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Acta Crystallogr Sect E Struct Rep Online. 2010 August 1; 66(Pt 8): m1040–m1041.
Published online 2010 July 31. doi:  10.1107/S1600536810029806
PMCID: PMC3007265

Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate

Abstract

In the title complex, [InCl2(C24H21N7)]Cl·C2H5OH·2H2O, the InIII ion is coordinated by four N atoms from the tris­(benz­imidazol-2-ylmeth­yl)amine (NTB) ligand and two Cl atoms in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H(...)O, O—H(...)O, O—H(...)Cl and weak C—H(...)Cl hydrogen bonds connect the cations, anions and solvent mol­ecules into a three-dimensional network. The ethanol solvent mol­ecule is disordered over two sites with refined occupancies of 0.54 (2) and 0.46 (2).

Related literature

For background information and the applications of indium complexes, see: Green et al. (2005 [triangle]); Krivokapic et al. (2001 [triangle]); Lu et al. (2005 [triangle]); Sun et al. (2009 [triangle]); Vagin et al. (2003 [triangle]). For the synthetic procedure, see: Hendriks et al. (1982 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-66-m1040-scheme1.jpg

Experimental

Crystal data

  • [InCl2(C24H21N7)]Cl·C2H6O·2H2O
  • M r = 710.75
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-66-m1040-efi1.jpg
  • a = 10.4152 (10) Å
  • b = 13.7394 (13) Å
  • c = 21.903 (2) Å
  • β = 103.75°
  • V = 3044.4 (5) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 1.08 mm−1
  • T = 298 K
  • 0.26 × 0.22 × 0.20 mm

Data collection

  • Bruker SMART CCD diffractometer
  • Absorption correction: multi-scan (SADABS; Sheldrick, 1997 [triangle]) T min = 0.846, T max = 0.900
  • 22634 measured reflections
  • 7526 independent reflections
  • 6941 reflections with I > 2σ(I)
  • R int = 0.033

Refinement

  • R[F 2 > 2σ(F 2)] = 0.038
  • wR(F 2) = 0.089
  • S = 1.15
  • 7526 reflections
  • 403 parameters
  • 6 restraints
  • H atoms treated by a mixture of independent and constrained refinement
  • Δρmax = 0.95 e Å−3
  • Δρmin = −0.55 e Å−3

Data collection: SMART (Bruker, 2007 [triangle]); cell refinement: SAINT-Plus (Bruker, 2007 [triangle]); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: PLATON (Spek, 2009 [triangle]); software used to prepare material for publication: SHELXTL (Sheldrick, 2008 [triangle]).

Table 1
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536810029806/lh5092sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810029806/lh5092Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The authors are grateful to the Science Technology Research Programme of the Education Office of Hubei Province (grant No. Q20092503) for financial support.

supplementary crystallographic information

Comment

Indium complexes are widely used as radiopharmaceuticals, photoelectronic materials and catalysts (Green et al., 2005; Lu et al., 2005; Sun et al., 2009). In the past few years, there has been considerable effort in designing Indium complexes because of their good optical properties applied in optical limiting materials (Vagin et al., 2003; Krivokapic et al., 2001). With this mind, the title compound, (I), was prepared and we report the crystal stucture herein.

In the molecular structure of (I), the InIII ion is coordinated by four N atoms from the NTB ligand and and two Cl atoms, forming a distorted octahedral coordination environmemt (Fig.1). Two benzimidazole(bzim)-N atoms (N2 and N6) occupy the axial positions, one bzim-N atom (N4), one amino N atom (N1) and two Cl atoms are located in the equatorial plane. In the crystal structure, intermolecular N—H···O, O—H···O, O—H···Cl and weak C—H···Cl hydrogen bonds form a three-dimensional network (Fig.2).

Experimental

The NTB ligand was prepared according to literature methods (Hendriks, et al., 1982). InCl3.4H2O (0.29 g,1 mmol) was added to a solution of NTB (0.41 g,1 mmol) in hot alcohol (50 ml) and refluxed for 1 h. The solution was filtered, then the filtrate was placed at room temperature and colorless single crystals suitable for an X-ray diffraction study were obtained by slow evaporation of the solvent for five days.

Refinement

The ethanol molecule is disordered with occupancies of 0.54 (2) and 0.46 (2) for the major and minor components, respectively. H atoms bonded to C atoms were placed in idealized positions [CH(methyl) = 0.96 Å, 0.97Å (methylene) and 0.93 Å (aromatic), with Uiso(H) = 1.5Ueq(methyl C) and 1.2Ueq(other C). N-bound hydrogen atoms were initially located from a difference Fourier map and then placed in ideal positions with N—H = 0.86Å and Uiso(H) = 1.2 Ueq(N). H atoms bonded to methanol O atoms were included with O-H = 0.82Å and Uiso(H) = 1.5Ueq(O). H atoms bonded to water O atoms were located from difference maps and refined with distance restraints of O-H = 0.82 (1) and H···H = 1.35 (2) Å and with Uiso(H) = 1.2Ueq(O).

Figures

Fig. 1.
The asymmetric unit of (I), with displacement ellipsoids drawn at the 50% probability level. The disorder is not shown. Hydrogen bonds are shown as dashed lines.
Fig. 2.
Part of the crystal structure of (I) showing hydrogen bonds as dashed lines.

Crystal data

[InCl2(C24H21N7)]Cl·C2H6O·2H2OF(000) = 1440
Mr = 710.75Dx = 1.551 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 5767 reflections
a = 10.4152 (10) Åθ = 2.4–28.3°
b = 13.7394 (13) ŵ = 1.08 mm1
c = 21.903 (2) ÅT = 298 K
β = 103.75°Block, colorless
V = 3044.4 (5) Å30.26 × 0.22 × 0.20 mm
Z = 4

Data collection

Bruker SMART CCD diffractometer7526 independent reflections
Radiation source: fine-focus sealed tube6941 reflections with I > 2σ(I)
graphiteRint = 0.033
[var phi] and ω scansθmax = 28.3°, θmin = 1.9°
Absorption correction: multi-scan (SADABS; Sheldrick, 1997)h = −13→13
Tmin = 0.846, Tmax = 0.900k = −13→18
22634 measured reflectionsl = −28→29

Refinement

Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.038Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.089H atoms treated by a mixture of independent and constrained refinement
S = 1.15w = 1/[σ2(Fo2) + (0.0382P)2 + 1.3452P] where P = (Fo2 + 2Fc2)/3
7526 reflections(Δ/σ)max < 0.001
403 parametersΔρmax = 0.95 e Å3
6 restraintsΔρmin = −0.55 e Å3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/UeqOcc. (<1)
In10.447613 (16)0.710677 (12)0.302721 (8)0.02890 (6)
C10.6729 (2)0.85480 (19)0.37586 (13)0.0380 (6)
H1A0.72090.88730.41370.046*
H1B0.67740.89500.34000.046*
C20.7324 (2)0.7572 (2)0.37027 (12)0.0354 (5)
C30.7475 (2)0.6060 (2)0.34430 (12)0.0352 (5)
C40.7229 (3)0.5111 (2)0.32325 (13)0.0419 (6)
H40.63930.49150.30110.050*
C50.8274 (3)0.4474 (2)0.33659 (15)0.0547 (8)
H50.81430.38300.32340.066*
C60.9521 (3)0.4770 (3)0.36927 (18)0.0671 (10)
H61.02060.43180.37690.081*
C70.9781 (3)0.5705 (3)0.39078 (17)0.0615 (9)
H71.06210.58960.41270.074*
C80.8723 (3)0.6355 (2)0.37807 (13)0.0422 (6)
C90.5226 (3)0.8079 (2)0.44197 (12)0.0395 (6)
H9A0.47540.85720.45960.047*
H9B0.61070.80250.46910.047*
C100.4529 (3)0.71260 (19)0.44155 (12)0.0352 (5)
C110.3720 (2)0.5684 (2)0.41656 (12)0.0354 (5)
C120.3344 (3)0.4790 (2)0.38883 (14)0.0432 (6)
H120.34040.46550.34800.052*
C130.2875 (3)0.4107 (2)0.42440 (16)0.0521 (8)
H130.26170.34990.40720.063*
C140.2782 (3)0.4307 (3)0.48525 (17)0.0551 (8)
H140.24490.38310.50740.066*
C150.3163 (3)0.5182 (3)0.51383 (15)0.0521 (8)
H150.31010.53100.55470.063*
C160.3648 (3)0.5868 (2)0.47842 (13)0.0397 (6)
C170.4499 (3)0.92644 (19)0.35714 (13)0.0383 (6)
H17A0.48070.96000.32440.046*
H17B0.45540.97100.39200.046*
C180.3108 (3)0.8943 (2)0.33274 (12)0.0363 (5)
C190.1407 (3)0.8058 (2)0.28851 (12)0.0366 (6)
C200.0541 (3)0.7343 (2)0.25857 (15)0.0478 (7)
H200.08430.67350.24950.057*
C21−0.0787 (3)0.7572 (3)0.24282 (16)0.0566 (8)
H21−0.13900.71090.22250.068*
C22−0.1246 (3)0.8477 (3)0.25658 (16)0.0566 (9)
H22−0.21480.86040.24480.068*
C23−0.0411 (3)0.9185 (3)0.28691 (15)0.0526 (8)
H23−0.07260.97840.29670.063*
C240.0937 (3)0.8965 (2)0.30258 (13)0.0408 (6)
C251.061 (3)0.7795 (16)0.5779 (14)0.163 (9)0.54 (2)
H25A1.07510.72030.55720.244*0.54 (2)
H25B1.00140.76720.60450.244*0.54 (2)
H25C1.14350.80280.60290.244*0.54 (2)
C261.0026 (12)0.8538 (10)0.5302 (6)0.101 (5)0.54 (2)
H26A0.90710.84880.52240.121*0.54 (2)
H26B1.02710.91740.54850.121*0.54 (2)
C25'1.058 (3)0.8492 (17)0.5828 (15)0.140 (9)0.46 (2)
H25D1.13510.85610.61660.209*0.46 (2)
H25E0.98430.82980.59930.209*0.46 (2)
H25F1.03830.91040.56130.209*0.46 (2)
C26'1.0832 (19)0.7717 (14)0.5365 (8)0.115 (7)0.46 (2)
H26C1.17100.74490.55220.138*0.46 (2)
H26D1.02010.71920.53460.138*0.46 (2)
Cl10.35306 (7)0.57777 (5)0.23656 (3)0.04797 (17)
Cl20.49870 (7)0.81165 (5)0.21877 (3)0.04437 (16)
Cl30.30232 (9)0.53452 (6)0.00493 (4)0.0574 (2)
N10.53335 (19)0.83983 (15)0.37826 (9)0.0316 (4)
N20.6621 (2)0.68466 (16)0.34018 (10)0.0341 (5)
N30.8591 (2)0.73183 (19)0.39420 (12)0.0431 (6)
H30.92040.76860.41550.052*
N40.4266 (2)0.65021 (16)0.39445 (10)0.0339 (5)
N50.4164 (2)0.67908 (18)0.49227 (11)0.0412 (5)
H5A0.42380.70950.52720.049*
N60.2781 (2)0.80711 (16)0.30802 (10)0.0350 (5)
N70.2042 (2)0.95009 (17)0.33077 (11)0.0421 (5)
H7A0.20451.00870.34460.050*
O20.4684 (3)0.6888 (2)0.09360 (12)0.0655 (7)
H2A0.416 (3)0.644 (2)0.0807 (16)0.079*
H2B0.460 (4)0.706 (3)0.1286 (11)0.079*
O30.7331 (3)0.6250 (2)0.10069 (13)0.0683 (7)
H3A0.662 (3)0.653 (3)0.0997 (17)0.082*
H3B0.726 (4)0.595 (3)0.0673 (13)0.082*
O11.0355 (12)0.8506 (10)0.4735 (6)0.079 (3)0.54 (2)
H11.10260.88280.47530.118*0.54 (2)
O1'1.0731 (18)0.8074 (14)0.4765 (8)0.097 (5)0.46 (2)
H1'1.09880.86390.47870.146*0.46 (2)

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
In10.02836 (9)0.02947 (10)0.02775 (10)0.00063 (6)0.00442 (6)−0.00344 (6)
C10.0342 (13)0.0353 (14)0.0431 (15)−0.0046 (10)0.0066 (11)−0.0048 (11)
C20.0305 (12)0.0396 (14)0.0356 (13)−0.0011 (10)0.0065 (10)−0.0018 (11)
C30.0306 (12)0.0425 (15)0.0323 (12)0.0054 (10)0.0071 (10)−0.0006 (11)
C40.0411 (14)0.0450 (16)0.0378 (14)0.0049 (12)0.0054 (11)−0.0067 (12)
C50.0592 (19)0.0491 (19)0.0544 (19)0.0177 (15)0.0111 (15)−0.0086 (15)
C60.0522 (19)0.066 (2)0.079 (3)0.0278 (17)0.0071 (18)−0.0071 (19)
C70.0341 (15)0.074 (2)0.070 (2)0.0131 (15)0.0005 (15)−0.0025 (19)
C80.0337 (13)0.0485 (17)0.0437 (15)0.0030 (12)0.0080 (11)−0.0016 (13)
C90.0470 (15)0.0390 (15)0.0315 (13)−0.0032 (12)0.0076 (11)−0.0066 (11)
C100.0343 (12)0.0371 (14)0.0329 (13)0.0027 (10)0.0052 (10)0.0017 (10)
C110.0311 (12)0.0368 (14)0.0372 (13)0.0009 (10)0.0058 (10)0.0053 (11)
C120.0445 (15)0.0382 (15)0.0450 (16)−0.0008 (12)0.0066 (12)0.0024 (12)
C130.0454 (16)0.0393 (17)0.068 (2)−0.0067 (13)0.0066 (15)0.0069 (15)
C140.0465 (17)0.053 (2)0.065 (2)−0.0027 (14)0.0120 (15)0.0229 (16)
C150.0501 (17)0.064 (2)0.0441 (16)0.0020 (15)0.0152 (14)0.0172 (15)
C160.0370 (13)0.0422 (15)0.0389 (14)0.0023 (11)0.0067 (11)0.0070 (12)
C170.0402 (14)0.0308 (13)0.0423 (15)0.0016 (11)0.0066 (11)−0.0046 (11)
C180.0373 (13)0.0352 (14)0.0353 (13)0.0056 (10)0.0066 (10)−0.0017 (11)
C190.0321 (12)0.0443 (16)0.0340 (13)0.0044 (11)0.0088 (10)0.0032 (11)
C200.0416 (15)0.0513 (18)0.0489 (17)−0.0063 (13)0.0074 (13)−0.0049 (14)
C210.0365 (15)0.078 (2)0.0540 (19)−0.0108 (15)0.0074 (14)−0.0010 (17)
C220.0332 (14)0.081 (3)0.0549 (19)0.0072 (15)0.0090 (13)0.0102 (17)
C230.0444 (16)0.062 (2)0.0530 (18)0.0169 (14)0.0144 (14)0.0100 (15)
C240.0380 (14)0.0466 (16)0.0379 (14)0.0071 (12)0.0095 (11)0.0036 (12)
C250.186 (19)0.160 (19)0.153 (19)0.005 (18)0.063 (15)0.027 (19)
C260.097 (7)0.124 (10)0.081 (9)0.009 (7)0.022 (6)−0.021 (6)
C25'0.132 (14)0.16 (2)0.14 (2)−0.010 (17)0.058 (13)0.017 (18)
C26'0.114 (12)0.120 (14)0.102 (12)−0.042 (10)0.010 (9)0.017 (10)
Cl10.0516 (4)0.0418 (4)0.0476 (4)−0.0079 (3)0.0061 (3)−0.0161 (3)
Cl20.0537 (4)0.0435 (4)0.0372 (3)−0.0036 (3)0.0134 (3)0.0040 (3)
Cl30.0627 (5)0.0534 (5)0.0556 (5)0.0060 (4)0.0133 (4)0.0069 (4)
N10.0316 (10)0.0297 (11)0.0327 (11)−0.0017 (8)0.0060 (8)−0.0022 (8)
N20.0304 (10)0.0347 (11)0.0360 (11)0.0009 (8)0.0053 (9)−0.0045 (9)
N30.0291 (11)0.0495 (15)0.0471 (14)−0.0048 (10)0.0015 (10)−0.0036 (11)
N40.0365 (11)0.0338 (12)0.0309 (11)−0.0014 (9)0.0071 (9)0.0001 (9)
N50.0473 (13)0.0463 (14)0.0311 (11)0.0003 (11)0.0113 (10)−0.0002 (10)
N60.0323 (10)0.0351 (12)0.0365 (11)0.0030 (9)0.0057 (9)−0.0032 (9)
N70.0437 (12)0.0378 (13)0.0440 (13)0.0089 (10)0.0090 (10)−0.0048 (10)
O20.087 (2)0.0677 (18)0.0421 (13)−0.0024 (13)0.0163 (13)−0.0034 (12)
O30.0772 (17)0.0528 (16)0.0736 (18)−0.0008 (13)0.0156 (15)0.0047 (13)
O10.073 (5)0.092 (8)0.068 (5)−0.036 (5)0.010 (4)−0.017 (5)
O1'0.092 (9)0.094 (10)0.087 (6)−0.042 (7)−0.015 (6)0.005 (8)

Geometric parameters (Å, °)

In1—N22.218 (2)C17—N11.481 (3)
In1—N42.232 (2)C17—C181.487 (4)
In1—N62.233 (2)C17—H17A0.9700
In1—Cl12.3928 (7)C17—H17B0.9700
In1—N12.446 (2)C18—N61.326 (3)
In1—Cl22.4604 (7)C18—N71.341 (3)
C1—N11.481 (3)C19—C201.389 (4)
C1—C21.495 (4)C19—N61.392 (3)
C1—H1A0.9700C19—C241.399 (4)
C1—H1B0.9700C20—C211.380 (4)
C2—N21.317 (3)C20—H200.9300
C2—N31.344 (3)C21—C221.391 (5)
C3—C41.386 (4)C21—H210.9300
C3—N21.390 (3)C22—C231.367 (5)
C3—C81.394 (4)C22—H220.9300
C4—C51.374 (4)C23—C241.397 (4)
C4—H40.9300C23—H230.9300
C5—C61.386 (5)C24—N71.383 (4)
C5—H50.9300C25—C261.48 (3)
C6—C71.374 (5)C25—H25A0.9600
C6—H60.9300C25—H25B0.9600
C7—C81.393 (4)C25—H25C0.9600
C7—H70.9300C26—O11.366 (17)
C8—N31.386 (4)C26—H26A0.9700
C9—N11.492 (3)C26—H26B0.9700
C9—C101.495 (4)C25'—C26'1.54 (4)
C9—H9A0.9700C25'—H25D0.9600
C9—H9B0.9700C25'—H25E0.9600
C10—N41.319 (3)C25'—H25F0.9600
C10—N51.338 (3)C26'—O1'1.38 (2)
C11—C121.385 (4)C26'—H26C0.9700
C11—N41.397 (3)C26'—H26D0.9700
C11—C161.398 (4)N3—H30.8600
C12—C131.380 (4)N5—H5A0.8600
C12—H120.9300N7—H7A0.8600
C13—C141.387 (5)O2—H2A0.823 (17)
C13—H130.9300O2—H2B0.825 (18)
C14—C151.369 (5)O3—H3A0.823 (18)
C14—H140.9300O3—H3B0.829 (18)
C15—C161.390 (4)O1—H10.8200
C15—H150.9300O1'—H1'0.8195
C16—N51.382 (4)
N2—In1—N484.98 (8)C21—C20—C19117.1 (3)
N2—In1—N6144.67 (8)C21—C20—H20121.4
N4—In1—N685.77 (8)C19—C20—H20121.4
N2—In1—Cl1109.53 (6)C20—C21—C22121.7 (3)
N4—In1—Cl198.44 (6)C20—C21—H21119.1
N6—In1—Cl1105.52 (6)C22—C21—H21119.1
N2—In1—N172.12 (7)C23—C22—C21122.0 (3)
N4—In1—N176.07 (7)C23—C22—H22119.0
N6—In1—N172.56 (7)C21—C22—H22119.0
Cl1—In1—N1174.22 (5)C22—C23—C24116.8 (3)
N2—In1—Cl289.41 (6)C22—C23—H23121.6
N4—In1—Cl2165.30 (6)C24—C23—H23121.6
N6—In1—Cl291.06 (6)N7—C24—C23132.5 (3)
Cl1—In1—Cl296.24 (3)N7—C24—C19105.9 (2)
N1—In1—Cl289.28 (5)C23—C24—C19121.5 (3)
N1—C1—C2107.9 (2)O1—C26—C25118.0 (15)
N1—C1—H1A110.1O1—C26—H26A107.8
C2—C1—H1A110.1C25—C26—H26A107.8
N1—C1—H1B110.1O1—C26—H26B107.8
C2—C1—H1B110.1C25—C26—H26B107.8
H1A—C1—H1B108.4H26A—C26—H26B107.1
N2—C2—N3112.1 (2)C26'—C25'—H25D109.5
N2—C2—C1121.8 (2)C26'—C25'—H25E109.5
N3—C2—C1126.0 (2)H25D—C25'—H25E109.5
C4—C3—N2130.2 (2)C26'—C25'—H25F109.5
C4—C3—C8121.7 (2)H25D—C25'—H25F109.5
N2—C3—C8108.1 (2)H25E—C25'—H25F109.5
C5—C4—C3117.0 (3)O1'—C26'—C25'113.3 (18)
C5—C4—H4121.5O1'—C26'—H26C108.9
C3—C4—H4121.5C25'—C26'—H26C108.9
C4—C5—C6121.4 (3)O1'—C26'—H26D108.9
C4—C5—H5119.3C25'—C26'—H26D108.9
C6—C5—H5119.3H26C—C26'—H26D107.7
C7—C6—C5122.4 (3)In1—Cl1—O291.52 (5)
C7—C6—H6118.8C17—N1—C1112.7 (2)
C5—C6—H6118.8C17—N1—C9111.1 (2)
C6—C7—C8116.7 (3)C1—N1—C9111.5 (2)
C6—C7—H7121.7C17—N1—In1106.19 (14)
C8—C7—H7121.7C1—N1—In1106.27 (15)
N3—C8—C7133.1 (3)C9—N1—In1108.81 (15)
N3—C8—C3106.0 (2)C2—N2—C3106.5 (2)
C7—C8—C3120.9 (3)C2—N2—In1117.06 (17)
N1—C9—C10113.3 (2)C3—N2—In1136.28 (17)
N1—C9—H9A108.9C2—N3—C8107.2 (2)
C10—C9—H9A108.9C2—N3—O1122.7 (4)
N1—C9—H9B108.9C8—N3—O1129.6 (4)
C10—C9—H9B108.9C2—N3—H3126.4
H9A—C9—H9B107.7C8—N3—H3126.4
N4—C10—N5112.2 (2)C10—N4—C11106.1 (2)
N4—C10—C9125.7 (2)C10—N4—In1114.55 (17)
N5—C10—C9121.9 (2)C11—N4—In1138.28 (17)
C12—C11—N4131.1 (3)C10—N5—C16107.8 (2)
C12—C11—C16120.7 (3)C10—N5—H5A126.1
N4—C11—C16108.1 (2)C16—N5—H5A126.1
C13—C12—C11117.1 (3)C18—N6—C19106.4 (2)
C13—C12—H12121.4C18—N6—In1115.33 (17)
C11—C12—H12121.4C19—N6—In1138.08 (18)
C12—C13—C14121.5 (3)C18—N7—C24107.8 (2)
C12—C13—H13119.3C18—N7—H7A126.1
C14—C13—H13119.3C24—N7—H7A126.1
C15—C14—C13122.3 (3)O3—O2—Cl3102.18 (10)
C15—C14—H14118.8O3—O2—Cl1108.16 (10)
C13—C14—H14118.8Cl3—O2—Cl190.17 (7)
C14—C15—C16116.4 (3)O3—O2—H2A110 (3)
C14—C15—H15121.8Cl1—O2—H2A71 (3)
C16—C15—H15121.8O3—O2—H2B110 (3)
N5—C16—C15132.4 (3)Cl3—O2—H2B128 (3)
N5—C16—C11105.7 (2)H2A—O2—H2B109 (3)
C15—C16—C11121.9 (3)O2—O3—H3B103 (3)
N1—C17—C18108.9 (2)H3A—O3—H3B108 (3)
N1—C17—H17A109.9C26—O1—N3108.6 (8)
C18—C17—H17A109.9C26—O1—H1109.4
N1—C17—H17B109.9N3—O1—H1141.9
C18—C17—H17B109.9C26—O1—H1'106.6
H17A—C17—H17B108.3N3—O1—H1'139.3
N6—C18—N7111.9 (2)C26'—O1'—H3115.6
N6—C18—C17123.3 (2)C26'—O1'—H1113.8
N7—C18—C17124.8 (2)H3—O1'—H1116.6
C20—C19—N6131.2 (3)C26'—O1'—H1'109.2
C20—C19—C24120.8 (3)H3—O1'—H1'121.1
N6—C19—C24108.0 (2)
N1—C1—C2—N232.2 (3)C4—C3—N2—In11.4 (5)
N1—C1—C2—N3−147.5 (3)C8—C3—N2—In1−175.54 (19)
N2—C3—C4—C5−177.2 (3)N4—In1—N2—C2−92.1 (2)
C8—C3—C4—C5−0.6 (4)N6—In1—N2—C2−16.7 (3)
C3—C4—C5—C6−0.4 (5)Cl1—In1—N2—C2170.69 (18)
C4—C5—C6—C70.8 (6)N1—In1—N2—C2−15.16 (18)
C5—C6—C7—C8−0.1 (6)Cl2—In1—N2—C274.28 (19)
C6—C7—C8—N3176.6 (3)N4—In1—N2—C382.8 (3)
C6—C7—C8—C3−1.0 (5)N6—In1—N2—C3158.2 (2)
C4—C3—C8—N3−176.8 (3)Cl1—In1—N2—C3−14.4 (3)
N2—C3—C8—N30.5 (3)N1—In1—N2—C3159.8 (3)
C4—C3—C8—C71.4 (4)Cl2—In1—N2—C3−110.8 (2)
N2—C3—C8—C7178.7 (3)N2—C2—N3—C80.4 (3)
N1—C9—C10—N413.9 (4)C1—C2—N3—C8−179.8 (3)
N1—C9—C10—N5−169.9 (2)N2—C2—N3—O1−171.9 (4)
N4—C11—C12—C13177.5 (3)C1—C2—N3—O17.9 (5)
C16—C11—C12—C131.3 (4)C7—C8—N3—C2−178.4 (3)
C11—C12—C13—C140.1 (4)C3—C8—N3—C2−0.5 (3)
C12—C13—C14—C15−0.9 (5)C7—C8—N3—O1−6.8 (6)
C13—C14—C15—C160.3 (5)C3—C8—N3—O1171.0 (4)
C14—C15—C16—N5−176.8 (3)N5—C10—N4—C11−1.7 (3)
C14—C15—C16—C111.2 (4)C9—C10—N4—C11174.7 (2)
C12—C11—C16—N5176.5 (2)N5—C10—N4—In1168.72 (17)
N4—C11—C16—N5−0.5 (3)C9—C10—N4—In1−14.8 (3)
C12—C11—C16—C15−2.0 (4)C12—C11—N4—C10−175.2 (3)
N4—C11—C16—C15−179.0 (2)C16—C11—N4—C101.4 (3)
N1—C17—C18—N6−27.6 (4)C12—C11—N4—In117.9 (4)
N1—C17—C18—N7155.0 (3)C16—C11—N4—In1−165.52 (19)
N6—C19—C20—C21−177.2 (3)N2—In1—N4—C1080.35 (18)
C24—C19—C20—C210.9 (4)N6—In1—N4—C10−65.52 (18)
C19—C20—C21—C22−0.4 (5)Cl1—In1—N4—C10−170.61 (17)
C20—C21—C22—C23−0.6 (5)N1—In1—N4—C107.55 (17)
C21—C22—C23—C241.2 (5)Cl2—In1—N4—C1012.4 (4)
C22—C23—C24—N7177.5 (3)N2—In1—N4—C11−113.5 (3)
C22—C23—C24—C19−0.7 (4)N6—In1—N4—C11100.6 (3)
C20—C19—C24—N7−179.0 (3)Cl1—In1—N4—C11−4.5 (3)
N6—C19—C24—N7−0.4 (3)N1—In1—N4—C11173.7 (3)
C20—C19—C24—C23−0.3 (4)Cl2—In1—N4—C11178.55 (17)
N6—C19—C24—C23178.2 (3)N4—C10—N5—C161.4 (3)
N2—In1—Cl1—O2−82.46 (8)C9—C10—N5—C16−175.2 (2)
N4—In1—Cl1—O2−170.10 (7)C15—C16—N5—C10177.8 (3)
N6—In1—Cl1—O2101.98 (8)C11—C16—N5—C10−0.5 (3)
Cl2—In1—Cl1—O29.13 (5)N7—C18—N6—C190.1 (3)
C18—C17—N1—C1153.9 (2)C17—C18—N6—C19−177.7 (2)
C18—C17—N1—C9−80.2 (3)N7—C18—N6—In1176.14 (17)
C18—C17—N1—In138.0 (2)C17—C18—N6—In1−1.6 (3)
C2—C1—N1—C17−155.8 (2)C20—C19—N6—C18178.5 (3)
C2—C1—N1—C978.6 (3)C24—C19—N6—C180.2 (3)
C2—C1—N1—In1−39.9 (2)C20—C19—N6—In13.9 (5)
C10—C9—N1—C17111.3 (2)C24—C19—N6—In1−174.4 (2)
C10—C9—N1—C1−122.2 (2)N2—In1—N6—C1819.4 (3)
C10—C9—N1—In1−5.3 (3)N4—In1—N6—C1894.52 (19)
N2—In1—N1—C17150.47 (17)Cl1—In1—N6—C18−167.88 (18)
N4—In1—N1—C17−120.38 (16)N1—In1—N6—C1817.80 (18)
N6—In1—N1—C17−30.48 (15)Cl2—In1—N6—C18−71.11 (19)
Cl2—In1—N1—C1760.86 (15)N2—In1—N6—C19−166.3 (2)
N2—In1—N1—C130.28 (16)N4—In1—N6—C19−91.1 (3)
N4—In1—N1—C1119.44 (16)Cl1—In1—N6—C196.5 (3)
N6—In1—N1—C1−150.67 (17)N1—In1—N6—C19−167.8 (3)
Cl2—In1—N1—C1−59.33 (15)Cl2—In1—N6—C19103.2 (3)
N2—In1—N1—C9−89.91 (17)N6—C18—N7—C24−0.4 (3)
N4—In1—N1—C9−0.75 (16)C17—C18—N7—C24177.3 (3)
N6—In1—N1—C989.14 (17)C23—C24—N7—C18−177.9 (3)
Cl2—In1—N1—C9−179.52 (16)C19—C24—N7—C180.5 (3)
N3—C2—N2—C3−0.1 (3)In1—Cl1—O2—O386.39 (9)
C1—C2—N2—C3−179.9 (2)In1—Cl1—O2—Cl3−170.73 (6)
N3—C2—N2—In1176.25 (17)C25—C26—O1—N389.1 (15)
C1—C2—N2—In1−3.6 (3)C2—N3—O1—C2670.9 (9)
C4—C3—N2—C2176.7 (3)C8—N3—O1—C26−99.5 (8)
C8—C3—N2—C2−0.3 (3)C25'—C26'—O1'—H3−107.0

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
C9—H9A···Cl3i0.972.703.655 (3)168
C1—H1A···Cl3ii0.972.743.558 (3)142
N7—H7A···O3ii0.862.012.826 (4)158
N5—H5A···O2i0.861.992.818 (4)161
O3—H3B···Cl3iii0.83 (2)2.35 (2)3.144 (3)161 (4)
O3—H3A···O20.82 (2)2.05 (2)2.861 (4)166 (4)
N3—H3···O10.861.902.745 (12)169
N3—H3···O1'0.861.892.718 (12)160
O2—H2B···Cl20.83 (2)2.41 (2)3.171 (3)154 (3)
O2—H2A···Cl30.82 (2)2.34 (2)3.108 (3)155 (3)
O1—H1···Cl3iv0.822.323.127 (11)167
O1'—H1'···Cl3iv0.822.493.178 (11)143

Symmetry codes: (i) x, −y+3/2, z+1/2; (ii) −x+1, y+1/2, −z+1/2; (iii) −x+1, −y+1, −z; (iv) x+1, −y+3/2, z+1/2.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LH5092).

References

  • Bruker (2007). SAINT-Plus and SMART Bruker AXS Inc., Madison, Wisconsin, USA.
  • Green, D. E., Ferreira, C. L., Stick, R. V., Patrick, B. O., Adam, M. J. & Orvig, C. (2005). Bioconjugate Chem.16, 1597–1609. [PubMed]
  • Hendriks, H. M. J., Birker, P. J. M. W. L., Rijn, J., Verschoor, G. C. & Reedijk, J. (1982). J. Am. Chem. Soc.104, 3607–3617.
  • Krivokapic, A., Anderson, H. L., Bourhill, G., Ives, R., Clark, S., McEwan, K. J., Kenneth, (2001). Adv. Mater.13, 652–656.
  • Lu, J., Ji, S., Teo, Y. & Loh, T. (2005). Org. Lett.7, 159–161. [PubMed]
  • Sheldrick, G. M. (1997). SADABS University of Göttingen, Germany.
  • Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [PubMed]
  • Spek, A. L. (2009). Acta Cryst D65, 148–155. [PMC free article] [PubMed]
  • Sun, Q., Liu, Y., Li, H. & Luo, Z. (2009). Acta Cryst. E65, m394–m395. [PMC free article] [PubMed]
  • Vagin, S., Barthel, M., Dini, D. & Hanack, M. (2003). Inorg. Chem.42, 2683–2694. [PubMed]

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