Search tips
Search criteria 


Logo of scirepAboutEditorial BoardFor AuthorsScientific Reports
Sci Rep. 2016; 6: 24234.
Published online 2016 April 18. doi:  10.1038/srep24234
PMCID: PMC4834571

Gamma radiation induces hydrogen absorption by copper in water


One of the most intricate issues of nuclear power is the long-term safety of repositories for radioactive waste. These repositories can have an impact on future generations for a period of time orders of magnitude longer than any known civilization. Several countries have considered copper as an outer corrosion barrier for canisters containing spent nuclear fuel. Among the many processes that must be considered in the safety assessments, radiation induced processes constitute a key-component. Here we show that copper metal immersed in water uptakes considerable amounts of hydrogen when exposed to γ-radiation. Additionally we show that the amount of hydrogen absorbed by copper depends on the total dose of radiation. At a dose of 69 kGy the uptake of hydrogen by metallic copper is 7 orders of magnitude higher than when the absorption is driven by H2(g) at a pressure of 1 atm in a non-irradiated dry system. Moreover, irradiation of copper in water causes corrosion of the metal and the formation of a variety of surface cavities, nanoparticle deposits, and islands of needle-shaped crystals. Hence, radiation enhanced uptake of hydrogen by spent nuclear fuel encapsulating materials should be taken into account in the safety assessments of nuclear waste repositories.


Nuclear power is often argued to be a fossil-free alternative in the global spectrum of electricity generation1,2. The safety of operating nuclear power plants is usually of main concern in discussions comparing different energy production techniques. However, at present, one of the most difficult issues to tackle is the long-term safety of repositories for radioactive waste originating from nuclear power plants, in particular the spent nuclear fuel3. The safety of such repositories must be guaranteed for time periods longer than the history of homo sapiens4. The safety relies on a series of natural and engineered barriers preventing the highly radioactive material from migrating into the biosphere5. In some repository concepts, metallic copper has been proposed as an outer corrosion resistant barrier on canisters containing the spent nuclear fuel6,7,8. As for the other barrier materials, studies of processes that have potential impact on the long-term integrity of the copper layer have been conducted both in laboratories and in the field under repository conditions9. A rather unique feature of the copper used in spent nuclear fuel canisters is that it will be exposed to ionizing radiation10,11,12,13,14. Because of this it is of vital importance to elucidate the effects of ionizing radiation on copper and on the interface between copper and surrounding matter.

The consequences of the exposure of many homogeneous systems to ionizing radiation are well-known on the basis of both experimental and theoretical studies performed over a period close to a century15. However, most systems of practical relevance are not homogeneous. In fact, one of the most crucial and thereby also interesting components of a system from a performance perspective is the interface between two phases. In nuclear technology, interfaces exposed to ionizing radiation constitute a key-point in any safety assessment and a common theme is the impact of radiation-induced corrosion in nuclear power plants, nuclear fuel reprocessing plants and repositories for radioactive waste16,17. In spite of the obvious importance of interfacial radiation chemistry, surprisingly, little is known about underlying mechanisms.To describe the radiation chemistry at an interface it is necessary to have information about: the homogeneous radiation chemistry of the two phases in contact; the energy deposition in the system; the yield of radiolysis products; and the reactivity of radiolysis products at the interface between the two homogeneous phases. γ-radiolysis of liquid water leads to a number of reactive species that are formed on different time scales18 as depicted in Fig. 1. The radiation chemical yield (G-value) of a product of γ-radiolysis of water may be affected by the presence of chemical species or materials in the aqueous medium19. Several studies have shown that the yield of the aqueous radiolysis product H2 can be significantly higher in water layers close to an oxide surface when compared to pure bulk water20,21. The magnitude of this effect depends on the nature of the oxide. However, no convincing mechanistic explanation that accounts for these observations has been given. In addition to the somewhat puzzling observations regarding the radiation chemical yield of H2, a number of studies on the interactions between other aqueous radiolysis products and oxide surfaces have been presented. It has been shown that H2O2 is catalytically decomposed22 to O2 and H2O via the intermediate formation of hydroxyl radicals on most oxide surfaces, and that the hydroxyl radical has a high affinity for oxide surfaces23. Additionally, under certain conditions, the decomposition of H2O2 at oxide surfaces can also lead to the formation of H224.

Figure 1
Time scale of events in water radiolysis leading to the primary products: H2; HO; H2O2; H3O+; HO; H and eaq.

It is known that hydrogen has undesirable effects on the life-time and performance of many metallic materials25. Hydrogen can be absorbed by metals via the diffusion of H-atoms through preferred specific pathways that have low energy barriers for H-atom migration26. Upon radical recombination of the H-atoms, H2 is formed and its effects on materials structure can be considerable. Such effects are the result of changes on vacancy-vacancy interactions27 which ultimately leads to the formation of internal cavities and other defects that are accompanied by the deterioration of the physical-chemical properties of the materials28. Furthermore, γ-radiation can induce changes in nuclear spin states of H2 and lead to the conversion of para- to ortho-hydrogen29. It is known that changes in the nuclear spin state of H2 cause changes in its magnetic properties and this affects its interactions with metals leading to increased stability of hydrogen at some positions in the copper lattice30. Additionally, γ-radiation is known to cause low temperature annealing of metals31. The fact that γ-radiation is capable of inducing structural changes in the bulk material32 and interface with water21—including corrosion33,34,35—lead us to develop this study, which is aimed at understanding whether γ-radiation is capable of triggering the uptake of hydrogen by high-purity metallic copper in aqueous medium. As shown above, one of the radiolysis products of water is hydrogen36. Hence, the undesirable effects that hydrogen has on copper could potentially hamper the barrier properties.

Radiation-induced hydrogen charging of copper metal in water

The γ-radiation-induced hydrogen charging of copper was investigated as a function of total radiation dose (D). For each total radiation dose, blanks or background samples were prepared. The background samples consist of non-irradiated copper exposed to water for the same period of time as that of the irradiated samples. The background samples are necessary because copper has some amount of hydrogen from the manufacturing and even without the influence of ionizing radiation copper can induce the formation of minute amounts of H2(g) when exposed to water37,38. This is because water can adsorb dissociatively on some copper surfaces and this process leads to the formation of both HO and H, the latter is a precursor of H238. In Fig. 2 the amount of H2(g) measured in copper that was irradiated in aqueous media is plotted as a function of the total dose (D) corrected for the background values. It is known that desorption of dissociatively adsorbed water from metal and oxide surfaces can occur via a channel that leads to the formation of H2(g)39. This is due to the recombination of surface adsorbed H-atoms that occurs when the temperature is increased in the temperature-programmed desorption (TPD) experiment40. In order to exclude the hypothesis that the H2 measured in our samples originates from the recombination of products of dissociatively adsorbed water at the copper surface, we also determined the amount of H2O that is adsorbed at the surface of the copper samples and investigated possible correlations with the amount of H2 measured. In Fig. 2 it can be seen that the amount of H2O present in the copper samples does not correlate with the amount of H2 detected. This fact excludes the possibility that the H2 measured originates from the recombination of products of dissociatively adsorbed water at the copper surface. The H2(g) was measured post-irradiation which indicates that H and/or H2 are stable in copper. Previous investigations of desorption of H2 from copper show that bulk H2 desorbs in the same temperature range41 as the H2 that was detected in our irradiation experiments (Fig. 3). This indicates that the majority of the hydrogen measured originates from the copper bulk because surface-adsorbed hydrogen desorbs at lower temperatures in the TPD measurements. It can be seen in Fig. 3 that the irradiated sample has a considerably higher hydrogen content that desorbs at temperatures corresponding to bulk hydrogen, T > 500 K. The hydrogen content of the irradiated samples is also higher at the surface and at a few subsurface layers—this is for T < 500 K. A scanning electron microscopy investigation showed that the surfaces of both non-irradiated and irradiated samples exposed to water became covered with particles of approximately 100 nm in size (Fig. 4). There are no significant differences in morphology or size of the particles formed at the surface of non-irradiated and irradiated samples. However, besides the formation of nanoparticles, irradiated samples display extensive surface erosion and the presence of islands of needle-shaped crystals (Figs 4c,d, ,55 and and6),6), which were not observed on non-irradiated samples. Erosion features are present all over the surface of the sample but are more pronounced in areas nearby islands of needle-shaped crystals (Fig. 5a–e). Here they reach considerable depth, affecting the material subsurface layers up to several hundred33 nm. As a result of erosion, a diversity of porous structures, cavities and ravines are formed (Fig. 5b–e). Needle-shaped crystals occur either as large islands (of approximately 50–200 μm) or as very small crystals surrounding eroded areas (Fig. 5e). Interestingly, all observed islands of needle-shaped crystals have a core part (central nucleation point (Fig. 6d)), which is surrounded by a circle of nucleation points consisting of smaller crystal islands that are in turn encircled by very small crystals (indicated by white arrows on Fig. 6e). Energy-dispersive X-ray microanalysis and X-ray photoelectron spectroscopy performed at these areas confirmed the presence of oxygen, copper and a small amount of carbon in the crystals (Fig. 6e). According to previous studies on the radiation chemistry of copper/water interfaces, the corrosion products formed are most likely oxygen-containing products—mostly cuprite, Cu2O—resulting from the oxidation of copper33. All islands of needle–shaped crystals have a light blue color (Fig. 6d). This suggests the presence of copper (II) hydroxide or copper (II) hydroxy carbonate because cuprite has a red-pink color42.

Figure 2
Amounts of H2 (An external file that holds a picture, illustration, etc.
Object name is srep24234-m4.jpg) and H2O (An external file that holds a picture, illustration, etc.
Object name is srep24234-m5.jpg) measured in samples of copper metal irradiated in water as a function of the total dose of γ-radiation deposited (D) (kGy). The measurements of H2 and H2O were performed after irradiation. Each data point corresponds ...
Figure 3
Plot of the H partial pressure in the UHV chamber (mbar) (×109) as a function of temperature (K) measured by temperature-programmed desorption (TPD). 69 kGy γ-irradiated copper sample (An external file that holds a picture, illustration, etc.
Object name is srep24234-m6.jpg); non-irradiated sample, background (An external file that holds a picture, illustration, etc.
Object name is srep24234-m7.jpg). Heating rate ...
Figure 4
Particles formed at the surface of metallic Cu in oxygen-free water: (a,b) non-irradiated sample, (c,d) sample which was exposed to a total dose of γ-radiation of 69 kGy.
Figure 5
Scanning electron microscopy images of erosion at the surface of metallic copper kept in oxygen-free water and exposed to a radiation dose of 69 kGy.
Figure 6
Islands of needle-shaped crystals formed at the surface of metallic copper in oxygen-free water after the γ-radiolysis (radiation dose of 69 kGy): (a–c) scanning electron microscopy images taken at different magnifications, (d) optical ...


According to the experimental data available, at an external pressure of 1 atm of H2(g), dry copper absorbs very little hydrogen at room temperature—in the order of 3 × 10−6 ppm. Nevertheless, at a temperature of 1173 K, the uptake of hydrogen by copper increases to 40 ppm43,44. The driving force for this process has been attributed to the increase in the number of H-atoms at the Cu surface caused by the increase in temperature. This is because at higher temperatures a larger fraction of H2 is dissociated into H-atoms. The uptaken hydrogen, which diffuses into the bulk of Cu as H-atoms, has been determined to be trapped at defects such as Cu atom vacancies and dislocations26,45. This implies that a material with a higher concentration of such defects will have a higher capacity to uptake H from its surroundings. Electrochemistry has also been used46 for driving the uptake of hydrogen by Cu. In this process, hydrogen atoms are electrochemically produced on the copper surface resulting in a significant hydrogen uptake. A mechanism for this process has been proposed and the authors concluded that the surface properties are determinant for the diffusion of hydrogen into bulk copper.

Based on the observations presented above, it is plausible that the γ-radiation-induced hydrogen uptake presented here can be attributed to the radiolytic formation of hydrogen atoms. For γ-radiolysis of oxygen-free bulk water, the G-value (in μmol·J−1) for H is 0.06 and for H2 is 0.047, respectively19. However, as mentioned above, the interfacial G-value can be considerably higher. In the radiolytic system, the competing processes related with the uptake of H-atoms by copper are19,47,48:

An external file that holds a picture, illustration, etc.
Object name is srep24234-m1.jpg
An external file that holds a picture, illustration, etc.
Object name is srep24234-m2.jpg
An external file that holds a picture, illustration, etc.
Object name is srep24234-m3.jpg

where CuH (s) denotes H-atoms dissolved in bulk copper, Df is the diffusion coefficient for the H-atom in bulk polycrystalline copper and k2 is the second-order rate constant. R1 is fast, occurs in the diffusion limit and has no activation energy large enough that could allow its experimental determination. For H-atoms adsorbed at the Cu surface, R2 and R3 are competing processes. At a copper surface in contact with a gas-phase, R2 occurs without energy barrier at the (111) surface plane49. Yet, as highlighted by the authors of the cited study, the kinetics and energetics of such a process are dependent on the type of surface—the crystallographic plane—as well as the presence of surface defects. In aqueous media, R2 is expected to be slower—and have an energy barrier—due to the presence of surface defects and solvation effects as well as the hindering that these pose to the encounters between surface H-atoms when compared to the solid-gas interface38. The energy barrier for R3 corresponds to the transfer of an H-atom from solution into bulk Cu. This process is composed of several elementary steps that the H-atoms undergo and that occur in different time-scales: diffusion from solution to the interface; adsorption onto the Cu surface; and diffusion from the Cu surface into the bulk. The measured energy barrier of 43.5 kJ·mol−1 corresponds to the rate-determining step for the overall process described by reaction R3. For a surface adsorbed H-atom at a solid-liquid interface there is currently no kinetic data available in the literature for its diffusion onto the bulk Cu. Due to geometric factors, the growth of an irregular structure on the surface of Cu (Figs 5 and and6)6) can lead to a decrease in the yield of R2 and an increase in R3. This is because the oxygen-containing copper compounds formed on the metallic surface have a lower density and more defects than the metal surface. H-atoms adsorbed onto such irregular surfaces will have a lower probability for encounters when compared with the corresponding process occurring at the less defective metal surface. The rationale for this is that the H-atoms are more strongly bound to the irregular surfaces and thereby less mobile. Hence the rate constant for R2 is decreased. At the same time, the rate constant for R3 is enhanced for strongly bound H-atoms50. In conclusion, this will favor H-uptake by the solid material.

It should be noted that in the previous studies of hydrogen charging of copper, the availability of surface H2(g) was much higher than in the present case—because a pressure of H2(g) of 1 atm leads to an availability of hydrogen at the copper surface which is several orders of magnitude higher than that in the present radiolysis experiments20. In spite of this, the amount of H2(g) uptaken by copper at T = 298 K in the pressurized gas experiments43—3 × 10−6 wt.ppm at p = 1 atm of H2(g)—is 7 orders of magnitude lower than the amounts of H2(g) that were uptaken by the material due to exposure to γ-radiation in aqueous media at T = 298 K in the current study (Fig. 2). Additionally, in order for the pressurized gas experiments to be able to charge the same amounts of hydrogen into bulk Cu as we obtained in the radiolysis experiments, temperatures in the order of T  800 K have to be used together with an H2(g) external pressure of p = 1 atm. Our results clearly show that γ-radiation has a very large impact on the uptake of hydrogen by copper metal.

The γ-radiation induced uptake of hydrogen by bulk copper reported here most likely occurs due to a combination of several phenomena where the primary cause is the production of H-atoms at the interface due to γ-radiolysis of interfacial water. Additional phenomena to consider are the formation of defects in the bulk solid when it undergoes γ-radiation annealing and structural alterations of the surface and subsurface layers of copper enhancing the diffusion of H-atoms into the bulk. The insights presented here are not only essential for improving the radiation resistance of materials for long-term nuclear waste storage, but also for the design of novel hydrogen storage compounds and materials for space exploration.


Sample preparation and irradiation

All the solutions used in this study were prepared using water from a Millipore Milli-Q system. Samples of copper metal (Aldrich, 99.98%)—size: 5 × 5 × 0.25 mm—were subject to a surface treatment in order to remove traces of oxide, carbon dioxide and other possible contaminants. The samples were placed in an ultrasonic water bath for a period of 5 min and after removal were washed and transferred to a glove-box with an inert N2(g) atmosphere. Under the protective atmosphere the samples were washed with a solution of 5% amidosulfonic acid (H3NSO3) (Aldrich, 99.9%) during 1 min. It has been shown previously that the amidosulfonic acid is an effective way for removing the products of copper oxidation from the copper surface51. After washing in the acidic solution, the copper samples were further washed with ethanol and water, and placed in vials containing 5 ml of water, sealed and irradiated. γ-Irradiation was performed using a MDS Nordion 1000 Elite 137Cs γ-source with a dose rate of 0.135 Gy·s−1, which was determined by Fricke dosimetry52.

Hydrogen measurements

The hydrogen content in the copper samples was determined using the thermal desorption spectroscopy (TDS) technique. The measurements were carried out with a thermal desorption apparatus designed and assembled at Aalto University, Finland. The apparatus consists of an ultra-high vacuum (UHV) chamber equipped with a vacuum furnace, coupled to a second air-lock vacuum chamber through which the samples are inserted. Additionally, there is a sample transportation mechanism with magnetic support for the sample basket. The pumping system has an effective pumping rate of 6.6 × 10−2 m3 s−1. The mass spectrometer unit and the furnace heating system are controlled with a computer using the Lab View software. The vacuum in the UHV chamber is kept at 7 × 10−9 bar. The heating system provides a direct control of the sample temperature in the temperature range from room temperature to 1123 K with a controlled heating rate that can be varied in the range 1–10 K·min−1. Prior to the TDS measurements, the samples were cleaned with acetone in an ultrasonic bath for 1 min and dried in a He gas flow to remove the residual water from the samples surface. The size of the samples for TDS measurements was 0.9 × 4.0 × 10.0 mm. The hydrogen concentration in the copper samples was determined from integration of the area of the TDS peaks after background correction.

Scanning electron microscopy

For scanning electron microscopy experiments samples were taken from solution, dried with compressed air flow, placed onto stubs and immediately transferred to the microscope chamber, so that the total exposure of samples to air was less than 30 min. Images were collected using a Zeiss Gemini Ultra Plus scanning electron microscope and a FEI Quanta 3D Dual Beam system, equipped with an Oxford Instruments energy-dispersive detector.

Additional Information

How to cite this article: Lousada, C. M. et al. Gamma radiation induces hydrogen absorption by copper in water. Sci. Rep. 6, 24234; doi: 10.1038/srep24234 (2016).


The Carl Tryggers Stiftelse för Vetenskaplig Forskning and the Finnish Research Programme for Nuclear Waste (KYT2018) are gratefully acknowledged for financial support. N.V.T. acknowledges funding by the Bavarian Ministry of Sciences, Research and the Arts.


Author Contributions C.M.L., I.L.S. and M.J. wrote the main manuscript text. C.M.L. prepared the Figures 1, ,22 and and3.3. N.V.T. prepared the Figures 4, ,55 and and6.6. M.J., N.V.T., Y.Y., H.H. and P.A.K. provided equipment and instrumentation. C.M.L. and I.L.S. performed the irradiation experiments. O.T. and Y.Y. performed the hydrogen measurement experiments. N.V.T. performed the microscopy characterizations. All authors reviewed the manuscript.


  • Chu S. & Majumdar A. Opportunities and challenges for a sustainable energy future. Nature 488, 294–303 (2012). [PubMed]
  • Lichter S. R. & Rothman S. Scientists’ attitudes towards nuclear energy. Nature 305, 91–94 (1983).
  • Ewing R. C. Long-term storage of spent nuclear fuel. Nat Mater 14, 252–257 (2015). [PubMed]
  • White T. D. et al. Pleistocene Homo sapiens from Middle Awash, Ethiopia. Nature 423, 742–747 (2003). [PubMed]
  • Apted M. & Ahn J. in Geological Repository Systems for Safe Disposal of Spent Nuclear Fuels and Radioactive Waste (eds Ahn Joonhong & Apted Michael J. ), 3–28, (Woodhead Publishing, 2010).10.1533/9781845699789.1.3 [Cross Ref]
  • Barnaby W. Nuclear waste problem solved, claims Sweden’s nuclear industry. Nature 274, 6–6 (1978).
  • Cohen B. L. The Disposal of Radioactive Wastes from Fission Reactors. Scientific American 236, 21–31 (1977). [PubMed]
  • Rosborg B. & Werme L. The Swedish nuclear waste program and the long-term corrosion behaviour of copper. Journal of Nuclear Materials 379, 142–153, (2008).
  • King F. Container Materials for the Storage and Disposal of Nuclear Waste. Corrosion 69, 986–1011 (2013).
  • Camanzi B. & Holmes-Siedle A. G. The race for new radiation monitors. Nat Mater 7, 343–345 (2008). [PubMed]
  • Compton A. H. A Geographic Study of Cosmic Rays. Physical Review 43, 387–403 (1933).
  • Weinberg A. Assessing the Oklo phenomenon. Nature 266, 206–206 (1977).
  • Was G. S. Fundamentals of Radiation Materials Science - Metals and Alloys. 1 edn, (Springer-Verlag, Berlin Heidelberg, 2007).10.1007/978-3-540-49472-0 [Cross Ref]
  • Jonsson M. An Overview of Interfacial Radiation Chemistry in Nuclear Technology. Israel Journal of Chemistry 54, 292–301 (2014).
  • Friedlander G. & Herrmann G. in Handbook of Nuclear Chemistry (eds Attila Vértes et al. ) Ch. 1, 1–37, ; (Springer, US, 2011).10.1007/978-1-4419-0720-2 [Cross Ref]
  • Féron D. in Nuclear Corrosion Science and Engineering (ed Féron Damien ) 31–56, (Woodhead Publishing, 2012).10.1533/9780857095343.1.31 [Cross Ref]
  • Wolski K. in Nuclear Corrosion Science and Engineering (ed Féron Damien ) 104–130, (Woodhead Publishing, 2012).10.1533/9780857095343.2.104 [Cross Ref]
  • Mozumder A. Fundamentals of Radiation Chemistry, (Academic Press, 1999).10.1016/B978-012509390-3/50007-2 [Cross Ref]
  • Richter Helen W. In Photochemistry and Radiation Chemistry Vol. 254 Advances in Chemistry Ch. 2, 5–33, (American Chemical Society, 1998).10.1021/ba-1998-0254 [Cross Ref]
  • Petrik N. G., Alexandrov A. B. & Vall A. I. Interfacial Energy Transfer during Gamma Radiolysis of Water on the Surface of ZrO2 and Some Other Oxides. The Journal of Physical Chemistry B 105, 5935–5944 (2001).
  • Reiff S. C. & LaVerne J. A. Radiation-Induced Chemical Changes to Iron Oxides. The Journal of Physical Chemistry B 119, 7358–7365 (2015). [PubMed]
  • Haber F. & Weiss J. The Catalytic Decomposition of Hydrogen Peroxide by Iron Salts. The Royal Society 147, (1934).10.1098/rspa.1934.0221 [Cross Ref]
  • Lousada C. M., Johansson A. J., Brinck T. & Jonsson M. Mechanism of H2O2 Decomposition on Transition Metal Oxide Surfaces. The Journal of Physical Chemistry C 116, 9533–9543 (2012).
  • Lousada C. M., LaVerne J. A. & Jonsson M. Enhanced hydrogen formation during the catalytic decomposition of H2O2 on metal oxide surfaces in the presence of HO radical scavengers. Physical Chemistry Chemical Physics 15, 12674–12679 (2013). [PubMed]
  • Wang J. S. in Hydrogen Effects in Materials 61–76, (eds Thompson Anthony W. & Moody Neville R. ), (John Wiley & Sons, Inc., 2013).10.1002/9781118803363 [Cross Ref]
  • Korzhavyi P. A. & Sandström R. Monovacancy in copper: Trapping efficiency for hydrogen and oxygen impurities. Computational Materials Science 84, 122–128 (2014).
  • Ganchenkova M. G., Yagodzinskyy Y. N., Borodin V. A. & Hänninen H. Effects of hydrogen and impurities on void nucleation in copper: simulation point of view. Philosophical Magazine 94, 3522–3548 (2014).
  • Nakahara S. & Okinaka Y. Defects Induced in Copper by Cathodic Charging of Hydrogen. Journal of The Electrochemical Society 136, 1892–1895 (1989).
  • Conant J. W., Edeskuty F. J., Huston J. E. & Thome F. V. The conversion of para to orthohydrogen in a gamma-ray and neutron radiation field. Cryogenics 15, 12–16 (1975).
  • Yucel S. Theory of ortho-para conversion in hydrogen adsorbed on metal and paramagnetic surfaces at low temperatures. Physical Review B 39, 3104–3115 (1989). [PubMed]
  • Karpukhin V. I., Krasikov Y. A., Nikolaenko V. A. & Shtrombakh Y. I. in Effects of Radiation on Materials: 19th International Symposium (ed Kumar A. S., Hamilton M. L., Rosinski S. T. & Grossbeck M. L. ) 525–534 (American Society for Testing and Materials, 2000).
  • Ossi P. In Radiation Effects in Solids Vol. 235 NATO Science Series (eds Sickafus KurtE, Kotomin EugeneA & Uberuaga BlasP ) Ch. 10, 259–319 (Springer, Netherlands, 2007).
  • Björkbacka Å., Hosseinpour S., Leygraf C. & Jonsson M. Radiation Induced Corrosion of Copper in Anoxic Aqueous Solution. Electrochemical and Solid-State Letters 15, C5–C7 (2012).
  • Björkbacka Å., Hosseinpour S., Johnson M., Leygraf C. & Jonsson M. Radiation induced corrosion of copper for spent nuclear fuel storage. Radiation Physics and Chemistry 92, 80–86 (2013).
  • Bjorkbacka A., Yang M., Gasparrini C., Leygraf C. & Jonsson M. Kinetics and mechanisms of reactions between H2O2 and copper and copper oxides. Dalton Transactions 44, 16045–16051 (2015). [PubMed]
  • Elliot A. J. Rate Constants and g-Values for the Simulation of the Radiolysis of Light Water over the Range 0–300 °C. Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs; AECL-11073,COG-94-167 (1994).
  • Andersson K. et al. Autocatalytic Water Dissociation on Cu(110) at Near Ambient Conditions. Journal of the American Chemical Society 130, 2793–2797 (2008). [PubMed]
  • Lousada C. M., Johansson A. J. & Korzhavyi P. A. Thermodynamics of H2O Splitting and H2 Formation at the Cu(110)–Water Interface. The Journal of Physical Chemistry C 119, 14102–14113 (2015).
  • Kasza R. V., Griffiths K., Shapter J. G., Norton P. R. & Harrington D. A. Interaction of water with stepped Ni(760): associative versus dissociative adsorption and autocatalytic decomposition. Surface Science 356, 195–208 (1996).
  • Michelsen H. A. & Auerbach D. J. A critical examination of data on the dissociative adsorption and associative desorption of hydrogen at copper surfaces. The Journal of Chemical Physics 94, 7502–7520 (1991).
  • Elliott A. J. et al. Absorption of hydrogen in copper. Journal of the Chemical Society, Faraday Transactions 91, 3659–3662 (1995).
  • Patnaik P. Handbook of Inorganic Chemicals. (McGraw-Hill Professional, 2002).
  • Nakahara S. & Okinaka Y. The hydrogen effect in copper. Materials Science and Engineering: A 101, 227–230 (1988).
  • McLellan R. B. Solid solutions of hydrogen in gold, silver and copper. Journal of Physics and Chemistry of Solids 34, 1137–1141 (1973).
  • Pan Y. & Byrne J. G. Thermal charging effects of Hydrogen in Copper and Cu-Al alloys. Materials Science and Engineering 74, 215–223 (1985).
  • DeWulf D. W. & Bard A. J. Electrochemical Determination of Hydrogen Transport Through Copper. Journal of The Electrochemical Society 132, 2965–2967 (1985).
  • Hagi H. Transactions of the Japan Institute of Metals 27, 233–240 (1986).
  • Neta P. Reactions of hydrogen atoms in aqueous solutions. Chemical Reviews 72, 533–543 (1972).
  • Cacciatore M. & Rutigliano M. The semiclassical and quantum-classical approaches to elementary surface processes: dissociative chemisorption and atom recombination on surfaces. Physica Scripta 78, 058115 (2008).
  • Truong T. N. & Truhlar D. G. Surface diffusion of hydrogen on copper: the effect of phonon-adsorbate coupling on the diffusion rate. The Journal of Physical Chemistry 91, 6229–6237 (1987).
  • Hosseinpour S., Göthelid M., Leygraf C. & Johnson C. M. Self-Assembled Monolayers as Inhibitors for the Atmospheric Corrosion of Copper Induced by Formic Acid: A Comparison between Hexanethiol and Hexaneselenol. Journal of The Electrochemical Society 161, C50–C56 (2014).
  • Choppin G. R., Liljenzin J.-O. & Rydberg J. A. N. in Radiochemistry and Nuclear Chemistry (Second Edition) (eds Choppinjan-Olov Liljenzin Gregory R. & Rydberg J. A. N. ) 166–191 (Butterworth-Heinemann, 1995).

Articles from Scientific Reports are provided here courtesy of Nature Publishing Group