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Acta Crystallogr Sect E Struct Rep Online. 2009 November 1; 65(Pt 11): m1472–m1473.
Published online 2009 October 31. doi:  10.1107/S1600536809044237
PMCID: PMC2971174

(μ-trans-1,2-Di-4-pyridylethyl­ene-κ2 N:N′)bis­[bis­(N,N-diethyl­dithio­carbamato-κ2 S,S′)zinc(II)] chloro­form solvate

Abstract

The dinuclear title solvate, [Zn2(C5H10NS2)4(C12H10N2)]·CHCl3, features two five-coordinate Zn atoms; both coordination polyhedra are distorted, but one has an NS4 donor set approximating to a square pyramid (with the N atom in the apical site), while the other is closer to a ZnNS4 trigonal-bipyramidal arrangement (with the N atom in an equatorial site). In both cases, the ZnII atom is chelated by two S,S′-bidentate dithiol­ate ligands. In the crystal, the chloro­form solvent mol­ecules reside in cavities defined by the dinuclear species and are held in place via C—H(...)S contacts.

Related literature

For background to supra­molecular polymers of zinc 1,1-dithiol­ates, see: Lai et al. (2002 [triangle]); Chen et al. (2006 [triangle]); Benson et al. (2007 [triangle]). For a related structure and the synthesis, see: Lai & Tiekink (2003 [triangle]). For additional geometrical analysis, see: Addison et al. (1984 [triangle]).

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Object name is e-65-m1472-scheme1.jpg

Experimental

Crystal data

  • [Zn2(C5H10NS2)4(C12H10N2)]·CHCl3
  • M r = 1025.37
  • Orthorhombic, An external file that holds a picture, illustration, etc.
Object name is e-65-m1472-efi1.jpg
  • a = 17.443 (3) Å
  • b = 15.739 (3) Å
  • c = 16.823 (3) Å
  • V = 4618.5 (14) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 1.61 mm−1
  • T = 98 K
  • 0.35 × 0.21 × 0.09 mm

Data collection

  • Rigaku AFC12K/SATURN724 diffractometer
  • Absorption correction: multi-scan (ABSCOR; Higashi, 1995 [triangle]) T min = 0.824, T max = 1
  • 36476 measured reflections
  • 9260 independent reflections
  • 8995 reflections with I > 2σ(I)
  • R int = 0.050

Refinement

  • R[F 2 > 2σ(F 2)] = 0.034
  • wR(F 2) = 0.075
  • S = 1.07
  • 9260 reflections
  • 477 parameters
  • 1 restraint
  • H-atom parameters constrained
  • Δρmax = 0.83 e Å−3
  • Δρmin = −0.40 e Å−3
  • Absolute structure: Flack (1983 [triangle]), 3766 Friedel pairs
  • Flack parameter: −0.004 (8)

Data collection: CrystalClear (Rigaku/MSC, 2005 [triangle]); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: DIAMOND (Brandenburg, 2006 [triangle]); software used to prepare material for publication: SHELXL97.

Table 1
Selected bond lengths (Å)
Table 2
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809044237/hb5173sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809044237/hb5173Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

supplementary crystallographic information

Comment

The title compound (I) was prepared in connection with crystal engineering studies of zinc(II) 1,1-dithiolates (Lai et al., 2002; Chen et al., 2006; Benson et al. 2007). The dinuclear compound features two five coordinate Zn atoms, each being coordinated by two dithiocarbamate ligands and a pyridine-N atom. The dithiocarbamate ligands are chelating but form disparate Zn—S bond distances that range from 2.3381 (10) to 2.6575 (9) Å. The coordination geometries for the Zn1 and Zn2 atoms are each based on a NS4 donor set but are distinct. Thus, the geometries for the Zn1 and Zn2 atoms are distorted towards trigonal bipyramidal (TB) and square pyramidal (SP), respectively. This is quantified by the values of τ = 0.56 and 0.36, respectively, compared with the ideal values of 1.0 and 0.0 for TB and SP, respectively (Addison et al., 1984).

The most closely related structure available for comparison is the diethyldithiocarbamate analogue of (I) which was co-crystallized with a trans-1,2-bis(4-pyridyl)ethylene molecule (Lai & Tiekink, 2003) rather than a solvent chloroform molecule as for (I). In the former, the range of Zn—S bond distances was considerably narrower, i.e. 2.4100 (10) to 2.4914 (11) Å, and the coordination geometry for Zn (the dinuclear molecule is centrosymmetric) was close to SP (τ = 0.13).

The solvent chlorofrom molecules in (I) reside in cavities defined by the dinuclear molecules and are held in place by C—H···S interactions, Table 1,

Experimental

Compound (I) was prepared by following a standard literature procedure (Lai & Tiekink, 2003) whereby two equivalents of Zn(S2CNEt2)2 were added to trans-1,2-bis(4-pyridyl)ethylene. Crystals were obtained from slow evaporation of a chloroform solution. When heated, the crystals turned opaque at 349–351 K and melted at 401–403 K.

Refinement

The H atoms were geometrically placed (C—H = 0.95–0.99 Å) and refined as riding with Uiso(H) = 1.2–1.5Ueq(C).

Figures

Fig. 1.
The molcular structure of (I) showing displacement ellipsoids at the 70% probability level.

Crystal data

[Zn2(C5H10NS2)4(C12H10N2)]·CHCl3F(000) = 2120
Mr = 1025.37Dx = 1.475 Mg m3
Orthorhombic, Pna21Mo Kα radiation, λ = 0.71069 Å
Hall symbol: P 2c -2nCell parameters from 19833 reflections
a = 17.443 (3) Åθ = 2.1–40.8°
b = 15.739 (3) ŵ = 1.61 mm1
c = 16.823 (3) ÅT = 98 K
V = 4618.5 (14) Å3Block, yellow
Z = 40.35 × 0.21 × 0.09 mm

Data collection

Rigaku AFC12K/SATURN724 diffractometer9260 independent reflections
Radiation source: fine-focus sealed tube8995 reflections with I > 2σ(I)
graphiteRint = 0.050
ω scansθmax = 27.5°, θmin = 2.1°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)h = −22→22
Tmin = 0.824, Tmax = 1k = −20→20
36476 measured reflectionsl = −17→21

Refinement

Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.034H-atom parameters constrained
wR(F2) = 0.075w = 1/[σ2(Fo2) + (0.0266P)2 + 3.3574P] where P = (Fo2 + 2Fc2)/3
S = 1.07(Δ/σ)max = 0.001
9260 reflectionsΔρmax = 0.83 e Å3
477 parametersΔρmin = −0.40 e Å3
1 restraintAbsolute structure: Flack (1983), 3766 Friedel pairs
Primary atom site location: structure-invariant direct methodsFlack parameter: −0.004 (8)

Special details

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
Zn10.48561 (2)0.46529 (2)0.25986 (2)0.01771 (8)
Zn20.52421 (2)1.04699 (2)−0.32727 (2)0.01811 (8)
S10.37402 (5)0.47688 (5)0.33808 (5)0.02142 (17)
S20.39216 (5)0.35268 (5)0.20769 (5)0.02060 (16)
S30.60161 (4)0.38777 (5)0.26719 (5)0.01975 (16)
S40.58224 (5)0.55975 (5)0.33339 (5)0.02023 (16)
S50.64756 (4)1.10741 (5)−0.32528 (6)0.02142 (16)
S60.59961 (5)0.96317 (5)−0.42580 (5)0.02180 (17)
S70.40173 (5)1.06415 (6)−0.38140 (6)0.02441 (18)
S80.45491 (5)1.17094 (5)−0.24764 (5)0.02131 (16)
N10.25911 (16)0.38216 (17)0.28033 (17)0.0202 (6)
N20.71730 (16)0.47956 (17)0.32773 (17)0.0202 (6)
N30.74526 (16)1.01190 (18)−0.40881 (17)0.0220 (6)
N40.30787 (18)1.1551 (2)−0.2899 (2)0.0353 (8)
N50.47859 (15)0.54237 (15)0.16051 (18)0.0165 (6)
N60.51719 (15)0.95913 (15)−0.2356 (2)0.0179 (5)
C10.33315 (19)0.40127 (18)0.2750 (2)0.0193 (6)
C20.22382 (19)0.3145 (2)0.2327 (2)0.0214 (7)
H2A0.18220.28770.26390.026*
H2B0.26270.27040.22120.026*
C30.1911 (3)0.3475 (2)0.1547 (2)0.0349 (9)
H3A0.15490.39370.16550.052*
H3B0.16440.30130.12710.052*
H3C0.23290.36880.12120.052*
C40.2053 (2)0.4269 (2)0.3333 (2)0.0259 (7)
H4A0.15550.43370.30590.031*
H4B0.22560.48420.34520.031*
C50.1932 (2)0.3788 (3)0.4108 (2)0.0343 (9)
H5A0.17580.32090.39920.051*
H5B0.15430.40810.44280.051*
H5C0.24150.37660.44040.051*
C60.64211 (18)0.4769 (2)0.3119 (2)0.0182 (6)
C70.7699 (2)0.4104 (2)0.3059 (2)0.0254 (7)
H7A0.81930.43510.28860.030*
H7B0.74800.37880.26030.030*
C80.7845 (2)0.3483 (3)0.3742 (3)0.0358 (9)
H8A0.81330.37710.41640.054*
H8B0.81430.29980.35460.054*
H8C0.73540.32820.39540.054*
C90.7508 (2)0.5538 (2)0.3680 (2)0.0243 (7)
H9A0.72680.60590.34640.029*
H9B0.80620.55620.35550.029*
C100.7411 (3)0.5535 (3)0.4577 (2)0.0343 (9)
H10A0.68680.54660.47090.051*
H10B0.75990.60740.47960.051*
H10C0.77050.50640.48060.051*
C110.67278 (19)1.0258 (2)−0.3888 (2)0.0185 (6)
C120.7677 (2)0.9474 (2)−0.4679 (2)0.0278 (8)
H12A0.81560.9656−0.49440.033*
H12B0.72720.9430−0.50900.033*
C130.7798 (2)0.8609 (2)−0.4302 (2)0.0340 (9)
H13A0.82040.8647−0.39000.051*
H13B0.79480.8199−0.47120.051*
H13C0.73210.8421−0.40490.051*
C140.80844 (19)1.0610 (2)−0.3729 (2)0.0274 (8)
H14A0.85471.0247−0.36980.033*
H14B0.79401.0773−0.31800.033*
C150.8274 (2)1.1405 (2)−0.4197 (2)0.0322 (8)
H15A0.84831.1245−0.47160.048*
H15B0.86541.1741−0.39050.048*
H15C0.78071.1742−0.42720.048*
C160.38029 (19)1.1340 (2)−0.3040 (2)0.0212 (7)
C170.2414 (2)1.1077 (3)−0.3288 (3)0.0414 (10)
H17A0.25691.0485−0.34050.050*
H17B0.19711.1061−0.29210.050*
C180.2196 (3)1.1518 (3)−0.4038 (3)0.0451 (11)
H18A0.20031.2087−0.39140.068*
H18B0.17951.1191−0.43090.068*
H18C0.26461.1564−0.43840.068*
C190.2882 (2)1.2217 (2)−0.2313 (2)0.0301 (8)
H19A0.24161.2521−0.24930.036*
H19B0.33061.2633−0.22830.036*
C200.2740 (2)1.1845 (3)−0.1493 (3)0.0383 (10)
H20A0.23131.1440−0.15190.058*
H20B0.26111.2302−0.11210.058*
H20C0.32021.1551−0.13090.058*
C210.47506 (18)0.62720 (19)0.1688 (2)0.0187 (6)
H210.47230.65030.22090.022*
C220.47521 (19)0.6821 (2)0.1050 (2)0.0199 (7)
H220.47180.74170.11360.024*
C230.48044 (18)0.6501 (2)0.0279 (2)0.0185 (6)
C240.48146 (19)0.5615 (2)0.0190 (2)0.0209 (7)
H240.48260.5366−0.03240.025*
C250.48072 (18)0.5108 (2)0.0864 (2)0.0199 (7)
H250.48180.45090.07980.024*
C260.48606 (19)0.7044 (2)−0.0429 (2)0.0197 (7)
H260.48150.6784−0.09370.024*
C270.4971 (2)0.7877 (2)−0.0400 (2)0.0212 (7)
H270.50040.81290.01130.025*
C280.50485 (19)0.8446 (2)−0.10882 (19)0.0170 (6)
C290.5127 (2)0.9317 (2)−0.0959 (2)0.0233 (7)
H290.51400.9536−0.04330.028*
C300.51845 (19)0.9857 (2)−0.1599 (2)0.0208 (7)
H300.52361.0448−0.15000.025*
C310.51125 (18)0.87512 (19)−0.2482 (2)0.0197 (6)
H310.51190.8549−0.30140.024*
C320.5043 (2)0.8172 (2)−0.1877 (2)0.0212 (7)
H320.49920.7585−0.19950.025*
C330.4971 (2)0.7614 (3)0.4505 (2)0.0313 (8)
H330.53060.78200.40630.038*
Cl10.44088 (7)0.84716 (6)0.48451 (7)0.0425 (2)
Cl20.43669 (6)0.68037 (8)0.41320 (8)0.0503 (3)
Cl30.55577 (7)0.72255 (6)0.52699 (7)0.0431 (3)

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Zn10.01558 (16)0.02010 (16)0.01744 (19)−0.00015 (13)0.00102 (15)0.00359 (15)
Zn20.01462 (16)0.02072 (17)0.01900 (19)−0.00070 (13)0.00125 (15)0.00434 (15)
S10.0177 (4)0.0264 (4)0.0202 (4)−0.0051 (3)0.0021 (3)−0.0059 (3)
S20.0192 (4)0.0200 (4)0.0226 (4)−0.0006 (3)0.0035 (3)−0.0026 (3)
S30.0168 (3)0.0178 (3)0.0247 (4)−0.0009 (3)0.0000 (3)0.0002 (3)
S40.0200 (4)0.0203 (4)0.0204 (4)0.0006 (3)−0.0014 (3)−0.0009 (3)
S50.0165 (3)0.0225 (3)0.0253 (4)−0.0024 (3)0.0019 (3)−0.0017 (3)
S60.0208 (4)0.0244 (4)0.0202 (4)−0.0017 (3)0.0016 (3)−0.0008 (3)
S70.0187 (4)0.0318 (4)0.0227 (4)0.0054 (3)−0.0028 (3)−0.0070 (4)
S80.0191 (4)0.0207 (3)0.0241 (4)−0.0002 (3)−0.0003 (3)−0.0009 (3)
N10.0179 (13)0.0221 (13)0.0206 (15)−0.0028 (10)0.0016 (11)−0.0041 (11)
N20.0175 (13)0.0220 (13)0.0210 (15)−0.0029 (10)0.0000 (11)0.0011 (11)
N30.0175 (14)0.0279 (14)0.0205 (15)0.0030 (11)0.0009 (11)0.0035 (12)
N40.0213 (16)0.0437 (19)0.041 (2)0.0091 (14)−0.0024 (14)−0.0157 (16)
N50.0147 (12)0.0169 (12)0.0178 (16)−0.0021 (9)−0.0002 (10)0.0002 (10)
N60.0172 (12)0.0188 (12)0.0179 (14)0.0014 (9)−0.0004 (11)0.0018 (11)
C10.0212 (15)0.0160 (13)0.0206 (17)−0.0023 (11)−0.0013 (12)0.0031 (12)
C20.0191 (15)0.0206 (15)0.0246 (18)−0.0026 (12)−0.0009 (13)−0.0035 (13)
C30.043 (2)0.0285 (18)0.034 (2)0.0029 (16)−0.0098 (18)−0.0050 (16)
C40.0174 (16)0.0299 (17)0.030 (2)−0.0014 (13)0.0040 (14)−0.0107 (15)
C50.0229 (18)0.054 (2)0.026 (2)−0.0052 (17)0.0018 (15)−0.0114 (18)
C60.0171 (15)0.0217 (14)0.0159 (16)−0.0040 (12)0.0006 (12)0.0020 (12)
C70.0163 (16)0.0306 (17)0.029 (2)0.0020 (13)0.0011 (14)−0.0009 (15)
C80.031 (2)0.035 (2)0.041 (3)0.0033 (16)−0.0037 (18)0.0049 (18)
C90.0196 (17)0.0286 (17)0.0249 (19)−0.0063 (13)−0.0022 (14)0.0006 (14)
C100.039 (2)0.040 (2)0.024 (2)−0.0037 (18)−0.0075 (17)−0.0049 (17)
C110.0173 (15)0.0226 (15)0.0156 (15)0.0035 (12)0.0038 (12)0.0048 (12)
C120.0229 (18)0.0343 (19)0.026 (2)0.0108 (14)0.0054 (15)0.0014 (16)
C130.041 (2)0.037 (2)0.024 (2)0.0156 (17)−0.0002 (17)−0.0029 (16)
C140.0120 (15)0.042 (2)0.028 (2)0.0027 (14)−0.0019 (13)0.0044 (16)
C150.0198 (17)0.042 (2)0.035 (2)−0.0045 (15)0.0030 (16)0.0036 (18)
C160.0192 (16)0.0223 (15)0.0222 (19)0.0017 (12)−0.0007 (13)−0.0006 (13)
C170.0250 (19)0.052 (2)0.047 (3)0.0083 (17)0.007 (2)−0.008 (2)
C180.034 (2)0.050 (3)0.051 (3)0.0033 (19)−0.002 (2)−0.006 (2)
C190.0235 (17)0.0352 (18)0.032 (2)0.0109 (14)−0.0013 (15)−0.0086 (17)
C200.035 (2)0.035 (2)0.046 (3)−0.0018 (17)0.0116 (19)−0.0060 (19)
C210.0184 (14)0.0202 (14)0.0174 (16)0.0011 (11)−0.0007 (13)−0.0028 (13)
C220.0213 (16)0.0183 (14)0.0201 (18)0.0009 (12)−0.0032 (13)−0.0008 (13)
C230.0150 (15)0.0225 (16)0.0181 (17)−0.0012 (12)−0.0005 (12)0.0012 (13)
C240.0198 (16)0.0209 (15)0.0218 (18)−0.0029 (12)−0.0012 (13)−0.0035 (14)
C250.0210 (16)0.0191 (15)0.0197 (17)−0.0008 (12)0.0002 (13)0.0026 (13)
C260.0222 (17)0.0220 (15)0.0149 (16)−0.0010 (12)−0.0016 (12)0.0019 (13)
C270.0250 (17)0.0225 (15)0.0161 (16)0.0000 (13)0.0006 (13)−0.0021 (13)
C280.0166 (15)0.0185 (14)0.0159 (16)0.0014 (12)0.0021 (12)0.0023 (12)
C290.0290 (19)0.0216 (16)0.0192 (18)0.0011 (13)0.0012 (14)0.0007 (14)
C300.0227 (16)0.0171 (15)0.0227 (18)−0.0007 (11)0.0005 (13)0.0013 (13)
C310.0217 (15)0.0206 (14)0.0167 (17)−0.0012 (12)0.0002 (13)−0.0006 (13)
C320.0262 (17)0.0178 (14)0.0196 (17)−0.0029 (12)0.0005 (14)−0.0003 (13)
C330.0268 (19)0.040 (2)0.027 (2)−0.0002 (16)0.0031 (16)0.0057 (17)
Cl10.0430 (6)0.0343 (5)0.0501 (7)0.0026 (4)0.0076 (5)0.0064 (5)
Cl20.0277 (5)0.0651 (7)0.0579 (7)−0.0034 (5)0.0009 (5)−0.0286 (6)
Cl30.0532 (7)0.0335 (5)0.0426 (6)−0.0029 (4)−0.0174 (5)0.0094 (4)

Geometric parameters (Å, °)

Zn1—N52.069 (3)C9—H9B0.9900
Zn1—S12.3567 (9)C10—H10A0.9800
Zn1—S32.3659 (9)C10—H10B0.9800
Zn1—S22.5629 (9)C10—H10C0.9800
Zn1—S42.5654 (9)C12—C131.517 (5)
Zn2—N62.075 (3)C12—H12A0.9900
Zn2—S72.3381 (10)C12—H12B0.9900
Zn2—S52.3526 (9)C13—H13A0.9800
Zn2—S62.4934 (10)C13—H13B0.9800
Zn2—S82.6575 (9)C13—H13C0.9800
S1—C11.746 (3)C14—C151.514 (5)
S2—C11.711 (3)C14—H14A0.9900
S3—C61.741 (3)C14—H14B0.9900
S4—C61.709 (3)C15—H15A0.9800
S5—C111.728 (3)C15—H15B0.9800
S6—C111.728 (3)C15—H15C0.9800
S7—C161.745 (3)C17—C181.490 (7)
S8—C161.712 (3)C17—H17A0.9900
N1—C11.329 (4)C17—H17B0.9900
N1—C21.468 (4)C18—H18A0.9800
N1—C41.473 (4)C18—H18B0.9800
N2—C61.339 (4)C18—H18C0.9800
N2—C71.470 (4)C19—C201.519 (6)
N2—C91.472 (4)C19—H19A0.9900
N3—C111.326 (4)C19—H19B0.9900
N3—C141.476 (4)C20—H20A0.9800
N3—C121.473 (5)C20—H20B0.9800
N4—C161.327 (4)C20—H20C0.9800
N4—C191.479 (5)C21—C221.377 (5)
N4—C171.525 (5)C21—H210.9500
N5—C251.343 (5)C22—C231.396 (5)
N5—C211.344 (4)C22—H220.9500
N6—C301.341 (5)C23—C241.402 (4)
N6—C311.343 (4)C23—C261.470 (5)
C2—C31.523 (5)C24—C251.386 (5)
C2—H2A0.9900C24—H240.9500
C2—H2B0.9900C25—H250.9500
C3—H3A0.9800C26—C271.326 (4)
C3—H3B0.9800C26—H260.9500
C3—H3C0.9800C27—C281.470 (5)
C4—C51.522 (6)C27—H270.9500
C4—H4A0.9900C28—C291.395 (5)
C4—H4B0.9900C28—C321.395 (5)
C5—H5A0.9800C29—C301.375 (5)
C5—H5B0.9800C29—H290.9500
C5—H5C0.9800C30—H300.9500
C7—C81.530 (5)C31—C321.372 (5)
C7—H7A0.9900C31—H310.9500
C7—H7B0.9900C32—H320.9500
C8—H8A0.9800C33—Cl31.754 (4)
C8—H8B0.9800C33—Cl11.764 (4)
C8—H8C0.9800C33—Cl21.769 (4)
C9—C101.519 (5)C33—H331.0000
C9—H9A0.9900
N5—Zn1—S1110.90 (8)H10A—C10—H10C109.5
N5—Zn1—S3113.27 (8)H10B—C10—H10C109.5
S1—Zn1—S3135.82 (4)N3—C11—S6121.3 (3)
N5—Zn1—S295.23 (8)N3—C11—S5121.4 (3)
S1—Zn1—S273.70 (3)S6—C11—S5117.29 (19)
S3—Zn1—S2101.84 (3)N3—C12—C13111.9 (3)
N5—Zn1—S495.08 (7)N3—C12—H12A109.2
S1—Zn1—S4103.21 (3)C13—C12—H12A109.2
S3—Zn1—S473.25 (3)N3—C12—H12B109.2
S2—Zn1—S4169.66 (3)C13—C12—H12B109.2
N6—Zn2—S7108.20 (8)H12A—C12—H12B107.9
N6—Zn2—S5108.23 (8)C12—C13—H13A109.5
S7—Zn2—S5142.61 (4)C12—C13—H13B109.5
N6—Zn2—S699.94 (8)H13A—C13—H13B109.5
S7—Zn2—S6106.51 (3)C12—C13—H13C109.5
S5—Zn2—S674.98 (3)H13A—C13—H13C109.5
N6—Zn2—S895.04 (8)H13B—C13—H13C109.5
S7—Zn2—S872.29 (3)N3—C14—C15112.5 (3)
S5—Zn2—S896.44 (3)N3—C14—H14A109.1
S6—Zn2—S8164.46 (3)C15—C14—H14A109.1
C1—S1—Zn186.85 (12)N3—C14—H14B109.1
C1—S2—Zn181.19 (11)C15—C14—H14B109.1
C6—S3—Zn187.36 (11)H14A—C14—H14B107.8
C6—S4—Zn181.79 (11)C14—C15—H15A109.5
C11—S5—Zn285.61 (11)C14—C15—H15B109.5
C11—S6—Zn281.30 (11)H15A—C15—H15B109.5
C16—S7—Zn288.75 (12)C14—C15—H15C109.5
C16—S8—Zn279.48 (12)H15A—C15—H15C109.5
C1—N1—C2122.3 (3)H15B—C15—H15C109.5
C1—N1—C4123.5 (3)N4—C16—S8122.7 (3)
C2—N1—C4114.2 (3)N4—C16—S7119.7 (3)
C6—N2—C7122.5 (3)S8—C16—S7117.67 (19)
C6—N2—C9120.4 (3)C18—C17—N4109.2 (4)
C7—N2—C9117.1 (3)C18—C17—H17A109.8
C11—N3—C14121.5 (3)N4—C17—H17A109.8
C11—N3—C12122.5 (3)C18—C17—H17B109.8
C14—N3—C12116.1 (3)N4—C17—H17B109.8
C16—N4—C19121.1 (3)H17A—C17—H17B108.3
C16—N4—C17121.6 (3)C17—C18—H18A109.5
C19—N4—C17117.1 (3)C17—C18—H18B109.5
C25—N5—C21117.7 (3)H18A—C18—H18B109.5
C25—N5—Zn1122.1 (2)C17—C18—H18C109.5
C21—N5—Zn1120.1 (2)H18A—C18—H18C109.5
C30—N6—C31117.2 (3)H18B—C18—H18C109.5
C30—N6—Zn2119.8 (2)N4—C19—C20111.7 (3)
C31—N6—Zn2123.0 (3)N4—C19—H19A109.3
N1—C1—S2121.9 (3)C20—C19—H19A109.3
N1—C1—S1120.6 (3)N4—C19—H19B109.3
S2—C1—S1117.47 (19)C20—C19—H19B109.3
N1—C2—C3112.4 (3)H19A—C19—H19B107.9
N1—C2—H2A109.1C19—C20—H20A109.5
C3—C2—H2A109.1C19—C20—H20B109.5
N1—C2—H2B109.1H20A—C20—H20B109.5
C3—C2—H2B109.1C19—C20—H20C109.5
H2A—C2—H2B107.9H20A—C20—H20C109.5
C2—C3—H3A109.5H20B—C20—H20C109.5
C2—C3—H3B109.5N5—C21—C22122.9 (3)
H3A—C3—H3B109.5N5—C21—H21118.6
C2—C3—H3C109.5C22—C21—H21118.6
H3A—C3—H3C109.5C21—C22—C23119.8 (3)
H3B—C3—H3C109.5C21—C22—H22120.1
N1—C4—C5111.7 (3)C23—C22—H22120.1
N1—C4—H4A109.3C22—C23—C24117.4 (3)
C5—C4—H4A109.3C22—C23—C26123.2 (3)
N1—C4—H4B109.3C24—C23—C26119.4 (3)
C5—C4—H4B109.3C25—C24—C23119.0 (3)
H4A—C4—H4B107.9C25—C24—H24120.5
C4—C5—H5A109.5C23—C24—H24120.5
C4—C5—H5B109.5N5—C25—C24123.1 (3)
H5A—C5—H5B109.5N5—C25—H25118.4
C4—C5—H5C109.5C24—C25—H25118.4
H5A—C5—H5C109.5C27—C26—C23123.7 (3)
H5B—C5—H5C109.5C27—C26—H26118.2
N2—C6—S4122.2 (2)C23—C26—H26118.2
N2—C6—S3120.6 (2)C26—C27—C28125.9 (3)
S4—C6—S3117.27 (19)C26—C27—H27117.1
N2—C7—C8112.9 (3)C28—C27—H27117.1
N2—C7—H7A109.0C29—C28—C32116.9 (3)
C8—C7—H7A109.0C29—C28—C27119.0 (3)
N2—C7—H7B109.0C32—C28—C27124.1 (3)
C8—C7—H7B109.0C30—C29—C28119.6 (3)
H7A—C7—H7B107.8C30—C29—H29120.2
C7—C8—H8A109.5C28—C29—H29120.2
C7—C8—H8B109.5N6—C30—C29123.3 (3)
H8A—C8—H8B109.5N6—C30—H30118.3
C7—C8—H8C109.5C29—C30—H30118.3
H8A—C8—H8C109.5N6—C31—C32123.0 (3)
H8B—C8—H8C109.5N6—C31—H31118.5
N2—C9—C10114.3 (3)C32—C31—H31118.5
N2—C9—H9A108.7C31—C32—C28120.0 (3)
C10—C9—H9A108.7C31—C32—H32120.0
N2—C9—H9B108.7C28—C32—H32120.0
C10—C9—H9B108.7Cl3—C33—Cl1110.7 (2)
H9A—C9—H9B107.6Cl3—C33—Cl2110.9 (2)
C9—C10—H10A109.5Cl1—C33—Cl2109.6 (2)
C9—C10—H10B109.5Cl3—C33—H33108.5
H10A—C10—H10B109.5Cl1—C33—H33108.5
C9—C10—H10C109.5Cl2—C33—H33108.5
N5—Zn1—S1—C184.10 (13)C9—N2—C6—S42.7 (4)
S3—Zn1—S1—C1−95.67 (11)C7—N2—C6—S32.5 (4)
S2—Zn1—S1—C1−5.33 (11)C9—N2—C6—S3−177.9 (2)
S4—Zn1—S1—C1−175.12 (11)Zn1—S4—C6—N2174.3 (3)
N5—Zn1—S2—C1−104.77 (13)Zn1—S4—C6—S3−5.19 (17)
S1—Zn1—S2—C15.50 (11)Zn1—S3—C6—N2−173.9 (3)
S3—Zn1—S2—C1140.11 (11)Zn1—S3—C6—S45.58 (18)
S4—Zn1—S2—C179.5 (2)C6—N2—C7—C8−96.2 (4)
N5—Zn1—S3—C684.91 (14)C9—N2—C7—C884.2 (4)
S1—Zn1—S3—C6−95.33 (12)C6—N2—C9—C1081.3 (4)
S2—Zn1—S3—C6−174.04 (11)C7—N2—C9—C10−99.1 (4)
S4—Zn1—S3—C6−3.45 (11)C14—N3—C11—S6−175.4 (2)
N5—Zn1—S4—C6−109.25 (13)C12—N3—C11—S64.8 (4)
S1—Zn1—S4—C6137.86 (11)C14—N3—C11—S54.9 (4)
S3—Zn1—S4—C63.54 (11)C12—N3—C11—S5−174.8 (2)
S2—Zn1—S4—C666.5 (2)Zn2—S6—C11—N3172.1 (3)
N6—Zn2—S5—C1190.19 (14)Zn2—S6—C11—S5−8.27 (16)
S7—Zn2—S5—C11−103.21 (12)Zn2—S5—C11—N3−171.6 (3)
S6—Zn2—S5—C11−5.53 (11)Zn2—S5—C11—S68.69 (17)
S8—Zn2—S5—C11−172.33 (11)C11—N3—C12—C13−88.1 (4)
N6—Zn2—S6—C11−100.79 (13)C14—N3—C12—C1392.1 (4)
S7—Zn2—S6—C11146.70 (11)C11—N3—C14—C15−90.3 (4)
S5—Zn2—S6—C115.58 (11)C12—N3—C14—C1589.5 (4)
S8—Zn2—S6—C1163.49 (16)C19—N4—C16—S88.8 (5)
N6—Zn2—S7—C1681.52 (14)C17—N4—C16—S8−166.8 (3)
S5—Zn2—S7—C16−85.08 (13)C19—N4—C16—S7−172.7 (3)
S6—Zn2—S7—C16−171.80 (12)C17—N4—C16—S711.7 (5)
S8—Zn2—S7—C16−8.02 (11)Zn2—S8—C16—N4166.5 (3)
N6—Zn2—S8—C16−99.21 (14)Zn2—S8—C16—S7−12.03 (17)
S7—Zn2—S8—C168.31 (12)Zn2—S7—C16—N4−165.1 (3)
S5—Zn2—S8—C16151.76 (12)Zn2—S7—C16—S813.47 (19)
S6—Zn2—S8—C1696.33 (16)C16—N4—C17—C18−92.5 (5)
S1—Zn1—N5—C25−118.7 (2)C19—N4—C17—C1891.7 (5)
S3—Zn1—N5—C2561.1 (2)C16—N4—C19—C20−92.2 (5)
S2—Zn1—N5—C25−44.2 (2)C17—N4—C19—C2083.6 (4)
S4—Zn1—N5—C25135.0 (2)C25—N5—C21—C22−1.4 (5)
S1—Zn1—N5—C2164.2 (2)Zn1—N5—C21—C22175.8 (2)
S3—Zn1—N5—C21−116.0 (2)N5—C21—C22—C23−1.1 (5)
S2—Zn1—N5—C21138.7 (2)C21—C22—C23—C243.1 (5)
S4—Zn1—N5—C21−42.0 (2)C21—C22—C23—C26−175.9 (3)
S7—Zn2—N6—C30−103.6 (2)C22—C23—C24—C25−2.8 (5)
S5—Zn2—N6—C3067.9 (2)C26—C23—C24—C25176.2 (3)
S6—Zn2—N6—C30145.2 (2)C21—N5—C25—C241.7 (5)
S8—Zn2—N6—C30−30.6 (2)Zn1—N5—C25—C24−175.4 (3)
S7—Zn2—N6—C3176.4 (3)C23—C24—C25—N50.4 (5)
S5—Zn2—N6—C31−112.2 (2)C22—C23—C26—C279.5 (5)
S6—Zn2—N6—C31−34.8 (3)C24—C23—C26—C27−169.5 (3)
S8—Zn2—N6—C31149.4 (2)C23—C26—C27—C28178.6 (3)
C2—N1—C1—S24.0 (4)C26—C27—C28—C29177.0 (4)
C4—N1—C1—S2−175.4 (3)C26—C27—C28—C32−2.5 (6)
C2—N1—C1—S1−175.2 (2)C32—C28—C29—C300.8 (5)
C4—N1—C1—S15.4 (5)C27—C28—C29—C30−178.7 (3)
Zn1—S2—C1—N1172.7 (3)C31—N6—C30—C29−1.1 (5)
Zn1—S2—C1—S1−8.05 (16)Zn2—N6—C30—C29178.8 (3)
Zn1—S1—C1—N1−172.1 (3)C28—C29—C30—N6−0.2 (5)
Zn1—S1—C1—S28.67 (17)C30—N6—C31—C321.9 (5)
C1—N1—C2—C3−91.9 (4)Zn2—N6—C31—C32−178.0 (3)
C4—N1—C2—C387.6 (4)N6—C31—C32—C28−1.3 (5)
C1—N1—C4—C5−97.5 (4)C29—C28—C32—C31−0.1 (5)
C2—N1—C4—C583.0 (4)C27—C28—C32—C31179.4 (3)
C7—N2—C6—S4−176.9 (3)

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
C33—H33···S8i1.002.723.598 (4)149

Symmetry codes: (i) −x+1, −y+2, z+1/2.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HB5173).

References

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