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Acta Crystallogr Sect E Struct Rep Online. 2010 August 1; 66(Pt 8): m992.
Published online 2010 July 21. doi:  10.1107/S1600536810028084
PMCID: PMC3007579

Dichloridobis(1,3-phenyl­propane-1,3-dionato-κ2 O,O′)tin(IV) toluene hemisolvate

Abstract

The two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C15H11O2)2Cl2]·0.5C7H8, adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. The two planes are aligned at an angle of 59.6 (1)°. The Cl atoms occupy cis positions in the octa­hedral SnCl2O4 coordination environment. The solvent mol­ecule is disordered about a center of inversion.

Related literature

For the crystal structure of anhydrous dichloro­dibis(1,3-phenyl­propane-1,3-dionato)tin(IV), see: Searle et al. (1989 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-66-0m992-scheme1.jpg

Experimental

Crystal data

  • [Sn(C15H11O2)2Cl2]·0.5C7H8
  • M r = 682.13
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-66-0m992-efi1.jpg
  • a = 8.0024 (1) Å
  • b = 21.5554 (2) Å
  • c = 16.6838 (2) Å
  • β = 97.2740 (5)°
  • V = 2854.71 (6) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 1.12 mm−1
  • T = 100 K
  • 0.40 × 0.35 × 0.30 mm

Data collection

  • Bruker SMART APEX diffractometer
  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996 [triangle]) T min = 0.663, T max = 0.730
  • 23143 measured reflections
  • 6534 independent reflections
  • 6269 reflections with I > 2σ(I)
  • R int = 0.014

Refinement

  • R[F 2 > 2σ(F 2)] = 0.018
  • wR(F 2) = 0.049
  • S = 1.02
  • 6534 reflections
  • 386 parameters
  • 43 restraints
  • H-atom parameters constrained
  • Δρmax = 0.51 e Å−3
  • Δρmin = −0.48 e Å−3

Data collection: APEX2 (Bruker, 2009 [triangle]); cell refinement: SAINT (Bruker, 2009 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: X-SEED (Barbour, 2001 [triangle]); software used to prepare material for publication: publCIF (Westrip, 2010 [triangle]).

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536810028084/bt5299sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810028084/bt5299Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

We thank the University of Malaya (RG020/09AFR) for supporting this study.

supplementary crystallographic information

Comment

The toluene solvate (Scheme I) was obtained from the reaction of dibenzyltin dichloride and dibenzoylmethane in ethanol. Since no toluene was used in the synthesis, the toluene in the crystal structure would have resulted from the cleavage of the tin–carbonbenzyl bond by the dibenzoylmethane molecule, which in the deprotonated form chelates to tin (Fig. 1). The six-membered Sn–O–C–C–C–O chelate rings adopt an envelope-shaped conformation, with the tin atom lying off the least-squares plane defined by the carbon/oxygen atoms. Bond dimensions are similar to those reported for the anhydrous compound (Searle et al., 1989).

Experimental

Dibenzyltin dichloride (1 mmol) and dibenzoylmethane (1 mmol) were refluxed in ethanol for 1 h. The toluene solvate was obtained as crystals when the solvent was allowed to evaporate.

Refinement

The toluene molecule is disordered over a center-of-inversion. The aromatic ring was refined as a hexagon of 1.39 Å sides, and the Cmethyl–Cphenyl distance was refined with a distance restraint of 1.54±0.01 Å; the displacement parameters of the seven carbon atoms were restrained to be nearly isotropic.

Hydrogen atoms were placed in calculated positions (C–H 0.95–0.98 Å) and included in the refinement in the riding model approximation, with U(H) set to 1.2–1.5Ueq(C).

Figures

Fig. 1.
Anisotropic displacement ellipsoid plot (Barbour, 2001) of SnCl2(C15H11O2).0.5C7H8 at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.

Crystal data

[Sn(C15H11O2)2Cl2]·0.5C7H8F(000) = 1372
Mr = 682.13Dx = 1.587 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 9775 reflections
a = 8.0024 (1) Åθ = 2.6–28.3°
b = 21.5554 (2) ŵ = 1.12 mm1
c = 16.6838 (2) ÅT = 100 K
β = 97.2740 (5)°Block, colorless
V = 2854.71 (6) Å30.40 × 0.35 × 0.30 mm
Z = 4

Data collection

Bruker SMART APEX diffractometer6534 independent reflections
Radiation source: fine-focus sealed tube6269 reflections with I > 2σ(I)
graphiteRint = 0.014
ω scansθmax = 27.5°, θmin = 1.6°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)h = −10→10
Tmin = 0.663, Tmax = 0.730k = −28→27
23143 measured reflectionsl = −21→20

Refinement

Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.018Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.049H-atom parameters constrained
S = 1.02w = 1/[σ2(Fo2) + (0.0264P)2 + 1.8695P] where P = (Fo2 + 2Fc2)/3
6534 reflections(Δ/σ)max = 0.001
386 parametersΔρmax = 0.51 e Å3
43 restraintsΔρmin = −0.48 e Å3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/UeqOcc. (<1)
Sn10.423028 (11)0.234239 (4)0.547401 (5)0.01263 (4)
Cl10.20470 (4)0.170342 (15)0.48111 (2)0.01801 (7)
Cl20.23181 (4)0.308712 (15)0.58666 (2)0.01822 (7)
O10.62198 (12)0.28585 (4)0.60498 (6)0.01569 (18)
O20.43258 (12)0.18534 (4)0.65338 (6)0.01634 (19)
O30.59905 (12)0.17245 (4)0.51420 (6)0.01660 (19)
O40.45921 (13)0.28244 (4)0.44524 (6)0.01604 (19)
C10.74806 (17)0.35237 (6)0.70667 (8)0.0146 (2)
C20.87260 (18)0.37017 (7)0.65982 (9)0.0187 (3)
H20.88710.34760.61230.022*
C30.97545 (18)0.42080 (7)0.68234 (9)0.0219 (3)
H31.06150.43210.65080.026*
C40.95274 (18)0.45488 (7)0.75081 (9)0.0209 (3)
H41.02230.48980.76580.025*
C50.82797 (19)0.43778 (7)0.79729 (9)0.0199 (3)
H50.81140.46130.84380.024*
C60.72730 (18)0.38632 (6)0.77598 (8)0.0176 (3)
H60.64400.37420.80870.021*
C70.63927 (16)0.29790 (6)0.68135 (8)0.0142 (2)
C80.56859 (18)0.26349 (6)0.73948 (8)0.0160 (3)
H80.58580.27820.79360.019*
C90.47456 (16)0.20909 (6)0.72458 (8)0.0142 (2)
C100.41507 (17)0.17367 (6)0.79168 (8)0.0153 (2)
C110.42603 (19)0.19764 (7)0.87008 (9)0.0208 (3)
H110.48110.23610.88250.025*
C120.3567 (2)0.16530 (8)0.92983 (9)0.0257 (3)
H120.36180.18230.98260.031*
C130.2798 (2)0.10820 (8)0.91288 (10)0.0259 (3)
H130.23280.08620.95400.031*
C140.27184 (19)0.08334 (7)0.83542 (10)0.0230 (3)
H140.22130.04390.82390.028*
C150.33758 (18)0.11603 (6)0.77509 (9)0.0183 (3)
H150.33000.09920.72210.022*
C160.62450 (16)0.16168 (6)0.44027 (8)0.0146 (2)
C170.70704 (16)0.10122 (6)0.42799 (8)0.0153 (3)
C180.67625 (18)0.05155 (6)0.47798 (9)0.0182 (3)
H180.60840.05760.52010.022*
C190.74452 (19)−0.00663 (7)0.46630 (9)0.0225 (3)
H190.7217−0.04040.49980.027*
C200.84583 (19)−0.01515 (7)0.40570 (10)0.0243 (3)
H200.8925−0.05490.39780.029*
C210.87930 (19)0.03398 (7)0.35662 (10)0.0245 (3)
H210.95000.02800.31560.029*
C220.80949 (18)0.09223 (7)0.36718 (9)0.0202 (3)
H220.83160.12570.33310.024*
C230.57756 (17)0.20051 (6)0.37482 (8)0.0158 (3)
H230.59890.18650.32310.019*
C240.50103 (17)0.25886 (6)0.37916 (8)0.0140 (2)
C250.45972 (16)0.29810 (6)0.30672 (8)0.0145 (2)
C260.36654 (18)0.35218 (6)0.31416 (9)0.0187 (3)
H260.33620.36370.36530.022*
C270.31824 (19)0.38901 (7)0.24702 (9)0.0221 (3)
H270.25540.42580.25230.027*
C280.36168 (19)0.37208 (7)0.17210 (9)0.0222 (3)
H280.32640.39690.12600.027*
C290.45660 (19)0.31897 (7)0.16435 (9)0.0211 (3)
H290.48740.30780.11310.025*
C300.50646 (17)0.28211 (7)0.23134 (8)0.0171 (3)
H300.57230.24600.22600.020*
C310.3563 (8)0.4768 (3)0.4741 (4)0.0210 (10)0.50
C320.4464 (8)0.4664 (3)0.5497 (4)0.0265 (13)0.50
H320.40190.43980.58720.032*0.50
C330.6015 (8)0.4950 (3)0.5706 (4)0.0285 (14)0.50
H330.66310.48790.62230.034*0.50
C340.6666 (8)0.5339 (3)0.5158 (5)0.0315 (15)0.50
H340.77260.55350.53000.038*0.50
C350.5765 (9)0.5443 (4)0.4401 (5)0.0266 (12)0.50
H350.62100.57090.40270.032*0.50
C360.4214 (9)0.5158 (3)0.4193 (4)0.0260 (12)0.50
H360.35990.52290.36760.031*0.50
C370.1816 (4)0.44999 (16)0.4561 (2)0.0292 (7)0.50
H37A0.18310.40640.47300.044*0.50
H37B0.14410.45270.39800.044*0.50
H37C0.10410.47340.48570.044*0.50

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Sn10.01623 (5)0.01190 (5)0.00992 (5)0.00085 (3)0.00233 (3)−0.00018 (3)
Cl10.02183 (16)0.01610 (15)0.01564 (15)−0.00272 (11)0.00060 (12)−0.00137 (11)
Cl20.01985 (15)0.01574 (15)0.01997 (16)0.00295 (11)0.00608 (12)−0.00062 (12)
O10.0185 (5)0.0165 (5)0.0126 (4)−0.0016 (4)0.0038 (4)−0.0010 (4)
O20.0221 (5)0.0148 (4)0.0119 (4)−0.0004 (4)0.0012 (4)−0.0007 (3)
O30.0206 (5)0.0164 (5)0.0128 (4)0.0043 (4)0.0021 (4)−0.0008 (4)
O40.0231 (5)0.0134 (4)0.0122 (4)0.0012 (4)0.0048 (4)0.0003 (3)
C10.0153 (6)0.0138 (6)0.0143 (6)0.0014 (5)0.0007 (5)0.0015 (5)
C20.0188 (6)0.0195 (7)0.0181 (7)0.0000 (5)0.0040 (5)−0.0013 (5)
C30.0184 (7)0.0219 (7)0.0260 (8)−0.0028 (5)0.0060 (6)0.0015 (6)
C40.0186 (7)0.0165 (6)0.0264 (7)−0.0016 (5)−0.0020 (6)0.0007 (5)
C50.0249 (7)0.0169 (6)0.0174 (7)0.0007 (5)0.0005 (5)−0.0023 (5)
C60.0199 (6)0.0171 (6)0.0160 (6)0.0005 (5)0.0032 (5)0.0010 (5)
C70.0140 (6)0.0141 (6)0.0144 (6)0.0028 (5)0.0013 (5)−0.0007 (5)
C80.0183 (6)0.0169 (7)0.0126 (6)0.0000 (5)0.0015 (5)−0.0005 (5)
C90.0148 (6)0.0145 (6)0.0135 (6)0.0032 (5)0.0021 (5)0.0012 (5)
C100.0150 (6)0.0165 (6)0.0143 (6)0.0016 (5)0.0012 (5)0.0032 (5)
C110.0232 (7)0.0230 (7)0.0161 (7)−0.0050 (5)0.0017 (5)0.0014 (5)
C120.0297 (8)0.0335 (8)0.0140 (7)−0.0048 (6)0.0035 (6)0.0032 (6)
C130.0277 (8)0.0292 (8)0.0217 (7)−0.0021 (6)0.0071 (6)0.0106 (6)
C140.0239 (7)0.0186 (7)0.0271 (8)−0.0015 (5)0.0060 (6)0.0057 (6)
C150.0207 (7)0.0156 (6)0.0191 (7)0.0020 (5)0.0040 (5)0.0011 (5)
C160.0137 (6)0.0141 (6)0.0162 (6)−0.0021 (5)0.0027 (5)−0.0021 (5)
C170.0142 (6)0.0140 (6)0.0171 (6)0.0004 (5)−0.0008 (5)−0.0029 (5)
C180.0196 (6)0.0168 (6)0.0178 (7)0.0010 (5)0.0006 (5)−0.0017 (5)
C190.0254 (7)0.0153 (6)0.0254 (7)0.0014 (5)−0.0018 (6)−0.0002 (5)
C200.0206 (7)0.0178 (7)0.0330 (8)0.0049 (5)−0.0025 (6)−0.0080 (6)
C210.0189 (7)0.0249 (7)0.0304 (8)0.0029 (6)0.0063 (6)−0.0080 (6)
C220.0186 (7)0.0190 (7)0.0236 (7)−0.0003 (5)0.0049 (5)−0.0028 (5)
C230.0196 (6)0.0151 (6)0.0133 (6)−0.0001 (5)0.0048 (5)−0.0017 (5)
C240.0151 (6)0.0138 (6)0.0132 (6)−0.0026 (5)0.0025 (5)−0.0006 (5)
C250.0155 (6)0.0144 (6)0.0138 (6)−0.0032 (5)0.0023 (5)0.0002 (5)
C260.0218 (7)0.0178 (7)0.0168 (6)0.0003 (5)0.0036 (5)0.0009 (5)
C270.0229 (7)0.0185 (7)0.0245 (7)0.0020 (5)0.0015 (6)0.0044 (6)
C280.0217 (7)0.0248 (7)0.0188 (7)−0.0041 (6)−0.0023 (5)0.0081 (6)
C290.0231 (7)0.0268 (7)0.0134 (6)−0.0057 (6)0.0025 (5)0.0018 (5)
C300.0180 (6)0.0184 (6)0.0150 (6)−0.0029 (5)0.0029 (5)−0.0001 (5)
C310.023 (2)0.018 (2)0.024 (2)0.0032 (17)0.0075 (19)0.0015 (16)
C320.041 (3)0.017 (3)0.025 (2)0.006 (2)0.017 (2)0.0064 (19)
C330.034 (3)0.028 (3)0.021 (2)0.011 (2)−0.003 (2)−0.004 (2)
C340.030 (2)0.026 (3)0.042 (3)−0.0038 (19)0.016 (2)−0.010 (2)
C350.033 (2)0.017 (2)0.032 (3)−0.0018 (16)0.012 (2)0.0031 (19)
C360.034 (2)0.019 (2)0.028 (2)0.0038 (18)0.0139 (19)0.0056 (17)
C370.0278 (16)0.0270 (16)0.0324 (17)−0.0008 (12)0.0020 (13)−0.0004 (13)

Geometric parameters (Å, °)

Sn1—O42.0477 (9)C17—C181.3981 (19)
Sn1—O22.0515 (10)C18—C191.391 (2)
Sn1—O32.0646 (9)C18—H180.9500
Sn1—O12.0756 (10)C19—C201.386 (2)
Sn1—Cl22.3667 (3)C19—H190.9500
Sn1—Cl12.3840 (3)C20—C211.385 (2)
O1—C71.2904 (16)C20—H200.9500
O2—C91.2981 (16)C21—C221.395 (2)
O3—C161.2962 (16)C21—H210.9500
O4—C241.2957 (16)C22—H220.9500
C1—C61.3961 (19)C23—C241.4049 (18)
C1—C21.3959 (19)C23—H230.9500
C1—C71.4906 (18)C24—C251.4779 (18)
C2—C31.390 (2)C25—C261.3978 (19)
C2—H20.9500C25—C301.3997 (19)
C3—C41.389 (2)C26—C271.387 (2)
C3—H30.9500C26—H260.9500
C4—C51.389 (2)C27—C281.388 (2)
C4—H40.9500C27—H270.9500
C5—C61.390 (2)C28—C291.389 (2)
C5—H50.9500C28—H280.9500
C6—H60.9500C29—C301.388 (2)
C7—C81.3963 (19)C29—H290.9500
C8—C91.3984 (19)C30—H300.9500
C8—H80.9500C31—C321.3900
C9—C101.4826 (18)C31—C361.3900
C10—C111.399 (2)C31—C371.507 (6)
C10—C151.4005 (19)C32—C331.3900
C11—C121.388 (2)C32—H320.9500
C11—H110.9500C33—C341.3900
C12—C131.389 (2)C33—H330.9500
C12—H120.9500C34—C351.3900
C13—C141.393 (2)C34—H340.9500
C13—H130.9500C35—C361.3900
C14—C151.386 (2)C35—H350.9500
C14—H140.9500C36—H360.9500
C15—H150.9500C37—H37A0.9800
C16—C231.3893 (19)C37—H37B0.9800
C16—C171.4870 (18)C37—H37C0.9800
C17—C221.3962 (19)
O4—Sn1—O2169.82 (4)O3—C16—C23125.49 (12)
O4—Sn1—O386.03 (4)O3—C16—C17114.46 (12)
O2—Sn1—O387.00 (4)C23—C16—C17120.02 (12)
O4—Sn1—O186.12 (4)C22—C17—C18119.43 (13)
O2—Sn1—O186.20 (4)C22—C17—C16122.25 (12)
O3—Sn1—O187.74 (4)C18—C17—C16118.30 (12)
O4—Sn1—Cl292.91 (3)C19—C18—C17120.31 (13)
O2—Sn1—Cl293.72 (3)C19—C18—H18119.8
O3—Sn1—Cl2177.21 (3)C17—C18—H18119.8
O1—Sn1—Cl289.61 (3)C20—C19—C18119.86 (14)
O4—Sn1—Cl194.56 (3)C20—C19—H19120.1
O2—Sn1—Cl192.76 (3)C18—C19—H19120.1
O3—Sn1—Cl189.29 (3)C19—C20—C21120.31 (14)
O1—Sn1—Cl1176.90 (3)C19—C20—H20119.8
Cl2—Sn1—Cl193.366 (12)C21—C20—H20119.8
C7—O1—Sn1123.02 (8)C20—C21—C22120.20 (14)
C9—O2—Sn1124.27 (8)C20—C21—H21119.9
C16—O3—Sn1124.44 (8)C22—C21—H21119.9
C24—O4—Sn1126.03 (8)C17—C22—C21119.88 (14)
C6—C1—C2119.22 (13)C17—C22—H22120.1
C6—C1—C7121.41 (12)C21—C22—H22120.1
C2—C1—C7119.37 (12)C16—C23—C24125.10 (12)
C3—C2—C1120.31 (13)C16—C23—H23117.4
C3—C2—H2119.8C24—C23—H23117.4
C1—C2—H2119.8O4—C24—C23123.80 (12)
C4—C3—C2120.20 (13)O4—C24—C25114.60 (11)
C4—C3—H3119.9C23—C24—C25121.60 (12)
C2—C3—H3119.9C26—C25—C30119.42 (13)
C5—C4—C3119.78 (13)C26—C25—C24118.11 (12)
C5—C4—H4120.1C30—C25—C24122.44 (12)
C3—C4—H4120.1C27—C26—C25120.19 (13)
C4—C5—C6120.20 (13)C27—C26—H26119.9
C4—C5—H5119.9C25—C26—H26119.9
C6—C5—H5119.9C28—C27—C26120.04 (14)
C5—C6—C1120.27 (13)C28—C27—H27120.0
C5—C6—H6119.9C26—C27—H27120.0
C1—C6—H6119.9C27—C28—C29120.19 (13)
O1—C7—C8125.22 (12)C27—C28—H28119.9
O1—C7—C1115.09 (12)C29—C28—H28119.9
C8—C7—C1119.67 (12)C30—C29—C28120.11 (14)
C7—C8—C9125.32 (13)C30—C29—H29119.9
C7—C8—H8117.3C28—C29—H29119.9
C9—C8—H8117.3C29—C30—C25120.02 (13)
O2—C9—C8124.37 (12)C29—C30—H30120.0
O2—C9—C10114.66 (12)C25—C30—H30120.0
C8—C9—C10120.97 (12)C32—C31—C36120.0
C11—C10—C15119.09 (13)C32—C31—C37118.7 (3)
C11—C10—C9121.86 (12)C36—C31—C37121.1 (3)
C15—C10—C9118.96 (12)C33—C32—C31120.0
C12—C11—C10120.17 (14)C33—C32—H32120.0
C12—C11—H11119.9C31—C32—H32120.0
C10—C11—H11119.9C32—C33—C34120.0
C13—C12—C11120.38 (15)C32—C33—H33120.0
C13—C12—H12119.8C34—C33—H33120.0
C11—C12—H12119.8C35—C34—C33120.0
C12—C13—C14119.80 (14)C35—C34—H34120.0
C12—C13—H13120.1C33—C34—H34120.0
C14—C13—H13120.1C36—C35—C34120.0
C15—C14—C13120.07 (14)C36—C35—H35120.0
C15—C14—H14120.0C34—C35—H35120.0
C13—C14—H14120.0C35—C36—C31120.0
C14—C15—C10120.46 (14)C35—C36—H36120.0
C14—C15—H15119.8C31—C36—H36120.0
C10—C15—H15119.8
O4—Sn1—O1—C7153.37 (10)C11—C12—C13—C14−0.2 (2)
O2—Sn1—O1—C7−33.32 (10)C12—C13—C14—C15−1.2 (2)
O3—Sn1—O1—C7−120.46 (10)C13—C14—C15—C101.1 (2)
Cl2—Sn1—O1—C760.43 (10)C11—C10—C15—C140.3 (2)
O4—Sn1—O2—C974.0 (2)C9—C10—C15—C14−176.28 (13)
O3—Sn1—O2—C9120.85 (10)Sn1—O3—C16—C2319.78 (18)
O1—Sn1—O2—C932.92 (10)Sn1—O3—C16—C17−158.46 (9)
Cl2—Sn1—O2—C9−56.45 (10)O3—C16—C17—C22−150.91 (13)
Cl1—Sn1—O2—C9−150.00 (10)C23—C16—C17—C2230.7 (2)
O4—Sn1—O3—C16−29.25 (10)O3—C16—C17—C1830.91 (17)
O2—Sn1—O3—C16158.17 (11)C23—C16—C17—C18−147.44 (13)
O1—Sn1—O3—C16−115.51 (10)C22—C17—C18—C19−1.2 (2)
Cl1—Sn1—O3—C1665.37 (10)C16—C17—C18—C19177.04 (13)
O2—Sn1—O4—C2476.8 (2)C17—C18—C19—C201.1 (2)
O3—Sn1—O4—C2429.95 (11)C18—C19—C20—C21−0.1 (2)
O1—Sn1—O4—C24117.95 (11)C19—C20—C21—C22−0.8 (2)
Cl2—Sn1—O4—C24−152.63 (11)C18—C17—C22—C210.3 (2)
Cl1—Sn1—O4—C24−59.02 (11)C16—C17—C22—C21−177.86 (13)
C6—C1—C2—C30.5 (2)C20—C21—C22—C170.7 (2)
C7—C1—C2—C3−179.98 (13)O3—C16—C23—C242.7 (2)
C1—C2—C3—C4−1.3 (2)C17—C16—C23—C24−179.11 (13)
C2—C3—C4—C50.7 (2)Sn1—O4—C24—C23−20.39 (19)
C3—C4—C5—C60.7 (2)Sn1—O4—C24—C25158.82 (9)
C4—C5—C6—C1−1.6 (2)C16—C23—C24—O4−2.7 (2)
C2—C1—C6—C51.0 (2)C16—C23—C24—C25178.13 (12)
C7—C1—C6—C5−178.56 (13)O4—C24—C25—C26−6.43 (18)
Sn1—O1—C7—C822.71 (18)C23—C24—C25—C26172.79 (13)
Sn1—O1—C7—C1−158.92 (8)O4—C24—C25—C30175.33 (12)
C6—C1—C7—O1153.74 (12)C23—C24—C25—C30−5.4 (2)
C2—C1—C7—O1−25.77 (18)C30—C25—C26—C271.2 (2)
C6—C1—C7—C8−27.79 (19)C24—C25—C26—C27−177.09 (13)
C2—C1—C7—C8152.70 (13)C25—C26—C27—C280.3 (2)
O1—C7—C8—C93.1 (2)C26—C27—C28—C29−1.4 (2)
C1—C7—C8—C9−175.23 (13)C27—C28—C29—C300.9 (2)
Sn1—O2—C9—C8−21.43 (18)C28—C29—C30—C250.6 (2)
Sn1—O2—C9—C10158.76 (9)C26—C25—C30—C29−1.7 (2)
C7—C8—C9—O2−4.1 (2)C24—C25—C30—C29176.55 (13)
C7—C8—C9—C10175.70 (13)C36—C31—C32—C330.0
O2—C9—C10—C11−169.73 (13)C37—C31—C32—C33−174.4 (4)
C8—C9—C10—C1110.4 (2)C31—C32—C33—C340.0
O2—C9—C10—C156.79 (18)C32—C33—C34—C350.0
C8—C9—C10—C15−173.03 (13)C33—C34—C35—C360.0
C15—C10—C11—C12−1.8 (2)C34—C35—C36—C310.0
C9—C10—C11—C12174.76 (14)C32—C31—C36—C350.0
C10—C11—C12—C131.7 (2)C37—C31—C36—C35174.2 (4)

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BT5299).

References

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