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Acta Crystallogr Sect E Struct Rep Online. 2010 August 1; 66(Pt 8): o2068–o2069.
Published online 2010 July 21. doi:  10.1107/S1600536810027753
PMCID: PMC3007240

9,9′-(Biphenyl-2,2′-di­yl)difluoren-9-ol 4-methyl­pyridine solvate

Abstract

The title compound, C38H26O2·C6H7N, crystallized as a host–guest complex from a solvent mixture of 4-methyl­pyridine and acetone. The dihedral angle between the rings in the biphenyl unit is 87.06 (3)°. The methyl­pyridine guest mol­ecules are linked to the host mol­ecules via O—H(...) N hydrogen bonds, forming discrete pairs. The other OH group of the host forms an intra­molecular O—H(...)O hydrogen bond.

Related literature

For the synthesis of the host compound, see: Weber et al. (1993 [triangle]). For related structures, see: Barbour et al. (1993 [triangle]); Ibragimov et al. (2001 [triangle]); Izotova et al. (2008 [triangle]); Sardone (1996 [triangle]); Weber (1996 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-66-o2068-scheme1.jpg

Experimental

Crystal data

  • C38H26O2·C6H7N
  • M r = 607.71
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-66-o2068-efi1.jpg
  • a = 15.801 (3) Å
  • b = 15.602 (3) Å
  • c = 14.136 (3) Å
  • β = 110.19 (3)°
  • V = 3270.8 (11) Å3
  • Z = 4
  • Cu Kα radiation
  • μ = 0.58 mm−1
  • T = 293 K
  • 0.58 × 0.56 × 0.4 mm

Data collection

  • Oxford Diffraction Xcalibur Ruby diffractometer
  • Absorption correction: multi-scan (CrysAlis PRO; Oxford Diffraction, 2007 [triangle]) T min = 0.749, T max = 0.792
  • 46372 measured reflections
  • 6787 independent reflections
  • 5450 reflections with I > 2σ(I)
  • R int = 0.035

Refinement

  • R[F 2 > 2σ(F 2)] = 0.041
  • wR(F 2) = 0.122
  • S = 1.06
  • 6787 reflections
  • 546 parameters
  • H atoms treated by a mixture of independent and constrained refinement
  • Δρmax = 0.21 e Å−3
  • Δρmin = −0.18 e Å−3

Data collection: CrysAlis PRO (Oxford Diffraction, 2007 [triangle]); cell refinement: CrysAlis PRO; data reduction: CrysAlis PRO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: XP (Siemens, 1994 [triangle]) and Mercury (Macrae et al., 2006 [triangle]); software used to prepare material for publication: SHELXL97.

Table 1
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810027753/zl2280sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810027753/zl2280Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

This work was supported by a Grant for Fundamental Research from the Center of Science and Technology, Uzbekistan (No. FA–F3–T-141).

supplementary crystallographic information

Comment

2,2'-Bis(9-hydroxy-9-fluorenyl) biphenyl is a versatile host compound with the capacity to form inclusion compounds (host–guest complexes) with a variety of guest molecules (about 35 guests reported in the literature, Weber (1996)). In this study we report on the structure of the inclusion compound formed by the host compound with 4-metylpyridine. The host molecule possesses three degrees of freedom for changing its conformation - rotation around the central aryl-aryl single bond and two rotations around the aryl fluorenyl covalent bonds. However, due to the stabilizing effect of the intramolecular hydrogen bond between two hydroxyl groups of the molecule (O2—H···O1, Table 1) the host molecules exhibit a considerable conformational rigidity and are held in a rigid spiral conformation (Fig.1.). In the title compound the hydrogen atom of the second hydroxyl group O1—H points outwards to make a hydrogen bond towards the methylpyridine guest molecule - a structural feature observed in all previously studied structures of the host molecule with polar guests such as acetonitrile, cyclohexanone, n-propylamine (Barbour et al., 1993), acetone (Sardone, 1996; Ibragimov et al., 2001), or ethylacetate (Izotova et al.,2008). In the crystals of the title compound the host and guest molecules are connected through intermolecular hydrogen bonds [N···H=1.77 (2) (Å)] which assemble them into 0-dimensional host-guest assemblies. The packing of the assemblies is based on van der Waals interactions (Fig. 2).].

The dihedral angle between the planes of the phenyl rings of the host compound is 87.06 (3)°. The fluorenyl fragments of the host molecule are planar within 0.0382 Å (C1—C13) and 0.0165 Å (C26—C38), respectively. The largest deviations are 0.0695 Å for C13 and 0.0307 Å for C36. The dihedral angle between the planes is 73.73 (4)°.

Experimental

2,2'-Bis(9-hydroxy-9-fluorenyl) biphenyl (host) was synthesized according to the procedure described by Weber et al. (1993). The air stable 4-methylpyridine solvated crystals were obtained by slow evaporation of the host compound from a mixture of acetone and 4-methylpyridine (1:1). The formation of acetone solvated crystals is not observed.

Refinement

H atoms atoms of the methyl group of 4-methyl pyridine were positioned geometrically, with C—H = 0.96 Å and constrained to ride on their parent atom, with Uiso(H) = 1.5Ueq(C). The remaining H atoms were located in difference syntheses and refined isotropically [O—H = 0.91 (2) and 0.93 (2) Å].

Figures

Fig. 1.
View of the asymmetric unit of the title compound. Hydrogen bonds are indicated as dashed lines.
Fig. 2.
View of the molecular packing along the c axis. Hydrogen atoms omitted for clarity.

Crystal data

C38H26O2·C6H7NF(000) = 1280
Mr = 607.71Dx = 1.234 Mg m3
Monoclinic, P21/cCu Kα radiation, λ = 1.54178 Å
Hall symbol: -P 2ybcCell parameters from 19833 reflections
a = 15.801 (3) Åθ = 4.1–75.8°
b = 15.602 (3) ŵ = 0.58 mm1
c = 14.136 (3) ÅT = 293 K
β = 110.19 (3)°Block, colourless
V = 3270.8 (11) Å30.58 × 0.56 × 0.4 mm
Z = 4

Data collection

Oxford Diffraction Xcalibur Ruby diffractometer6787 independent reflections
Radiation source: fine-focus sealed tube5450 reflections with I > 2σ(I)
graphiteRint = 0.035
Detector resolution: 10.2576 pixels mm-1θmax = 75.8°, θmin = 4.1°
ω scansh = −19→19
Absorption correction: multi-scan (CrysAlis PRO; Oxford Diffraction, 2007)k = −18→19
Tmin = 0.749, Tmax = 0.792l = −17→17
46372 measured reflections

Refinement

Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.041H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.122w = 1/[σ2(Fo2) + (0.0748P)2 + 0.1854P] where P = (Fo2 + 2Fc2)/3
S = 1.06(Δ/σ)max = 0.011
6787 reflectionsΔρmax = 0.21 e Å3
546 parametersΔρmin = −0.18 e Å3
0 restraintsExtinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methodsExtinction coefficient: 0.0018 (2)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
N10.28630 (10)0.22388 (8)0.23144 (12)0.0762 (4)
C390.30568 (13)0.07376 (12)0.24668 (15)0.0794 (5)
C400.33566 (13)0.15436 (12)0.23830 (18)0.0865 (5)
C410.20339 (12)0.21306 (10)0.23211 (14)0.0705 (4)
C420.16876 (11)0.13410 (10)0.24206 (12)0.0666 (4)
C430.22017 (12)0.06195 (9)0.24911 (10)0.0632 (4)
C440.18342 (18)−0.02567 (12)0.25497 (16)0.1027 (7)
H44C0.1305−0.02080.27330.154*
H44A0.2281−0.05900.30480.154*
H44B0.1681−0.05330.19060.154*
H390.3454 (15)0.0278 (14)0.2504 (16)0.102 (7)*
H400.3967 (17)0.1637 (15)0.2386 (18)0.111 (7)*
H410.1658 (13)0.2628 (13)0.2245 (14)0.086 (6)*
H420.1102 (14)0.1315 (12)0.2448 (15)0.088 (6)*
O10.33690 (6)0.38807 (6)0.22672 (7)0.0492 (2)
O20.29222 (6)0.55099 (7)0.27689 (7)0.0571 (2)
C10.42742 (8)0.33134 (7)0.12905 (10)0.0470 (3)
C20.37556 (10)0.29484 (9)0.03880 (11)0.0586 (3)
C30.41119 (13)0.22588 (10)0.00192 (13)0.0696 (4)
C40.49610 (13)0.19436 (9)0.05510 (14)0.0723 (4)
C50.54802 (11)0.23036 (9)0.14612 (14)0.0656 (4)
C60.51351 (9)0.29984 (8)0.18251 (10)0.0520 (3)
C70.55424 (8)0.35289 (8)0.27283 (11)0.0529 (3)
C80.63650 (10)0.34711 (11)0.35155 (14)0.0703 (4)
C90.65709 (11)0.40714 (13)0.42803 (14)0.0775 (5)
C100.59787 (11)0.47218 (11)0.42739 (13)0.0705 (4)
C110.51546 (10)0.47859 (10)0.34950 (11)0.0586 (3)
C120.49418 (8)0.41807 (8)0.27288 (9)0.0478 (3)
C130.40518 (7)0.40751 (7)0.18496 (9)0.0433 (3)
C140.37663 (8)0.48741 (7)0.11860 (9)0.0436 (2)
C150.44456 (10)0.53162 (9)0.09671 (12)0.0574 (3)
C160.42725 (11)0.60509 (10)0.03888 (13)0.0680 (4)
C170.34103 (12)0.63647 (10)0.00125 (13)0.0677 (4)
C180.27204 (10)0.59256 (9)0.01963 (11)0.0572 (3)
C190.28788 (8)0.51801 (7)0.07821 (8)0.0443 (3)
C200.20356 (7)0.47327 (7)0.07992 (8)0.0424 (2)
C210.16213 (9)0.42064 (9)−0.00338 (9)0.0527 (3)
C220.08037 (9)0.38101 (9)−0.01885 (10)0.0581 (3)
C230.03635 (9)0.39469 (9)0.04847 (10)0.0551 (3)
C240.07593 (8)0.44634 (8)0.13146 (9)0.0486 (3)
C250.15942 (7)0.48553 (7)0.14956 (8)0.0422 (2)
C260.19745 (8)0.53939 (8)0.24648 (9)0.0486 (3)
C270.15271 (9)0.62719 (9)0.23645 (11)0.0596 (3)
C280.15284 (12)0.69314 (10)0.17149 (15)0.0752 (4)
C290.10562 (16)0.76798 (12)0.1749 (2)0.1026 (7)
C300.06147 (16)0.77686 (16)0.2424 (3)0.1200 (10)
C310.06224 (13)0.71165 (17)0.3087 (2)0.1020 (8)
C320.10751 (9)0.63569 (12)0.30554 (13)0.0720 (5)
C330.11990 (9)0.55660 (13)0.36463 (11)0.0717 (5)
C340.09016 (13)0.5321 (2)0.44281 (16)0.1002 (8)
C350.11436 (15)0.4533 (3)0.48663 (15)0.1152 (10)
C360.16715 (14)0.3978 (2)0.45519 (14)0.0985 (7)
C370.19693 (11)0.42109 (14)0.37662 (11)0.0729 (4)
C380.17243 (8)0.49993 (10)0.33219 (10)0.0577 (3)
H10.3237 (12)0.3311 (13)0.2227 (14)0.081 (5)*
H20.3139 (13)0.4960 (13)0.2749 (15)0.085 (6)*
H2A0.3128 (11)0.3175 (10)0.0000 (12)0.065 (4)*
H30.3744 (13)0.1986 (12)−0.0629 (15)0.084 (5)*
H40.5219 (13)0.1475 (12)0.0259 (14)0.081 (5)*
H50.6077 (13)0.2082 (11)0.1823 (13)0.077 (5)*
H80.6729 (12)0.3022 (12)0.3498 (13)0.074 (5)*
H90.7146 (15)0.4039 (12)0.4813 (16)0.089 (6)*
H100.6156 (13)0.5164 (12)0.4842 (15)0.082 (5)*
H110.4705 (12)0.5253 (11)0.3478 (13)0.071 (5)*
H150.5066 (12)0.5097 (10)0.1242 (12)0.066 (4)*
H160.4775 (13)0.6340 (12)0.0264 (15)0.086 (5)*
H170.3270 (12)0.6881 (12)−0.0403 (14)0.077 (5)*
H180.2106 (12)0.6142 (10)−0.0075 (13)0.068 (4)*
H210.1946 (11)0.4155 (10)−0.0559 (12)0.067 (4)*
H220.0537 (12)0.3458 (11)−0.0780 (14)0.074 (5)*
H23−0.0239 (12)0.3697 (10)0.0375 (12)0.068 (4)*
H240.0443 (10)0.4565 (10)0.1799 (12)0.061 (4)*
H280.1918 (13)0.6868 (12)0.1288 (14)0.084 (5)*
H290.1079 (17)0.8148 (17)0.1337 (19)0.117 (8)*
H300.0265 (19)0.8288 (19)0.249 (2)0.145 (10)*
H310.0313 (17)0.7197 (16)0.3573 (19)0.117 (8)*
H340.0531 (17)0.5695 (15)0.4681 (19)0.119 (8)*
H350.0927 (16)0.4365 (16)0.5376 (19)0.116 (7)*
H360.1851 (18)0.3430 (17)0.488 (2)0.125 (9)*
H370.2321 (14)0.3819 (12)0.3531 (14)0.083 (6)*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
N10.0829 (9)0.0576 (7)0.1004 (10)−0.0149 (6)0.0472 (8)−0.0029 (6)
C390.0788 (11)0.0619 (9)0.0957 (12)0.0086 (8)0.0279 (9)−0.0065 (8)
C400.0700 (11)0.0746 (11)0.1267 (16)−0.0055 (8)0.0491 (11)−0.0080 (10)
C410.0745 (10)0.0558 (8)0.0872 (11)0.0020 (7)0.0356 (8)−0.0012 (7)
C420.0636 (9)0.0695 (9)0.0730 (9)−0.0106 (7)0.0316 (7)−0.0043 (7)
C430.0851 (10)0.0523 (7)0.0506 (7)−0.0121 (7)0.0213 (7)−0.0021 (5)
C440.152 (2)0.0651 (11)0.0863 (13)−0.0351 (12)0.0351 (13)0.0005 (9)
O10.0466 (4)0.0488 (5)0.0612 (5)−0.0032 (3)0.0300 (4)0.0030 (4)
O20.0365 (4)0.0776 (6)0.0583 (5)−0.0087 (4)0.0179 (4)−0.0200 (4)
C10.0486 (6)0.0417 (6)0.0587 (7)−0.0047 (5)0.0287 (5)−0.0013 (5)
C20.0632 (8)0.0534 (7)0.0641 (8)−0.0096 (6)0.0283 (7)−0.0083 (6)
C30.0897 (11)0.0555 (8)0.0748 (10)−0.0151 (7)0.0426 (9)−0.0158 (7)
C40.0960 (12)0.0450 (7)0.0989 (12)−0.0021 (7)0.0631 (10)−0.0074 (7)
C50.0674 (9)0.0492 (7)0.0948 (11)0.0072 (6)0.0467 (8)0.0058 (7)
C60.0520 (7)0.0442 (6)0.0689 (8)−0.0002 (5)0.0327 (6)0.0043 (5)
C70.0443 (6)0.0528 (7)0.0646 (7)−0.0018 (5)0.0226 (6)0.0067 (5)
C80.0490 (7)0.0720 (10)0.0857 (11)0.0070 (7)0.0179 (7)0.0146 (8)
C90.0529 (8)0.0949 (12)0.0711 (10)−0.0132 (8)0.0038 (7)0.0076 (9)
C100.0604 (9)0.0814 (10)0.0632 (9)−0.0163 (8)0.0131 (7)−0.0065 (7)
C110.0545 (7)0.0617 (8)0.0609 (8)−0.0108 (6)0.0215 (6)−0.0089 (6)
C120.0422 (6)0.0496 (6)0.0543 (7)−0.0048 (5)0.0201 (5)0.0019 (5)
C130.0397 (5)0.0442 (6)0.0509 (6)−0.0047 (4)0.0221 (5)−0.0029 (4)
C140.0439 (6)0.0438 (6)0.0491 (6)−0.0048 (4)0.0238 (5)−0.0037 (4)
C150.0505 (7)0.0581 (7)0.0732 (8)−0.0066 (6)0.0336 (7)0.0025 (6)
C160.0701 (9)0.0628 (8)0.0861 (10)−0.0128 (7)0.0463 (8)0.0092 (7)
C170.0797 (10)0.0557 (8)0.0779 (10)−0.0004 (7)0.0401 (8)0.0165 (7)
C180.0587 (8)0.0564 (7)0.0606 (7)0.0034 (6)0.0259 (6)0.0079 (6)
C190.0470 (6)0.0468 (6)0.0443 (6)−0.0040 (5)0.0224 (5)−0.0027 (4)
C200.0390 (5)0.0466 (6)0.0417 (5)−0.0002 (4)0.0140 (4)0.0006 (4)
C210.0520 (7)0.0630 (7)0.0434 (6)−0.0029 (6)0.0168 (5)−0.0053 (5)
C220.0552 (7)0.0622 (8)0.0497 (7)−0.0098 (6)0.0088 (6)−0.0111 (6)
C230.0429 (6)0.0607 (7)0.0562 (7)−0.0123 (5)0.0100 (5)−0.0006 (6)
C240.0400 (6)0.0573 (7)0.0493 (6)−0.0049 (5)0.0164 (5)−0.0005 (5)
C250.0375 (5)0.0457 (6)0.0433 (6)−0.0014 (4)0.0140 (4)−0.0015 (4)
C260.0366 (5)0.0616 (7)0.0503 (6)−0.0067 (5)0.0182 (5)−0.0129 (5)
C270.0420 (6)0.0619 (8)0.0728 (9)−0.0088 (5)0.0174 (6)−0.0258 (7)
C280.0680 (9)0.0530 (8)0.1008 (12)−0.0131 (7)0.0244 (9)−0.0193 (8)
C290.0922 (14)0.0532 (10)0.149 (2)−0.0084 (9)0.0251 (14)−0.0250 (12)
C300.0833 (14)0.0724 (14)0.198 (3)0.0004 (11)0.0401 (16)−0.0593 (17)
C310.0645 (10)0.1012 (16)0.146 (2)−0.0073 (10)0.0435 (12)−0.0675 (15)
C320.0436 (7)0.0881 (11)0.0850 (10)−0.0084 (7)0.0233 (7)−0.0417 (9)
C330.0408 (6)0.1188 (14)0.0589 (8)−0.0129 (7)0.0216 (6)−0.0340 (8)
C340.0558 (9)0.189 (3)0.0647 (11)−0.0137 (12)0.0324 (8)−0.0342 (14)
C350.0709 (12)0.229 (3)0.0525 (10)−0.0207 (16)0.0295 (9)0.0039 (15)
C360.0721 (11)0.162 (2)0.0577 (10)−0.0131 (13)0.0174 (8)0.0232 (12)
C370.0598 (8)0.1069 (13)0.0501 (7)−0.0048 (9)0.0163 (7)0.0044 (8)
C380.0412 (6)0.0888 (10)0.0435 (6)−0.0095 (6)0.0152 (5)−0.0142 (6)

Geometric parameters (Å, °)

N1—C401.320 (2)C15—C161.379 (2)
N1—C411.324 (2)C15—H150.984 (17)
C39—C401.363 (3)C16—C171.371 (2)
C39—C431.376 (3)C16—H160.98 (2)
C39—H390.94 (2)C17—C181.386 (2)
C40—H400.97 (2)C17—H170.976 (18)
C41—C421.375 (2)C18—C191.3994 (18)
C41—H410.96 (2)C18—H180.973 (18)
C42—C431.372 (2)C19—C201.5117 (15)
C42—H420.94 (2)C20—C211.3991 (17)
C43—C441.499 (2)C20—C251.4022 (16)
C44—H44C0.9600C21—C221.3799 (19)
C44—H44A0.9600C21—H211.041 (17)
C44—H44B0.9600C22—C231.376 (2)
O1—C131.4298 (13)C22—H220.967 (18)
O1—H10.91 (2)C23—C241.3820 (18)
O2—C261.4197 (14)C23—H230.990 (17)
O2—H20.93 (2)C24—C251.3952 (16)
C1—C21.3790 (19)C24—H240.991 (16)
C1—C61.3976 (18)C25—C261.5414 (16)
C1—C131.5338 (16)C26—C271.5256 (19)
C2—C31.396 (2)C26—C381.5278 (18)
C2—H2A1.016 (16)C27—C281.380 (2)
C3—C41.382 (3)C27—C321.401 (2)
C3—H30.995 (19)C28—C291.395 (3)
C4—C51.384 (3)C28—H281.01 (2)
C4—H40.994 (19)C29—C301.370 (4)
C5—C61.3895 (19)C29—H290.94 (3)
C5—H50.969 (18)C30—C311.380 (4)
C6—C71.470 (2)C30—H301.00 (3)
C7—C121.3910 (18)C31—C321.393 (3)
C7—C81.392 (2)C31—H310.98 (3)
C8—C91.382 (3)C32—C331.465 (3)
C8—H80.912 (18)C33—C381.394 (2)
C9—C101.378 (3)C33—C341.395 (3)
C9—H90.96 (2)C34—C351.369 (4)
C10—C111.389 (2)C34—H340.98 (3)
C10—H101.022 (19)C35—C361.379 (4)
C11—C121.3879 (19)C35—H350.94 (3)
C11—H111.013 (17)C36—C371.396 (2)
C12—C131.5306 (18)C36—H360.97 (3)
C13—C141.5313 (16)C37—C381.375 (2)
C14—C151.3976 (16)C37—H370.96 (2)
C14—C191.4028 (17)
C40—N1—C41117.11 (14)C17—C16—C15119.61 (13)
C40—C39—C43119.96 (16)C17—C16—H16121.6 (11)
C40—C39—H39117.5 (13)C15—C16—H16118.8 (11)
C43—C39—H39122.6 (13)C16—C17—C18119.44 (13)
N1—C40—C39123.38 (17)C16—C17—H17121.1 (11)
N1—C40—H40115.8 (14)C18—C17—H17119.4 (11)
C39—C40—H40120.8 (14)C17—C18—C19122.03 (14)
N1—C41—C42123.00 (16)C17—C18—H18119.8 (10)
N1—C41—H41118.2 (12)C19—C18—H18118.2 (10)
C42—C41—H41118.8 (12)C18—C19—C14118.24 (11)
C43—C42—C41119.75 (15)C18—C19—C20114.50 (11)
C43—C42—H42121.9 (12)C14—C19—C20126.81 (10)
C41—C42—H42118.4 (12)C21—C20—C25117.99 (10)
C42—C43—C39116.77 (14)C21—C20—C19114.61 (10)
C42—C43—C44121.44 (17)C25—C20—C19127.09 (10)
C39—C43—C44121.75 (17)C22—C21—C20122.47 (12)
C43—C44—H44C109.5C22—C21—H21121.2 (9)
C43—C44—H44A109.5C20—C21—H21116.3 (9)
H44C—C44—H44A109.5C23—C22—C21119.35 (12)
C43—C44—H44B109.5C23—C22—H22120.9 (10)
H44C—C44—H44B109.5C21—C22—H22119.7 (11)
H44A—C44—H44B109.5C22—C23—C24119.28 (12)
C13—O1—H1111.7 (12)C22—C23—H23121.3 (10)
C26—O2—H2103.6 (12)C24—C23—H23119.4 (10)
C2—C1—C6120.77 (12)C23—C24—C25122.23 (12)
C2—C1—C13128.91 (12)C23—C24—H24119.5 (9)
C6—C1—C13110.32 (11)C25—C24—H24118.3 (9)
C1—C2—C3118.44 (15)C24—C25—C20118.66 (10)
C1—C2—H2A120.9 (9)C24—C25—C26117.11 (10)
C3—C2—H2A120.7 (9)C20—C25—C26124.23 (10)
C4—C3—C2120.79 (15)O2—C26—C27108.68 (10)
C4—C3—H3119.8 (11)O2—C26—C38110.24 (10)
C2—C3—H3119.4 (11)C27—C26—C38101.36 (11)
C3—C4—C5120.92 (14)O2—C26—C25112.68 (9)
C3—C4—H4119.7 (11)C27—C26—C25112.39 (10)
C5—C4—H4119.2 (11)C38—C26—C25110.92 (10)
C4—C5—C6118.58 (15)C28—C27—C32120.77 (15)
C4—C5—H5120.2 (11)C28—C27—C26128.64 (14)
C6—C5—H5121.2 (11)C32—C27—C26110.59 (14)
C5—C6—C1120.48 (14)C27—C28—C29118.5 (2)
C5—C6—C7130.59 (13)C27—C28—H28117.9 (11)
C1—C6—C7108.91 (11)C29—C28—H28123.3 (11)
C12—C7—C8119.73 (14)C30—C29—C28121.0 (3)
C12—C7—C6108.53 (11)C30—C29—H29119.3 (16)
C8—C7—C6131.74 (14)C28—C29—H29119.5 (17)
C9—C8—C7118.96 (16)C29—C30—C31120.7 (2)
C9—C8—H8124.2 (11)C29—C30—H30125.0 (18)
C7—C8—H8116.8 (11)C31—C30—H30114.2 (18)
C10—C9—C8121.20 (15)C30—C31—C32119.3 (2)
C10—C9—H9120.1 (12)C30—C31—H31119.5 (15)
C8—C9—H9118.7 (12)C32—C31—H31121.2 (15)
C9—C10—C11120.46 (15)C31—C32—C27119.6 (2)
C9—C10—H10119.4 (11)C31—C32—C33131.87 (19)
C11—C10—H10120.1 (11)C27—C32—C33108.53 (13)
C12—C11—C10118.56 (14)C38—C33—C34119.2 (2)
C12—C11—H11119.5 (10)C38—C33—C32108.91 (13)
C10—C11—H11122.0 (10)C34—C33—C32131.87 (19)
C11—C12—C7121.08 (12)C35—C34—C33119.1 (2)
C11—C12—C13127.88 (12)C35—C34—H34118.7 (15)
C7—C12—C13110.90 (11)C33—C34—H34122.2 (15)
O1—C13—C14108.72 (9)C34—C35—C36121.6 (2)
O1—C13—C12107.48 (9)C34—C35—H35118.8 (16)
C14—C13—C12113.81 (9)C36—C35—H35119.6 (16)
O1—C13—C1112.84 (9)C35—C36—C37120.0 (2)
C14—C13—C1112.74 (9)C35—C36—H36120.9 (17)
C12—C13—C1101.07 (9)C37—C36—H36119.1 (17)
C15—C14—C19118.57 (11)C38—C37—C36118.5 (2)
C15—C14—C13116.81 (11)C38—C37—H37121.2 (12)
C19—C14—C13124.62 (10)C36—C37—H37120.2 (12)
C16—C15—C14122.08 (14)C37—C38—C33121.53 (15)
C16—C15—H15119.4 (9)C37—C38—C26127.86 (13)
C14—C15—H15118.5 (10)C33—C38—C26110.60 (14)
C41—N1—C40—C39−0.5 (3)C15—C14—C19—C20170.49 (11)
C43—C39—C40—N1−0.5 (3)C13—C14—C19—C20−8.82 (18)
C40—N1—C41—C421.7 (3)C18—C19—C20—C2181.73 (14)
N1—C41—C42—C43−1.8 (3)C14—C19—C20—C21−90.39 (15)
C41—C42—C43—C390.6 (2)C18—C19—C20—C25−91.68 (15)
C41—C42—C43—C44−176.98 (16)C14—C19—C20—C2596.20 (15)
C40—C39—C43—C420.4 (3)C25—C20—C21—C22−0.01 (19)
C40—C39—C43—C44178.04 (19)C19—C20—C21—C22−174.06 (12)
C6—C1—C2—C3−0.20 (19)C20—C21—C22—C231.4 (2)
C13—C1—C2—C3179.11 (12)C21—C22—C23—C24−1.4 (2)
C1—C2—C3—C40.6 (2)C22—C23—C24—C250.1 (2)
C2—C3—C4—C5−0.1 (2)C23—C24—C25—C201.29 (18)
C3—C4—C5—C6−0.9 (2)C23—C24—C25—C26−178.23 (12)
C4—C5—C6—C11.31 (19)C21—C20—C25—C24−1.31 (17)
C4—C5—C6—C7−176.71 (13)C19—C20—C25—C24171.90 (11)
C2—C1—C6—C5−0.77 (18)C21—C20—C25—C26178.17 (11)
C13—C1—C6—C5179.79 (11)C19—C20—C25—C26−8.61 (18)
C2—C1—C6—C7177.64 (11)C24—C25—C26—O2159.13 (11)
C13—C1—C6—C7−1.79 (13)C20—C25—C26—O2−20.36 (17)
C5—C6—C7—C12176.47 (13)C24—C25—C26—C27−77.67 (14)
C1—C6—C7—C12−1.72 (14)C20—C25—C26—C27102.84 (13)
C5—C6—C7—C8−4.2 (2)C24—C25—C26—C3835.00 (15)
C1—C6—C7—C8177.62 (15)C20—C25—C26—C38−144.49 (11)
C12—C7—C8—C9−0.6 (2)O2—C26—C27—C2862.88 (17)
C6—C7—C8—C9−179.85 (14)C38—C26—C27—C28179.01 (14)
C7—C8—C9—C10−0.1 (3)C25—C26—C27—C28−62.53 (17)
C8—C9—C10—C110.3 (3)O2—C26—C27—C32−116.98 (12)
C9—C10—C11—C120.2 (2)C38—C26—C27—C32−0.86 (13)
C10—C11—C12—C7−0.9 (2)C25—C26—C27—C32117.61 (12)
C10—C11—C12—C13174.32 (13)C32—C27—C28—C29−1.1 (2)
C8—C7—C12—C111.06 (19)C26—C27—C28—C29179.03 (14)
C6—C7—C12—C11−179.51 (11)C27—C28—C29—C301.3 (3)
C8—C7—C12—C13−174.87 (12)C28—C29—C30—C31−0.3 (3)
C6—C7—C12—C134.57 (13)C29—C30—C31—C32−0.9 (3)
C11—C12—C13—O1−62.44 (15)C30—C31—C32—C271.0 (3)
C7—C12—C13—O1113.13 (11)C30—C31—C32—C33−179.83 (18)
C11—C12—C13—C1458.00 (16)C28—C27—C32—C310.0 (2)
C7—C12—C13—C14−126.43 (11)C26—C27—C32—C31179.84 (13)
C11—C12—C13—C1179.12 (12)C28—C27—C32—C33−179.35 (13)
C7—C12—C13—C1−5.31 (12)C26—C27—C32—C330.52 (15)
C2—C1—C13—O170.32 (16)C31—C32—C33—C38−179.12 (16)
C6—C1—C13—O1−110.30 (11)C27—C32—C33—C380.08 (16)
C2—C1—C13—C14−53.32 (16)C31—C32—C33—C340.1 (3)
C6—C1—C13—C14126.06 (11)C27—C32—C33—C34179.33 (16)
C2—C1—C13—C12−175.19 (12)C38—C33—C34—C350.9 (3)
C6—C1—C13—C124.19 (12)C32—C33—C34—C35−178.31 (17)
O1—C13—C14—C15160.77 (11)C33—C34—C35—C36−0.2 (3)
C12—C13—C14—C1541.03 (15)C34—C35—C36—C37−0.3 (3)
C1—C13—C14—C15−73.33 (14)C35—C36—C37—C380.0 (3)
O1—C13—C14—C19−19.91 (15)C36—C37—C38—C330.7 (2)
C12—C13—C14—C19−139.65 (11)C36—C37—C38—C26179.36 (14)
C1—C13—C14—C19105.99 (13)C34—C33—C38—C37−1.2 (2)
C19—C14—C15—C161.5 (2)C32—C33—C38—C37178.19 (13)
C13—C14—C15—C16−179.09 (13)C34—C33—C38—C26179.98 (13)
C14—C15—C16—C170.0 (2)C32—C33—C38—C26−0.66 (15)
C15—C16—C17—C18−1.7 (3)O2—C26—C38—C37−62.87 (17)
C16—C17—C18—C191.9 (2)C27—C26—C38—C37−177.84 (14)
C17—C18—C19—C14−0.3 (2)C25—C26—C38—C3762.64 (17)
C17—C18—C19—C20−173.15 (13)O2—C26—C38—C33115.88 (12)
C15—C14—C19—C18−1.37 (17)C27—C26—C38—C330.91 (13)
C13—C14—C19—C18179.32 (11)C25—C26—C38—C33−118.61 (12)

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
O2—H2···O10.93 (2)1.90 (2)2.7943 (15)161.7 (18)
O1—H1···N10.91 (2)1.79 (2)2.6913 (16)168.7 (18)

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: ZL2280).

References

  • Barbour, L. J., Bourne, S. A., Caira, M. R., Nassimbeni, L. R., Weber, E., Skobridis, E. K. & Wierig, A. (1993). Supramol. Chem.1, 331–336.
  • Ibragimov, B. T., Beketov, K. M., Weber, E., Seidel, J., Sumarna, O., Makhkamov, K. K. & Kohnke, K. (2001). J. Phys. Org. Chem.14, 697–703.
  • Izotova, L., Ashurov, J., Ibragimov, B. & Weber, E. (2008). Acta Cryst. E64, o1627. [PMC free article] [PubMed]
  • Macrae, C. F., Edgington, P. R., McCabe, P., Pidcock, E., Shields, G. P., Taylor, R., Towler, M. & van de Streek, J. (2006). J. Appl. Cryst.39, 453–457.
  • Oxford Diffraction. (2007). CrysAlis PRO Oxford Diffraction Ltd, Abingdon, England.
  • Sardone, N. (1996). Private communication (refcode NABNIN). CCDC, Union Road, Cambridge, England.
  • Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [PubMed]
  • Siemens (1994). XP. Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA.
  • Weber, E. (1996). Shape and symmetry in the design of new hosts, in Comprehensive Supramolecular Chemistry, Vol. 6, Solid State Supramolecular Chemistry: Crystal Engineering, edited by D. D. MacNicol, E. Toda & R. Bishop. pp. 535–592. Oxford: Pergamon.
  • Weber, E., Skobridis, K., Wierig, A., Stathi, S., Nassimbeni, L. R. & Niven, M. L. (1993). Angew. Chem. Int. Ed. Engl.32, 606–608.

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