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Acta Crystallogr Sect E Struct Rep Online. 2009 May 1; 65(Pt 5): m597–m598.
Published online 2009 April 30. doi:  10.1107/S160053680901486X
PMCID: PMC2977633

[μ-N,N,N′,N′-Tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ4 P,P′:P′′,P′′′]bis­[bis­(nitrato-κO)palladium(II)]

Abstract

The asymmetric unit of the title complex, [Pd2(NO3)4(C58H52N2P4)], contains one half-mol­ecule, in which the central benzene ring is located on a crystallographic centre of inversion. The Pd atom has a distorted square-planar coordination consisting of two P and two O atoms. In the crystal structure, inter­molecular C—H(...)O inter­actions link the mol­ecules into chains, and π–π contacts between the phenyl rings [centroid–centroid distance = 3.928 (3) Å] may further stabilize the structure.

Related literature

For related structures, see: Aucott et al. (2002 [triangle]); Ganesamoorthy et al. (2008 [triangle]); Wang et al. (2008 [triangle]). For bond-length data, see: Allen et al. (1987 [triangle]). For ring-puckering parameters, see: Cremer & Pople (1975 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-65-0m597-scheme1.jpg

Experimental

Crystal data

  • [Pd2(NO3)4(C58H52N2P4)]
  • M r = 1361.74
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-65-0m597-efi1.jpg
  • a = 8.0715 (2) Å
  • b = 21.3419 (7) Å
  • c = 16.0283 (5) Å
  • β = 92.937 (3)°
  • V = 2757.43 (14) Å3
  • Z = 2
  • Mo Kα radiation
  • μ = 0.84 mm−1
  • T = 294 K
  • 0.40 × 0.15 × 0.15 mm

Data collection

  • Oxford Diffraction Gemini S Untra diffractometer
  • Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2007 [triangle]) T min = 0.773, T max = 0.882
  • 13871 measured reflections
  • 6838 independent reflections
  • 3511 reflections with I > 2σ(I)
  • R int = 0.035

Refinement

  • R[F 2 > 2σ(F 2)] = 0.036
  • wR(F 2) = 0.072
  • S = 0.80
  • 6838 reflections
  • 370 parameters
  • H-atom parameters constrained
  • Δρmax = 1.04 e Å−3
  • Δρmin = −0.37 e Å−3

Data collection: CrysAlis CCD (Oxford Diffraction, 2007 [triangle]); cell refinement: CrysAlis RED (Oxford Diffraction, 2007 [triangle]); data reduction: CrysAlis RED; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: PLATON (Spek, 2009 [triangle]); software used to prepare material for publication: SHELXL97.

Table 1
Selected geometric parameters (Å, °)
Table 2
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S160053680901486X/hk2653sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053680901486X/hk2653Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

This work was supported by the Innovation Project of Guangxi Graduate Education, China (grant No. 2008106020703M246).

supplementary crystallographic information

Comment

The potential applications as catalysts of palladium(II) complexes, containing phosphine ligands, had been extensively studied so far. A lot of analogs were reported (Aucott et al., 2002; Ganesamoorthy et al., 2008; Wang et al., 2008), and some of them are catalytically active in homogeneous hydrogenations and in other organic reactions. We report herein the crystal structure of the title complex.

The asymmetric unit of the title complex contains one-half molecule (Fig. 1), in which the central benzene ring is located on a crystallographic centre of inversion. The Pd atom is in a distorted square-planar coordination by two P and two O atoms. The Pd-P and Pd-O bond lengths (Allen et al., 1987) and angles (Table 1) are within normal ranges. Rings A (C5-C10), B (C11-C16), C (C18-C23) and D (C24-C29) are, of course, planar and they are oriented at dihedral angles of A/B = 64.08 (3), A/C = 17.77 (3), A/D = 78.70 (3), B/C = 64.54 (3) and B/D = 27.80 (3) °. Ring E (Pd1/P1/P2/N1/C4/C17) is not planar, having total puckering amplitude, QT, of 2.670 (2) Å and twisted conformation [[var phi] = -88.23 (3) and θ = 100.40 (3) °] (Cremer & Pople, 1975).

In the crystal structure, intermolecular C-H···O interactions (Table 2) link the molecules into chains, in which they may be effective in the stabilization of the structure. The π–π contact between the phenyl rings, Cg2—Cg4i [symmetry code: (i) 1/2 + x, 1/2 - y, z + 1/2, where Cg2 and Cg4 are centroids of the rings B (C11-C16) and D (C24-C29), respectively] may further stabilize the structure, with centroid-centroid distance of 3.928 (3) Å.

Experimental

For the preparation of the title complex, PdCl2(0.0350 g, 0.2 mmol) in CH3CN (10 ml) was stirred at 348-353 K for 4 h, until the solid palladium salt was dissolved completely to give a yellow solution. Then, the liquor was cooled to about 277 K for a few hours, and the yellow precipitate, Pd(CH3CN)2Cl2, was collected by filtration. Then, Pd(CH3CN)2Cl2 (0.0265 g, 0.1 mmol) in CH3CN (5 ml) was stirred at room temperature for 20 min, and AgNO3 (0.0345 g, 0.2 mmol) in DMF (5 ml) was added dropwise with stirring. A pale precipitate of AgCl formed and the solution was filtered, The phosphine ligand, (L), (0.0450 g, 0.05 mmol) was added until the color of solution turned to red, and then the stirring is continued for 2 h. After filtration, diffusion of diethyl ether at room temperature into the solution the yellow crystals of the title complex, [Pd2(L)(NO3)4], were obtained.

Refinement

H atoms were positioned geometrically, with C-H = 0.93 and 0.97 Å for aromatic and methylene H, respectively, and constrained to ride on their parent atoms, with Uiso(H) = 1.2Ueq(C).

Figures

Fig. 1.
The molecular structure of the title molecule, with the atom-numbering scheme [symmetry code ('): -x, -y, -z].

Crystal data

[Pd2(NO3)4(C58H52N2P4)]F(000) = 1380
Mr = 1361.74Dx = 1.640 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 4249 reflections
a = 8.0715 (2) Åθ = 11.3–28.6°
b = 21.3419 (7) ŵ = 0.84 mm1
c = 16.0283 (5) ÅT = 294 K
β = 92.937 (3)°Block, yellow
V = 2757.43 (14) Å30.4 × 0.15 × 0.15 mm
Z = 2

Data collection

Gemini S Untra diffractometer6838 independent reflections
Radiation source: Enhance (Mo) X-ray Source3511 reflections with I > 2σ(I)
graphiteRint = 0.035
Detector resolution: 16.0855 pixels mm-1θmax = 30.2°, θmin = 2.8°
ω scansh = −11→9
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2007)k = −28→27
Tmin = 0.773, Tmax = 0.882l = −22→21
13871 measured reflections

Refinement

Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.036Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.072H-atom parameters constrained
S = 0.80w = 1/[σ2(Fo2) + (0.0313P)2] where P = (Fo2 + 2Fc2)/3
6838 reflections(Δ/σ)max = 0.004
370 parametersΔρmax = 1.04 e Å3
0 restraintsΔρmin = −0.37 e Å3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
Pd11.39486 (3)1.789182 (12)0.214196 (13)0.02504 (8)
P11.22599 (9)1.78487 (4)0.10059 (4)0.02366 (18)
P21.30017 (9)1.88209 (4)0.24940 (5)0.02471 (19)
O11.4811 (3)1.60188 (12)0.22173 (15)0.0613 (8)
O21.3721 (3)1.67330 (12)0.29761 (14)0.0461 (6)
O31.4938 (2)1.69934 (10)0.18353 (12)0.0311 (5)
O41.8332 (3)1.83114 (12)0.33338 (14)0.0518 (7)
O51.7301 (3)1.81444 (13)0.20792 (14)0.0486 (7)
O61.5755 (2)1.80091 (10)0.31524 (11)0.0298 (5)
N11.0910 (3)1.90013 (12)0.11125 (14)0.0271 (6)
N21.4459 (3)1.65651 (15)0.23480 (18)0.0391 (7)
N31.7185 (3)1.81587 (13)0.28399 (18)0.0372 (7)
C10.9830 (3)1.93941 (14)−0.02623 (17)0.0299 (8)
H1A0.97291.8985−0.04570.036*
C21.0433 (3)1.94993 (14)0.05573 (16)0.0240 (7)
C31.0617 (3)2.01198 (14)0.07878 (18)0.0286 (8)
H3A1.10612.02120.13200.034*
C41.0437 (3)1.83578 (14)0.09201 (17)0.0264 (7)
H4A0.99361.83350.03580.032*
H4B0.96241.82170.13040.032*
C51.3384 (3)1.80561 (14)0.00986 (17)0.0264 (7)
C61.5000 (4)1.82739 (15)0.0189 (2)0.0352 (8)
H6A1.55271.83040.07170.042*
C71.5828 (4)1.84462 (17)−0.0511 (2)0.0417 (9)
H7A1.69161.8589−0.04510.050*
C81.5067 (4)1.84081 (16)−0.1282 (2)0.0390 (8)
H8A1.56371.8523−0.17480.047*
C91.3461 (4)1.82008 (16)−0.1380 (2)0.0378 (9)
H9A1.29451.8180−0.19110.045*
C101.2609 (4)1.80238 (15)−0.06993 (18)0.0321 (8)
H10A1.15201.7883−0.07690.039*
C111.1447 (3)1.70636 (15)0.08770 (17)0.0249 (7)
C121.2026 (4)1.66574 (15)0.02931 (19)0.0305 (8)
H12A1.27941.6793−0.00810.037*
C131.1461 (5)1.60480 (16)0.0265 (2)0.0422 (9)
H13A1.18481.5774−0.01320.051*
C141.0363 (4)1.58451 (16)0.0802 (2)0.0438 (9)
H14A0.99991.54320.07760.053*
C150.9767 (5)1.62465 (18)0.1396 (2)0.0497 (10)
H15A0.89981.61040.17650.060*
C161.0314 (4)1.68549 (16)0.1437 (2)0.0387 (9)
H16A0.99281.71260.18390.046*
C171.1050 (3)1.91098 (15)0.20009 (16)0.0267 (7)
H17A1.01311.89060.22580.032*
H17B1.09631.95560.21050.032*
C181.4595 (4)1.93885 (15)0.23045 (18)0.0279 (7)
C191.4731 (4)1.96391 (15)0.15109 (19)0.0353 (8)
H19A1.39391.95450.10880.042*
C201.6040 (4)2.00260 (17)0.1352 (2)0.0411 (9)
H20A1.61232.01960.08220.049*
C211.7229 (4)2.01633 (16)0.1973 (2)0.0404 (9)
H21A1.81052.04290.18630.048*
C221.7118 (4)1.99062 (17)0.2755 (2)0.0398 (9)
H22A1.79261.99950.31720.048*
C231.5816 (4)1.95192 (15)0.29200 (19)0.0348 (8)
H23A1.57521.93440.34480.042*
C241.2525 (3)1.88447 (15)0.35784 (17)0.0258 (7)
C251.2340 (4)1.83006 (16)0.40314 (18)0.0320 (8)
H25A1.26171.79170.38020.038*
C261.1751 (4)1.83253 (18)0.4817 (2)0.0410 (9)
H26A1.16231.79570.51170.049*
C271.1346 (4)1.8891 (2)0.5166 (2)0.0490 (10)
H27A1.09321.89030.56960.059*
C281.1551 (4)1.9432 (2)0.4734 (2)0.0479 (10)
H28A1.13011.98140.49760.058*
C291.2133 (4)1.94164 (17)0.39349 (19)0.0374 (8)
H29A1.22601.97870.36390.045*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Pd10.02445 (13)0.02725 (13)0.02345 (13)0.00320 (13)0.00145 (9)0.00167 (13)
P10.0258 (4)0.0238 (4)0.0215 (4)0.0005 (4)0.0019 (3)0.0011 (4)
P20.0240 (4)0.0260 (5)0.0242 (4)0.0002 (4)0.0017 (3)0.0016 (4)
O10.092 (2)0.0341 (16)0.0588 (17)0.0263 (16)0.0099 (14)0.0110 (14)
O20.0473 (15)0.0508 (17)0.0411 (15)0.0053 (13)0.0123 (12)0.0066 (13)
O30.0336 (12)0.0306 (13)0.0294 (12)0.0073 (11)0.0068 (9)0.0021 (11)
O40.0329 (14)0.0729 (19)0.0481 (15)−0.0094 (14)−0.0126 (11)0.0088 (14)
O50.0395 (14)0.078 (2)0.0293 (13)−0.0059 (14)0.0083 (10)0.0091 (13)
O60.0195 (11)0.0434 (15)0.0266 (11)0.0012 (11)0.0019 (8)0.0020 (10)
N10.0311 (15)0.0222 (14)0.0275 (14)0.0011 (13)−0.0017 (11)−0.0015 (12)
N20.0383 (17)0.044 (2)0.0356 (18)0.0165 (16)0.0058 (13)0.0134 (17)
N30.0301 (17)0.0392 (17)0.0421 (18)0.0000 (14)−0.0012 (14)0.0075 (15)
C10.0334 (18)0.0218 (17)0.0339 (18)0.0022 (15)−0.0028 (14)−0.0037 (15)
C20.0243 (17)0.0253 (17)0.0226 (17)0.0047 (15)0.0042 (13)0.0035 (15)
C30.0331 (18)0.0288 (19)0.0235 (16)0.0015 (16)−0.0044 (13)−0.0022 (15)
C40.0241 (17)0.0296 (18)0.0258 (17)0.0001 (15)0.0036 (13)0.0042 (15)
C50.0266 (17)0.0259 (18)0.0268 (17)0.0001 (14)0.0038 (13)0.0016 (14)
C60.035 (2)0.035 (2)0.0363 (19)0.0006 (18)0.0026 (15)0.0065 (17)
C70.035 (2)0.050 (2)0.040 (2)−0.0088 (19)0.0065 (16)0.0088 (19)
C80.042 (2)0.044 (2)0.0331 (19)−0.0032 (19)0.0169 (15)0.0040 (17)
C90.048 (2)0.034 (2)0.0313 (19)0.0001 (19)0.0014 (16)0.0023 (17)
C100.0289 (17)0.036 (2)0.0320 (18)−0.0045 (16)0.0041 (14)0.0015 (16)
C110.0276 (17)0.0246 (17)0.0222 (15)0.0014 (16)−0.0017 (13)0.0026 (16)
C120.0293 (18)0.0280 (19)0.0346 (18)0.0013 (16)0.0043 (14)0.0048 (17)
C130.063 (3)0.024 (2)0.039 (2)0.0072 (19)0.0000 (18)−0.0046 (18)
C140.064 (3)0.0213 (19)0.045 (2)−0.0073 (19)−0.0067 (19)0.0044 (18)
C150.066 (3)0.043 (2)0.042 (2)−0.018 (2)0.0138 (18)0.008 (2)
C160.049 (2)0.032 (2)0.035 (2)−0.0066 (18)0.0085 (16)0.0010 (17)
C170.0216 (16)0.0277 (18)0.0310 (18)0.0059 (15)0.0035 (13)0.0050 (15)
C180.0253 (17)0.0257 (18)0.0328 (18)0.0046 (15)0.0016 (13)−0.0034 (15)
C190.0320 (19)0.033 (2)0.041 (2)−0.0028 (17)0.0057 (15)0.0012 (17)
C200.038 (2)0.041 (2)0.045 (2)0.0015 (19)0.0106 (16)0.0052 (18)
C210.037 (2)0.029 (2)0.056 (2)−0.0055 (17)0.0153 (17)−0.0056 (19)
C220.0274 (19)0.039 (2)0.054 (2)−0.0034 (17)0.0044 (15)−0.0153 (19)
C230.040 (2)0.034 (2)0.0301 (18)0.0011 (17)0.0053 (15)−0.0023 (17)
C240.0182 (16)0.0330 (19)0.0260 (16)−0.0040 (15)0.0005 (12)0.0046 (16)
C250.0304 (18)0.039 (2)0.0266 (18)−0.0057 (17)0.0020 (14)−0.0024 (17)
C260.042 (2)0.048 (3)0.032 (2)−0.017 (2)0.0028 (16)0.0041 (19)
C270.044 (2)0.072 (3)0.032 (2)−0.018 (2)0.0144 (16)−0.014 (2)
C280.044 (2)0.055 (3)0.046 (2)−0.002 (2)0.0145 (17)−0.013 (2)
C290.038 (2)0.039 (2)0.036 (2)−0.0014 (18)0.0014 (15)0.0011 (18)

Geometric parameters (Å, °)

Pd1—P12.2198 (7)C10—H10A0.9300
Pd1—P22.2087 (9)C11—C121.375 (4)
Pd1—O32.144 (2)C11—C161.388 (4)
Pd1—O62.1377 (17)C12—C131.378 (4)
P1—C41.829 (3)C12—H12A0.9300
P1—C51.808 (3)C13—C141.338 (5)
P1—C111.807 (3)C13—H13A0.9300
P2—C171.833 (3)C14—C151.385 (5)
P2—C181.803 (3)C14—H14A0.9300
P2—C241.800 (3)C15—C161.372 (5)
O1—N21.221 (4)C15—H15A0.9300
O2—N21.248 (3)C16—H16A0.9300
O3—N21.301 (3)C17—H17A0.9700
O4—N31.231 (3)C17—H17B0.9700
O5—N31.228 (3)C18—C191.389 (4)
O6—N31.320 (3)C18—C231.387 (4)
N1—C21.426 (3)C19—C201.375 (4)
N1—C41.454 (4)C19—H19A0.9300
N1—C171.441 (3)C20—C211.378 (4)
C1—C21.396 (4)C20—H20A0.9300
C1—C3i1.373 (4)C21—C221.376 (4)
C1—H1A0.9300C21—H21A0.9300
C2—C31.381 (4)C22—C231.373 (4)
C3—C1i1.373 (4)C22—H22A0.9300
C3—H3A0.9300C23—H23A0.9300
C4—H4A0.9700C24—C251.381 (4)
C4—H4B0.9700C24—C291.391 (4)
C5—C61.386 (4)C25—C261.370 (4)
C5—C101.396 (4)C25—H25A0.9300
C6—C71.384 (4)C26—C271.376 (5)
C6—H6A0.9300C26—H26A0.9300
C7—C81.354 (4)C27—C281.360 (5)
C7—H7A0.9300C27—H27A0.9300
C8—C91.371 (4)C28—C291.387 (4)
C8—H8A0.9300C28—H28A0.9300
C9—C101.372 (4)C29—H29A0.9300
C9—H9A0.9300
P2—Pd1—P192.34 (3)C9—C10—H10A120.2
O3—Pd1—P189.72 (5)C12—C11—P1121.9 (2)
O3—Pd1—P2177.92 (5)C12—C11—C16119.8 (3)
O3—Pd1—O691.77 (8)C16—C11—P1118.1 (2)
O6—Pd1—P1173.04 (6)C11—C12—C13119.6 (3)
O6—Pd1—P286.15 (6)C11—C12—H12A120.2
C4—P1—Pd1119.67 (10)C13—C12—H12A120.2
C5—P1—Pd1109.72 (9)C12—C13—H13A119.5
C5—P1—C4103.24 (13)C14—C13—C12120.9 (3)
C11—P1—Pd1109.65 (9)C14—C13—H13A119.5
C11—P1—C4104.84 (13)C13—C14—C15120.4 (3)
C11—P1—C5109.21 (14)C13—C14—H14A119.8
C17—P2—Pd1119.53 (10)C15—C14—H14A119.8
C18—P2—Pd1107.51 (10)C14—C15—H15A120.1
C18—P2—C17107.81 (14)C16—C15—C14119.8 (3)
C24—P2—Pd1111.46 (11)C16—C15—H15A120.1
C24—P2—C17100.67 (13)C11—C16—H16A120.2
C24—P2—C18109.47 (14)C15—C16—C11119.6 (3)
N2—O3—Pd1110.94 (18)C15—C16—H16A120.2
N3—O6—Pd1108.45 (16)P2—C17—H17A108.9
C2—N1—C4120.8 (2)P2—C17—H17B108.9
C2—N1—C17120.1 (2)N1—C17—P2113.2 (2)
C17—N1—C4111.6 (2)N1—C17—H17A108.9
O1—N2—O2122.5 (3)N1—C17—H17B108.9
O1—N2—O3118.9 (3)H17A—C17—H17B107.7
O2—N2—O3118.5 (3)C19—C18—P2120.2 (2)
O4—N3—O5123.5 (3)C23—C18—P2120.1 (2)
O4—N3—O6117.6 (3)C23—C18—C19119.1 (3)
O5—N3—O6118.9 (2)C18—C19—H19A120.0
C2—C1—H1A119.2C20—C19—C18119.9 (3)
C3i—C1—C2121.6 (3)C20—C19—H19A120.0
C3i—C1—H1A119.2C19—C20—C21120.5 (3)
C1—C2—N1122.5 (3)C19—C20—H20A119.8
C3—C2—C1115.7 (3)C21—C20—H20A119.8
C3—C2—N1121.7 (2)C20—C21—H21A120.1
C1i—C3—C2122.6 (3)C22—C21—C20119.8 (3)
C1i—C3—H3A118.7C22—C21—H21A120.1
C2—C3—H3A118.7C21—C22—H22A119.9
P1—C4—H4A109.6C23—C22—C21120.1 (3)
P1—C4—H4B109.6C23—C22—H22A119.9
N1—C4—P1110.08 (19)C18—C23—H23A119.8
N1—C4—H4A109.6C22—C23—C18120.5 (3)
N1—C4—H4B109.6C22—C23—H23A119.8
H4A—C4—H4B108.2C25—C24—C29119.3 (3)
C6—C5—P1120.5 (2)C25—C24—P2121.2 (2)
C6—C5—C10119.2 (3)C29—C24—P2119.1 (2)
C10—C5—P1120.3 (2)C24—C25—H25A119.9
C5—C6—H6A120.1C26—C25—C24120.2 (3)
C7—C6—C5119.7 (3)C26—C25—H25A119.9
C7—C6—H6A120.1C25—C26—C27120.5 (4)
C6—C7—H7A119.7C25—C26—H26A119.8
C8—C7—C6120.5 (3)C27—C26—H26A119.8
C8—C7—H7A119.7C26—C27—H27A120.0
C7—C8—C9120.4 (3)C28—C27—C26120.0 (3)
C7—C8—H8A119.8C28—C27—H27A120.0
C9—C8—H8A119.8C27—C28—C29120.4 (4)
C8—C9—C10120.5 (3)C27—C28—H28A119.8
C8—C9—H9A119.7C29—C28—H28A119.8
C10—C9—H9A119.7C24—C29—H29A120.2
C5—C10—H10A120.2C28—C29—C24119.7 (3)
C9—C10—C5119.7 (3)C28—C29—H29A120.2

Symmetry codes: (i) −x+2, −y+4, −z.

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
C4—H4B···O5ii0.972.313.248 (3)163

Symmetry codes: (ii) x−1, y, z.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HK2653).

References

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