PMCCPMCCPMCC

Search tips
Search criteria 

Advanced

 
Logo of actaeInternational Union of Crystallographysearchopen accessarticle submissionjournal home pagethis article
 
Acta Crystallogr Sect E Struct Rep Online. 2010 February 1; 66(Pt 2): m218.
Published online 2010 January 30. doi:  10.1107/S1600536810001790
PMCID: PMC2979948

[1,1′-Bis(dicyclo­hexyl­phosphino)cobalto­cenium-κ2 P,P′]chlorido(η5-cyclo­penta­dien­yl)ruthenium(II) hexa­fluorido­phosphate

Abstract

In the title structure, [CoRu(C5H5)(C17H26P)2Cl]PF6, the RuII atom is bonded to a cyclo­penta­dienyl ring, a Cl atom and two P atoms of the chelating 1,1′-bis­(dicyclo­hexyl­phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF6 counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898 (7):0.102 (7). The components are linked by C—H(...)F and C—H(...)Cl hydrogen bonds.

Related literature

For synthesis and crystal structure of the related compound [Ru(η5-C5H5(dppc)]PF6 (dppc = 1,1′-bis­(diphenyl­phos­phino)cobaltocenium), see: Wu et al. (2006 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-66-0m218-scheme1.jpg

Experimental

Crystal data

  • [CoRu(C5H5)(C17H26P)2Cl]PF6
  • M r = 928.21
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-66-0m218-efi1.jpg
  • a = 14.0095 (16) Å
  • b = 16.9051 (19) Å
  • c = 17.987 (2) Å
  • β = 110.107 (2)°
  • V = 4000.3 (8) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 1.04 mm−1
  • T = 292 K
  • 0.30 × 0.20 × 0.20 mm

Data collection

  • Bruker SMART CCD area-detector diffractometer
  • Absorption correction: multi-scan (SADABS; Sheldrick, 2004 [triangle]) T min = 0.747, T max = 0.820
  • 45838 measured reflections
  • 9503 independent reflections
  • 7178 reflections with I > 2σ(I)
  • R int = 0.139

Refinement

  • R[F 2 > 2σ(F 2)] = 0.046
  • wR(F 2) = 0.108
  • S = 0.96
  • 9503 reflections
  • 489 parameters
  • H-atom parameters constrained
  • Δρmax = 0.75 e Å−3
  • Δρmin = −0.54 e Å−3

Data collection: SMART (Bruker, 2001 [triangle]); cell refinement: SAINT (Bruker, 2001 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: SHELXTL (Sheldrick, 2008 [triangle]); software used to prepare material for publication: SHELXTL.

Table 1
Selected geometric parameters (Å, °)
Table 2
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810001790/wm2296sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810001790/wm2296Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The author acknowledges financial support from the National Natural Science Foundation of China (Nos. 20572029, 20772039).

supplementary crystallographic information

Comment

The molecular structure of [Ru(η5-C5H5)(di-cypc)Cl][PF6] (di-cypc is 1,1'-bis(dicyclohexylphosphino) cobaltocenium), (I), is shown in Fig. 1. The configuration about the Rh(II) atom is similar to that of the related compound [Ru(η5-C5H5(dppc)][PF6] (dppc is 1,1'-bis(diphenylphosphino)cobaltocenium (Wu et al., 2006). The Ru—P distances of 2.3297 (7) and 2.3282 (8) Å are somewhat longer than those in the dppc analogue (2.2656 (11) and 2.2695 (11) Å, respectively, which is due to the bulky cyclohexyl ligand. On the other hand, this results in a smaller P—Ru—P chelate angle of 97.67 (3)° in (I) title compound compared with 99.70 (4)° in [Ru(η5-C5H5(dppc)][PF6]. The Cp rings are symmetrically disposed about the Co atom and the dihedral ange between the two Cp rings is 3.36 (17)° (4.1 (1)° in [Ru(η5-C5H5(dppc)][PF6]).

Molecules are linked by C—H···F and C—H···Cl hydrogen bonds, as shown in Fig. 2.

Experimental

The synthetic method has been described earlier (Wu et al., 2006). A mixture of [Ru(η5-C5H5)(PPh3)2Cl] (0.544 g, 0.75 mmol) and [di-cypc][PF6] (0.575 g, 0.8 mmol, slight excess) was refluxed in CH2Cl2 (30 ml) for 24 h. The solution was evaporated, and the residue was chromatographed on alumina by elution with CH2Cl2 to give the title compound as a green solid (0.619, 63%). Crystals appropriate for data collection were obtained by slow evaporation from dichloromethane and hexane solution at room temperature.

Refinement

All H atoms were placed in geometrically idealized positions and constrained to ride on their parent atoms with C—H = 0.93 Å or 0.97 Å with Uiso(H) = 1.2Ueq(C). The PF- anion is disordered over two positons. The final occupancies were refined to a ratio of 0.898 (7):0.102 (7) for the major and minor components, respectively, using also the DFIX commant to constrain the P—F distances.

Figures

Fig. 1.
The molecular structure of (I), with atom labels and 30% probability displacement ellipsoids for all non-H atoms. H atoms are omitted for clarity. For the PF6- anion only one orientation is shown.
Fig. 2.
The packing of (I), showing the molecules connected by C—H···F and C—H···Cl hydrogen bonds (dashed lines).

Crystal data

[CoRu(C5H5)(C17H26P)2Cl]PF6F(000) = 1912
Mr = 928.21Dx = 1.541 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 6151 reflections
a = 14.0095 (16) Åθ = 2.3–25.7°
b = 16.9051 (19) ŵ = 1.03 mm1
c = 17.987 (2) ÅT = 292 K
β = 110.107 (2)°Block, black
V = 4000.3 (8) Å30.30 × 0.20 × 0.20 mm
Z = 4

Data collection

Bruker SMART CCD area-detector diffractometer9503 independent reflections
Radiation source: fine-focus sealed tube7178 reflections with I > 2σ(I)
graphiteRint = 0.139
[var phi] and ω scansθmax = 28.0°, θmin = 1.6°
Absorption correction: multi-scan (SADABS; Sheldrick, 2004)h = −18→18
Tmin = 0.747, Tmax = 0.820k = −21→22
45838 measured reflectionsl = −23→23

Refinement

Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.046Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.108H-atom parameters constrained
S = 0.96w = 1/[σ2(Fo2) + (0.0494P)2] where P = (Fo2 + 2Fc2)/3
9503 reflections(Δ/σ)max < 0.001
489 parametersΔρmax = 0.75 e Å3
0 restraintsΔρmin = −0.54 e Å3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/UeqOcc. (<1)
Ru10.556184 (17)0.318279 (13)0.174161 (14)0.03634 (8)
Co10.27620 (3)0.44068 (2)0.04044 (2)0.03548 (10)
Cl10.57558 (6)0.42143 (4)0.08576 (5)0.04739 (19)
P10.46046 (5)0.40312 (4)0.22280 (4)0.03324 (16)
P20.42263 (6)0.26549 (4)0.06948 (4)0.03325 (16)
P30.98214 (7)0.37054 (6)0.13022 (6)0.0576 (2)
F11.07889 (19)0.40569 (15)0.19711 (15)0.0894 (7)
F20.8878 (2)0.3330 (2)0.06407 (19)0.1320 (12)
F30.9724 (3)0.3074 (2)0.18898 (18)0.1047 (16)0.898 (7)
F40.9097 (3)0.4248 (3)0.1547 (4)0.170 (2)0.898 (7)
F50.9920 (4)0.4375 (4)0.0729 (3)0.176 (3)0.898 (7)
F61.0572 (3)0.3183 (3)0.1041 (3)0.138 (2)0.898 (7)
F3'0.9364 (19)0.3730 (18)0.1922 (14)0.074 (9)*0.102 (7)
F4'0.938 (2)0.4442 (15)0.1044 (16)0.068 (8)*0.102 (7)
F5'1.024 (2)0.3797 (19)0.0653 (17)0.077 (9)*0.102 (7)
F6'1.028 (2)0.2862 (15)0.1421 (18)0.077 (9)*0.102 (7)
C10.2150 (2)0.33276 (15)0.00525 (18)0.0415 (7)
H10.18640.29960.03310.050*
C20.1622 (3)0.39175 (18)−0.04980 (19)0.0512 (8)
H20.09340.4038−0.06430.061*
C30.2331 (3)0.42879 (18)−0.07845 (18)0.0531 (8)
H30.21890.4692−0.11580.064*
C40.3289 (3)0.39428 (16)−0.04090 (17)0.0434 (7)
H40.38880.4092−0.04850.052*
C50.3199 (2)0.33255 (15)0.01089 (16)0.0354 (6)
C60.2576 (2)0.47172 (16)0.14378 (18)0.0412 (7)
H60.22420.44290.17150.049*
C70.2126 (3)0.52909 (17)0.08465 (19)0.0479 (8)
H70.14460.54410.06670.058*
C80.2881 (2)0.55932 (16)0.05777 (19)0.0465 (7)
H80.27880.59790.01910.056*
C90.3811 (2)0.52080 (15)0.09986 (18)0.0407 (7)
H90.44330.52990.09350.049*
C100.3627 (2)0.46562 (15)0.15355 (16)0.0349 (6)
C110.3404 (2)0.18618 (15)0.08930 (17)0.0361 (6)
H110.2950.21450.11140.043*
C120.3969 (2)0.12615 (16)0.15388 (19)0.0446 (7)
H12A0.44120.09390.13510.054*
H12B0.43880.15430.20070.054*
C130.3222 (3)0.07303 (19)0.1752 (2)0.0594 (9)
H13A0.35960.03340.21300.071*
H13B0.28380.10460.20010.071*
C140.2496 (3)0.03233 (18)0.1032 (2)0.0624 (10)
H14A0.20060.00200.11860.075*
H14B0.2871−0.00420.08200.075*
C150.1937 (3)0.09141 (19)0.0395 (2)0.0589 (9)
H15A0.15060.12450.05870.071*
H15B0.15060.0632−0.00690.071*
C160.2687 (3)0.14333 (17)0.01675 (19)0.0482 (7)
H16A0.30800.1107−0.00650.058*
H16B0.23150.1819−0.02250.058*
C170.4554 (3)0.22163 (18)−0.0142 (2)0.0495 (8)
H170.3900.210−0.0560.059*
C180.5113 (3)0.14241 (19)0.0066 (2)0.0643 (10)
H18A0.57860.15120.04510.077*
H18B0.47460.10790.03050.077*
C190.5209 (4)0.1021 (2)−0.0667 (3)0.0865 (14)
H19A0.55830.0530−0.05120.104*
H19B0.45370.0895−0.10340.104*
C200.5743 (4)0.1540 (2)−0.1068 (3)0.0778 (12)
H20A0.57380.1289−0.15550.093*
H20B0.64450.1605−0.07290.093*
C210.5242 (4)0.2340 (2)−0.1256 (2)0.0764 (12)
H21A0.45730.2281−0.16550.092*
H21B0.56420.2678−0.14720.092*
C220.5138 (3)0.2734 (2)−0.0520 (2)0.0629 (10)
H22A0.58090.2838−0.01400.075*
H22B0.47900.3236−0.06680.075*
C230.5363 (2)0.48242 (18)0.2890 (2)0.0483 (8)
H230.5730.45460.3380.058*
C240.6185 (3)0.5190 (2)0.2663 (3)0.0739 (12)
H24A0.58920.55410.22150.089*
H24B0.65640.47810.25060.089*
C250.6908 (3)0.5662 (2)0.3366 (3)0.0805 (13)
H25A0.72400.53040.37990.097*
H25B0.74290.59150.32070.097*
C260.6322 (4)0.6288 (2)0.3643 (3)0.0892 (14)
H26A0.67720.65220.41300.107*
H26B0.61160.67040.32480.107*
C270.5423 (4)0.5986 (2)0.3780 (3)0.0846 (14)
H27A0.50150.64310.38360.101*
H27B0.56380.56980.42770.101*
C280.4770 (3)0.5453 (2)0.3138 (2)0.0571 (9)
H28A0.44050.57710.26800.068*
H28B0.42710.51980.33220.068*
C290.3897 (2)0.36368 (16)0.28573 (16)0.0372 (6)
H290.3460.40660.29250.045*
C300.4575 (3)0.3384 (2)0.36804 (19)0.0602 (9)
H30A0.49740.38340.39500.072*
H30B0.50420.29800.36330.072*
C310.3972 (3)0.3061 (2)0.4179 (2)0.0667 (11)
H31A0.44390.28730.46820.080*
H31B0.35660.34820.42860.080*
C320.3283 (3)0.2393 (2)0.3758 (2)0.0642 (10)
H32A0.36930.19480.37050.077*
H32B0.28790.22210.40710.077*
C330.2587 (3)0.26442 (19)0.2949 (2)0.0537 (8)
H33A0.21320.30550.30040.064*
H33B0.21770.21970.26830.064*
C340.3193 (2)0.29517 (16)0.24557 (17)0.0389 (6)
H34A0.27270.31280.19470.047*
H34B0.35970.25240.23600.047*
C350.6341 (3)0.2047 (2)0.2061 (3)0.0632 (10)
H350.60570.15740.18230.076*
C360.6228 (3)0.2370 (2)0.2737 (2)0.0668 (11)
H360.58550.21560.30280.080*
C370.6792 (3)0.3091 (2)0.2901 (2)0.0687 (11)
H370.68560.34310.33220.082*
C380.7228 (3)0.3197 (2)0.2324 (3)0.0691 (11)
H380.76330.36220.22920.083*
C390.6959 (3)0.2555 (2)0.1797 (3)0.0635 (10)
H390.71520.24780.13560.076*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Ru10.03591 (14)0.03186 (13)0.04509 (15)0.00501 (9)0.01884 (10)0.00734 (9)
Co10.0434 (2)0.02687 (19)0.0391 (2)0.00810 (15)0.01801 (17)0.00400 (15)
Cl10.0557 (5)0.0404 (4)0.0578 (5)0.0007 (3)0.0344 (4)0.0092 (3)
P10.0381 (4)0.0284 (3)0.0365 (4)−0.0033 (3)0.0171 (3)0.0012 (3)
P20.0430 (4)0.0250 (3)0.0385 (4)0.0069 (3)0.0227 (3)0.0045 (3)
P30.0459 (5)0.0635 (6)0.0611 (6)0.0046 (4)0.0155 (4)0.0177 (5)
F10.0789 (16)0.0942 (18)0.0911 (17)−0.0274 (13)0.0240 (14)−0.0058 (14)
F20.092 (2)0.179 (3)0.094 (2)−0.032 (2)−0.0087 (17)−0.006 (2)
F30.127 (3)0.095 (3)0.082 (2)−0.043 (2)0.0239 (19)0.0314 (17)
F40.117 (3)0.124 (3)0.292 (7)0.051 (3)0.097 (4)−0.012 (4)
F50.150 (4)0.190 (5)0.166 (4)−0.024 (4)0.026 (3)0.126 (4)
F60.111 (3)0.191 (5)0.128 (4)0.029 (3)0.063 (3)−0.047 (3)
C10.0474 (17)0.0326 (14)0.0459 (17)0.0037 (12)0.0176 (14)−0.0023 (12)
C20.0497 (19)0.0461 (17)0.0472 (18)0.0119 (14)0.0029 (15)−0.0088 (14)
C30.079 (2)0.0419 (17)0.0366 (17)0.0149 (16)0.0174 (16)0.0053 (13)
C40.062 (2)0.0330 (14)0.0426 (17)0.0089 (13)0.0272 (15)0.0039 (12)
C50.0457 (16)0.0281 (13)0.0347 (14)0.0060 (11)0.0167 (12)0.0006 (11)
C60.0470 (17)0.0377 (15)0.0459 (17)0.0031 (13)0.0247 (14)−0.0019 (13)
C70.0519 (19)0.0376 (15)0.0567 (19)0.0181 (14)0.0216 (16)−0.0027 (14)
C80.060 (2)0.0259 (14)0.0559 (19)0.0090 (13)0.0237 (16)0.0048 (13)
C90.0514 (18)0.0282 (13)0.0493 (17)−0.0018 (12)0.0259 (15)0.0002 (12)
C100.0444 (16)0.0262 (12)0.0386 (15)0.0014 (11)0.0201 (13)−0.0026 (11)
C110.0468 (17)0.0281 (13)0.0395 (15)0.0020 (12)0.0226 (13)0.0008 (11)
C120.0573 (19)0.0320 (14)0.0517 (18)0.0042 (13)0.0280 (15)0.0091 (13)
C130.074 (2)0.0442 (18)0.073 (2)0.0086 (17)0.043 (2)0.0217 (17)
C140.074 (2)0.0316 (16)0.097 (3)−0.0104 (16)0.049 (2)−0.0031 (17)
C150.060 (2)0.0438 (18)0.077 (2)−0.0094 (16)0.0289 (19)−0.0124 (17)
C160.061 (2)0.0358 (15)0.0510 (18)−0.0004 (14)0.0235 (16)−0.0063 (14)
C170.071 (2)0.0437 (17)0.0494 (19)0.0183 (16)0.0405 (17)0.0063 (15)
C180.098 (3)0.0478 (19)0.071 (2)0.0283 (19)0.059 (2)0.0128 (17)
C190.127 (4)0.051 (2)0.113 (4)0.020 (2)0.081 (3)−0.005 (2)
C200.111 (4)0.070 (2)0.079 (3)0.018 (2)0.068 (3)−0.009 (2)
C210.117 (4)0.073 (2)0.064 (2)0.024 (2)0.063 (3)0.011 (2)
C220.080 (3)0.055 (2)0.072 (2)0.0091 (18)0.050 (2)0.0057 (18)
C230.0467 (18)0.0396 (16)0.059 (2)−0.0109 (14)0.0180 (16)−0.0092 (15)
C240.076 (3)0.055 (2)0.107 (3)−0.0203 (19)0.052 (3)−0.017 (2)
C250.066 (3)0.061 (2)0.119 (4)−0.035 (2)0.037 (3)−0.025 (2)
C260.088 (3)0.063 (2)0.125 (4)−0.035 (2)0.049 (3)−0.040 (3)
C270.093 (3)0.064 (2)0.107 (4)−0.027 (2)0.048 (3)−0.041 (2)
C280.061 (2)0.0498 (19)0.068 (2)−0.0166 (16)0.0323 (18)−0.0213 (17)
C290.0514 (17)0.0310 (14)0.0347 (15)−0.0052 (12)0.0218 (13)−0.0013 (11)
C300.074 (2)0.064 (2)0.0385 (18)−0.0202 (18)0.0139 (17)0.0041 (16)
C310.102 (3)0.060 (2)0.043 (2)−0.009 (2)0.032 (2)0.0099 (16)
C320.093 (3)0.0506 (19)0.061 (2)−0.0102 (19)0.041 (2)0.0104 (17)
C330.064 (2)0.0480 (18)0.061 (2)−0.0110 (15)0.0362 (18)0.0027 (15)
C340.0469 (17)0.0355 (14)0.0409 (16)−0.0045 (12)0.0236 (14)−0.0028 (12)
C350.053 (2)0.0452 (18)0.090 (3)0.0214 (16)0.024 (2)0.0171 (19)
C360.056 (2)0.071 (2)0.071 (3)0.0219 (19)0.0193 (19)0.032 (2)
C370.053 (2)0.079 (3)0.060 (2)0.0167 (19)0.0004 (19)0.008 (2)
C380.0350 (18)0.073 (3)0.093 (3)0.0050 (16)0.0141 (19)0.020 (2)
C390.050 (2)0.063 (2)0.083 (3)0.0228 (17)0.0287 (19)0.016 (2)

Geometric parameters (Å, °)

Ru1—C352.186 (3)C15—H15A0.9700
Ru1—C362.195 (3)C15—H15B0.9700
Ru1—C392.199 (3)C16—H16A0.9700
Ru1—C382.206 (3)C16—H16B0.9700
Ru1—C372.208 (4)C17—C221.509 (5)
Ru1—P22.3282 (8)C17—C181.531 (4)
Ru1—P12.3297 (7)C17—H170.97
Ru1—Cl12.4372 (7)C18—C191.531 (5)
Co1—C42.011 (3)C18—H18A0.9700
Co1—C92.014 (3)C18—H18B0.9700
Co1—C22.021 (3)C19—C201.490 (6)
Co1—C32.022 (3)C19—H19A0.9700
Co1—C12.023 (3)C19—H19B0.9700
Co1—C102.023 (3)C20—C211.508 (5)
Co1—C82.028 (3)C20—H20A0.9700
Co1—C62.033 (3)C20—H20B0.9700
Co1—C72.036 (3)C21—C221.532 (5)
Co1—C52.055 (2)C21—H21A0.9700
P1—C101.836 (3)C21—H21B0.9700
P1—C231.864 (3)C22—H22A0.9700
P1—C291.866 (3)C22—H22B0.9700
P2—C51.851 (3)C23—C241.484 (5)
P2—C171.872 (3)C23—C281.507 (5)
P2—C111.880 (3)C23—H230.97
P3—F4'1.39 (2)C24—C251.543 (5)
P3—F3'1.47 (2)C24—H24A0.9700
P3—F5'1.48 (3)C24—H24B0.9700
P3—F31.541 (3)C25—C261.525 (6)
P3—F41.541 (4)C25—H25A0.9700
P3—F6'1.55 (3)C25—H25B0.9700
P3—F61.564 (4)C26—C271.456 (6)
P3—F51.568 (4)C26—H26A0.9700
P3—F21.576 (3)C26—H26B0.9700
P3—F11.586 (3)C27—C281.503 (5)
C1—C21.421 (4)C27—H27A0.9700
C1—C51.437 (4)C27—H27B0.9700
C1—H10.9300C28—H28A0.9700
C2—C31.413 (5)C28—H28B0.9700
C2—H20.9300C29—C301.520 (4)
C3—C41.405 (4)C29—C341.532 (4)
C3—H30.9300C29—H290.97
C4—C51.433 (4)C30—C311.529 (5)
C4—H40.9300C30—H30A0.9700
C6—C71.417 (4)C30—H30B0.9700
C6—C101.426 (4)C31—C321.510 (5)
C6—H60.9300C31—H31A0.9700
C7—C81.401 (4)C31—H31B0.9700
C7—H70.9300C32—C331.507 (5)
C8—C91.420 (4)C32—H32A0.9700
C8—H80.9300C32—H32B0.9700
C9—C101.428 (4)C33—C341.515 (4)
C9—H90.9300C33—H33A0.9700
C11—C161.528 (4)C33—H33B0.9700
C11—C121.541 (4)C34—H34A0.9700
C11—H110.97C34—H34B0.9700
C12—C131.525 (4)C35—C361.390 (5)
C12—H12A0.9700C35—C391.413 (5)
C12—H12B0.9700C35—H350.9300
C13—C141.509 (5)C36—C371.428 (5)
C13—H13A0.9700C36—H360.9300
C13—H13B0.9700C37—C381.385 (6)
C14—C151.519 (5)C37—H370.9300
C14—H14A0.9700C38—C391.405 (5)
C14—H14B0.9700C38—H380.9300
C15—C161.529 (4)C39—H390.9300
C35—Ru1—C3637.00 (14)C10—C9—H9125.8
C35—Ru1—C3937.60 (13)Co1—C9—H9126.2
C36—Ru1—C3962.51 (15)C6—C10—C9106.7 (2)
C35—Ru1—C3862.18 (15)C6—C10—P1128.5 (2)
C36—Ru1—C3862.32 (15)C9—C10—P1124.7 (2)
C39—Ru1—C3837.20 (14)C6—C10—Co169.78 (17)
C35—Ru1—C3762.14 (15)C9—C10—Co168.95 (16)
C36—Ru1—C3737.85 (14)P1—C10—Co1127.72 (13)
C39—Ru1—C3761.93 (16)C16—C11—C12110.4 (2)
C38—Ru1—C3736.56 (15)C16—C11—P2116.2 (2)
C35—Ru1—P293.77 (11)C12—C11—P2115.0 (2)
C36—Ru1—P2114.70 (11)C16—C11—H11104.6
C39—Ru1—P2107.88 (11)C12—C11—H11104.6
C38—Ru1—P2144.42 (12)P2—C11—H11104.6
C37—Ru1—P2152.44 (11)C13—C12—C11110.9 (3)
C35—Ru1—P1137.89 (11)C13—C12—H12A109.4
C36—Ru1—P1102.56 (11)C11—C12—H12A109.4
C39—Ru1—P1153.98 (12)C13—C12—H12B109.4
C38—Ru1—P1117.82 (12)C11—C12—H12B109.4
C37—Ru1—P192.97 (12)H12A—C12—H12B108.0
P2—Ru1—P197.67 (3)C14—C13—C12111.8 (3)
C35—Ru1—Cl1129.99 (11)C14—C13—H13A109.2
C36—Ru1—Cl1150.32 (11)C12—C13—H13A109.2
C39—Ru1—Cl194.46 (10)C14—C13—H13B109.2
C38—Ru1—Cl188.00 (11)C12—C13—H13B109.2
C37—Ru1—Cl1116.14 (12)H13A—C13—H13B107.9
P2—Ru1—Cl189.17 (3)C13—C14—C15111.6 (3)
P1—Ru1—Cl190.70 (3)C13—C14—H14A109.3
C4—Co1—C9105.38 (13)C15—C14—H14A109.3
C4—Co1—C269.05 (14)C13—C14—H14B109.3
C9—Co1—C2158.76 (13)C15—C14—H14B109.3
C4—Co1—C340.76 (13)H14A—C14—H14B108.0
C9—Co1—C3121.73 (13)C14—C15—C16110.9 (3)
C2—Co1—C340.91 (14)C14—C15—H15A109.5
C4—Co1—C169.05 (12)C16—C15—H15A109.5
C9—Co1—C1157.84 (12)C14—C15—H15B109.5
C2—Co1—C141.14 (12)C16—C15—H15B109.5
C3—Co1—C168.85 (13)H15A—C15—H15B108.1
C4—Co1—C10124.76 (12)C11—C16—C15110.7 (3)
C9—Co1—C1041.43 (11)C11—C16—H16A109.5
C2—Co1—C10158.10 (13)C15—C16—H16A109.5
C3—Co1—C10160.39 (14)C11—C16—H16B109.5
C1—Co1—C10123.08 (11)C15—C16—H16B109.5
C4—Co1—C8117.80 (12)H16A—C16—H16B108.1
C9—Co1—C841.14 (12)C22—C17—C18107.9 (3)
C2—Co1—C8121.91 (13)C22—C17—P2117.0 (2)
C3—Co1—C8103.87 (13)C18—C17—P2113.3 (2)
C1—Co1—C8160.71 (12)C22—C17—H17106)
C10—Co1—C869.52 (12)C18—C17—H17106
C4—Co1—C6163.88 (12)P2—C17—H17106
C9—Co1—C668.93 (12)C19—C18—C17111.5 (3)
C2—Co1—C6121.71 (14)C19—C18—H18A109.3
C3—Co1—C6155.12 (13)C17—C18—H18A109.3
C1—Co1—C6110.20 (12)C19—C18—H18B109.3
C10—Co1—C641.18 (11)C17—C18—H18B109.3
C8—Co1—C668.50 (12)H18A—C18—H18B108.0
C4—Co1—C7152.84 (12)C20—C19—C18111.3 (3)
C9—Co1—C768.67 (13)C20—C19—H19A109.4
C2—Co1—C7106.45 (13)C18—C19—H19A109.4
C3—Co1—C7118.31 (13)C20—C19—H19B109.4
C1—Co1—C7126.10 (13)C18—C19—H19B109.4
C10—Co1—C769.24 (12)H19A—C19—H19B108.0
C8—Co1—C740.34 (12)C19—C20—C21111.3 (3)
C6—Co1—C740.76 (12)C19—C20—H20A109.4
C4—Co1—C541.26 (11)C21—C20—H20A109.4
C9—Co1—C5120.52 (12)C19—C20—H20B109.4
C2—Co1—C569.61 (12)C21—C20—H20B109.4
C3—Co1—C569.22 (12)H20A—C20—H20B108.0
C1—Co1—C541.27 (11)C20—C21—C22111.8 (3)
C10—Co1—C5108.48 (11)C20—C21—H21A109.2
C8—Co1—C5154.65 (12)C22—C21—H21A109.3
C6—Co1—C5127.55 (11)C20—C21—H21B109.2
C7—Co1—C5164.39 (12)C22—C21—H21B109.2
C10—P1—C2398.49 (14)H21A—C21—H21B107.9
C10—P1—C29100.92 (13)C17—C22—C21111.4 (3)
C23—P1—C29100.04 (14)C17—C22—H22A109.4
C10—P1—Ru1119.39 (9)C21—C22—H22A109.4
C23—P1—Ru1114.06 (11)C17—C22—H22B109.4
C29—P1—Ru1120.17 (9)C21—C22—H22B109.4
C5—P2—C1798.20 (14)H22A—C22—H22B108.0
C5—P2—C1197.89 (13)C24—C23—C28110.3 (3)
C17—P2—C11101.89 (14)C24—C23—P1116.7 (3)
C5—P2—Ru1118.51 (9)C28—C23—P1116.4 (2)
C17—P2—Ru1116.82 (13)C24—C23—H23104
C11—P2—Ru1119.63 (10)C28—C23—H23104
F4'—P3—F3'88.3 (17)P1—C23—H23103.8
F4'—P3—F5'83.8 (17)C23—C24—C25110.0 (3)
F3'—P3—F5'172.0 (17)C23—C24—H24A109.7
F4'—P3—F3135.6 (14)C25—C24—H24A109.7
F3'—P3—F348.1 (12)C23—C24—H24B109.7
F5'—P3—F3139.9 (13)C25—C24—H24B109.7
F4'—P3—F446.0 (13)H24A—C24—H24B108.2
F3'—P3—F442.5 (11)C26—C25—C24110.6 (4)
F5'—P3—F4129.7 (13)C26—C25—H25A109.5
F3—P3—F489.7 (3)C24—C25—H25A109.5
F4'—P3—F6'169.2 (16)C26—C25—H25B109.5
F3'—P3—F6'100.8 (17)C24—C25—H25B109.5
F5'—P3—F6'87.2 (16)H25A—C25—H25B108.1
F3—P3—F6'52.8 (12)C27—C26—C25113.9 (3)
F4—P3—F6'142.2 (13)C27—C26—H26A108.8
F4'—P3—F6131.9 (14)C25—C26—H26A108.8
F3'—P3—F6139.4 (13)C27—C26—H26B108.8
F5'—P3—F648.3 (13)C25—C26—H26B108.8
F3—P3—F692.4 (3)H26A—C26—H26B107.7
F4—P3—F6177.8 (3)C26—C27—C28114.4 (4)
F6'—P3—F640.0 (11)C26—C27—H27A108.7
F4'—P3—F542.7 (13)C28—C27—H27A108.7
F3'—P3—F5129.8 (12)C26—C27—H27B108.7
F5'—P3—F542.2 (12)C28—C27—H27B108.7
F3—P3—F5177.6 (3)H27A—C27—H27B107.6
F4—P3—F588.5 (3)C27—C28—C23113.5 (3)
F6'—P3—F5129.2 (12)C27—C28—H28A108.9
F6—P3—F589.4 (3)C23—C28—H28A108.9
F4'—P3—F287.1 (10)C27—C28—H28B108.9
F3'—P3—F296.5 (9)C23—C28—H28B108.9
F5'—P3—F284.3 (10)H28A—C28—H28B107.7
F3—P3—F289.44 (18)C30—C29—C34109.4 (2)
F4—P3—F289.5 (2)C30—C29—P1114.0 (2)
F6'—P3—F286.1 (10)C34—C29—P1111.99 (19)
F6—P3—F291.3 (2)C30—C29—H29107.0
F5—P3—F292.0 (2)C34—C29—H29107.0
F4'—P3—F194.7 (10)P1—C29—H29107.0
F3'—P3—F184.0 (9)C29—C30—C31112.7 (3)
F5'—P3—F195.4 (10)C29—C30—H30A109.1
F3—P3—F189.60 (15)C31—C30—H30A109.1
F4—P3—F192.0 (2)C29—C30—H30B109.1
F6'—P3—F192.1 (10)C31—C30—H30B109.1
F6—P3—F187.24 (18)H30A—C30—H30B107.8
F5—P3—F189.0 (2)C32—C31—C30111.0 (3)
F2—P3—F1178.18 (18)C32—C31—H31A109.4
C2—C1—C5109.0 (3)C30—C31—H31A109.4
C2—C1—Co169.39 (17)C32—C31—H31B109.4
C5—C1—Co170.56 (16)C30—C31—H31B109.4
C2—C1—H1125.5H31A—C31—H31B108.0
C5—C1—H1125.5C33—C32—C31111.3 (3)
Co1—C1—H1126.1C33—C32—H32A109.4
C3—C2—C1107.6 (3)C31—C32—H32A109.4
C3—C2—Co169.58 (19)C33—C32—H32B109.4
C1—C2—Co169.47 (17)C31—C32—H32B109.4
C3—C2—H2126.2H32A—C32—H32B108.0
C1—C2—H2126.2C32—C33—C34110.8 (3)
Co1—C2—H2126.3C32—C33—H33A109.5
C4—C3—C2108.4 (3)C34—C33—H33A109.5
C4—C3—Co169.17 (17)C32—C33—H33B109.5
C2—C3—Co169.51 (18)C34—C33—H33B109.5
C4—C3—H3125.8H33A—C33—H33B108.1
C2—C3—H3125.8C33—C34—C29112.5 (2)
Co1—C3—H3127.1C33—C34—H34A109.1
C3—C4—C5109.4 (3)C29—C34—H34A109.1
C3—C4—Co170.07 (18)C33—C34—H34B109.1
C5—C4—Co171.01 (16)C29—C34—H34B109.1
C3—C4—H4125.3H34A—C34—H34B107.8
C5—C4—H4125.3C36—C35—C39108.8 (4)
Co1—C4—H4125.2C36—C35—Ru171.84 (19)
C4—C5—C1105.6 (2)C39—C35—Ru171.69 (18)
C4—C5—P2126.2 (2)C36—C35—H35125.6
C1—C5—P2128.2 (2)C39—C35—H35125.6
C4—C5—Co167.73 (15)Ru1—C35—H35122.5
C1—C5—Co168.17 (15)C35—C36—C37107.1 (4)
P2—C5—Co1129.80 (15)C35—C36—Ru171.2 (2)
C7—C6—C10108.4 (3)C37—C36—Ru171.6 (2)
C7—C6—Co169.76 (17)C35—C36—H36126.4
C10—C6—Co169.04 (16)C37—C36—H36126.4
C7—C6—H6125.8Ru1—C36—H36122.6
C10—C6—H6125.8C38—C37—C36108.1 (4)
Co1—C6—H6127.0C38—C37—Ru171.7 (2)
C8—C7—C6108.4 (3)C36—C37—Ru170.6 (2)
C8—C7—Co169.51 (16)C38—C37—H37125.9
C6—C7—Co169.48 (16)C36—C37—H37125.9
C8—C7—H7125.8Ru1—C37—H37123.4
C6—C7—H7125.8C37—C38—C39108.7 (4)
Co1—C7—H7126.8C37—C38—Ru171.8 (2)
C7—C8—C9108.1 (3)C39—C38—Ru171.1 (2)
C7—C8—Co170.16 (16)C37—C38—H38125.6
C9—C8—Co168.91 (15)C39—C38—H38125.6
C7—C8—H8125.9Ru1—C38—H38123.1
C9—C8—H8125.9C38—C39—C35107.2 (4)
Co1—C8—H8126.6C38—C39—Ru171.68 (19)
C8—C9—C10108.3 (3)C35—C39—Ru170.71 (19)
C8—C9—Co169.96 (17)C38—C39—H39126.4
C10—C9—Co169.61 (16)C35—C39—H39126.4
C8—C9—H9125.8Ru1—C39—H39122.9
C35—Ru1—P1—C10−150.51 (19)C5—Co1—C8—C7−171.8 (3)
C36—Ru1—P1—C10−163.67 (15)C4—Co1—C8—C9−81.5 (2)
C39—Ru1—P1—C10144.8 (2)C2—Co1—C8—C9−162.98 (18)
C38—Ru1—P1—C10131.21 (16)C3—Co1—C8—C9−122.74 (19)
C37—Ru1—P1—C10159.32 (15)C1—Co1—C8—C9172.1 (3)
P2—Ru1—P1—C10−46.16 (10)C10—Co1—C8—C937.92 (17)
Cl1—Ru1—P1—C1043.10 (10)C6—Co1—C8—C982.16 (19)
C35—Ru1—P1—C2393.6 (2)C7—Co1—C8—C9119.6 (3)
C36—Ru1—P1—C2380.41 (17)C5—Co1—C8—C9−52.2 (4)
C39—Ru1—P1—C2328.9 (3)C7—C8—C9—C100.2 (3)
C38—Ru1—P1—C2315.29 (17)Co1—C8—C9—C10−59.22 (19)
C37—Ru1—P1—C2343.40 (17)C7—C8—C9—Co159.4 (2)
P2—Ru1—P1—C23−162.08 (13)C4—Co1—C9—C8114.87 (18)
Cl1—Ru1—P1—C23−72.82 (13)C2—Co1—C9—C843.3 (4)
C35—Ru1—P1—C29−25.1 (2)C3—Co1—C9—C873.8 (2)
C36—Ru1—P1—C29−38.30 (16)C1—Co1—C9—C8−173.1 (3)
C39—Ru1—P1—C29−89.9 (3)C10—Co1—C9—C8−119.5 (2)
C38—Ru1—P1—C29−103.42 (16)C6—Co1—C9—C8−81.03 (19)
C37—Ru1—P1—C29−75.31 (16)C7—Co1—C9—C8−37.16 (18)
P2—Ru1—P1—C2979.21 (11)C5—Co1—C9—C8156.89 (18)
Cl1—Ru1—P1—C29168.47 (11)C4—Co1—C9—C10−125.59 (17)
C35—Ru1—P2—C5179.85 (15)C2—Co1—C9—C10162.8 (3)
C36—Ru1—P2—C5148.14 (16)C3—Co1—C9—C10−166.69 (17)
C39—Ru1—P2—C5−144.54 (15)C1—Co1—C9—C10−53.5 (4)
C38—Ru1—P2—C5−135.5 (2)C8—Co1—C9—C10119.5 (2)
C37—Ru1—P2—C5152.3 (3)C6—Co1—C9—C1038.51 (16)
P1—Ru1—P2—C540.48 (11)C7—Co1—C9—C1082.38 (18)
Cl1—Ru1—P2—C5−50.12 (11)C5—Co1—C9—C10−83.57 (18)
C35—Ru1—P2—C17−62.99 (15)C7—C6—C10—C90.5 (3)
C36—Ru1—P2—C17−94.71 (16)Co1—C6—C10—C959.32 (19)
C39—Ru1—P2—C17−27.38 (15)C7—C6—C10—P1178.5 (2)
C38—Ru1—P2—C17−18.4 (2)Co1—C6—C10—P1−122.7 (2)
C37—Ru1—P2—C17−90.6 (3)C7—C6—C10—Co1−58.8 (2)
P1—Ru1—P2—C17157.63 (11)C8—C9—C10—C6−0.4 (3)
Cl1—Ru1—P2—C1767.04 (11)Co1—C9—C10—C6−59.86 (19)
C35—Ru1—P2—C1160.60 (15)C8—C9—C10—P1−178.5 (2)
C36—Ru1—P2—C1128.88 (16)Co1—C9—C10—P1122.1 (2)
C39—Ru1—P2—C1196.21 (15)C8—C9—C10—Co159.4 (2)
C38—Ru1—P2—C11105.2 (2)C23—P1—C10—C6−110.6 (3)
C37—Ru1—P2—C1133.0 (3)C29—P1—C10—C6−8.6 (3)
P1—Ru1—P2—C11−78.78 (10)Ru1—P1—C10—C6125.5 (2)
Cl1—Ru1—P2—C11−169.37 (10)C23—P1—C10—C967.0 (3)
C4—Co1—C1—C2−81.7 (2)C29—P1—C10—C9169.1 (2)
C9—Co1—C1—C2−160.9 (3)Ru1—P1—C10—C9−56.8 (3)
C3—Co1—C1—C2−37.9 (2)C23—P1—C10—Co1156.09 (19)
C10—Co1—C1—C2159.63 (19)C29—P1—C10—Co1−101.89 (18)
C8—Co1—C1—C233.0 (5)Ru1—P1—C10—Co132.2 (2)
C6—Co1—C1—C2115.5 (2)C4—Co1—C10—C6−169.32 (16)
C7—Co1—C1—C272.4 (2)C9—Co1—C10—C6118.0 (2)
C5—Co1—C1—C2−120.1 (3)C2—Co1—C10—C6−45.3 (4)
C4—Co1—C1—C538.37 (17)C3—Co1—C10—C6153.7 (3)
C9—Co1—C1—C5−40.8 (4)C1—Co1—C10—C6−83.18 (19)
C2—Co1—C1—C5120.1 (3)C8—Co1—C10—C680.39 (17)
C3—Co1—C1—C582.19 (18)C7—Co1—C10—C637.16 (17)
C10—Co1—C1—C5−80.27 (19)C5—Co1—C10—C6−126.45 (16)
C8—Co1—C1—C5153.1 (4)C4—Co1—C10—C972.63 (19)
C6—Co1—C1—C5−124.42 (17)C2—Co1—C10—C9−163.3 (3)
C7—Co1—C1—C5−167.49 (17)C3—Co1—C10—C935.7 (4)
C5—C1—C2—C3−0.3 (3)C1—Co1—C10—C9158.77 (17)
Co1—C1—C2—C359.4 (2)C8—Co1—C10—C9−37.66 (17)
C5—C1—C2—Co1−59.6 (2)C6—Co1—C10—C9−118.0 (2)
C4—Co1—C2—C3−37.19 (17)C7—Co1—C10—C9−80.89 (18)
C9—Co1—C2—C341.2 (4)C5—Co1—C10—C9115.51 (17)
C1—Co1—C2—C3−118.9 (3)C4—Co1—C10—P1−45.6 (2)
C10—Co1—C2—C3−170.4 (3)C9—Co1—C10—P1−118.3 (3)
C8—Co1—C2—C373.3 (2)C2—Co1—C10—P178.4 (4)
C6—Co1—C2—C3156.25 (17)C3—Co1—C10—P1−82.6 (4)
C7—Co1—C2—C3114.49 (19)C1—Co1—C10—P140.5 (2)
C5—Co1—C2—C3−81.43 (19)C8—Co1—C10—P1−155.9 (2)
C4—Co1—C2—C181.74 (19)C6—Co1—C10—P1123.7 (3)
C9—Co1—C2—C1160.1 (3)C7—Co1—C10—P1160.8 (2)
C3—Co1—C2—C1118.9 (3)C5—Co1—C10—P1−2.8 (2)
C10—Co1—C2—C1−51.4 (4)C5—P2—C11—C1662.5 (2)
C8—Co1—C2—C1−167.77 (18)C17—P2—C11—C16−37.7 (2)
C6—Co1—C2—C1−84.8 (2)Ru1—P2—C11—C16−168.25 (18)
C7—Co1—C2—C1−126.58 (19)C5—P2—C11—C12−166.4 (2)
C5—Co1—C2—C137.50 (17)C17—P2—C11—C1293.5 (2)
C1—C2—C3—C4−0.9 (3)Ru1—P2—C11—C12−37.1 (2)
Co1—C2—C3—C458.4 (2)C16—C11—C12—C13−55.5 (3)
C1—C2—C3—Co1−59.3 (2)P2—C11—C12—C13170.6 (2)
C9—Co1—C3—C476.1 (2)C11—C12—C13—C1454.8 (4)
C2—Co1—C3—C4−120.2 (3)C12—C13—C14—C15−55.2 (4)
C1—Co1—C3—C4−82.04 (19)C13—C14—C15—C1656.0 (4)
C10—Co1—C3—C449.1 (4)C12—C11—C16—C1556.8 (3)
C8—Co1—C3—C4116.71 (19)P2—C11—C16—C15−169.9 (2)
C6—Co1—C3—C4−174.7 (3)C14—C15—C16—C11−57.0 (3)
C7—Co1—C3—C4157.35 (18)C5—P2—C17—C2274.2 (3)
C5—Co1—C3—C4−37.70 (18)C11—P2—C17—C22174.1 (3)
C4—Co1—C3—C2120.2 (3)Ru1—P2—C17—C22−53.6 (3)
C9—Co1—C3—C2−163.71 (17)C5—P2—C17—C18−159.4 (3)
C1—Co1—C3—C238.12 (17)C11—P2—C17—C18−59.5 (3)
C10—Co1—C3—C2169.3 (3)Ru1—P2—C17—C1872.8 (3)
C8—Co1—C3—C2−123.12 (19)C22—C17—C18—C19−58.4 (4)
C6—Co1—C3—C2−54.5 (4)P2—C17—C18—C19170.5 (3)
C7—Co1—C3—C2−82.5 (2)C17—C18—C19—C2057.4 (5)
C5—Co1—C3—C282.46 (19)C18—C19—C20—C21−53.9 (5)
C2—C3—C4—C51.8 (3)C19—C20—C21—C2253.8 (5)
Co1—C3—C4—C560.4 (2)C18—C17—C22—C2157.8 (4)
C2—C3—C4—Co1−58.6 (2)P2—C17—C22—C21−173.1 (3)
C9—Co1—C4—C3−121.1 (2)C20—C21—C22—C17−56.8 (5)
C2—Co1—C4—C337.32 (19)C10—P1—C23—C24−88.4 (3)
C1—Co1—C4—C381.5 (2)C29—P1—C23—C24168.8 (3)
C10—Co1—C4—C3−162.01 (18)Ru1—P1—C23—C2439.2 (3)
C8—Co1—C4—C3−78.6 (2)C10—P1—C23—C2844.8 (3)
C6—Co1—C4—C3171.9 (4)C29—P1—C23—C28−58.0 (3)
C7—Co1—C4—C3−48.0 (4)Ru1—P1—C23—C28172.4 (2)
C5—Co1—C4—C3119.9 (3)C28—C23—C24—C2559.1 (4)
C9—Co1—C4—C5119.02 (18)P1—C23—C24—C25−165.0 (3)
C2—Co1—C4—C5−82.57 (19)C23—C24—C25—C26−57.1 (5)
C3—Co1—C4—C5−119.9 (3)C24—C25—C26—C2750.3 (6)
C1—Co1—C4—C5−38.37 (17)C25—C26—C27—C28−45.6 (6)
C10—Co1—C4—C578.1 (2)C26—C27—C28—C2347.5 (5)
C8—Co1—C4—C5161.46 (18)C24—C23—C28—C27−54.3 (5)
C6—Co1—C4—C552.0 (5)P1—C23—C28—C27169.7 (3)
C7—Co1—C4—C5−167.8 (3)C10—P1—C29—C30−155.5 (2)
C3—C4—C5—C1−1.9 (3)C23—P1—C29—C30−54.7 (3)
Co1—C4—C5—C157.90 (18)Ru1—P1—C29—C3070.8 (2)
C3—C4—C5—P2176.3 (2)C10—P1—C29—C3479.6 (2)
Co1—C4—C5—P2−123.9 (2)C23—P1—C29—C34−179.7 (2)
C3—C4—C5—Co1−59.8 (2)Ru1—P1—C29—C34−54.1 (2)
C2—C1—C5—C41.3 (3)C34—C29—C30—C31−53.5 (4)
Co1—C1—C5—C4−57.61 (18)P1—C29—C30—C31−179.8 (2)
C2—C1—C5—P2−176.9 (2)C29—C30—C31—C3254.9 (4)
Co1—C1—C5—P2124.2 (2)C30—C31—C32—C33−55.5 (4)
C2—C1—C5—Co158.92 (19)C31—C32—C33—C3456.5 (4)
C17—P2—C5—C4−58.3 (3)C32—C33—C34—C29−56.6 (4)
C11—P2—C5—C4−161.6 (2)C30—C29—C34—C3354.5 (4)
Ru1—P2—C5—C468.4 (3)P1—C29—C34—C33−178.1 (2)
C17—P2—C5—C1119.5 (3)C39—Ru1—C35—C36117.8 (4)
C11—P2—C5—C116.2 (3)C38—Ru1—C35—C3680.1 (3)
Ru1—P2—C5—C1−113.8 (2)C37—Ru1—C35—C3638.5 (2)
C17—P2—C5—Co1−148.2 (2)P2—Ru1—C35—C36−127.5 (2)
C11—P2—C5—Co1108.5 (2)P1—Ru1—C35—C36−21.7 (3)
Ru1—P2—C5—Co1−21.6 (2)Cl1—Ru1—C35—C36140.5 (2)
C9—Co1—C5—C4−78.2 (2)C36—Ru1—C35—C39−117.8 (4)
C2—Co1—C5—C481.1 (2)C38—Ru1—C35—C39−37.7 (2)
C3—Co1—C5—C437.3 (2)C37—Ru1—C35—C39−79.3 (3)
C1—Co1—C5—C4118.5 (3)P2—Ru1—C35—C39114.7 (2)
C10—Co1—C5—C4−122.05 (19)P1—Ru1—C35—C39−139.5 (2)
C8—Co1—C5—C4−41.1 (4)Cl1—Ru1—C35—C3922.7 (3)
C6—Co1—C5—C4−163.97 (18)C39—C35—C36—C37−0.4 (4)
C7—Co1—C5—C4159.1 (4)Ru1—C35—C36—C37−62.9 (2)
C4—Co1—C5—C1−118.5 (3)C39—C35—C36—Ru162.5 (2)
C9—Co1—C5—C1163.36 (17)C39—Ru1—C36—C35−37.5 (2)
C2—Co1—C5—C1−37.39 (18)C38—Ru1—C36—C35−79.7 (3)
C3—Co1—C5—C1−81.22 (19)C37—Ru1—C36—C35−116.2 (4)
C10—Co1—C5—C1119.46 (17)P2—Ru1—C36—C3560.7 (2)
C8—Co1—C5—C1−159.5 (3)P1—Ru1—C36—C35165.3 (2)
C6—Co1—C5—C177.5 (2)Cl1—Ru1—C36—C35−80.1 (3)
C7—Co1—C5—C140.6 (5)C35—Ru1—C36—C37116.2 (4)
C4—Co1—C5—P2119.3 (3)C39—Ru1—C36—C3778.8 (3)
C9—Co1—C5—P241.2 (2)C38—Ru1—C36—C3736.6 (2)
C2—Co1—C5—P2−159.6 (2)P2—Ru1—C36—C37176.9 (2)
C3—Co1—C5—P2156.6 (2)P1—Ru1—C36—C37−78.5 (2)
C1—Co1—C5—P2−122.2 (3)Cl1—Ru1—C36—C3736.1 (4)
C10—Co1—C5—P2−2.7 (2)C35—C36—C37—C380.4 (4)
C8—Co1—C5—P278.3 (3)Ru1—C36—C37—C38−62.2 (2)
C6—Co1—C5—P2−44.6 (3)C35—C36—C37—Ru162.7 (2)
C7—Co1—C5—P2−81.6 (5)C35—Ru1—C37—C3880.0 (3)
C4—Co1—C6—C7153.4 (4)C36—Ru1—C37—C38117.6 (4)
C9—Co1—C6—C781.4 (2)C39—Ru1—C37—C3837.2 (2)
C2—Co1—C6—C7−78.0 (2)P2—Ru1—C37—C38111.6 (3)
C3—Co1—C6—C7−39.2 (4)P1—Ru1—C37—C38−135.6 (2)
C1—Co1—C6—C7−122.32 (19)Cl1—Ru1—C37—C38−43.4 (3)
C10—Co1—C6—C7120.1 (2)C35—Ru1—C37—C36−37.6 (2)
C8—Co1—C6—C737.07 (19)C39—Ru1—C37—C36−80.4 (2)
C5—Co1—C6—C7−165.66 (19)C38—Ru1—C37—C36−117.6 (4)
C4—Co1—C6—C1033.2 (5)P2—Ru1—C37—C36−6.1 (4)
C9—Co1—C6—C10−38.75 (16)P1—Ru1—C37—C36106.7 (2)
C2—Co1—C6—C10161.84 (16)Cl1—Ru1—C37—C36−161.0 (2)
C3—Co1—C6—C10−159.3 (3)C36—C37—C38—C39−0.3 (4)
C1—Co1—C6—C10117.57 (16)Ru1—C37—C38—C39−61.9 (2)
C8—Co1—C6—C10−83.05 (17)C36—C37—C38—Ru161.5 (2)
C7—Co1—C6—C10−120.1 (2)C35—Ru1—C38—C37−79.9 (3)
C5—Co1—C6—C1074.2 (2)C36—Ru1—C38—C37−37.9 (2)
C10—C6—C7—C8−0.4 (3)C39—Ru1—C38—C37−118.0 (3)
Co1—C6—C7—C8−58.8 (2)P2—Ru1—C38—C37−132.3 (2)
C10—C6—C7—Co158.4 (2)P1—Ru1—C38—C3752.2 (3)
C4—Co1—C7—C8−44.2 (4)Cl1—Ru1—C38—C37141.9 (2)
C9—Co1—C7—C837.88 (18)C35—Ru1—C38—C3938.1 (2)
C2—Co1—C7—C8−120.2 (2)C36—Ru1—C38—C3980.2 (2)
C3—Co1—C7—C8−77.6 (2)C37—Ru1—C38—C39118.0 (3)
C1—Co1—C7—C8−161.08 (19)P2—Ru1—C38—C39−14.3 (3)
C10—Co1—C7—C882.4 (2)P1—Ru1—C38—C39170.20 (19)
C6—Co1—C7—C8119.9 (3)Cl1—Ru1—C38—C39−100.1 (2)
C5—Co1—C7—C8166.8 (4)C37—C38—C39—C350.1 (4)
C4—Co1—C7—C6−164.2 (3)Ru1—C38—C39—C35−62.2 (2)
C9—Co1—C7—C6−82.06 (19)C37—C38—C39—Ru162.3 (2)
C2—Co1—C7—C6119.8 (2)C36—C35—C39—C380.2 (4)
C3—Co1—C7—C6162.41 (19)Ru1—C35—C39—C3862.8 (2)
C1—Co1—C7—C679.0 (2)C36—C35—C39—Ru1−62.6 (2)
C10—Co1—C7—C6−37.52 (17)C35—Ru1—C39—C38−116.5 (4)
C8—Co1—C7—C6−119.9 (3)C36—Ru1—C39—C38−79.6 (3)
C5—Co1—C7—C646.9 (5)C37—Ru1—C39—C38−36.6 (2)
C6—C7—C8—C90.2 (3)P2—Ru1—C39—C38171.3 (2)
Co1—C7—C8—C9−58.6 (2)P1—Ru1—C39—C38−20.1 (4)
C6—C7—C8—Co158.8 (2)Cl1—Ru1—C39—C3880.8 (2)
C4—Co1—C8—C7158.90 (19)C36—Ru1—C39—C3536.9 (2)
C9—Co1—C8—C7−119.6 (3)C38—Ru1—C39—C35116.5 (4)
C2—Co1—C8—C777.4 (2)C37—Ru1—C39—C3579.9 (3)
C3—Co1—C8—C7117.7 (2)P2—Ru1—C39—C35−72.2 (2)
C1—Co1—C8—C752.5 (5)P1—Ru1—C39—C3596.4 (3)
C10—Co1—C8—C7−81.7 (2)Cl1—Ru1—C39—C35−162.8 (2)
C6—Co1—C8—C7−37.45 (19)

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
C9—H9···Cl10.932.653.284 (3)127
C6—H6···F1i0.932.323.176 (4)152
C3—H3···F4ii0.932.473.181 (6)134

Symmetry codes: (i) x−1, y, z; (ii) −x+1, −y+1, −z.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: WM2296).

References

  • Bruker (2001). SMART and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
  • Sheldrick, G. M. (2004). SADABS University of Göttingen, Germany.
  • Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [PubMed]
  • Wu, X. H., Yu, G.-A., Meng, X.-G., Chen, Y., Ren, Y. & Liu, S.-H. (2006). Jiegou Huaxue, 25, 1471–1474.

Articles from Acta Crystallographica Section E: Structure Reports Online are provided here courtesy of International Union of Crystallography