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1.  4-Bromo-2-({4-[(hy­droxy­imino)­meth­yl]phen­yl}imino­meth­yl)phenol 
In the title compound, C14H11BrN2O2, the mean planes of the two benzene rings are almost parallel to each other, making a dihedral angle of 4.09 (1)°. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, inter­molecular O—H⋯N and C—H⋯O hydrogen bonds link the mol­ecules into a chain-like supra­molecular structure.
doi:10.1107/S160053681002698X
PMCID: PMC3007216  PMID: 21588325
2.  4-[(Ethoxy­imino)(phen­yl)meth­yl]-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one 
In the mol­ecule of the title compound, C19H19N3O2, the central pyrazole ring makes dihedral angles of 9.89 (3) and 66.06 (5)° with the two phenyl rings, and the two phenyl rings form an angle of 74.05 (5)°. An intra­molecular C—H⋯O hydrogen bond forms a six-membered ring, producing an S(6) ring motif. In the crystal structure, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link each mol­ecule to two others, forming an infinite one-dimensional supra­molecular structure along the c axis.
doi:10.1107/S1600536808026263
PMCID: PMC2960692  PMID: 21201773

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