Di-μ-azido-bis­({N′-[1-(2-pyrid­yl-κN)ethyl­idene]acetohydrazidato-κ2
               N′,O}dicopper(II))

doi:10.1107/S1600536810034860

Acta Crystallogr Sect E Struct Rep Online. 2010 October 1; 66(Pt 10): m1271.

Published online 2010 September 18. doi: 10.1107/S1600536810034860

PMCID: PMC2983124

Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene]acetohydrazidato-κ² N′,O}dicopper(II))

Amitabha Datta,^a Kuheli Das,^a Yan-Ming Jhou,^a Jui-Hsien Huang,^a and Hon Man Lee^a^*

^aNational Changhua University of Education, Department of Chemistry, Changhua, Taiwan, 50058

Correspondence e-mail: leehm/at/cc.ncue.edu.tw

Received August 24, 2010; Accepted August 30, 2010.

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Abstract

The dimeric title compound, [Cu₂(C₉H₁₀N₃O)₂(N₃)₂], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu (...)

Cu distance is 3.238 (1) Å. Non-classical intermolecular C—H (...)

N hydrogen bonds link the dimers into chains along the c axis.

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