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Acta Crystallogr Sect E Struct Rep Online. 2009 November 1; 65(Pt 11): m1391.
Published online 2009 October 17. doi:  10.1107/S1600536809041919
PMCID: PMC2971188

cis-Dichlorido­bis(trimethoxy­phos­phine)palladium(II) at 125 K

Abstract

The title compound, [PdCl2(C3H9O3P)2], which is isotypic with its platinum analogue, adopts a slightly distorted cis square-planar geometry for the Pd centre.

Related literature

For the platinum analogue, see: Bao et al. (1987 [triangle]). For related platinum complexes, see: Slawin et al. (2007a [triangle],b [triangle]). For cis-bis­(triisopropoxyphosphino)platinum dichloride, see: Slawin et al. (2009 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-65-m1391-scheme1.jpg

Experimental

Crystal data

  • [PdCl2(C3H9O3P)2]
  • M r = 425.46
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-65-m1391-efi1.jpg
  • a = 6.8059 (19) Å
  • b = 16.897 (5) Å
  • c = 13.374 (4) Å
  • β = 100.086 (7)°
  • V = 1514.2 (7) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 1.80 mm−1
  • T = 125 K
  • 0.22 × 0.16 × 0.13 mm

Data collection

  • Rigaku SCXmini diffractometer
  • Absorption correction: multi-scan (ABSCOR; Higashi, 1995 [triangle]) T min = 0.662, T max = 0.791
  • 6333 measured reflections
  • 2639 independent reflections
  • 2338 reflections with I > 2σ(I)
  • R int = 0.072

Refinement

  • R[F 2 > 2σ(F 2)] = 0.054
  • wR(F 2) = 0.090
  • S = 1.07
  • 2639 reflections
  • 161 parameters
  • H-atom parameters constrained
  • Δρmax = 1.26 e Å−3
  • Δρmin = −0.71 e Å−3
  • Absolute structure: Flack (1983 [triangle]), 1308 Friedel pairs
  • Flack parameter: −0.01 (5)

Data collection: SCXmini (Rigaku, 2006 [triangle]); cell refinement: PROCESS-AUTO (Rigaku, 1998 [triangle]); data reduction: PROCESS-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: CrystalStructure (Rigaku, 2006 [triangle]); software used to prepare material for publication: CrystalStructure.

Table 1
Selected geometric parameters (Å, °)

Supplementary Material

Crystal structure: contains datablocks General, I. DOI: 10.1107/S1600536809041919/fi2085sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809041919/fi2085Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

supplementary crystallographic information

Comment

[PdCl2(P(OMe)3)2] is isomorphous with its platinum analogue [PtCl2(P(OMe)3)2] (2) (Bao et al., 1987) and adopts a cis square planar geometry, Whereas the Pt complex was reported to have quite dissmilar bond lengths for Pt—P1/Pt—P2 and Pt—Cl1/PtCl2 bond lengths these pairs of bonds are equivalent in the title compound.

The Pd—Cl bond bonds in (1) ( Pd(1)—Cl(1) 2.356?(2), Pd(1)—Cl(2) 2.358?(2) Å ) are shorter than the Pt—Cl bonds in (2) whilst the Pd—P bonds ( Pd(1)—P(1) 2.241?(2), Pd(1)—P(2) 2.233?(2) Å ) are longer than the Pt—P bonds in (2). The P—M—P angle ( P(1)—Pd(1)—P(2) 92.38?(8) ° ) is reduced and the Cl—M—Cl angle is enlarged ( Cl(1)—Pd(1)—Cl(2) 89.71?(8) ° ) on going from Pt to Pd with the palladium compound reported here having angles which are closer to ideal square planar .

Experimental

0.5 g (1.75 mmol) of PdCl2(COD) was dissolved in dichloromethane (5 mL) in a round-bottomed flask. To this 0.41 mL (3.5 mmol) of trimethylphosphite was added. The solution was stirred for 0.5 h at room temperature. The product was precipitated via slow diffusion of hexane and was then filtered off and dried under vacuum, [PdCl2(P(OMe)3)2] (1.36 mmol, ca 77%). 31P-{1H}NMR: δ 97.9 p.p.m..

Refinement

All H atoms were included in calculated positions and refined as riding atoms with Uĩso~(H) = 1.5 U~eq~. The highest peak in the difference map is 1.097 Å from atom Pd1.

Figures

Fig. 1.
The structure of the title compound with displacement ellipsoids drawn at the 50% probability level, hydrogen atoms omitted for clarity.

Crystal data

[PdCl2(C3H9O3P)2]F(000) = 848.00
Mr = 425.46Dx = 1.866 Mg m3
Monoclinic, CcMo Kα radiation, λ = 0.71075 Å
Hall symbol: C -2ycCell parameters from 7139 reflections
a = 6.8059 (19) Åθ = 3.1–27.7°
b = 16.897 (5) ŵ = 1.80 mm1
c = 13.374 (4) ÅT = 125 K
β = 100.086 (7)°Chunk, yellow
V = 1514.2 (7) Å30.22 × 0.16 × 0.13 mm
Z = 4

Data collection

Rigaku SCXmini diffractometer2639 independent reflections
Radiation source: fine-focus sealed tube2338 reflections with F2 > 2.0σ(F2)
graphiteRint = 0.072
Detector resolution: 6.85 pixels mm-1θmax = 25.4°, θmin = 2.1°
ω scansh = −8→8
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)k = −20→20
Tmin = 0.662, Tmax = 0.791l = −16→16
6333 measured reflections

Refinement

Refinement on F2H-atom parameters constrained
R[F2 > 2σ(F2)] = 0.054w = 1/[σ^2^(Fo^2^) + (0.0247P)^2^] where P = (Fo^2^ + 2Fc^2^)/3
wR(F2) = 0.090(Δ/σ)max < 0.001
S = 1.07Δρmax = 1.26 e Å3
2639 reflectionsΔρmin = −0.71 e Å3
161 parametersAbsolute structure: Flack,(1983), 1308 Friedel pairs
Primary atom site location: structure-invariant direct methodsFlack parameter: −0.01 (5)
Hydrogen site location: inferred from neighbouring sites

Special details

Geometry. ENTER SPECIAL DETAILS OF THE MOLECULAR GEOMETRY
Refinement. Refinement was performed using all reflections. The weighted R-factor (wR) and goodness of fit (S) are based on F2. R-factor (gt) are based on F. The threshold expression of F2 > 2.0 σ(F2) is used only for calculating R-factor (gt).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
Pd(1)0.50973 (10)0.10743 (4)0.45788 (7)0.01777 (16)
Cl(1)0.4602 (3)0.23766 (14)0.39555 (17)0.0298 (6)
Cl(2)0.2407 (3)0.06430 (14)0.33413 (17)0.0277 (6)
P(1)0.5605 (3)−0.01677 (14)0.51540 (16)0.0183 (5)
P(2)0.7614 (3)0.15409 (14)0.57243 (17)0.0201 (5)
O(1)0.7314 (8)−0.0612 (3)0.4734 (4)0.0215 (14)
O(2)0.3841 (8)−0.0766 (3)0.4858 (4)0.0210 (14)
O(3)0.6237 (9)−0.0227 (3)0.6348 (4)0.0252 (15)
O(4)0.9294 (8)0.0917 (3)0.6089 (4)0.0259 (15)
O(5)0.6928 (8)0.1816 (3)0.6740 (4)0.0267 (15)
O(6)0.8710 (8)0.2305 (3)0.5430 (4)0.0202 (14)
C(1)0.7285 (16)−0.0650 (6)0.3643 (6)0.034 (2)
C(2)0.1966 (14)−0.0676 (5)0.5230 (7)0.030 (2)
C(3)0.6711 (15)−0.0993 (5)0.6843 (7)0.033 (2)
C(4)1.1106 (14)0.1149 (5)0.6777 (7)0.036 (2)
C(5)0.5731 (15)0.2526 (5)0.6788 (6)0.032 (2)
C(6)0.9618 (13)0.2290 (5)0.4527 (8)0.032 (2)
H(1)0.7662−0.11830.34590.041*
H(2)0.8233−0.02650.34550.041*
H(3)0.5939−0.05270.32810.041*
H(4)0.2211−0.07230.59720.037*
H(5)0.1031−0.10900.49350.037*
H(6)0.1394−0.01550.50340.037*
H(7)0.6000−0.10450.74170.040*
H(8)0.8152−0.10280.70890.040*
H(9)0.6298−0.14190.63540.040*
H(10)1.20470.13870.63880.043*
H(11)1.17160.06810.71380.043*
H(12)1.07740.15340.72690.043*
H(13)0.66140.29800.69750.038*
H(14)0.48740.24540.72980.038*
H(15)0.49010.26210.61230.038*
H(16)1.09300.25460.46720.038*
H(17)0.87640.25750.39770.038*
H(18)0.97750.17400.43210.038*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Pd(1)0.0217 (3)0.0152 (3)0.0159 (3)0.0006 (3)0.0018 (2)−0.0001 (3)
Cl(1)0.0375 (15)0.0183 (13)0.0301 (14)0.0010 (12)−0.0040 (11)0.0048 (10)
Cl(2)0.0321 (14)0.0253 (14)0.0223 (13)−0.0027 (12)−0.0050 (11)0.0006 (10)
P(1)0.0228 (14)0.0171 (13)0.0157 (13)−0.0017 (11)0.0056 (10)−0.0012 (9)
P(2)0.0234 (15)0.0173 (14)0.0193 (13)−0.0010 (11)0.0031 (11)−0.0002 (10)
O(1)0.031 (3)0.019 (3)0.014 (3)0.013 (3)0.003 (2)0.002 (2)
O(2)0.024 (3)0.019 (3)0.020 (3)0.001 (2)0.004 (2)0.004 (2)
O(3)0.038 (4)0.019 (3)0.016 (3)0.005 (3)−0.002 (2)0.002 (2)
O(4)0.021 (3)0.017 (3)0.037 (3)0.000 (2)−0.003 (3)−0.001 (2)
O(5)0.036 (4)0.026 (3)0.019 (3)0.000 (3)0.006 (2)−0.002 (2)
O(6)0.025 (3)0.019 (3)0.017 (3)0.000 (2)0.005 (2)0.004 (2)
C(1)0.050 (7)0.038 (6)0.014 (5)0.015 (5)0.006 (5)−0.010 (4)
C(2)0.030 (6)0.026 (5)0.036 (6)−0.002 (5)0.008 (4)−0.002 (5)
C(3)0.046 (6)0.024 (5)0.030 (5)0.006 (5)0.006 (4)−0.002 (4)
C(4)0.026 (5)0.029 (6)0.047 (6)0.006 (4)−0.007 (4)0.007 (5)
C(5)0.045 (6)0.036 (6)0.016 (5)−0.003 (5)0.011 (4)−0.009 (4)
C(6)0.037 (8)0.028 (5)0.033 (5)−0.005 (4)0.013 (5)−0.008 (5)

Geometric parameters (Å, °)

Pd(1)—Cl(1)2.356 (2)C(1)—H(2)0.980
Pd(1)—Cl(2)2.358 (2)C(1)—H(3)0.980
Pd(1)—P(1)2.241 (2)C(2)—H(4)0.980
Pd(1)—P(2)2.233 (2)C(2)—H(5)0.980
P(1)—O(1)1.568 (6)C(2)—H(6)0.980
P(1)—O(2)1.567 (6)C(3)—H(7)0.980
P(1)—O(3)1.583 (5)C(3)—H(8)0.980
P(2)—O(4)1.568 (6)C(3)—H(9)0.980
P(2)—O(5)1.582 (6)C(4)—H(10)0.980
P(2)—O(6)1.575 (6)C(4)—H(11)0.980
O(1)—C(1)1.457 (10)C(4)—H(12)0.980
O(2)—C(2)1.457 (12)C(5)—H(13)0.980
O(3)—C(3)1.464 (10)C(5)—H(14)0.980
O(4)—C(4)1.458 (10)C(5)—H(15)0.980
O(5)—C(5)1.458 (11)C(6)—H(16)0.980
O(6)—C(6)1.451 (12)C(6)—H(17)0.980
C(1)—H(1)0.980C(6)—H(18)0.980
Cl(1)···O(5)i3.473 (5)H(4)···O(6)iii3.594
Cl(1)···C(5)i3.563 (8)H(4)···C(4)viii3.466
O(1)···C(2)ii3.121 (11)H(4)···C(5)iii3.367
O(2)···O(6)iii3.352 (7)H(4)···H(8)viii3.402
O(2)···C(6)iii3.367 (10)H(4)···H(11)viii2.891
O(3)···C(1)iv3.369 (10)H(4)···H(13)iii2.636
O(4)···C(2)ii3.550 (11)H(4)···H(15)iii3.232
O(5)···Cl(1)v3.473 (5)H(5)···Cl(1)iii2.989
O(5)···C(1)iv3.194 (11)H(5)···O(1)viii2.624
O(6)···O(2)vi3.352 (7)H(5)···O(6)iii3.271
C(1)···O(3)vii3.369 (10)H(5)···C(1)viii2.915
C(1)···O(5)vii3.194 (11)H(5)···C(5)iii3.440
C(1)···C(2)ii3.506 (13)H(5)···H(1)viii2.756
C(2)···O(1)viii3.121 (11)H(5)···H(2)viii2.858
C(2)···O(4)viii3.550 (11)H(5)···H(13)iii3.113
C(2)···C(1)viii3.506 (13)H(5)···H(15)iii2.879
C(5)···Cl(1)v3.563 (8)H(5)···H(17)iii3.321
C(6)···O(2)vi3.367 (10)H(6)···O(1)viii2.842
Pd(1)···H(7)vii3.060H(6)···O(4)viii2.832
Pd(1)···H(10)viii3.493H(6)···C(1)viii3.188
Cl(1)···H(1)ix2.793H(6)···C(4)viii3.238
Cl(1)···H(5)vi2.989H(6)···H(1)viii3.469
Cl(1)···H(7)vii3.300H(6)···H(2)viii2.745
Cl(1)···H(12)i3.121H(6)···H(10)viii3.158
Cl(1)···H(13)i3.103H(6)···H(11)viii3.121
Cl(1)···H(14)i3.585H(6)···H(18)viii3.466
Cl(1)···H(16)viii2.843H(7)···Pd(1)iv3.060
Cl(1)···H(18)viii3.571H(7)···Cl(1)iv3.300
Cl(2)···H(2)viii3.255H(7)···Cl(2)iv3.005
Cl(2)···H(4)vii3.151H(7)···C(1)iv3.339
Cl(2)···H(7)vii3.005H(7)···H(2)iv2.897
Cl(2)···H(8)x3.149H(7)···H(3)iv2.900
Cl(2)···H(11)x2.747H(7)···H(13)iii3.370
Cl(2)···H(13)i2.949H(7)···H(18)iv3.489
Cl(2)···H(18)viii3.031H(8)···Cl(2)xiv3.149
O(1)···H(4)ii3.457H(8)···C(5)xi3.076
O(1)···H(5)ii2.624H(8)···H(2)iv2.842
O(1)···H(6)ii2.842H(8)···H(3)iv3.543
O(1)···H(16)iii3.250H(8)···H(4)ii3.402
O(2)···H(16)iii3.216H(8)···H(13)xi2.917
O(2)···H(17)iii3.038H(8)···H(14)xi2.814
O(3)···H(2)iv3.022H(8)···H(15)xi2.973
O(3)···H(3)iv2.920H(8)···H(18)iv3.229
O(4)···H(1)iv3.567H(9)···O(6)iii2.917
O(4)···H(2)iv3.543H(9)···C(5)xi3.465
O(4)···H(4)ii3.429H(9)···C(6)iii3.325
O(4)···H(6)ii2.832H(9)···H(13)iii3.578
O(5)···H(1)iv2.506H(9)···H(14)xi3.173
O(5)···H(2)iv3.494H(9)···H(15)xi3.001
O(5)···H(3)iv3.151H(9)···H(16)iii2.826
O(5)···H(10)viii3.352H(10)···Pd(1)ii3.493
O(6)···H(4)vi3.594H(10)···O(5)ii3.352
O(6)···H(5)vi3.271H(10)···C(5)ii3.132
O(6)···H(9)vi2.917H(10)···H(6)ii3.158
C(1)···H(5)ii2.915H(10)···H(14)ii2.759
C(1)···H(6)ii3.188H(10)···H(15)ii2.914
C(1)···H(7)vii3.339H(11)···Cl(2)xiv2.747
C(1)···H(12)vii3.575H(11)···C(2)ii3.457
C(1)···H(16)iii3.534H(11)···H(2)iv3.268
C(2)···H(1)viii3.535H(11)···H(3)xiv3.021
C(2)···H(2)viii3.235H(11)···H(4)ii2.891
C(2)···H(11)viii3.457H(11)···H(6)ii3.121
C(2)···H(13)iii3.293H(12)···Cl(1)v3.121
C(2)···H(15)iii3.502H(12)···C(1)iv3.575
C(3)···H(2)iv3.075H(12)···H(1)iv2.925
C(3)···H(3)iv3.305H(12)···H(2)iv3.327
C(3)···H(14)xi3.381H(12)···H(14)ii3.188
C(3)···H(15)xi3.443H(12)···H(17)v3.161
C(4)···H(1)iv3.522H(13)···Cl(1)v3.103
C(4)···H(2)iv3.554H(13)···Cl(2)v2.949
C(4)···H(4)ii3.466H(13)···C(2)vi3.293
C(4)···H(6)ii3.238H(13)···H(4)vi2.636
C(4)···H(14)ii3.361H(13)···H(5)vi3.113
C(5)···H(1)iv3.293H(13)···H(7)vi3.370
C(5)···H(4)vi3.367H(13)···H(8)ix2.917
C(5)···H(5)vi3.440H(13)···H(9)vi3.578
C(5)···H(8)ix3.076H(14)···Cl(1)v3.585
C(5)···H(9)ix3.465H(14)···C(3)ix3.381
C(5)···H(10)viii3.132H(14)···C(4)viii3.361
C(5)···H(17)xii3.430H(14)···C(6)xii3.047
C(6)···H(9)vi3.325H(14)···H(1)iv3.097
C(6)···H(14)xiii3.047H(14)···H(3)iv3.538
H(1)···Cl(1)xi2.793H(14)···H(8)ix2.814
H(1)···O(4)vii3.567H(14)···H(9)ix3.173
H(1)···O(5)vii2.506H(14)···H(10)viii2.759
H(1)···C(2)ii3.535H(14)···H(12)viii3.188
H(1)···C(4)vii3.522H(14)···H(16)xii3.131
H(1)···C(5)vii3.293H(14)···H(17)xii2.492
H(1)···H(5)ii2.756H(14)···H(18)xii3.040
H(1)···H(6)ii3.469H(15)···C(2)vi3.502
H(1)···H(12)vii2.925H(15)···C(3)ix3.443
H(1)···H(14)vii3.097H(15)···H(4)vi3.232
H(1)···H(16)iii3.050H(15)···H(5)vi2.879
H(1)···H(17)iii3.545H(15)···H(8)ix2.973
H(2)···Cl(2)ii3.255H(15)···H(9)ix3.001
H(2)···O(3)vii3.022H(15)···H(10)viii2.914
H(2)···O(4)vii3.543H(15)···H(16)viii3.041
H(2)···O(5)vii3.494H(16)···Cl(1)ii2.843
H(2)···C(2)ii3.235H(16)···O(1)vi3.250
H(2)···C(3)vii3.075H(16)···O(2)vi3.216
H(2)···C(4)vii3.554H(16)···C(1)vi3.534
H(2)···H(5)ii2.858H(16)···H(1)vi3.050
H(2)···H(6)ii2.745H(16)···H(9)vi2.826
H(2)···H(7)vii2.897H(16)···H(14)xiii3.131
H(2)···H(8)vii2.842H(16)···H(15)ii3.041
H(2)···H(11)vii3.268H(17)···O(2)vi3.038
H(2)···H(12)vii3.327H(17)···C(5)xiii3.430
H(3)···O(3)vii2.920H(17)···H(1)vi3.545
H(3)···O(5)vii3.151H(17)···H(5)vi3.321
H(3)···C(3)vii3.305H(17)···H(12)i3.161
H(3)···H(7)vii2.900H(17)···H(14)xiii2.492
H(3)···H(8)vii3.543H(18)···Cl(1)ii3.571
H(3)···H(11)x3.021H(18)···Cl(2)ii3.031
H(3)···H(14)vii3.538H(18)···H(6)ii3.466
H(4)···Cl(2)iv3.151H(18)···H(7)vii3.489
H(4)···O(1)viii3.457H(18)···H(8)vii3.229
H(4)···O(4)viii3.429H(18)···H(14)xiii3.040
Cl(1)—Pd(1)—Cl(2)89.71 (8)O(2)—C(2)—H(4)109.5
Cl(1)—Pd(1)—P(1)179.04 (9)O(2)—C(2)—H(5)109.5
Cl(1)—Pd(1)—P(2)87.59 (8)O(2)—C(2)—H(6)109.5
Cl(2)—Pd(1)—P(1)90.32 (8)H(4)—C(2)—H(5)109.5
Cl(2)—Pd(1)—P(2)177.30 (8)H(4)—C(2)—H(6)109.5
P(1)—Pd(1)—P(2)92.38 (8)H(5)—C(2)—H(6)109.5
Pd(1)—P(1)—O(1)113.9 (2)O(3)—C(3)—H(7)109.5
Pd(1)—P(1)—O(2)116.9 (2)O(3)—C(3)—H(8)109.5
Pd(1)—P(1)—O(3)113.8 (2)O(3)—C(3)—H(9)109.5
O(1)—P(1)—O(2)100.6 (3)H(7)—C(3)—H(8)109.5
O(1)—P(1)—O(3)104.1 (3)H(7)—C(3)—H(9)109.5
O(2)—P(1)—O(3)106.0 (3)H(8)—C(3)—H(9)109.5
Pd(1)—P(2)—O(4)113.9 (2)O(4)—C(4)—H(10)109.5
Pd(1)—P(2)—O(5)112.8 (2)O(4)—C(4)—H(11)109.5
Pd(1)—P(2)—O(6)117.3 (2)O(4)—C(4)—H(12)109.5
O(4)—P(2)—O(5)103.9 (3)H(10)—C(4)—H(11)109.5
O(4)—P(2)—O(6)106.1 (3)H(10)—C(4)—H(12)109.5
O(5)—P(2)—O(6)101.4 (3)H(11)—C(4)—H(12)109.5
P(1)—O(1)—C(1)119.9 (5)O(5)—C(5)—H(13)109.5
P(1)—O(2)—C(2)121.6 (5)O(5)—C(5)—H(14)109.5
P(1)—O(3)—C(3)120.7 (5)O(5)—C(5)—H(15)109.5
P(2)—O(4)—C(4)120.4 (5)H(13)—C(5)—H(14)109.5
P(2)—O(5)—C(5)122.1 (5)H(13)—C(5)—H(15)109.5
P(2)—O(6)—C(6)118.9 (5)H(14)—C(5)—H(15)109.5
O(1)—C(1)—H(1)109.5O(6)—C(6)—H(16)109.5
O(1)—C(1)—H(2)109.5O(6)—C(6)—H(17)109.5
O(1)—C(1)—H(3)109.5O(6)—C(6)—H(18)109.5
H(1)—C(1)—H(2)109.5H(16)—C(6)—H(17)109.5
H(1)—C(1)—H(3)109.5H(16)—C(6)—H(18)109.5
H(2)—C(1)—H(3)109.5H(17)—C(6)—H(18)109.5
Cl(1)—Pd(1)—P(2)—O(4)−151.9 (2)O(1)—P(1)—O(2)—C(2)170.3 (5)
Cl(1)—Pd(1)—P(2)—O(5)90.0 (2)O(2)—P(1)—O(1)—C(1)73.0 (6)
Cl(1)—Pd(1)—P(2)—O(6)−27.2 (2)O(1)—P(1)—O(3)—C(3)−52.8 (7)
Cl(2)—Pd(1)—P(1)—O(1)98.3 (2)O(3)—P(1)—O(1)—C(1)−177.4 (6)
Cl(2)—Pd(1)—P(1)—O(2)−18.5 (2)O(2)—P(1)—O(3)—C(3)52.8 (7)
Cl(2)—Pd(1)—P(1)—O(3)−142.6 (2)O(3)—P(1)—O(2)—C(2)62.1 (6)
P(1)—Pd(1)—P(2)—O(4)27.1 (2)Pd(1)—P(2)—O(4)—C(4)175.4 (5)
P(1)—Pd(1)—P(2)—O(5)−91.0 (2)Pd(1)—P(2)—O(5)—C(5)−71.2 (6)
P(1)—Pd(1)—P(2)—O(6)151.9 (2)Pd(1)—P(2)—O(6)—C(6)−58.1 (5)
P(2)—Pd(1)—P(1)—O(1)−81.8 (2)O(4)—P(2)—O(5)—C(5)165.0 (6)
P(2)—Pd(1)—P(1)—O(2)161.4 (2)O(5)—P(2)—O(4)—C(4)−61.6 (7)
P(2)—Pd(1)—P(1)—O(3)37.3 (2)O(4)—P(2)—O(6)—C(6)70.5 (5)
Pd(1)—P(1)—O(1)—C(1)−52.9 (6)O(6)—P(2)—O(4)—C(4)44.8 (7)
Pd(1)—P(1)—O(2)—C(2)−65.9 (6)O(5)—P(2)—O(6)—C(6)178.7 (5)
Pd(1)—P(1)—O(3)—C(3)−177.3 (5)O(6)—P(2)—O(5)—C(5)55.1 (6)

Symmetry codes: (i) x−1/2, −y+1/2, z−1/2; (ii) x+1, y, z; (iii) x−1/2, y−1/2, z; (iv) x, −y, z+1/2; (v) x+1/2, −y+1/2, z+1/2; (vi) x+1/2, y+1/2, z; (vii) x, −y, z−1/2; (viii) x−1, y, z; (ix) x−1/2, y+1/2, z; (x) x−1, −y, z−1/2; (xi) x+1/2, y−1/2, z; (xii) x−1/2, −y+1/2, z+1/2; (xiii) x+1/2, −y+1/2, z−1/2; (xiv) x+1, −y, z+1/2.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: FI2085).

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