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Acta Crystallogr Sect E Struct Rep Online. 2011 January 1; 67(Pt 1): m117–m118.
Published online 2010 December 24. doi:  10.1107/S1600536810052530
PMCID: PMC3050204

Dicarbonyl­chlorido(phen­oxy­thio­carbonyl-κ2 C,S)bis­(triphenyl­phosphane-κP)molybdenum(II)


In the title complex, [Mo(C7H5OS)Cl(C18H15P)2(CO)2], the geometry around the metal atom is a capped octa­hedron. The phen­oxy­thio­carbonyl ligand coordinates the MoII atom through the C and S atoms. A one-dimensional structure is formed by π–π inter­molecular inter­actions and a supra­molecular aggregation is determined by inter­molecular C—H(...)O, C—H(...)Cl, C—H(...)π(arene) hydrogen bonds and CO(...)π(arene) inter­actions [O(...)centroid distances = 3.485 (4) and 3.722 (3) Å].

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