PMCCPMCCPMCC

Search tips
Search criteria 

Advanced

 
Logo of actaeInternational Union of Crystallographysearchopen accessarticle submissionjournal home pagethis article
 
Acta Crystallogr Sect E Struct Rep Online. 2010 November 1; 66(Pt 11): m1423.
Published online 2010 October 20. doi:  10.1107/S1600536810040833
PMCID: PMC3009133

2-6,6′-Dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(II)neodymium(III)

Abstract

In the title complex, [CuNd(C20H22N2O4)(NO3)3], the CuII ion is coordinated in a distorted square-planar environment by two O atoms and two N atoms of a tetra­dentate Schiff base ligand. The NdIII ion is ten-coordinated by three bis-chelating nitrate groups and four O atoms of the Schiff base ligand. The atoms of one of the nitrato ligands are disordered over two sets of sites, with refined occupancies of 0.567 (13) and 0.433 (17).

Related literature

For the crystal structures of related copper–lanthanide complexes, see: Xing et al. (2008 [triangle], 2009 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-66-m1423-scheme1.jpg

Experimental

Crystal data

  • [CuNd(C20H22N2O4)(NO3)3]
  • M r = 748.21
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-66-m1423-efi1.jpg
  • a = 11.729 (2) Å
  • b = 14.850 (3) Å
  • c = 15.063 (3) Å
  • β = 100.85 (3)°
  • V = 2576.7 (9) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 2.89 mm−1
  • T = 295 K
  • 0.22 × 0.18 × 0.13 mm

Data collection

  • Rigaku R-AXIS RAPID diffractometer
  • Absorption correction: multi-scan (ABSCOR; Higashi, 1995 [triangle]) T min = 0.569, T max = 0.705
  • 24553 measured reflections
  • 5867 independent reflections
  • 4644 reflections with I > 2σ(I)
  • R int = 0.045

Refinement

  • R[F 2 > 2σ(F 2)] = 0.042
  • wR(F 2) = 0.118
  • S = 1.06
  • 5867 reflections
  • 376 parameters
  • H-atom parameters constrained
  • Δρmax = 1.32 e Å−3
  • Δρmin = −1.79 e Å−3

Data collection: RAPID-AUTO (Rigaku, 1998 [triangle]); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002 [triangle]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: DIAMOND (Brandenburg, 1999 [triangle]); software used to prepare material for publication: SHELXL97.

Supplementary Material

Crystal structure: contains datablocks I. DOI: 10.1107/S1600536810040833/lh5135sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810040833/lh5135Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (No. 30872450) and Heilongjiang Key Laboratory of Anesthesia and Critical Care Research.

supplementary crystallographic information

Comment

The molecular structure of the title complex is shown in Fig.1. The octodentate Schiff base ligand links the CuII and NdIII ions into a dinuclear complex through two phenolate O atoms, which is similar to the structures of copper-lanthanum complexes with similar ligands (Xing et al., 2008;2009). The NdIII ion is ten-coordinated by four oxygen atoms from the ligand and six oxygen atoms from three nitrate ions. The CuII ion is four-coordinated by two nitrogen atoms and two oxygen atoms from the ligand.

Experimental

The title complex was obtained by the treatment of copper(II) acetate monohydrate (0.0499 g, 0.25 mmol) with the Schiff base (0.1595 g, 0.25 mmol) in methanol/acetone (20 ml:5 ml) at room temperature. Then the mixture was refluxed for 3 h after the addition of neodymium (III) nitrate hexahydrate (0.1595 g, 0.25 mmol). The reaction mixture was cooled and filtered; diethyl ether was allowed to diffuse slowly into the solution of the filtrate. Single crystals were obtained after several days. Analysis calculated for C20H22CuN5O13Nd: C, 32.08; H, 2.94; Cu, 8.49; N, 9.36; Nd, 19.28; found: C, 32.10; H, 2.98; Cu, 8.52; N, 9.39; Nd, 19.31%.

Refinement

H atoms bound to C atoms were placed in calculated positions and treated as riding on their parent atoms, with C—H = 0.93 Å (aromatic), C—H = 0.97 Å (methylene), and with Uiso(H) = 1.2Ueq(C) or C—H = 0.96 Å (methyl) and with Uiso(H) = 1.5Ueq(C).

Figures

Fig. 1.
The molecular structure of the title complex, showing 40% probability displacement ellipsoids. All H atoms have been omitted for clarity. The disorder is not shown.

Crystal data

[CuNd(C20H22N2O4)(NO3)3]F(000) = 1480
Mr = 748.21Dx = 1.929 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 17594 reflections
a = 11.729 (2) Åθ = 3.1–27.4°
b = 14.850 (3) ŵ = 2.89 mm1
c = 15.063 (3) ÅT = 295 K
β = 100.85 (3)°Prism, brown
V = 2576.7 (9) Å30.22 × 0.18 × 0.13 mm
Z = 4

Data collection

Rigaku R-AXIS RAPID diffractometer5867 independent reflections
Radiation source: fine-focus sealed tube4644 reflections with I > 2σ(I)
graphiteRint = 0.045
Detector resolution: 10.000 pixels mm-1θmax = 27.4°, θmin = 3.1°
ω scansh = −13→15
Absorption correction: multi-scan (ABSCOR;Higashi, 1995)k = −19→19
Tmin = 0.569, Tmax = 0.705l = −19→19
24553 measured reflections

Refinement

Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.042Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.118H-atom parameters constrained
S = 1.06w = 1/[σ2(Fo2) + (0.0577P)2 + 4.6815P] where P = (Fo2 + 2Fc2)/3
5867 reflections(Δ/σ)max = 0.001
376 parametersΔρmax = 1.32 e Å3
0 restraintsΔρmin = −1.79 e Å3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/UeqOcc. (<1)
Nd10.25894 (2)0.250636 (15)0.565858 (17)0.03466 (10)
Cu10.55090 (5)0.26892 (4)0.53616 (4)0.04027 (16)
O10.2027 (3)0.1636 (2)0.4114 (2)0.0475 (8)
O20.4131 (3)0.1970 (2)0.4958 (2)0.0439 (8)
O30.4360 (3)0.3442 (2)0.5784 (2)0.0366 (7)
O40.2599 (3)0.4087 (2)0.6418 (2)0.0445 (8)
O50.0721 (3)0.3308 (2)0.5050 (3)0.0517 (9)
O60.2129 (3)0.3654 (3)0.4382 (3)0.0529 (9)
O70.0552 (5)0.4417 (4)0.4096 (4)0.105 (2)
O80.0829 (3)0.1495 (3)0.5693 (3)0.0550 (9)
O90.2512 (3)0.0858 (2)0.5984 (3)0.0564 (10)
O100.0964 (5)0.0073 (3)0.6032 (4)0.0943 (17)
N5'0.342 (3)0.2126 (16)0.761 (2)0.069 (6)0.433 (13)
O11'0.410 (2)0.2061 (16)0.7055 (19)0.069 (4)0.433 (13)
O12'0.2416 (15)0.240 (2)0.7292 (19)0.059 (3)0.433 (13)
O13'0.373 (2)0.1966 (15)0.8385 (13)0.121 (7)0.433 (13)
N50.304 (2)0.2457 (12)0.7648 (17)0.069 (6)0.567 (13)
O110.3847 (17)0.2374 (13)0.7216 (13)0.069 (4)0.567 (13)
O120.1995 (11)0.2380 (14)0.7202 (13)0.059 (3)0.567 (13)
O130.3259 (19)0.2521 (11)0.8489 (9)0.121 (7)0.567 (13)
N10.6498 (4)0.1632 (3)0.5145 (3)0.0495 (11)
N20.6655 (3)0.3664 (3)0.5549 (3)0.0366 (8)
N30.1118 (4)0.3809 (3)0.4494 (3)0.0547 (12)
N40.1408 (4)0.0791 (3)0.5906 (3)0.0542 (11)
C10.0887 (5)0.1565 (5)0.3578 (5)0.0682 (18)
H1A0.09070.17320.29660.102*
H1B0.03700.19600.38160.102*
H1C0.06170.09560.35930.102*
C20.2896 (4)0.1137 (3)0.3844 (3)0.0401 (10)
C30.2723 (5)0.0496 (4)0.3175 (4)0.0524 (13)
H3A0.19770.03800.28590.063*
C40.3658 (6)0.0023 (4)0.2970 (4)0.0598 (15)
H4A0.3536−0.04100.25160.072*
C50.4759 (5)0.0187 (4)0.3430 (4)0.0535 (14)
H5A0.5378−0.01480.33020.064*
C60.4959 (4)0.0866 (3)0.4103 (4)0.0443 (11)
C70.4019 (4)0.1341 (3)0.4317 (3)0.0384 (10)
C80.6123 (5)0.0994 (3)0.4591 (4)0.0516 (13)
H8A0.66660.05660.44950.062*
C90.7734 (5)0.1518 (4)0.5613 (5)0.0608 (16)
H9A0.78540.08990.58150.073*
H9B0.82380.16330.51840.073*
C100.8068 (5)0.2126 (5)0.6401 (4)0.0622 (16)
H10A0.86390.18240.68530.075*
H10B0.73900.22420.66660.075*
C110.8565 (5)0.3017 (4)0.6162 (4)0.0594 (15)
H11A0.86470.34150.66810.071*
H11B0.93320.29150.60300.071*
C120.7822 (4)0.3475 (4)0.5360 (4)0.0507 (13)
H12A0.81860.40340.52320.061*
H12B0.77550.30900.48330.061*
C130.6470 (4)0.4465 (3)0.5813 (3)0.0366 (10)
H13A0.70720.48750.58240.044*
C140.5442 (4)0.4804 (3)0.6095 (3)0.0316 (9)
C150.5476 (4)0.5709 (3)0.6402 (3)0.0418 (11)
H15A0.61310.60610.63960.050*
C160.4541 (4)0.6062 (3)0.6707 (4)0.0459 (12)
H16A0.45590.66570.69040.055*
C170.3572 (4)0.5538 (3)0.6725 (3)0.0440 (11)
H17A0.29460.57790.69420.053*
C180.3526 (4)0.4661 (3)0.6423 (3)0.0347 (9)
C190.4461 (4)0.4276 (3)0.6092 (3)0.0301 (9)
C200.1685 (5)0.4403 (4)0.6868 (5)0.0643 (17)
H20A0.19980.45080.74950.097*
H20B0.10840.39570.68150.097*
H20C0.13680.49540.65920.097*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Nd10.03264 (15)0.03176 (15)0.04069 (16)−0.00236 (9)0.00975 (11)0.00024 (9)
Cu10.0327 (3)0.0394 (3)0.0499 (4)−0.0008 (2)0.0108 (3)−0.0036 (3)
O10.0373 (18)0.051 (2)0.051 (2)−0.0014 (16)0.0001 (15)−0.0091 (17)
O20.0324 (16)0.0447 (18)0.056 (2)−0.0078 (14)0.0118 (15)−0.0193 (16)
O30.0317 (16)0.0320 (15)0.0488 (18)−0.0047 (13)0.0146 (14)−0.0081 (14)
O40.0328 (17)0.0444 (18)0.061 (2)−0.0023 (14)0.0216 (16)−0.0115 (16)
O50.0390 (19)0.055 (2)0.063 (2)0.0002 (16)0.0136 (17)0.0114 (18)
O60.047 (2)0.055 (2)0.061 (2)−0.0024 (17)0.0220 (18)0.0114 (18)
O70.082 (3)0.092 (4)0.142 (5)0.032 (3)0.023 (3)0.067 (4)
O80.0376 (19)0.052 (2)0.075 (3)−0.0042 (17)0.0098 (18)0.007 (2)
O90.054 (2)0.0395 (19)0.077 (3)0.0041 (17)0.015 (2)0.0063 (18)
O100.115 (4)0.054 (3)0.109 (4)−0.043 (3)0.009 (3)0.012 (3)
N5'0.086 (15)0.067 (12)0.049 (4)−0.047 (9)−0.003 (8)0.014 (9)
O11'0.059 (9)0.086 (12)0.058 (8)−0.019 (7)−0.001 (5)0.008 (7)
O12'0.048 (8)0.075 (3)0.058 (5)−0.044 (8)0.018 (8)−0.005 (3)
O13'0.171 (15)0.140 (13)0.043 (4)−0.087 (12)0.000 (6)0.006 (8)
N50.086 (15)0.067 (12)0.049 (4)−0.047 (9)−0.003 (8)0.014 (9)
O110.059 (9)0.086 (12)0.058 (8)−0.019 (7)−0.001 (5)0.008 (7)
O120.048 (8)0.075 (3)0.058 (5)−0.044 (8)0.018 (8)−0.005 (3)
O130.171 (15)0.140 (13)0.043 (4)−0.087 (12)0.000 (6)0.006 (8)
N10.035 (2)0.049 (2)0.067 (3)0.0028 (19)0.015 (2)−0.001 (2)
N20.0322 (19)0.038 (2)0.042 (2)−0.0054 (16)0.0115 (16)−0.0019 (16)
N30.051 (3)0.045 (2)0.066 (3)0.002 (2)0.006 (2)0.013 (2)
N40.067 (3)0.041 (2)0.054 (3)−0.019 (2)0.009 (2)0.000 (2)
C10.038 (3)0.086 (5)0.073 (4)0.000 (3)−0.007 (3)−0.017 (4)
C20.041 (3)0.042 (3)0.039 (2)−0.003 (2)0.010 (2)0.002 (2)
C30.063 (3)0.053 (3)0.040 (3)−0.010 (3)0.007 (2)−0.006 (2)
C40.080 (4)0.053 (3)0.049 (3)0.000 (3)0.020 (3)−0.016 (3)
C50.066 (4)0.047 (3)0.056 (3)0.004 (3)0.031 (3)−0.006 (2)
C60.046 (3)0.042 (3)0.050 (3)−0.004 (2)0.022 (2)−0.004 (2)
C70.042 (3)0.034 (2)0.041 (2)−0.0062 (19)0.012 (2)−0.0018 (19)
C80.048 (3)0.039 (3)0.075 (4)0.003 (2)0.031 (3)0.002 (3)
C90.034 (3)0.051 (3)0.095 (5)0.008 (2)0.008 (3)0.009 (3)
C100.047 (3)0.080 (4)0.059 (4)0.018 (3)0.009 (3)0.019 (3)
C110.037 (3)0.063 (4)0.080 (4)−0.004 (3)0.018 (3)−0.011 (3)
C120.043 (3)0.046 (3)0.070 (4)−0.008 (2)0.030 (3)−0.002 (3)
C130.034 (2)0.039 (2)0.037 (2)−0.0070 (19)0.0059 (19)0.0032 (19)
C140.030 (2)0.035 (2)0.030 (2)−0.0031 (17)0.0043 (17)−0.0025 (17)
C150.045 (3)0.036 (2)0.043 (3)−0.007 (2)0.003 (2)−0.006 (2)
C160.049 (3)0.036 (2)0.053 (3)−0.003 (2)0.010 (2)−0.013 (2)
C170.043 (3)0.042 (3)0.048 (3)0.006 (2)0.011 (2)−0.010 (2)
C180.033 (2)0.034 (2)0.038 (2)0.0009 (18)0.0086 (18)−0.0026 (18)
C190.033 (2)0.028 (2)0.029 (2)0.0001 (17)0.0047 (17)−0.0024 (16)
C200.044 (3)0.072 (4)0.087 (5)−0.003 (3)0.038 (3)−0.024 (3)

Geometric parameters (Å, °)

Nd1—O22.395 (3)C1—H1B0.9600
Nd1—O32.476 (3)C1—H1C0.9600
Nd1—O92.501 (4)C2—C31.373 (7)
Nd1—O52.510 (4)C2—C71.408 (7)
Nd1—O12'2.51 (3)C3—C41.386 (8)
Nd1—O112.53 (2)C3—H3A0.9300
Nd1—O62.550 (4)C4—C51.368 (8)
Nd1—O122.557 (19)C4—H4A0.9300
Nd1—O82.562 (4)C5—C61.418 (7)
Nd1—O11'2.57 (3)C5—H5A0.9300
Nd1—O42.609 (3)C6—C71.397 (7)
Nd1—O12.634 (3)C6—C81.436 (7)
Cu1—O21.938 (3)C8—H8A0.9300
Cu1—O31.949 (3)C9—C101.484 (9)
Cu1—N21.959 (4)C9—H9A0.9700
Cu1—N12.015 (4)C9—H9B0.9700
O1—C21.383 (6)C10—C111.517 (9)
O1—C11.431 (6)C10—H10A0.9700
O2—C71.332 (5)C10—H10B0.9700
O3—C191.319 (5)C11—C121.511 (8)
O4—C181.381 (5)C11—H11A0.9700
O4—C201.451 (6)C11—H11B0.9700
O5—N31.272 (6)C12—H12A0.9700
O6—N31.250 (6)C12—H12B0.9700
O7—N31.211 (6)C13—C141.442 (6)
O8—N41.256 (6)C13—H13A0.9300
O9—N41.283 (6)C14—C191.392 (6)
O10—N41.217 (6)C14—C151.418 (6)
N5'—O13'1.18 (4)C15—C161.371 (7)
N5'—O12'1.25 (4)C15—H15A0.9300
N5'—O11'1.26 (5)C16—C171.382 (7)
N5—O131.25 (3)C16—H16A0.9300
N5—O111.25 (3)C17—C181.376 (6)
N5—O121.29 (2)C17—H17A0.9300
N1—C81.284 (7)C18—C191.409 (6)
N1—C91.498 (6)C20—H20A0.9600
N2—C131.286 (6)C20—H20B0.9600
N2—C121.476 (6)C20—H20C0.9600
C1—H1A0.9600
O2—Nd1—O361.89 (10)O11—N5—O12117 (2)
O2—Nd1—O979.58 (13)O13—N5—Nd1174.0 (13)
O3—Nd1—O9126.52 (12)O11—N5—Nd158.8 (14)
O2—Nd1—O5132.55 (12)O12—N5—Nd160.0 (13)
O3—Nd1—O5115.05 (11)N5—O11—Nd196.2 (15)
O9—Nd1—O5118.32 (12)N5—O12—Nd194.1 (14)
O2—Nd1—O12'128.2 (6)C8—N1—C9113.9 (5)
O3—Nd1—O12'100.5 (4)C8—N1—Cu1122.9 (4)
O9—Nd1—O12'74.5 (7)C9—N1—Cu1123.2 (4)
O5—Nd1—O12'99.3 (6)C13—N2—C12116.9 (4)
O2—Nd1—O1191.5 (4)C13—N2—Cu1125.3 (3)
O3—Nd1—O1168.8 (5)C12—N2—Cu1117.9 (3)
O9—Nd1—O1177.2 (5)O7—N3—O6121.1 (5)
O5—Nd1—O11133.7 (4)O7—N3—O5121.8 (5)
O12'—Nd1—O1139.5 (6)O6—N3—O5117.1 (4)
O2—Nd1—O687.72 (12)O7—N3—Nd1172.4 (5)
O3—Nd1—O674.83 (12)O6—N3—Nd159.6 (2)
O9—Nd1—O6142.32 (14)O5—N3—Nd157.9 (2)
O5—Nd1—O650.31 (12)O10—N4—O8122.9 (5)
O12'—Nd1—O6137.4 (7)O10—N4—O9120.6 (5)
O11—Nd1—O6138.9 (5)O8—N4—O9116.5 (4)
O2—Nd1—O12137.2 (4)O10—N4—Nd1177.3 (4)
O3—Nd1—O12109.9 (3)O8—N4—Nd159.6 (2)
O9—Nd1—O1274.0 (5)O9—N4—Nd157.0 (2)
O5—Nd1—O1289.9 (4)O1—C1—H1A109.5
O12'—Nd1—O1211.0 (5)O1—C1—H1B109.5
O11—Nd1—O1250.4 (5)H1A—C1—H1B109.5
O6—Nd1—O12132.8 (5)O1—C1—H1C109.5
O2—Nd1—O8119.49 (12)H1A—C1—H1C109.5
O3—Nd1—O8174.30 (12)H1B—C1—H1C109.5
O9—Nd1—O850.46 (12)C3—C2—O1124.9 (5)
O5—Nd1—O868.53 (12)C3—C2—C7121.1 (5)
O12'—Nd1—O874.3 (4)O1—C2—C7114.0 (4)
O11—Nd1—O8105.5 (5)C2—C3—C4120.1 (5)
O6—Nd1—O8110.47 (12)C2—C3—H3A120.0
O12—Nd1—O865.2 (3)C4—C3—H3A120.0
O2—Nd1—O11'79.3 (5)C5—C4—C3120.5 (5)
O3—Nd1—O11'69.1 (7)C5—C4—H4A119.7
O9—Nd1—O11'68.4 (6)C3—C4—H4A119.7
O5—Nd1—O11'147.2 (5)C4—C5—C6120.2 (5)
O12'—Nd1—O11'49.6 (7)C4—C5—H5A119.9
O11—Nd1—O11'14.0 (5)C6—C5—H5A119.9
O6—Nd1—O11'143.7 (7)C7—C6—C5119.5 (5)
O12—Nd1—O11'60.0 (6)C7—C6—C8122.1 (5)
O8—Nd1—O11'105.5 (7)C5—C6—C8118.3 (5)
O2—Nd1—O4123.43 (10)O2—C7—C6123.2 (4)
O3—Nd1—O461.78 (10)O2—C7—C2118.2 (4)
O9—Nd1—O4142.31 (13)C6—C7—C2118.6 (4)
O5—Nd1—O470.42 (12)N1—C8—C6127.3 (5)
O12'—Nd1—O467.8 (7)N1—C8—H8A116.3
O11—Nd1—O473.1 (4)C6—C8—H8A116.3
O6—Nd1—O473.29 (12)C10—C9—N1113.2 (5)
O12—Nd1—O469.3 (5)C10—C9—H9A108.9
O8—Nd1—O4117.08 (11)N1—C9—H9A108.9
O11'—Nd1—O485.8 (5)C10—C9—H9B108.9
O2—Nd1—O162.08 (11)N1—C9—H9B108.9
O3—Nd1—O1114.20 (11)H9A—C9—H9B107.7
O9—Nd1—O171.39 (13)C9—C10—C11113.3 (5)
O5—Nd1—O181.61 (12)C9—C10—H10A108.9
O12'—Nd1—O1141.4 (6)C11—C10—H10A108.9
O11—Nd1—O1141.7 (4)C9—C10—H10B108.9
O6—Nd1—O171.31 (12)C11—C10—H10B108.9
O12—Nd1—O1134.5 (4)H10A—C10—H10B107.7
O8—Nd1—O170.22 (13)C12—C11—C10113.1 (5)
O11'—Nd1—O1128.0 (4)C12—C11—H11A109.0
O4—Nd1—O1143.89 (12)C10—C11—H11A109.0
O2—Cu1—O380.28 (13)C12—C11—H11B109.0
O2—Cu1—N2164.12 (16)C10—C11—H11B109.0
O3—Cu1—N291.55 (14)H11A—C11—H11B107.8
O2—Cu1—N189.51 (16)N2—C12—C11110.3 (4)
O3—Cu1—N1162.74 (16)N2—C12—H12A109.6
N2—Cu1—N1101.46 (17)C11—C12—H12A109.6
O2—Cu1—Nd139.55 (9)N2—C12—H12B109.6
O3—Cu1—Nd142.17 (9)C11—C12—H12B109.6
N2—Cu1—Nd1133.71 (11)H12A—C12—H12B108.1
N1—Cu1—Nd1124.04 (12)N2—C13—C14127.8 (4)
C2—O1—C1117.2 (4)N2—C13—H13A116.1
C2—O1—Nd1116.6 (3)C14—C13—H13A116.1
C1—O1—Nd1125.9 (3)C19—C14—C15120.5 (4)
C7—O2—Cu1125.2 (3)C19—C14—C13122.6 (4)
C7—O2—Nd1125.0 (3)C15—C14—C13116.9 (4)
Cu1—O2—Nd1109.44 (14)C16—C15—C14119.8 (4)
C19—O3—Cu1129.1 (3)C16—C15—H15A120.1
C19—O3—Nd1125.0 (3)C14—C15—H15A120.1
Cu1—O3—Nd1105.93 (12)C15—C16—C17120.2 (4)
C18—O4—C20116.6 (4)C15—C16—H16A119.9
C18—O4—Nd1119.8 (2)C17—C16—H16A119.9
C20—O4—Nd1123.6 (3)C18—C17—C16120.5 (5)
N3—O5—Nd196.6 (3)C18—C17—H17A119.7
N3—O6—Nd195.3 (3)C16—C17—H17A119.7
N4—O8—Nd195.4 (3)C17—C18—O4124.6 (4)
N4—O9—Nd197.6 (3)C17—C18—C19121.1 (4)
O13'—N5'—O12'123 (3)O4—C18—C19114.3 (4)
O13'—N5'—O11'121 (3)O3—C19—C14123.4 (4)
O12'—N5'—O11'116 (3)O3—C19—C18118.7 (4)
O13'—N5'—Nd1179 (3)C14—C19—C18117.9 (4)
O12'—N5'—Nd156.6 (18)O4—C20—H20A109.5
O11'—N5'—Nd159.2 (18)O4—C20—H20B109.5
N5'—O11'—Nd195.8 (19)H20A—C20—H20B109.5
N5'—O12'—Nd199 (2)O4—C20—H20C109.5
O13—N5—O11120 (2)H20A—C20—H20C109.5
O13—N5—O12122 (2)H20B—C20—H20C109.5
O3—Nd1—Cu1—O2−160.4 (2)O6—Nd1—N5'—O11'−97.7 (17)
O9—Nd1—Cu1—O249.8 (2)O12—Nd1—N5'—O11'176 (2)
O5—Nd1—Cu1—O2−100.2 (2)O8—Nd1—N5'—O11'131.7 (17)
O12'—Nd1—Cu1—O2127.1 (8)O4—Nd1—N5'—O11'−110.1 (17)
O11—Nd1—Cu1—O2123.2 (5)O1—Nd1—N5'—O11'74 (2)
O6—Nd1—Cu1—O2−92.6 (2)O13'—N5'—O11'—Nd1179 (2)
O12—Nd1—Cu1—O2127.0 (6)O12'—N5'—O11'—Nd1−3(3)
O8—Nd1—Cu1—O230.4 (2)O2—Nd1—O11'—N5'−168.7 (17)
O11'—Nd1—Cu1—O2110.6 (6)O3—Nd1—O11'—N5'127.5 (17)
O4—Nd1—Cu1—O2−165.54 (19)O9—Nd1—O11'—N5'−85.7 (17)
O1—Nd1—Cu1—O2−21.42 (19)O5—Nd1—O11'—N5'23 (2)
O2—Nd1—Cu1—O3160.4 (2)O12'—Nd1—O11'—N5'2.0 (15)
O9—Nd1—Cu1—O3−149.77 (18)O11—Nd1—O11'—N5'41 (4)
O5—Nd1—Cu1—O360.23 (19)O6—Nd1—O11'—N5'120.3 (18)
O12'—Nd1—Cu1—O3−72.5 (8)O12—Nd1—O11'—N5'−2.3 (16)
O11—Nd1—Cu1—O3−76.4 (4)O8—Nd1—O11'—N5'−50.8 (17)
O6—Nd1—Cu1—O367.80 (17)O4—Nd1—O11'—N5'66.2 (16)
O12—Nd1—Cu1—O3−72.6 (6)O1—Nd1—O11'—N5'−127.5 (14)
O8—Nd1—Cu1—O3−169.2 (2)O13'—N5'—O12'—Nd1−179 (2)
O11'—Nd1—Cu1—O3−89.0 (6)O11'—N5'—O12'—Nd13(3)
O4—Nd1—Cu1—O3−5.14 (17)O2—Nd1—O12'—N5'10 (2)
O1—Nd1—Cu1—O3138.99 (17)O3—Nd1—O12'—N5'−52.7 (18)
O2—Nd1—Cu1—N2158.8 (2)O9—Nd1—O12'—N5'72.5 (17)
O3—Nd1—Cu1—N2−1.6 (2)O5—Nd1—O12'—N5'−170.5 (17)
O9—Nd1—Cu1—N2−151.41 (19)O11—Nd1—O12'—N5'−16.0 (14)
O5—Nd1—Cu1—N258.6 (2)O6—Nd1—O12'—N5'−131.6 (16)
O12'—Nd1—Cu1—N2−74.1 (8)O12—Nd1—O12'—N5'158 (7)
O11—Nd1—Cu1—N2−78.0 (5)O8—Nd1—O12'—N5'125.1 (18)
O6—Nd1—Cu1—N266.16 (19)O11'—Nd1—O12'—N5'−2.0 (16)
O12—Nd1—Cu1—N2−74.2 (6)O4—Nd1—O12'—N5'−106.2 (17)
O8—Nd1—Cu1—N2−170.9 (2)O1—Nd1—O12'—N5'101.3 (16)
O11'—Nd1—Cu1—N2−90.6 (6)O2—Nd1—N5—O1115.0 (14)
O4—Nd1—Cu1—N2−6.77 (18)O3—Nd1—N5—O11−41.8 (13)
O1—Nd1—Cu1—N2137.35 (18)O9—Nd1—N5—O1186.7 (12)
O2—Nd1—Cu1—N1−33.5 (2)O5—Nd1—N5—O11−157.5 (12)
O3—Nd1—Cu1—N1166.1 (2)O12'—Nd1—N5—O11164 (3)
O9—Nd1—Cu1—N116.4 (2)O6—Nd1—N5—O11−104.4 (12)
O5—Nd1—Cu1—N1−133.6 (2)O12—Nd1—N5—O11166 (2)
O12'—Nd1—Cu1—N193.6 (8)O8—Nd1—N5—O11136.7 (13)
O11—Nd1—Cu1—N189.8 (5)O11'—Nd1—N5—O1116.1 (19)
O6—Nd1—Cu1—N1−126.06 (19)O4—Nd1—N5—O11−102.1 (14)
O12—Nd1—Cu1—N193.6 (6)O1—Nd1—N5—O1193.0 (17)
O8—Nd1—Cu1—N1−3.1 (2)O2—Nd1—N5—O12−150.9 (13)
O11'—Nd1—Cu1—N177.2 (6)O3—Nd1—N5—O12152.4 (13)
O4—Nd1—Cu1—N1161.00 (18)O9—Nd1—N5—O12−79.1 (13)
O1—Nd1—Cu1—N1−54.87 (19)O5—Nd1—N5—O1236.7 (14)
O2—Nd1—O1—C216.3 (3)O12'—Nd1—N5—O12−2(4)
O3—Nd1—O1—C251.0 (3)O11—Nd1—N5—O12−166 (2)
O9—Nd1—O1—C2−71.5 (3)O6—Nd1—N5—O1289.8 (14)
O5—Nd1—O1—C2164.7 (3)O8—Nd1—N5—O12−29.1 (13)
O12'—Nd1—O1—C2−100.9 (10)O11'—Nd1—N5—O12−149.7 (18)
O11—Nd1—O1—C2−35.0 (9)O4—Nd1—N5—O1292.1 (14)
O6—Nd1—O1—C2113.9 (3)O1—Nd1—N5—O12−72.8 (16)
O12—Nd1—O1—C2−113.8 (7)O13—N5—O11—Nd1−173.1 (14)
O8—Nd1—O1—C2−125.2 (3)O12—N5—O11—Nd114 (2)
O11'—Nd1—O1—C2−30.7 (9)O2—Nd1—O11—N5−166.6 (12)
O4—Nd1—O1—C2125.7 (3)O3—Nd1—O11—N5134.5 (13)
O2—Nd1—O1—C1−170.0 (5)O9—Nd1—O11—N5−87.6 (13)
O3—Nd1—O1—C1−135.4 (4)O5—Nd1—O11—N529.5 (16)
O9—Nd1—O1—C1102.1 (5)O12'—Nd1—O11—N5−6.5 (14)
O5—Nd1—O1—C1−21.6 (5)O6—Nd1—O11—N5105.2 (14)
O12'—Nd1—O1—C172.8 (10)O12—Nd1—O11—N5−8.0 (12)
O11—Nd1—O1—C1138.6 (9)O8—Nd1—O11—N5−45.3 (13)
O6—Nd1—O1—C1−72.5 (5)O11'—Nd1—O11—N5−137 (6)
O12—Nd1—O1—C159.9 (8)O4—Nd1—O11—N568.8 (12)
O8—Nd1—O1—C148.5 (4)O1—Nd1—O11—N5−122.9 (10)
O11'—Nd1—O1—C1143.0 (9)O13—N5—O12—Nd1173.4 (14)
O4—Nd1—O1—C1−60.7 (5)O11—N5—O12—Nd1−14 (2)
O3—Cu1—O2—C7160.0 (4)O2—Nd1—O12—N540.2 (16)
N2—Cu1—O2—C7100.1 (6)O3—Nd1—O12—N5−29.4 (14)
N1—Cu1—O2—C7−34.0 (4)O9—Nd1—O12—N594.2 (13)
Nd1—Cu1—O2—C7173.2 (5)O5—Nd1—O12—N5−146.2 (13)
O3—Cu1—O2—Nd1−13.20 (15)O12'—Nd1—O12—N53(5)
N2—Cu1—O2—Nd1−73.1 (6)O11—Nd1—O12—N57.7 (11)
N1—Cu1—O2—Nd1152.82 (19)O6—Nd1—O12—N5−116.9 (12)
O3—Nd1—O2—C7−161.7 (4)O8—Nd1—O12—N5147.6 (15)
O9—Nd1—O2—C756.7 (4)O11'—Nd1—O12—N520.3 (12)
O5—Nd1—O2—C7−62.4 (4)O4—Nd1—O12—N5−77.1 (13)
O12'—Nd1—O2—C7117.4 (8)O1—Nd1—O12—N5135.8 (11)
O11—Nd1—O2—C7133.4 (6)O2—Cu1—N1—C823.6 (4)
O6—Nd1—O2—C7−87.7 (4)O3—Cu1—N1—C877.0 (8)
O12—Nd1—O2—C7108.9 (6)N2—Cu1—N1—C8−144.8 (4)
O8—Nd1—O2—C724.7 (4)Nd1—Cu1—N1—C844.1 (5)
O11'—Nd1—O2—C7126.5 (7)O2—Cu1—N1—C9−156.4 (4)
O4—Nd1—O2—C7−155.9 (3)O3—Cu1—N1—C9−103.1 (6)
O1—Nd1—O2—C7−17.7 (3)N2—Cu1—N1—C935.1 (5)
O3—Nd1—O2—Cu111.59 (13)Nd1—Cu1—N1—C9−135.9 (4)
O9—Nd1—O2—Cu1−130.06 (19)O2—Cu1—N2—C1355.3 (8)
O5—Nd1—O2—Cu1110.87 (18)O3—Cu1—N2—C13−3.3 (4)
O12'—Nd1—O2—Cu1−69.3 (7)N1—Cu1—N2—C13−171.8 (4)
O11—Nd1—O2—Cu1−53.3 (5)Nd1—Cu1—N2—C13−2.2 (5)
O6—Nd1—O2—Cu185.59 (17)O2—Cu1—N2—C12−123.6 (6)
O12—Nd1—O2—Cu1−77.8 (6)O3—Cu1—N2—C12177.8 (4)
O8—Nd1—O2—Cu1−162.10 (15)N1—Cu1—N2—C129.2 (4)
O11'—Nd1—O2—Cu1−60.3 (6)Nd1—Cu1—N2—C12178.9 (3)
O4—Nd1—O2—Cu117.4 (2)Nd1—O6—N3—O7171.1 (6)
O1—Nd1—O2—Cu1155.6 (2)Nd1—O6—N3—O5−8.2 (5)
O2—Cu1—O3—C19−168.3 (4)Nd1—O5—N3—O7−171.0 (6)
N2—Cu1—O3—C19−2.0 (4)Nd1—O5—N3—O68.3 (5)
N1—Cu1—O3—C19137.2 (5)O2—Nd1—N3—O6−20.8 (3)
Nd1—Cu1—O3—C19179.2 (4)O3—Nd1—N3—O640.4 (3)
O2—Cu1—O3—Nd112.51 (14)O9—Nd1—N3—O6−118.0 (3)
N2—Cu1—O3—Nd1178.82 (15)O5—Nd1—N3—O6−171.4 (5)
N1—Cu1—O3—Nd1−42.0 (6)O12'—Nd1—N3—O6144.5 (6)
O2—Nd1—O3—C19169.5 (4)O11—Nd1—N3—O6100.8 (8)
O9—Nd1—O3—C19−141.1 (3)O12—Nd1—N3—O6153.4 (5)
O5—Nd1—O3—C1942.9 (4)O8—Nd1—N3—O6−143.0 (3)
O12'—Nd1—O3—C19−62.7 (8)O11'—Nd1—N3—O688.5 (14)
O11—Nd1—O3—C19−86.7 (5)O4—Nd1—N3—O697.9 (3)
O6—Nd1—O3—C1973.9 (3)O1—Nd1—N3—O6−73.6 (3)
O12—Nd1—O3—C19−56.7 (6)O2—Nd1—N3—O5150.6 (3)
O11'—Nd1—O3—C19−101.7 (6)O3—Nd1—N3—O5−148.1 (3)
O4—Nd1—O3—C19−5.0 (3)O9—Nd1—N3—O553.4 (4)
O1—Nd1—O3—C19134.8 (3)O12'—Nd1—N3—O5−44.1 (6)
O2—Nd1—O3—Cu1−11.30 (13)O11—Nd1—N3—O5−87.7 (8)
O9—Nd1—O3—Cu138.1 (2)O6—Nd1—N3—O5171.4 (5)
O5—Nd1—O3—Cu1−137.93 (14)O12—Nd1—N3—O5−35.2 (5)
O12'—Nd1—O3—Cu1116.6 (7)O8—Nd1—N3—O528.4 (3)
O11—Nd1—O3—Cu192.5 (4)O11'—Nd1—N3—O5−100.0 (14)
O6—Nd1—O3—Cu1−106.93 (16)O4—Nd1—N3—O5−90.7 (3)
O12—Nd1—O3—Cu1122.5 (5)O1—Nd1—N3—O597.9 (3)
O11'—Nd1—O3—Cu177.5 (5)Nd1—O8—N4—O10178.7 (5)
O4—Nd1—O3—Cu1174.18 (19)Nd1—O8—N4—O9−1.7 (5)
O1—Nd1—O3—Cu1−46.00 (18)Nd1—O9—N4—O10−178.6 (5)
O2—Nd1—O4—C180.3 (4)Nd1—O9—N4—O81.8 (5)
O3—Nd1—O4—C186.1 (3)O2—Nd1—N4—O8−142.4 (3)
O9—Nd1—O4—C18120.3 (3)O3—Nd1—N4—O8169.7 (3)
O5—Nd1—O4—C18−128.4 (3)O9—Nd1—N4—O8−178.2 (5)
O12'—Nd1—O4—C18122.3 (6)O5—Nd1—N4—O8−8.0 (3)
O11—Nd1—O4—C1880.7 (6)O12'—Nd1—N4—O890.7 (7)
O6—Nd1—O4—C18−75.3 (3)O11—Nd1—N4—O8125.9 (5)
O12—Nd1—O4—C18134.0 (5)O6—Nd1—N4—O8−46.8 (4)
O8—Nd1—O4—C18179.8 (3)O12—Nd1—N4—O880.4 (5)
O11'—Nd1—O4—C1874.6 (7)O11'—Nd1—N4—O8139.1 (6)
O1—Nd1—O4—C18−87.0 (4)O4—Nd1—N4—O858.0 (4)
O2—Nd1—O4—C20−178.0 (4)O1—Nd1—N4—O8−87.8 (3)
O3—Nd1—O4—C20−172.2 (5)O2—Nd1—N4—O935.8 (3)
O9—Nd1—O4—C20−58.0 (5)O3—Nd1—N4—O9−12.1 (5)
O5—Nd1—O4—C2053.3 (4)O5—Nd1—N4—O9170.1 (3)
O12'—Nd1—O4—C20−56.0 (6)O12'—Nd1—N4—O9−91.2 (7)
O11—Nd1—O4—C20−97.6 (6)O11—Nd1—N4—O9−56.0 (5)
O6—Nd1—O4—C20106.4 (4)O6—Nd1—N4—O9131.4 (3)
O12—Nd1—O4—C20−44.3 (5)O12—Nd1—N4—O9−101.4 (5)
O8—Nd1—O4—C201.5 (5)O8—Nd1—N4—O9178.2 (5)
O11'—Nd1—O4—C20−103.7 (8)O11'—Nd1—N4—O9−42.7 (6)
O1—Nd1—O4—C2094.7 (4)O4—Nd1—N4—O9−123.8 (3)
O2—Nd1—O5—N3−38.4 (4)O1—Nd1—N4—O990.4 (3)
O3—Nd1—O5—N335.5 (3)C1—O1—C2—C3−8.7 (7)
O9—Nd1—O5—N3−140.8 (3)Nd1—O1—C2—C3165.5 (4)
O12'—Nd1—O5—N3141.8 (6)C1—O1—C2—C7170.9 (5)
O11—Nd1—O5—N3119.5 (7)Nd1—O1—C2—C7−14.9 (5)
O6—Nd1—O5—N3−4.7 (3)O1—C2—C3—C4−178.8 (5)
O12—Nd1—O5—N3147.5 (5)C7—C2—C3—C41.6 (8)
O8—Nd1—O5—N3−149.3 (3)C2—C3—C4—C50.0 (9)
O11'—Nd1—O5—N3125.4 (12)C3—C4—C5—C6−2.1 (9)
O4—Nd1—O5—N379.5 (3)C4—C5—C6—C72.5 (8)
O1—Nd1—O5—N3−77.3 (3)C4—C5—C6—C8177.9 (5)
O2—Nd1—O6—N3160.6 (3)Cu1—O2—C7—C626.4 (6)
O3—Nd1—O6—N3−137.9 (3)Nd1—O2—C7—C6−161.4 (4)
O9—Nd1—O6—N391.0 (4)Cu1—O2—C7—C2−154.7 (3)
O5—Nd1—O6—N34.8 (3)Nd1—O2—C7—C217.5 (6)
O12'—Nd1—O6—N3−48.9 (7)C5—C6—C7—O2178.0 (5)
O11—Nd1—O6—N3−109.7 (6)C8—C6—C7—O22.8 (8)
O12—Nd1—O6—N3−34.7 (5)C5—C6—C7—C2−0.9 (7)
O8—Nd1—O6—N339.9 (3)C8—C6—C7—C2−176.1 (5)
O11'—Nd1—O6—N3−131.0 (8)C3—C2—C7—O2179.9 (5)
O4—Nd1—O6—N3−73.4 (3)O1—C2—C7—O20.3 (6)
O1—Nd1—O6—N399.4 (3)C3—C2—C7—C6−1.2 (7)
O2—Nd1—O8—N443.6 (3)O1—C2—C7—C6179.2 (4)
O9—Nd1—O8—N41.0 (3)C9—N1—C8—C6174.1 (5)
O5—Nd1—O8—N4171.4 (3)Cu1—N1—C8—C6−5.9 (8)
O12'—Nd1—O8—N4−81.7 (8)C7—C6—C8—N1−13.3 (9)
O11—Nd1—O8—N4−57.2 (5)C5—C6—C8—N1171.4 (5)
O6—Nd1—O8—N4142.9 (3)C8—N1—C9—C10−166.0 (5)
O12—Nd1—O8—N4−88.3 (6)Cu1—N1—C9—C1014.1 (7)
O11'—Nd1—O8—N4−42.7 (5)N1—C9—C10—C11−91.0 (6)
O4—Nd1—O8—N4−135.9 (3)C9—C10—C11—C1249.6 (7)
O1—Nd1—O8—N482.8 (3)C13—N2—C12—C1198.1 (5)
O2—Nd1—O9—N4−144.2 (3)Cu1—N2—C12—C11−82.9 (5)
O3—Nd1—O9—N4172.9 (3)C10—C11—C12—N260.2 (6)
O5—Nd1—O9—N4−11.2 (4)C12—N2—C13—C14−175.7 (4)
O12'—Nd1—O9—N481.2 (5)Cu1—N2—C13—C145.4 (7)
O11—Nd1—O9—N4121.8 (5)N2—C13—C14—C19−1.6 (7)
O6—Nd1—O9—N4−71.9 (4)N2—C13—C14—C15176.8 (5)
O12—Nd1—O9—N469.8 (4)C19—C14—C15—C160.7 (7)
O8—Nd1—O9—N4−1.0 (3)C13—C14—C15—C16−177.8 (4)
O11'—Nd1—O9—N4133.3 (7)C14—C15—C16—C170.6 (8)
O4—Nd1—O9—N483.1 (4)C15—C16—C17—C18−1.0 (8)
O1—Nd1—O9—N4−80.3 (3)C16—C17—C18—O4179.8 (5)
O2—Nd1—N5'—O12'−172.2 (17)C16—C17—C18—C190.1 (8)
O3—Nd1—N5'—O12'128.3 (18)C20—O4—C18—C17−8.2 (7)
O9—Nd1—N5'—O12'−99.4 (18)Nd1—O4—C18—C17173.4 (4)
O5—Nd1—N5'—O12'11 (2)C20—O4—C18—C19171.5 (5)
O11—Nd1—N5'—O12'143 (3)Nd1—O4—C18—C19−6.9 (5)
O6—Nd1—N5'—O12'79 (2)Cu1—O3—C19—C145.6 (6)
O12—Nd1—N5'—O12'−7(2)Nd1—O3—C19—C14−175.3 (3)
O8—Nd1—N5'—O12'−52.0 (18)Cu1—O3—C19—C18−175.4 (3)
O11'—Nd1—N5'—O12'176 (3)Nd1—O3—C19—C183.6 (5)
O4—Nd1—N5'—O12'66.2 (17)C15—C14—C19—O3177.4 (4)
O1—Nd1—N5'—O12'−109.3 (18)C13—C14—C19—O3−4.2 (7)
O2—Nd1—N5'—O11'11.5 (18)C15—C14—C19—C18−1.5 (6)
O3—Nd1—N5'—O11'−48.0 (17)C13—C14—C19—C18176.9 (4)
O9—Nd1—N5'—O11'84.3 (16)C17—C18—C19—O3−177.9 (4)
O5—Nd1—N5'—O11'−165.1 (15)O4—C18—C19—O32.4 (6)
O12'—Nd1—N5'—O11'−176 (3)C17—C18—C19—C141.2 (7)
O11—Nd1—N5'—O11'−33 (2)O4—C18—C19—C14−178.5 (4)

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LH5135).

References

  • Brandenburg, K. (1999). DIAMOND Crystal Impact GbR, Bonn, Germany.
  • Higashi, T. (1995). ABSCOR Rigaku Corporation, Tokyo, Japan.
  • Rigaku (1998). RAPID-AUTO Rigaku Corporation, Tokyo, Japan.
  • Rigaku/MSC (2002). CrystalStructure Rigaku/MSC Inc., The Woodlands, Texas, USA.
  • Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [PubMed]
  • Xing, J.-C., Wang, J.-H., Yan, P.-F. & Li, G.-M. (2008). Acta Cryst. E64, m1206. [PMC free article] [PubMed]
  • Xing, J.-C., Xu, Y.-M., Cui, X.-G. & Li, W.-Z. (2009). Acta Cryst. E65, m443. [PMC free article] [PubMed]

Articles from Acta Crystallographica Section E: Structure Reports Online are provided here courtesy of International Union of Crystallography