-membered rings with twisted conformations. In the crystal structure, three weak C—H⋯π inter­actions are found.
doi:10.1107/S1600536809023277
PMCID: PMC2969479  PMID: 21582947

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