PMCCPMCCPMCC

Search tips
Search criteria 

Advanced

 
Logo of actaeInternational Union of Crystallographysearchopen accessarticle submissionjournal home pagethis article
 
Acta Crystallogr Sect E Struct Rep Online. 2010 June 1; 66(Pt 6): m681.
Published online 2010 May 22. doi:  10.1107/S1600536810017782
PMCID: PMC2979511

{4′-[4-(4,4′-Bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis­(perchlorate) acetonitrile disolvate sesquihydrate

Abstract

The asymmetric unit of the title compound, [PtCl(C32H24N5)](ClO4)2·2CH3CN·1.5H2O, comprises two unique PtII complex cations, four perchlorate anions, four acetonitrile solvent mol­ecules and three water mol­ecules. The Pt atom is four-coordinated by a tridentate chelating 2,2′:6′,2′′-terpyridine ligand and a chloride ion in a square-planar geometry with modest distortion imposed by the constraint of the terpyridyl ligand. The r.m.s. deviations from the plane comprising the four ligand donor atoms and the Pt atom are 0.0381 and 0.0472 Å in the two complex cations.

Related literature

For the synthesis of the terpyridyl ligand, see: Kronke (1976 [triangle]); Collin et al. (1991 [triangle]). For the synthesis of PtII–terpyridyl complexes, see: Jarosz et al. (2008 [triangle]). For the structures of similar complexes, see: Chakraborty et al. (2005 [triangle]); Sakai et al. (2003 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-66-0m681-scheme1.jpg

Experimental

Crystal data

  • [PtCl(C32H24N5)](ClO4)2·2C2H3N·1.5H2O
  • M r = 1017.14
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-66-0m681-efi1.jpg
  • a = 13.3990 (15) Å
  • b = 14.5018 (15) Å
  • c = 41.279 (4) Å
  • β = 90.390 (1)°
  • V = 8020.8 (14) Å3
  • Z = 8
  • Mo Kα radiation
  • μ = 3.76 mm−1
  • T = 298 K
  • 0.20 × 0.19 × 0.18 mm

Data collection

  • Bruker SMART diffractometer
  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996 [triangle]) T min = 0.520, T max = 0.551
  • 41405 measured reflections
  • 14131 independent reflections
  • 5677 reflections with I > 2σ(I)
  • R int = 0.143

Refinement

  • R[F 2 > 2σ(F 2)] = 0.114
  • wR(F 2) = 0.339
  • S = 1.03
  • 14131 reflections
  • 1022 parameters
  • H-atom parameters constrained
  • Δρmax = 3.13 e Å−3
  • Δρmin = −1.62 e Å−3

Data collection: SMART (Siemens, 1996 [triangle]); cell refinement: SAINT (Siemens, 1996 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: ORTEP-3 (Farrugia, 1997 [triangle]) and DIAMOND (Brandenburg, 1998 [triangle]); software used to prepare material for publication: SHELXTL (Sheldrick, 2008 [triangle]).

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810017782/sj2800sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810017782/sj2800Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

This work was supported financially by the National Basic Research Program of China (973 Program 2007CB613304) and the Foundation of the Bureau of Inter­national Cooperation of the Chinese Academy of Science (GJHZ200817).

supplementary crystallographic information

Comment

The molecular structure of the title compound is shown in Fig. 1. The complex consists of a distorted square-planar geometry around the PtII center with three coordination sites occupied by the terpyridyl ligand and the fourth taken up by the chloride ion. The rms deviation from a plane comprising the four ligand donor atoms and the Pt atom is 0.0381. The Pt-N distance of the platinum to the central nitrogen atom (Pt1-N1, 1.99 (2) Å) of the terpyridine ligand, which is slightly longer than to the other two outer nitrogen atoms (Pt1-N2 1.95 (2) Å, Pt1-N3 1.98 (2) Å). All the Pt-N distances are in the range generally observed in typical platinum terpyridine complexes [Chakraborty et al. (2005), Sakai et al. (2003)]. The bond angles (N1-Pt1-N2 82.7 (9)°, N1-Pt1-N3 80.6 (10)°, N2-Pt1-N3 163.2 (9)°, N1-Pt1-Cl5 179.1 (7)°) deviate from the idealized values of 90° and 180° as a consequence of the geometric constraints imposed by the terpyridine ligand.

Experimental

The ligand 4'-p-tolyl-[2,2':6',2'']terpyridine was prepared by a literature method (Kronke, 1976), and bromination was carried out in the presence of N-bromosuccinimide and a small amount of benzoyl peroxide in CCl4. The title complex was prepared as previously reported (Jarosz et al., 2008). The bipyridinium appended terpyridine ligand (0.56 g, 1 mmol), synthesized according to a previously reported procedure (Collin et al., 1991), was mixed with Pt(DMSO)2Cl2 (0.47 g, 1.1 mmol) in 50 mL acetonitrile/chloroform (v/v, 2:1). The mixture was stirred at reflux for 30 h, and a saturated aqueous solution of sodium perchlorate was added after cooled to room temperature. The resulting orange precipitate was collected by filtration and washed with water and diethyl ether. Recrystallization by vapor diffusion of diethyl ether into a dichloromethane/acetonitrile (v/v, 1:1) mixture gave yellow crystals.

Refinement

The H atoms were placed in calculated positions [aromatic C-H = 0.93Å and Uiso(H) = 1.2Ueq(C)]. Those of the methyl groups were rotated to fit the electron densidy [ C-H = 0.96Å and Uiso(H) = 1.5Ueq(C)]. The H atoms were included in the refinements in the riding-model approximation. The water H atoms were located in a difference Fourier map and fixed in these positions with distance restraints of O-H = 0.85Å.

Figures

Fig. 1.
The asymmetric unit of the title compound with ellipsoids drawn at the 30% probability level.

Crystal data

[PtCl(C32H24N5)](ClO4)2·2C2H3N·1.5H2OF(000) = 4024
Mr = 1017.14Dx = 1.685 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 3681 reflections
a = 13.3990 (15) Åθ = 3.0–26.3°
b = 14.5018 (15) ŵ = 3.76 mm1
c = 41.279 (4) ÅT = 298 K
β = 90.390 (1)°Block, yellow
V = 8020.8 (14) Å30.20 × 0.19 × 0.18 mm
Z = 8

Data collection

Bruker SMART diffractometer14131 independent reflections
Radiation source: fine-focus sealed tube5677 reflections with I > 2σ(I)
graphiteRint = 0.143
[var phi] and ω scansθmax = 25.0°, θmin = 1.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)h = −9→15
Tmin = 0.520, Tmax = 0.551k = −17→17
41405 measured reflectionsl = −49→49

Refinement

Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.114Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.339H-atom parameters constrained
S = 1.03w = 1/[σ2(Fo2) + (0.1592P)2] where P = (Fo2 + 2Fc2)/3
14131 reflections(Δ/σ)max = 0.001
1022 parametersΔρmax = 3.13 e Å3
0 restraintsΔρmin = −1.62 e Å3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
Pt11.00170 (8)0.10758 (6)1.01667 (2)0.0650 (4)
Pt20.53663 (9)0.11377 (6)0.48389 (2)0.0829 (4)
Cl10.0671 (10)0.0539 (12)0.5808 (4)0.164 (5)
Cl20.5896 (12)0.5208 (11)0.7315 (5)0.175 (5)
Cl30.4122 (12)−0.0009 (10)0.7348 (4)0.168 (5)
Cl40.4248 (7)0.0004 (8)0.0713 (3)0.125 (3)
Cl51.0569 (4)0.0586 (3)1.06877 (12)0.0551 (13)
Cl60.5889 (6)0.0758 (4)0.43079 (13)0.086 (2)
N10.9535 (18)0.1489 (12)0.9734 (5)0.067 (5)
N21.1315 (15)0.1115 (12)0.9954 (5)0.074 (6)
N30.8571 (17)0.1189 (13)1.0260 (6)0.079 (6)
N40.755 (2)0.3066 (18)0.7641 (6)0.099 (7)
N50.688 (2)0.0280 (17)0.6237 (6)0.107 (8)
N60.496 (2)0.1483 (14)0.5265 (6)0.085 (7)
N70.670 (2)0.1392 (14)0.5035 (6)0.090 (7)
N80.3955 (18)0.0981 (13)0.4785 (5)0.081 (6)
N90.276 (2)0.2922 (18)0.7373 (6)0.102 (8)
N100.210 (3)0.0023 (18)0.8747 (6)0.112 (8)
N111.044 (3)0.227 (3)0.4477 (10)0.171 (15)
N120.745 (5)0.504 (4)0.6440 (16)0.27 (3)
N130.497 (3)0.381 (3)0.8142 (9)0.154 (13)
N140.208 (3)0.286 (3)0.8722 (10)0.162 (14)
O10.089 (3)0.148 (3)0.5762 (11)0.27 (2)
O20.005 (4)0.043 (5)0.6071 (13)0.47 (5)
O30.156 (3)0.006 (4)0.5856 (10)0.35 (3)
O40.020 (5)0.021 (5)0.5527 (16)0.38 (3)
O50.574 (5)0.581 (5)0.7056 (18)0.39 (3)
O60.686 (5)0.484 (4)0.7293 (18)0.48 (5)
O70.520 (5)0.449 (6)0.7302 (16)0.50 (6)
O80.580 (7)0.568 (7)0.761 (2)0.48 (5)
O90.465 (4)−0.066 (4)0.7172 (13)0.31 (2)
O100.313 (3)−0.027 (3)0.7382 (11)0.33 (3)
O110.421 (3)0.087 (3)0.7216 (10)0.252 (18)
O120.457 (7)0.011 (5)0.765 (2)0.65 (9)
O130.466 (2)−0.027 (3)0.0417 (7)0.214 (16)
O140.413 (4)0.096 (3)0.0707 (12)0.32 (3)
O150.489 (3)−0.024 (3)0.0965 (10)0.239 (16)
O160.3319 (18)−0.041 (2)0.0752 (9)0.224 (15)
O170.021 (3)0.345 (4)0.6881 (10)0.33 (3)
H17C0.02470.39970.69500.400*
H17D0.01280.34520.66770.400*
O180.497 (4)0.216 (3)0.1285 (13)0.38 (3)
H18C0.52500.25740.11730.450*
H18D0.46970.17750.11560.450*
O190.917 (6)0.590 (5)0.6892 (18)0.52 (5)
H19C0.94890.55650.70270.624*
H19D0.87300.55640.67980.624*
C11.0300 (19)0.1675 (15)0.9510 (6)0.065 (6)
C20.995 (2)0.1954 (15)0.9202 (6)0.074 (7)
H21.04090.20390.90350.088*
C30.893 (2)0.2106 (16)0.9142 (6)0.073 (7)
C40.824 (2)0.1924 (16)0.9392 (7)0.078 (7)
H40.75680.19890.93460.093*
C50.853 (2)0.1650 (16)0.9702 (7)0.070 (7)
C61.133 (2)0.1401 (15)0.9633 (7)0.071 (7)
C71.211 (2)0.1420 (16)0.9419 (7)0.079 (7)
H71.20280.15760.92020.095*
C81.304 (2)0.1183 (16)0.9557 (7)0.084 (8)
H81.36150.11930.94310.101*
C91.309 (2)0.0935 (16)0.9882 (7)0.085 (8)
H91.37100.07820.99730.102*
C101.225 (2)0.0911 (16)1.0073 (7)0.082 (8)
H101.23200.07521.02900.098*
C110.798 (2)0.1477 (17)0.9999 (7)0.078 (7)
C120.695 (2)0.1630 (16)1.0016 (7)0.079 (7)
H120.65950.18100.98320.095*
C130.646 (2)0.1513 (17)1.0309 (7)0.083 (7)
H130.57820.16381.03250.100*
C140.699 (2)0.1210 (16)1.0576 (7)0.081 (7)
H140.66780.10901.07710.097*
C150.802 (2)0.1087 (16)1.0543 (7)0.082 (7)
H150.83720.09211.07290.099*
C160.857 (2)0.2462 (18)0.8811 (6)0.084 (7)
C170.928 (2)0.2789 (18)0.8595 (7)0.089 (8)
H170.99550.27480.86460.107*
C180.898 (2)0.318 (2)0.8302 (7)0.100 (9)
H180.94510.33990.81580.120*
C190.797 (3)0.324 (2)0.8226 (7)0.096 (8)
C200.726 (2)0.291 (2)0.8442 (8)0.101 (9)
H200.65840.29540.83910.121*
C210.756 (2)0.2523 (19)0.8734 (7)0.093 (8)
H210.70880.23030.88790.112*
C220.761 (2)0.374 (2)0.7931 (7)0.101 (9)
H22A0.80630.42450.78810.121*
H22B0.69550.40060.79710.121*
C230.823 (2)0.310 (2)0.7389 (7)0.104 (9)
H230.87700.35000.73920.125*
C240.806 (2)0.249 (2)0.7132 (7)0.104 (9)
H240.85320.24750.69680.125*
C250.724 (3)0.192 (2)0.7104 (7)0.100 (9)
C260.661 (2)0.193 (2)0.7368 (7)0.103 (9)
H260.60860.15110.73690.124*
C270.672 (2)0.251 (2)0.7630 (7)0.101 (9)
H270.62520.25210.77950.122*
C280.781 (3)0.048 (2)0.6364 (8)0.108 (10)
H280.83750.02200.62710.129*
C290.790 (3)0.106 (2)0.6631 (8)0.110 (10)
H290.85270.12700.66900.131*
C300.709 (3)0.133 (2)0.6809 (8)0.103 (9)
C310.617 (3)0.103 (2)0.6700 (7)0.101 (9)
H310.56090.11500.68220.121*
C320.606 (3)0.054 (2)0.6414 (8)0.103 (9)
H320.54280.03950.63400.124*
C330.561 (3)0.170 (2)0.5499 (8)0.093 (9)
C340.530 (3)0.2014 (17)0.5799 (7)0.092 (9)
H340.57700.22370.59460.110*
C350.431 (3)0.2003 (17)0.5884 (7)0.085 (8)
C360.364 (2)0.1746 (17)0.5633 (7)0.089 (8)
H360.29600.17820.56730.107*
C370.395 (3)0.1446 (17)0.5334 (7)0.085 (8)
C380.667 (3)0.171 (2)0.5354 (8)0.098 (9)
C390.753 (3)0.1968 (19)0.5525 (8)0.099 (9)
H390.74680.21570.57390.119*
C400.848 (3)0.1950 (18)0.5382 (8)0.099 (9)
H400.90580.20910.54980.118*
C410.850 (3)0.170 (2)0.5055 (9)0.104 (9)
H410.90940.17420.49420.125*
C420.764 (3)0.1401 (19)0.4894 (8)0.099 (9)
H420.76960.11950.46820.119*
C430.334 (3)0.1154 (17)0.5051 (7)0.085 (8)
C440.231 (3)0.1084 (18)0.5069 (7)0.092 (9)
H440.19640.12570.52530.110*
C450.184 (2)0.0736 (17)0.4792 (7)0.090 (8)
H450.11640.05820.48030.108*
C460.234 (3)0.0613 (18)0.4504 (7)0.091 (8)
H460.19960.04860.43120.110*
C470.338 (3)0.0689 (17)0.4511 (7)0.090 (8)
H470.37280.05370.43230.108*
C480.397 (3)0.2339 (19)0.6212 (7)0.092 (8)
C490.461 (2)0.2842 (19)0.6410 (7)0.097 (9)
H490.52690.29360.63480.117*
C500.427 (3)0.3202 (19)0.6701 (7)0.100 (9)
H500.46990.35390.68340.119*
C510.329 (3)0.306 (2)0.6794 (7)0.100 (9)
C520.264 (3)0.256 (2)0.6595 (7)0.103 (9)
H520.19860.24630.66570.123*
C530.299 (3)0.2197 (19)0.6305 (7)0.097 (9)
H530.25550.18610.61720.116*
C540.290 (2)0.3566 (19)0.7086 (7)0.103 (9)
H54A0.22640.38510.70320.123*
H54B0.33630.40520.71450.123*
C550.350 (3)0.284 (2)0.7604 (9)0.116 (11)
H550.40850.31710.75830.139*
C560.337 (3)0.226 (2)0.7869 (8)0.111 (10)
H560.38730.22230.80250.133*
C570.250 (3)0.174 (2)0.7905 (8)0.109 (10)
C580.175 (3)0.190 (2)0.7679 (8)0.110 (10)
H580.11370.15990.77080.132*
C590.186 (3)0.248 (2)0.7405 (7)0.107 (10)
H590.13430.25650.72550.128*
C600.128 (3)0.038 (2)0.8590 (8)0.117 (11)
H600.06450.02460.86670.140*
C610.139 (3)0.096 (2)0.8310 (7)0.111 (10)
H610.08300.11970.82030.133*
C620.236 (3)0.115 (2)0.8200 (8)0.113 (10)
C630.320 (3)0.078 (2)0.8361 (8)0.113 (10)
H630.38430.09250.82970.135*
C640.302 (3)0.020 (2)0.8615 (8)0.114 (10)
H640.3567−0.00970.87080.137*
C651.010 (4)0.223 (3)0.4218 (14)0.17 (2)
C660.955 (4)0.225 (3)0.3905 (11)0.20 (2)
H66A0.88520.23600.39450.303*
H66B0.96240.16720.37950.303*
H66C0.98050.27370.37710.303*
C670.725 (6)0.425 (5)0.6406 (18)0.24 (3)
C680.720 (3)0.329 (3)0.6295 (9)0.154 (14)
H68A0.68620.32560.60900.231*
H68B0.68500.29230.64510.231*
H68C0.78680.30490.62720.231*
C690.459 (4)0.453 (4)0.8142 (11)0.161 (17)
C700.409 (4)0.544 (3)0.8068 (11)0.20 (2)
H70A0.44790.57680.79120.301*
H70B0.40450.57940.82630.301*
H70C0.34360.53240.79830.301*
C710.198 (4)0.359 (4)0.8609 (14)0.19 (2)
C720.195 (4)0.461 (4)0.8581 (12)0.21 (2)
H72A0.13600.48400.86840.321*
H72B0.19400.47810.83560.321*
H72C0.25290.48710.86840.321*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Pt10.0891 (8)0.0383 (5)0.0674 (6)−0.0043 (5)−0.0096 (5)−0.0055 (4)
Pt20.1299 (11)0.0437 (6)0.0754 (8)0.0258 (6)0.0100 (6)0.0125 (5)
Cl10.132 (10)0.190 (13)0.169 (12)−0.009 (9)−0.016 (8)0.050 (10)
Cl20.160 (12)0.157 (12)0.209 (16)0.004 (10)−0.036 (11)0.013 (11)
Cl30.188 (14)0.139 (11)0.178 (13)−0.007 (10)0.054 (10)0.036 (9)
Cl40.089 (7)0.133 (8)0.152 (9)−0.007 (6)−0.024 (6)−0.002 (7)
Cl50.077 (4)0.035 (3)0.053 (3)0.001 (2)−0.013 (3)−0.008 (2)
Cl60.140 (6)0.068 (4)0.051 (4)0.052 (4)0.017 (4)0.000 (3)
N10.072 (16)0.044 (11)0.085 (16)−0.015 (10)−0.016 (13)−0.005 (9)
N20.075 (15)0.054 (12)0.092 (17)−0.008 (11)−0.032 (12)−0.001 (11)
N30.094 (17)0.058 (13)0.086 (16)−0.001 (11)−0.012 (14)0.000 (11)
N40.11 (2)0.10 (2)0.085 (18)−0.007 (16)0.001 (15)−0.005 (15)
N50.12 (2)0.101 (19)0.096 (19)0.002 (17)0.004 (18)−0.008 (14)
N60.12 (2)0.057 (13)0.079 (17)0.020 (13)−0.003 (16)0.020 (11)
N70.11 (2)0.077 (15)0.079 (18)0.017 (13)0.006 (15)0.001 (12)
N80.14 (2)0.055 (12)0.051 (13)0.025 (12)0.021 (13)0.018 (10)
N90.13 (2)0.088 (18)0.082 (18)−0.006 (17)0.003 (17)0.002 (14)
N100.15 (3)0.10 (2)0.092 (19)−0.017 (19)−0.014 (19)0.015 (15)
N110.19 (4)0.13 (3)0.19 (4)0.02 (2)−0.04 (3)−0.01 (3)
N120.31 (7)0.18 (5)0.34 (7)0.00 (5)−0.01 (5)0.02 (5)
N130.16 (3)0.14 (3)0.16 (3)0.01 (2)−0.01 (2)0.02 (3)
N140.19 (4)0.15 (3)0.15 (3)0.00 (3)0.00 (3)−0.01 (3)
O10.23 (4)0.20 (4)0.37 (6)0.02 (3)0.05 (4)0.08 (4)
O20.31 (6)0.75 (12)0.34 (7)−0.02 (7)0.23 (6)0.13 (7)
O30.22 (4)0.50 (8)0.33 (5)0.18 (5)−0.04 (4)0.13 (5)
O40.38 (8)0.38 (9)0.38 (8)−0.01 (6)−0.01 (7)0.00 (6)
O50.39 (9)0.39 (9)0.39 (9)0.00 (7)0.00 (7)0.02 (7)
O60.35 (7)0.35 (8)0.73 (12)0.26 (7)0.04 (8)0.17 (7)
O70.44 (9)0.70 (13)0.38 (8)−0.38 (10)−0.07 (6)0.26 (9)
O80.47 (13)0.48 (12)0.48 (12)0.00 (10)0.00 (10)0.00 (10)
O90.32 (6)0.31 (6)0.32 (6)0.01 (5)0.01 (5)0.00 (5)
O100.16 (3)0.43 (7)0.39 (6)−0.06 (4)0.11 (4)0.18 (5)
O110.25 (4)0.21 (4)0.30 (5)0.05 (3)0.09 (4)0.04 (3)
O120.93 (18)0.37 (9)0.63 (12)0.12 (10)−0.59 (14)0.11 (9)
O130.16 (3)0.33 (4)0.15 (3)0.06 (3)0.07 (2)0.04 (3)
O140.38 (6)0.17 (3)0.42 (7)−0.06 (4)0.18 (5)−0.16 (4)
O150.24 (4)0.25 (5)0.23 (4)0.01 (3)−0.01 (3)0.00 (3)
O160.087 (19)0.20 (3)0.38 (5)−0.08 (2)0.01 (2)0.01 (3)
O170.16 (3)0.58 (9)0.26 (5)−0.03 (4)−0.01 (3)0.08 (5)
O180.49 (8)0.12 (3)0.52 (8)0.04 (4)−0.09 (6)0.02 (4)
O190.52 (13)0.52 (12)0.52 (11)0.00 (9)0.00 (9)−0.01 (9)
C10.077 (19)0.043 (13)0.077 (18)0.003 (12)−0.016 (15)−0.004 (12)
C20.08 (2)0.060 (16)0.08 (2)−0.009 (13)−0.011 (14)−0.005 (13)
C30.08 (2)0.065 (16)0.079 (19)−0.009 (13)−0.010 (15)−0.004 (13)
C40.08 (2)0.065 (17)0.08 (2)−0.009 (13)−0.014 (16)0.002 (14)
C50.08 (2)0.050 (14)0.08 (2)−0.008 (13)−0.009 (16)−0.005 (13)
C60.07 (2)0.057 (15)0.09 (2)−0.019 (12)−0.025 (17)−0.018 (13)
C70.08 (2)0.069 (17)0.09 (2)−0.005 (14)−0.015 (18)−0.010 (13)
C80.09 (2)0.072 (18)0.09 (2)−0.003 (15)−0.015 (16)−0.007 (15)
C90.08 (2)0.071 (18)0.10 (2)0.003 (14)−0.023 (17)0.002 (16)
C100.08 (2)0.068 (18)0.09 (2)0.001 (14)−0.013 (18)−0.007 (14)
C110.08 (2)0.061 (16)0.09 (2)−0.012 (14)−0.015 (18)−0.002 (14)
C120.08 (2)0.062 (16)0.09 (2)−0.003 (15)−0.006 (16)0.009 (14)
C130.09 (2)0.067 (17)0.09 (2)−0.004 (15)−0.005 (18)−0.004 (15)
C140.09 (2)0.065 (17)0.09 (2)−0.004 (15)−0.004 (16)0.003 (14)
C150.09 (2)0.067 (17)0.09 (2)−0.007 (16)−0.015 (16)0.002 (14)
C160.09 (2)0.082 (19)0.08 (2)−0.003 (16)−0.013 (17)0.011 (15)
C170.09 (2)0.09 (2)0.08 (2)−0.005 (16)−0.010 (17)0.012 (15)
C180.10 (3)0.11 (2)0.09 (2)−0.006 (19)−0.006 (18)0.012 (18)
C190.10 (3)0.10 (2)0.08 (2)−0.006 (19)−0.007 (19)0.004 (18)
C200.10 (2)0.11 (2)0.09 (2)−0.004 (18)−0.002 (19)0.007 (18)
C210.09 (2)0.10 (2)0.09 (2)−0.010 (17)−0.004 (17)0.013 (17)
C220.11 (2)0.10 (2)0.09 (2)−0.005 (17)−0.003 (17)−0.001 (19)
C230.11 (3)0.11 (3)0.09 (2)−0.014 (19)−0.003 (19)−0.013 (19)
C240.11 (3)0.11 (2)0.09 (2)−0.01 (2)0.005 (18)−0.016 (19)
C250.11 (3)0.10 (2)0.09 (2)−0.010 (19)0.004 (19)−0.008 (18)
C260.11 (3)0.11 (2)0.09 (2)−0.013 (19)0.005 (19)−0.009 (19)
C270.11 (3)0.11 (2)0.09 (2)−0.01 (2)0.004 (18)−0.007 (19)
C280.11 (3)0.11 (3)0.10 (3)0.00 (2)0.01 (2)−0.012 (19)
C290.12 (3)0.11 (3)0.10 (2)−0.01 (2)0.00 (2)−0.01 (2)
C300.11 (3)0.10 (2)0.09 (2)−0.008 (19)0.01 (2)−0.009 (18)
C310.11 (3)0.10 (2)0.09 (2)0.00 (2)0.005 (19)−0.008 (18)
C320.12 (3)0.10 (2)0.10 (2)−0.01 (2)0.01 (2)−0.003 (18)
C330.13 (3)0.075 (19)0.08 (2)0.013 (18)0.00 (2)0.013 (16)
C340.12 (3)0.072 (19)0.08 (2)0.009 (17)0.004 (18)0.008 (15)
C350.12 (3)0.064 (17)0.07 (2)0.009 (16)−0.004 (19)0.006 (14)
C360.12 (2)0.066 (17)0.08 (2)0.015 (17)0.001 (18)0.013 (15)
C370.12 (3)0.064 (17)0.07 (2)0.024 (16)−0.002 (19)0.014 (14)
C380.13 (3)0.08 (2)0.09 (3)0.022 (19)0.00 (2)0.011 (17)
C390.13 (3)0.08 (2)0.09 (2)0.015 (19)0.00 (2)0.006 (16)
C400.12 (3)0.08 (2)0.10 (3)0.015 (17)0.00 (2)0.007 (17)
C410.12 (3)0.08 (2)0.11 (3)0.02 (2)0.00 (2)0.005 (19)
C420.12 (3)0.08 (2)0.10 (2)0.020 (18)0.00 (2)0.007 (16)
C430.12 (3)0.063 (17)0.07 (2)0.021 (18)0.001 (18)0.011 (14)
C440.13 (3)0.074 (18)0.08 (2)0.025 (19)0.003 (18)0.007 (15)
C450.12 (2)0.068 (17)0.08 (2)0.021 (16)−0.004 (19)0.012 (15)
C460.13 (3)0.073 (18)0.07 (2)0.018 (18)−0.007 (19)0.008 (14)
C470.13 (3)0.066 (17)0.08 (2)0.025 (17)0.005 (19)0.011 (14)
C480.12 (3)0.072 (19)0.08 (2)0.002 (18)−0.004 (19)0.008 (15)
C490.12 (3)0.08 (2)0.09 (2)0.000 (18)0.001 (19)−0.007 (16)
C500.13 (3)0.08 (2)0.08 (2)−0.008 (19)0.000 (19)0.007 (17)
C510.13 (3)0.09 (2)0.08 (2)−0.01 (2)0.00 (2)0.001 (17)
C520.13 (3)0.09 (2)0.09 (2)−0.011 (19)0.00 (2)0.002 (18)
C530.12 (3)0.08 (2)0.08 (2)−0.004 (18)0.007 (19)0.000 (16)
C540.13 (3)0.09 (2)0.09 (2)−0.008 (18)0.003 (19)−0.001 (17)
C550.14 (3)0.10 (3)0.10 (3)−0.01 (2)0.00 (2)0.01 (2)
C560.14 (3)0.10 (2)0.09 (2)−0.01 (2)0.00 (2)0.007 (18)
C570.14 (3)0.09 (2)0.09 (2)−0.01 (2)0.00 (2)0.008 (19)
C580.14 (3)0.10 (2)0.10 (3)−0.01 (2)0.00 (2)0.006 (19)
C590.14 (3)0.09 (2)0.09 (2)−0.01 (2)0.00 (2)0.004 (18)
C600.15 (3)0.10 (3)0.10 (3)−0.02 (2)0.00 (2)0.01 (2)
C610.14 (3)0.10 (2)0.09 (2)−0.01 (2)0.00 (2)0.008 (18)
C620.14 (3)0.10 (2)0.09 (2)−0.02 (2)0.00 (2)0.010 (19)
C630.14 (3)0.10 (2)0.10 (2)−0.01 (2)0.00 (2)0.011 (19)
C640.14 (3)0.10 (3)0.10 (2)0.00 (2)−0.01 (2)0.016 (19)
C650.19 (5)0.14 (4)0.18 (5)0.02 (3)−0.07 (4)0.01 (4)
C660.21 (5)0.18 (5)0.21 (5)0.01 (4)−0.05 (4)−0.01 (4)
C670.27 (7)0.16 (6)0.29 (7)−0.01 (6)−0.02 (5)−0.01 (6)
C680.18 (4)0.12 (3)0.17 (4)−0.01 (3)−0.01 (3)0.01 (3)
C690.17 (5)0.15 (5)0.16 (4)0.01 (4)0.00 (3)0.01 (4)
C700.21 (5)0.18 (5)0.21 (5)0.03 (4)0.00 (4)0.00 (4)
C710.20 (5)0.16 (5)0.20 (6)0.02 (5)0.02 (4)0.00 (5)
C720.21 (5)0.20 (6)0.23 (6)0.02 (5)−0.01 (4)0.00 (5)

Geometric parameters (Å, °)

Pt1—N21.95 (2)C21—H210.9300
Pt1—N31.98 (2)C22—H22A0.9700
Pt1—N11.99 (2)C22—H22B0.9700
Pt1—Cl52.378 (5)C23—C241.39 (4)
Pt2—N61.91 (2)C23—H230.9300
Pt2—N81.92 (2)C24—C251.38 (4)
Pt2—N71.99 (3)C24—H240.9300
Pt2—Cl62.370 (5)C25—C261.38 (3)
Cl1—O21.38 (4)C25—C301.50 (4)
Cl1—O31.40 (4)C26—C271.38 (3)
Cl1—O41.40 (7)C26—H260.9300
Cl1—O11.40 (4)C27—H270.9300
Cl2—O51.40 (7)C28—C291.39 (4)
Cl2—O81.40 (9)C28—H280.9300
Cl2—O71.40 (6)C29—C301.37 (4)
Cl2—O61.40 (5)C29—H290.9300
Cl3—O111.39 (4)C30—C311.38 (4)
Cl3—O91.39 (5)C31—C321.38 (4)
Cl3—O101.39 (4)C31—H310.9300
Cl3—O121.40 (6)C32—H320.9300
Cl4—O151.39 (4)C33—C341.38 (4)
Cl4—O161.39 (2)C33—C381.54 (4)
Cl4—O141.40 (4)C34—C351.38 (4)
Cl4—O131.40 (3)C34—H340.9300
N1—C51.38 (3)C35—C361.41 (4)
N1—C11.41 (3)C35—C481.51 (4)
N2—C101.38 (3)C36—C371.38 (4)
N2—C61.39 (3)C36—H360.9300
N3—C151.40 (3)C37—C431.48 (4)
N3—C111.40 (3)C38—C391.39 (4)
N4—C271.37 (3)C39—C401.41 (4)
N4—C231.39 (3)C39—H390.9300
N4—C221.55 (3)C40—C411.40 (4)
N5—C321.37 (3)C40—H400.9300
N5—C281.38 (4)C41—C421.40 (4)
N6—C331.34 (3)C41—H410.9300
N6—C371.38 (3)C42—H420.9300
N7—C421.39 (4)C43—C441.38 (4)
N7—C381.40 (3)C44—C451.40 (4)
N8—C431.40 (3)C44—H440.9300
N8—C471.43 (3)C45—C461.38 (3)
N9—C551.37 (4)C45—H450.9300
N9—C591.38 (4)C46—C471.40 (4)
N9—C541.52 (3)C46—H460.9300
N10—C601.37 (4)C47—H470.9300
N10—C641.38 (4)C48—C531.39 (4)
N11—C651.16 (5)C48—C491.39 (4)
N12—C671.18 (6)C49—C501.39 (3)
N13—C691.16 (5)C49—H490.9300
N14—C711.16 (5)C50—C511.39 (4)
O17—H17C0.8499C50—H500.9300
O17—H17D0.8499C51—C521.39 (4)
O18—H18C0.8500C51—C541.51 (4)
O18—H18D0.8502C52—C531.39 (3)
O19—H19C0.8501C52—H520.9300
O19—H19D0.8501C53—H530.9300
C1—C21.41 (3)C54—H54A0.9700
C1—C61.52 (3)C54—H54B0.9700
C2—C31.41 (3)C55—C561.39 (4)
C2—H20.9300C55—H550.9300
C3—C41.41 (3)C56—C571.40 (4)
C3—C161.54 (3)C56—H560.9300
C4—C51.39 (3)C57—C581.39 (4)
C4—H40.9300C57—C621.51 (4)
C5—C111.46 (3)C58—C591.42 (4)
C6—C71.37 (3)C58—H580.9300
C7—C81.41 (3)C59—H590.9300
C7—H70.9300C60—C611.44 (4)
C8—C91.39 (3)C60—H600.9300
C8—H80.9300C61—C621.41 (4)
C9—C101.38 (3)C61—H610.9300
C9—H90.9300C62—C631.40 (4)
C10—H100.9300C63—C641.37 (4)
C11—C121.40 (3)C63—H630.9300
C12—C131.39 (3)C64—H640.9300
C12—H120.9300C65—C661.49 (5)
C13—C141.38 (3)C66—H66A0.9600
C13—H130.9300C66—H66B0.9600
C14—C151.39 (3)C66—H66C0.9600
C14—H140.9300C67—C681.48 (7)
C15—H150.9300C68—H68A0.9600
C16—C171.39 (3)C68—H68B0.9600
C16—C211.39 (4)C68—H68C0.9600
C17—C181.39 (3)C69—C701.50 (6)
C17—H170.9300C70—H70A0.9600
C18—C191.39 (4)C70—H70B0.9600
C18—H180.9300C70—H70C0.9600
C19—C201.39 (4)C71—C721.49 (6)
C19—C221.50 (4)C72—H72A0.9600
C20—C211.39 (3)C72—H72B0.9600
C20—H200.9300C72—H72C0.9600
N2—Pt1—N3163.2 (9)N4—C27—C26118 (3)
N2—Pt1—N182.7 (9)N4—C27—H27121.1
N3—Pt1—N180.6 (10)C26—C27—H27121.1
N2—Pt1—Cl598.2 (6)N5—C28—C29120 (3)
N3—Pt1—Cl598.5 (7)N5—C28—H28120.1
N1—Pt1—Cl5179.1 (7)C29—C28—H28120.1
N6—Pt2—N881.2 (11)C30—C29—C28122 (3)
N6—Pt2—N780.8 (12)C30—C29—H29118.8
N8—Pt2—N7162.0 (10)C28—C29—H29118.8
N6—Pt2—Cl6178.2 (7)C29—C30—C31116 (3)
N8—Pt2—Cl699.4 (6)C29—C30—C25120 (3)
N7—Pt2—Cl698.6 (8)C31—C30—C25124 (3)
O2—Cl1—O3110 (3)C32—C31—C30122 (3)
O2—Cl1—O4110 (4)C32—C31—H31118.9
O3—Cl1—O4109 (4)C30—C31—H31118.9
O2—Cl1—O1110 (4)N5—C32—C31121 (3)
O3—Cl1—O1109 (3)N5—C32—H32119.3
O4—Cl1—O1109 (3)C31—C32—H32119.3
O5—Cl2—O8110 (5)N6—C33—C34121 (3)
O5—Cl2—O7110 (4)N6—C33—C38109 (3)
O8—Cl2—O7109 (5)C34—C33—C38129 (3)
O5—Cl2—O6109 (4)C35—C34—C33122 (3)
O8—Cl2—O6109 (5)C35—C34—H34119.2
O7—Cl2—O6109 (5)C33—C34—H34119.2
O11—Cl3—O9112 (3)C34—C35—C36115 (3)
O11—Cl3—O10112 (3)C34—C35—C48121 (3)
O9—Cl3—O10111 (3)C36—C35—C48123 (3)
O11—Cl3—O12102 (4)C37—C36—C35123 (3)
O9—Cl3—O12109 (4)C37—C36—H36118.3
O10—Cl3—O12111 (5)C35—C36—H36118.3
O15—Cl4—O16111 (2)C36—C37—N6118 (3)
O15—Cl4—O14109 (3)C36—C37—C43129 (3)
O16—Cl4—O14109 (2)N6—C37—C43112 (3)
O15—Cl4—O13110 (2)C39—C38—N7122 (3)
O16—Cl4—O13110 (2)C39—C38—C33124 (3)
O14—Cl4—O13108 (2)N7—C38—C33113 (3)
C5—N1—C1128 (2)C38—C39—C40122 (3)
C5—N1—Pt1116.9 (17)C38—C39—H39119.0
C1—N1—Pt1114.5 (16)C40—C39—H39119.0
C10—N2—C6113 (2)C41—C40—C39115 (3)
C10—N2—Pt1130 (2)C41—C40—H40122.3
C6—N2—Pt1117.2 (17)C39—C40—H40122.3
C15—N3—C11112 (2)C42—C41—C40121 (3)
C15—N3—Pt1133 (2)C42—C41—H41119.3
C11—N3—Pt1115.2 (19)C40—C41—H41119.3
C27—N4—C23122 (3)N7—C42—C41123 (3)
C27—N4—C22116 (3)N7—C42—H42118.3
C23—N4—C22122 (3)C41—C42—H42118.3
C32—N5—C28117 (3)C44—C43—N8128 (3)
C33—N6—C37120 (3)C44—C43—C37121 (3)
C33—N6—Pt2122 (2)N8—C43—C37110 (3)
C37—N6—Pt2118 (2)C43—C44—C45116 (3)
C42—N7—C38115 (3)C43—C44—H44122.2
C42—N7—Pt2130 (2)C45—C44—H44122.2
C38—N7—Pt2114 (2)C46—C45—C44122 (3)
C43—N8—C47111 (3)C46—C45—H45119.1
C43—N8—Pt2118 (2)C44—C45—H45119.1
C47—N8—Pt2130.6 (18)C45—C46—C47118 (3)
C55—N9—C59121 (3)C45—C46—H46121.2
C55—N9—C54121 (3)C47—C46—H46121.2
C59—N9—C54118 (3)C46—C47—N8125 (3)
C60—N10—C64117 (3)C46—C47—H47117.7
H17C—O17—H17D109.0N8—C47—H47117.7
H18C—O18—H18D108.0C53—C48—C49120 (3)
H19C—O19—H19D108.8C53—C48—C35119 (3)
C2—C1—N1114 (2)C49—C48—C35121 (3)
C2—C1—C6132 (3)C50—C49—C48120 (3)
N1—C1—C6113 (2)C50—C49—H49120.0
C1—C2—C3121 (2)C48—C49—H49120.0
C1—C2—H2119.5C51—C50—C49120 (3)
C3—C2—H2119.5C51—C50—H50120.0
C4—C3—C2119 (2)C49—C50—H50120.0
C4—C3—C16121 (2)C50—C51—C52120 (3)
C2—C3—C16120 (2)C50—C51—C54119 (3)
C5—C4—C3123 (3)C52—C51—C54121 (3)
C5—C4—H4118.3C51—C52—C53120 (3)
C3—C4—H4118.3C51—C52—H52120.0
N1—C5—C4114 (2)C53—C52—H52120.0
N1—C5—C11113 (2)C48—C53—C52120 (3)
C4—C5—C11133 (3)C48—C53—H53120.0
C7—C6—N2130 (2)C52—C53—H53120.0
C7—C6—C1118 (3)C51—C54—N9112 (2)
N2—C6—C1112 (2)C51—C54—H54A109.3
C6—C7—C8114 (3)N9—C54—H54A109.3
C6—C7—H7122.8C51—C54—H54B109.3
C8—C7—H7122.8N9—C54—H54B109.3
C9—C8—C7119 (3)H54A—C54—H54B107.9
C9—C8—H8120.4N9—C55—C56121 (3)
C7—C8—H8120.4N9—C55—H55119.6
C10—C9—C8121 (3)C56—C55—H55119.6
C10—C9—H9119.3C55—C56—C57121 (3)
C8—C9—H9119.3C55—C56—H56119.6
N2—C10—C9123 (3)C57—C56—H56119.6
N2—C10—H10118.7C58—C57—C56117 (3)
C9—C10—H10118.7C58—C57—C62123 (4)
C12—C11—N3124 (3)C56—C57—C62120 (3)
C12—C11—C5121 (3)C57—C58—C59123 (3)
N3—C11—C5114 (3)C57—C58—H58118.3
C13—C12—C11120 (3)C59—C58—H58118.3
C13—C12—H12120.1N9—C59—C58117 (3)
C11—C12—H12120.1N9—C59—H59121.7
C14—C13—C12119 (3)C58—C59—H59121.7
C14—C13—H13120.4N10—C60—C61121 (3)
C12—C13—H13120.4N10—C60—H60119.4
C13—C14—C15118 (3)C61—C60—H60119.4
C13—C14—H14121.0C62—C61—C60118 (3)
C15—C14—H14121.0C62—C61—H61121.0
C14—C15—N3126 (3)C60—C61—H61121.0
C14—C15—H15116.8C63—C62—C61121 (3)
N3—C15—H15116.8C63—C62—C57120 (4)
C17—C16—C21120 (3)C61—C62—C57119 (4)
C17—C16—C3118 (3)C64—C63—C62117 (4)
C21—C16—C3121 (3)C64—C63—H63121.5
C16—C17—C18120 (3)C62—C63—H63121.5
C16—C17—H17120.0C63—C64—N10125 (3)
C18—C17—H17120.0C63—C64—H64117.3
C19—C18—C17120 (3)N10—C64—H64117.3
C19—C18—H18120.0N11—C65—C66171 (6)
C17—C18—H18120.0C65—C66—H66A109.5
C20—C19—C18120 (3)C65—C66—H66B109.5
C20—C19—C22118 (3)H66A—C66—H66B109.5
C18—C19—C22121 (3)C65—C66—H66C109.5
C19—C20—C21120 (3)H66A—C66—H66C109.5
C19—C20—H20120.0H66B—C66—H66C109.5
C21—C20—H20120.0N12—C67—C68165 (9)
C16—C21—C20120 (3)C67—C68—H68A109.5
C16—C21—H21120.0C67—C68—H68B109.5
C20—C21—H21120.0H68A—C68—H68B109.5
C19—C22—N4109 (2)C67—C68—H68C109.5
C19—C22—H22A109.8H68A—C68—H68C109.5
N4—C22—H22A109.8H68B—C68—H68C109.5
C19—C22—H22B109.8N13—C69—C70168 (5)
N4—C22—H22B109.8C69—C70—H70A109.5
H22A—C22—H22B108.3C69—C70—H70B109.5
N4—C23—C24117 (3)H70A—C70—H70B109.5
N4—C23—H23121.7C69—C70—H70C109.5
C24—C23—H23121.7H70A—C70—H70C109.5
C25—C24—C23125 (3)H70B—C70—H70C109.5
C25—C24—H24117.7N14—C71—C72160 (7)
C23—C24—H24117.7C71—C72—H72A109.5
C26—C25—C24115 (3)C71—C72—H72B109.5
C26—C25—C30125 (3)H72A—C72—H72B109.5
C24—C25—C30121 (3)C71—C72—H72C109.5
C25—C26—C27124 (3)H72A—C72—H72C109.5
C25—C26—H26117.8H72B—C72—H72C109.5
C27—C26—H26117.8
N2—Pt1—N1—C5−178.3 (16)C23—C24—C25—C30177 (3)
N3—Pt1—N1—C50.2 (15)C24—C25—C26—C276(5)
Cl5—Pt1—N1—C5−10 (33)C30—C25—C26—C27−176 (3)
N2—Pt1—N1—C1−4.9 (14)C23—N4—C27—C264(4)
N3—Pt1—N1—C1173.7 (15)C22—N4—C27—C26177 (3)
Cl5—Pt1—N1—C1164 (31)C25—C26—C27—N4−5(5)
N3—Pt1—N2—C10175 (2)C32—N5—C28—C29−11 (4)
N1—Pt1—N2—C10−180 (2)N5—C28—C29—C3011 (5)
Cl5—Pt1—N2—C100(2)C28—C29—C30—C31−3(5)
N3—Pt1—N2—C6−4(4)C28—C29—C30—C25177 (3)
N1—Pt1—N2—C61.2 (15)C26—C25—C30—C29−152 (3)
Cl5—Pt1—N2—C6−178.6 (15)C24—C25—C30—C2926 (5)
N2—Pt1—N3—C15−171 (2)C26—C25—C30—C3128 (5)
N1—Pt1—N3—C15−176 (2)C24—C25—C30—C31−154 (3)
Cl5—Pt1—N3—C154(2)C29—C30—C31—C32−5(5)
N2—Pt1—N3—C115(4)C25—C30—C31—C32175 (3)
N1—Pt1—N3—C110.0 (16)C28—N5—C32—C313(4)
Cl5—Pt1—N3—C11179.9 (15)C30—C31—C32—N55(5)
N8—Pt2—N6—C33177 (2)C37—N6—C33—C34−9(4)
N7—Pt2—N6—C33−2(2)Pt2—N6—C33—C34175.2 (19)
Cl6—Pt2—N6—C33−73 (29)C37—N6—C33—C38−179 (2)
N8—Pt2—N6—C371.4 (17)Pt2—N6—C33—C386(3)
N7—Pt2—N6—C37−177.7 (18)N6—C33—C34—C359(4)
Cl6—Pt2—N6—C37111 (29)C38—C33—C34—C35176 (3)
N6—Pt2—N7—C42−175 (2)C33—C34—C35—C36−7(4)
N8—Pt2—N7—C42−177 (2)C33—C34—C35—C48180 (2)
Cl6—Pt2—N7—C424(2)C34—C35—C36—C376(4)
N6—Pt2—N7—C38−2.7 (18)C48—C35—C36—C37180 (2)
N8—Pt2—N7—C38−6(4)C35—C36—C37—N6−7(4)
Cl6—Pt2—N7—C38175.5 (17)C35—C36—C37—C43180 (2)
N6—Pt2—N8—C43−0.9 (16)C33—N6—C37—C368(3)
N7—Pt2—N8—C432(3)Pt2—N6—C37—C36−176.1 (17)
Cl6—Pt2—N8—C43−179.2 (15)C33—N6—C37—C43−177 (2)
N6—Pt2—N8—C47−180 (2)Pt2—N6—C37—C43−2(3)
N7—Pt2—N8—C47−177 (2)C42—N7—C38—C39−4(4)
Cl6—Pt2—N8—C472(2)Pt2—N7—C38—C39−177 (2)
C5—N1—C1—C2−8(3)C42—N7—C38—C33179 (2)
Pt1—N1—C1—C2179.1 (15)Pt2—N7—C38—C336(3)
C5—N1—C1—C6179.9 (19)N6—C33—C38—C39176 (3)
Pt1—N1—C1—C67(2)C34—C33—C38—C397(5)
N1—C1—C2—C35(3)N6—C33—C38—N7−7(3)
C6—C1—C2—C3175 (2)C34—C33—C38—N7−176 (3)
C1—C2—C3—C4−4(3)N7—C38—C39—C402(4)
C1—C2—C3—C16177 (2)C33—C38—C39—C40179 (2)
C2—C3—C4—C54(4)C38—C39—C40—C413(4)
C16—C3—C4—C5−176 (2)C39—C40—C41—C42−7(4)
C1—N1—C5—C49(3)C38—N7—C42—C410(4)
Pt1—N1—C5—C4−179.1 (15)Pt2—N7—C42—C41172 (2)
C1—N1—C5—C11−173 (2)C40—C41—C42—N75(4)
Pt1—N1—C5—C110(2)C47—N8—C43—C44−1(3)
C3—C4—C5—N1−6(3)Pt2—N8—C43—C44−180 (2)
C3—C4—C5—C11176 (2)C47—N8—C43—C37179.3 (19)
C10—N2—C6—C77(3)Pt2—N8—C43—C370(3)
Pt1—N2—C6—C7−174.0 (19)C36—C37—C43—C44−5(4)
C10—N2—C6—C1−176.8 (18)N6—C37—C43—C44−179 (2)
Pt1—N2—C6—C12(2)C36—C37—C43—N8175 (2)
C2—C1—C6—C71(4)N6—C37—C43—N81(3)
N1—C1—C6—C7170.5 (19)N8—C43—C44—C455(4)
C2—C1—C6—N2−176 (2)C37—C43—C44—C45−175 (2)
N1—C1—C6—N2−6(3)C43—C44—C45—C46−10 (4)
N2—C6—C7—C8−6(4)C44—C45—C46—C4711 (4)
C1—C6—C7—C8178 (2)C45—C46—C47—N8−7(4)
C6—C7—C8—C92(3)C43—N8—C47—C462(3)
C7—C8—C9—C100(4)Pt2—N8—C47—C46−179.2 (18)
C6—N2—C10—C9−4(3)C34—C35—C48—C53−171 (3)
Pt1—N2—C10—C9176.8 (17)C36—C35—C48—C5315 (4)
C8—C9—C10—N21(4)C34—C35—C48—C4913 (4)
C15—N3—C11—C12−1(3)C36—C35—C48—C49−160 (3)
Pt1—N3—C11—C12−177.7 (19)C53—C48—C49—C500(4)
C15—N3—C11—C5176.3 (19)C35—C48—C49—C50175 (2)
Pt1—N3—C11—C50(3)C48—C49—C50—C510(4)
N1—C5—C11—C12178 (2)C49—C50—C51—C520(4)
C4—C5—C11—C12−4(4)C49—C50—C51—C54−172 (3)
N1—C5—C11—N30(3)C50—C51—C52—C530(5)
C4—C5—C11—N3179 (2)C54—C51—C52—C53172 (3)
N3—C11—C12—C131(4)C49—C48—C53—C520(4)
C5—C11—C12—C13−176 (2)C35—C48—C53—C52−176 (2)
C11—C12—C13—C14−3(4)C51—C52—C53—C480(4)
C12—C13—C14—C154(4)C50—C51—C54—N9−108 (3)
C13—C14—C15—N3−4(4)C52—C51—C54—N981 (4)
C11—N3—C15—C143(3)C55—N9—C54—C5196 (4)
Pt1—N3—C15—C14178.3 (18)C59—N9—C54—C51−89 (3)
C4—C3—C16—C17168 (2)C59—N9—C55—C564(5)
C2—C3—C16—C17−12 (4)C54—N9—C55—C56179 (3)
C4—C3—C16—C21−7(4)N9—C55—C56—C571(5)
C2—C3—C16—C21173 (2)C55—C56—C57—C58−5(5)
C21—C16—C17—C180(4)C55—C56—C57—C62−178 (3)
C3—C16—C17—C18−175 (2)C56—C57—C58—C596(5)
C16—C17—C18—C190(4)C62—C57—C58—C59178 (3)
C17—C18—C19—C200(5)C55—N9—C59—C58−4(4)
C17—C18—C19—C22173 (3)C54—N9—C59—C58−179 (2)
C18—C19—C20—C210(5)C57—C58—C59—N9−1(5)
C22—C19—C20—C21−174 (3)C64—N10—C60—C61−3(5)
C17—C16—C21—C200(4)N10—C60—C61—C620(5)
C3—C16—C21—C20175 (2)C60—C61—C62—C630(5)
C19—C20—C21—C160(5)C60—C61—C62—C57180 (3)
C20—C19—C22—N4−96 (3)C58—C57—C62—C63160 (3)
C18—C19—C22—N490 (3)C56—C57—C62—C63−28 (5)
C27—N4—C22—C1980 (3)C58—C57—C62—C61−20 (5)
C23—N4—C22—C19−108 (3)C56—C57—C62—C61152 (3)
C27—N4—C23—C24−4(4)C61—C62—C63—C643(5)
C22—N4—C23—C24−176 (3)C57—C62—C63—C64−176 (3)
N4—C23—C24—C254(5)C62—C63—C64—N10−7(5)
C23—C24—C25—C26−5(5)C60—N10—C64—C637(5)

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SJ2800).

References

  • Brandenburg, K. (1998). DIAMOND Crystal Impact GbR, Bonn, Germany.
  • Chakraborty, S., Wadas, T. J., Hester, H., Flaschenreim, C., Schmehl, R. & Eisenberg, R. (2005). Inorg. Chem.44, 6284–6293. [PubMed]
  • Collin, J. P., Guillerez, S., Sauvage, J. P., Barigelletti, F., De Cola, L., Flamigni, L. & Balzani, V. (1991). Inorg. Chem.30, 4230–4238.
  • Farrugia, L. J. (1997). J. Appl. Cryst.30, 565.
  • Jarosz, P., Thall, J., Schneider, J., Kumaresan, D., Schmehl, R. & Eisenberg, R. (2008). Energ. Environ. Sci.1, 573–583.
  • Kronke, F. (1976). Synthesis, pp. 1–24.
  • Sakai, K., Kurashima, M., Osada, M. & Takahashi, S. (2003). Acta Cryst. E59, m515–m517.
  • Sheldrick, G. M. (1996). SADABS University of Göttingen, Germany.
  • Sheldrick, G. M. (2008). Acta Cryst A64, 112–122. [PubMed]
  • Siemens (1996). SMART and SAINT Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA.

Articles from Acta Crystallographica Section E: Structure Reports Online are provided here courtesy of International Union of Crystallography