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Acta Crystallogr Sect E Struct Rep Online. 2010 November 1; 66(Pt 11): m1350–m1351.
Published online 2010 October 2. doi:  10.1107/S1600536810038675
PMCID: PMC3009304
(Di-2-pyridyl­amine)­(methanol)sulfato­copper(II)
Paul DeBurgomastera and Jon Zubietaa*
aDepartment of Chemistry, Syracuse University, Syracuse, New York 13244, USA
Correspondence e-mail: jazubiet/at/syr.edu
Received September 20, 2010; Accepted September 27, 2010.
Abstract
The title complex, [Cu(SO4)(C10H9N3)(CH3OH)], is a mononuclear species with the CuII ion in a Jahn–Teller-distorted ‘4 + 1’ square-pyramidal geometry. The basal plane is defined by the pyridyl N-atom donors of the bipyridyl­amine (bpa) ligand and two O-atom donors of the sulfate ligand. The coordination geometry is completed by the axial coordination of a methanol O-atom donor. The axial bond length displays the usual elongation: Cu—O(axial) = 2.168 (2), Cu—O(basal) = 2.016 (2) (average) and Cu—N(basal) = 1.951 (3) Å (average). In the crystal structure, the complex mol­ecules are linked through N—H(...)O and O—H(...)O hydrogen bonds into chains along [100].
Articles from Acta Crystallographica Section E: Structure Reports Online are provided here courtesy of
International Union of Crystallography