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Acta Crystallogr Sect E Struct Rep Online. 2009 October 1; 65(Pt 10): m1180.
Published online 2009 September 9. doi:  10.1107/S1600536809034795
PMCID: PMC2970407

Bis(2-cyclo­hexyl­imino­methyl-4,6-dihydro­seleno­phenolato)cobalt(II) acetonitrile solvate

Abstract

In the title compound, [Co(C13H16NOSe2)2]·CH3CN, the CoII atom is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a distorted tetra­hedral coordination for the metal ion.

Related literature

For background to Schiff bases, see: Shi et al. (2007 [triangle], 2008 [triangle]). For reference structural data, see: Allen et al. (1987 [triangle]).

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Object name is e-65-m1180-scheme1.jpg

Experimental

Crystal data

  • [Co(C13H16NOSe2)2]·C2H3N
  • M r = 820.36
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-65-m1180-efi1.jpg
  • a = 9.4745 (5) Å
  • b = 16.3895 (5) Å
  • c = 20.4615 (5) Å
  • β = 91.845 (2)°
  • V = 3175.7 (2) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 5.15 mm−1
  • T = 298 K
  • 0.20 × 0.14 × 0.12 mm

Data collection

  • Enraf–Nonius CAD-4 diffractometer
  • Absorption correction: ψ scan (North et al., 1968 [triangle]) T min = 0.426, T max = 0.577
  • 30082 measured reflections
  • 5592 independent reflections
  • 4034 reflections with I > 2σ(I)
  • R int = 0.043
  • 200 standard reflections every 3 reflections intensity decay: 1%

Refinement

  • R[F 2 > 2σ(F 2)] = 0.044
  • wR(F 2) = 0.141
  • S = 1.08
  • 5592 reflections
  • 348 parameters
  • H-atom parameters constrained
  • Δρmax = 0.88 e Å−3
  • Δρmin = −0.83 e Å−3

Data collection: CAD-4 Software (Enraf–Nonius, 1989 [triangle]); cell refinement: CAD-4 Software; data reduction: XCAD4 (Harms & Wocadlo, 1995 [triangle]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: SHELXTL (Sheldrick, 2008 [triangle]); software used to prepare material for publication: SHELXTL.

Table 1
Selected bond lengths (Å)

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809034795/hb5080sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809034795/hb5080Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The project was supported by the Scientific Research Foundation for Returned Overseas Chinese Scholars, State Education Ministry, Educational Commission of Hubei Province (D20091703) and the Natural Science Foundation of Hubei Province (2008CDB038).

supplementary crystallographic information

Comment

There has been much research interest in Schiff base metal complexes due to their molecular architectures and biological activities (Shi et al., 2007; Shi et al., 2008). In this work, we report here the crystal structure of the title compound, (I). In (I), all bond lengths are within normal ranges (Allen et al., 1987) (Fig. 1). The CoII is four-coordinated in a distorted tetrahedral coordination by two N atoms and two O atoms of the Schiff base ligand.

Experimental

A mixture of 3,5-dihydroseleno-2-hydroxybenzaldehyde (564 mg, 2 mmol), cyclohexanamine (198 mg, 2 mmol) and CoCl2.6H2O (1 mmol, 238 mg) was stirred in acetonitrile (10 ml) for 1 h. After keeping the filtrate in air for 8 d, blue blocks of (I) were formed.

Refinement

All H atoms were positioned geometrically (C—H = 0.93 Å for the aromatic H atoms and C—H = 0.96 Å for the aliphatic H atoms) and were refined as riding, with Uiso(H) = 1.2Ueq(C) and Uiso(H) = 1.2Ueq(N).

Figures

Fig. 1.
The structure of the title compound (I) showing 30% probability displacement ellipsoids.

Crystal data

[Co(C13H16NOSe2)2]·C2H3NF(000) = 1612
Mr = 820.36Dx = 1.716 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 25 reflections
a = 9.4745 (5) Åθ = 9–12°
b = 16.3895 (5) ŵ = 5.15 mm1
c = 20.4615 (5) ÅT = 298 K
β = 91.845 (2)°Block, blue
V = 3175.7 (2) Å30.20 × 0.14 × 0.12 mm
Z = 4

Data collection

Enraf–Nonius CAD-4 diffractometer4034 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.043
graphiteθmax = 25.0°, θmin = 1.6°
ω/2θ scansh = −11→11
Absorption correction: ψ scan (North et al., 1968)k = −19→19
Tmin = 0.426, Tmax = 0.577l = −23→24
30082 measured reflections200 standard reflections every 3 reflections
5592 independent reflections intensity decay: 1%

Refinement

Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.044Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.141H-atom parameters constrained
S = 1.08w = 1/[σ2(Fo2) + (0.0729P)2 + 2.8479P] where P = (Fo2 + 2Fc2)/3
5592 reflections(Δ/σ)max < 0.001
348 parametersΔρmax = 0.88 e Å3
0 restraintsΔρmin = −0.83 e Å3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
Co10.71461 (6)0.25063 (3)0.18676 (3)0.03902 (18)
Se10.78872 (10)0.32963 (5)0.40908 (3)0.0967 (3)
H10.77850.36640.38210.145*
Se21.23778 (8)0.10610 (5)0.43164 (3)0.0848 (2)
H21.30330.09610.40770.127*
Se30.26742 (7)0.13073 (4)0.12309 (4)0.0831 (2)
H3A0.33360.11050.14420.125*
Se40.14412 (10)0.40993 (5)−0.02853 (5)0.1130 (3)
H40.10260.3769−0.05230.169*
C10.8578 (5)0.2201 (3)0.3084 (2)0.0512 (12)
C20.8960 (6)0.2438 (3)0.3727 (3)0.0576 (13)
C31.0044 (6)0.2114 (3)0.4092 (3)0.0630 (15)
H31.02450.22930.45160.076*
C41.0837 (6)0.1511 (3)0.3810 (3)0.0568 (13)
C51.0558 (6)0.1246 (3)0.3186 (3)0.0561 (13)
H51.11060.08350.30100.067*
C60.9441 (5)0.1593 (3)0.2806 (2)0.0493 (12)
C70.9286 (5)0.1301 (3)0.2144 (2)0.0520 (12)
H70.98470.08590.20340.062*
C80.8488 (6)0.1210 (3)0.1028 (2)0.0590 (13)
H80.93820.09170.09870.071*
C90.8394 (8)0.1865 (4)0.0513 (3)0.0756 (18)
H9A0.91830.22370.05740.091*
H9B0.75300.21740.05620.091*
C100.8410 (10)0.1508 (5)−0.0167 (3)0.101 (3)
H10A0.93040.1236−0.02290.121*
H10B0.83180.1944−0.04870.121*
C110.7212 (10)0.0904 (4)−0.0274 (3)0.106 (3)
H11A0.72750.0658−0.07030.127*
H11B0.63160.1188−0.02580.127*
C120.7271 (10)0.0240 (4)0.0245 (3)0.096 (2)
H12A0.8114−0.00870.01950.115*
H12B0.6457−0.01150.01880.115*
C130.7288 (7)0.0613 (4)0.0934 (3)0.0749 (17)
H13A0.63990.08900.10010.090*
H13B0.73850.01810.12570.090*
C140.4488 (5)0.2682 (3)0.1182 (2)0.0471 (11)
C150.3182 (5)0.2362 (3)0.0947 (3)0.0576 (13)
C160.2303 (6)0.2780 (4)0.0515 (3)0.0655 (15)
H160.14550.25480.03680.079*
C170.2684 (6)0.3539 (4)0.0304 (3)0.0653 (15)
C180.3922 (6)0.3876 (4)0.0509 (3)0.0645 (14)
H180.41620.43930.03620.077*
C190.4854 (5)0.3461 (3)0.0941 (2)0.0514 (12)
C200.6163 (6)0.3879 (3)0.1118 (3)0.0573 (13)
H200.62590.44020.09490.069*
C210.8396 (6)0.4181 (3)0.1603 (3)0.0614 (14)
H210.84760.45440.12250.074*
C220.9765 (6)0.3710 (4)0.1690 (4)0.0810 (19)
H22A0.99350.34000.12960.097*
H22B0.96890.33290.20490.097*
C231.1006 (7)0.4290 (5)0.1830 (4)0.096 (2)
H23A1.18630.39750.19040.115*
H23B1.11370.46380.14530.115*
C241.0754 (7)0.4805 (5)0.2413 (4)0.096 (2)
H24A1.15320.51840.24780.116*
H24B1.07150.44610.27980.116*
C250.9388 (8)0.5275 (5)0.2329 (4)0.102 (2)
H25A0.94580.56540.19680.123*
H25B0.92250.55870.27230.123*
C260.8150 (7)0.4698 (4)0.2196 (4)0.084 (2)
H26A0.80300.43480.25730.101*
H26B0.72910.50130.21280.101*
C270.3987 (11)0.2810 (6)0.3050 (5)0.129 (3)
H27A0.41150.25610.26310.193*
H27B0.30410.27140.31850.193*
H27C0.46450.25800.33650.193*
C280.4218 (9)0.3646 (6)0.3003 (5)0.114 (3)
N10.8459 (4)0.1584 (3)0.1690 (2)0.0520 (10)
N20.7197 (4)0.3621 (2)0.14735 (19)0.0513 (10)
N30.4406 (11)0.4297 (7)0.2980 (7)0.198 (6)
O10.7504 (4)0.2540 (2)0.27880 (17)0.0631 (10)
O20.5246 (4)0.2252 (2)0.15900 (18)0.0597 (9)

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Co10.0356 (3)0.0429 (3)0.0382 (3)0.0049 (3)−0.0047 (2)0.0054 (3)
Se10.1520 (7)0.0796 (5)0.0579 (4)0.0525 (5)−0.0053 (4)−0.0112 (3)
Se20.0823 (5)0.0871 (5)0.0825 (5)0.0177 (4)−0.0361 (4)0.0025 (4)
Se30.0677 (4)0.0769 (4)0.1036 (5)−0.0214 (3)−0.0137 (4)0.0174 (4)
Se40.0972 (6)0.1095 (6)0.1279 (7)0.0072 (5)−0.0632 (5)0.0329 (5)
C10.054 (3)0.051 (3)0.048 (3)0.003 (2)−0.004 (2)0.005 (2)
C20.074 (4)0.052 (3)0.047 (3)0.012 (3)0.001 (3)0.003 (2)
C30.087 (4)0.051 (3)0.050 (3)0.001 (3)−0.018 (3)0.000 (2)
C40.056 (3)0.053 (3)0.059 (3)0.000 (2)−0.015 (3)0.007 (2)
C50.055 (3)0.050 (3)0.063 (3)0.006 (2)−0.008 (3)−0.003 (2)
C60.048 (3)0.043 (3)0.056 (3)−0.001 (2)−0.007 (2)0.001 (2)
C70.048 (3)0.056 (3)0.052 (3)0.007 (2)−0.002 (2)−0.003 (2)
C80.059 (3)0.069 (3)0.049 (3)0.008 (3)−0.003 (2)−0.009 (3)
C90.106 (5)0.069 (4)0.053 (3)−0.026 (3)0.013 (3)−0.005 (3)
C100.162 (8)0.086 (5)0.056 (4)−0.018 (5)0.023 (4)0.004 (3)
C110.174 (8)0.082 (5)0.058 (4)−0.013 (5)−0.040 (4)0.003 (3)
C120.151 (7)0.067 (4)0.068 (4)−0.019 (4)−0.015 (4)−0.005 (3)
C130.109 (5)0.057 (3)0.058 (3)−0.011 (3)−0.009 (3)0.008 (3)
C140.041 (3)0.058 (3)0.042 (3)0.003 (2)0.002 (2)0.003 (2)
C150.048 (3)0.068 (3)0.056 (3)0.004 (2)−0.003 (2)−0.003 (3)
C160.047 (3)0.087 (4)0.062 (3)−0.003 (3)−0.009 (3)−0.005 (3)
C170.061 (4)0.067 (4)0.067 (4)0.009 (3)−0.016 (3)0.008 (3)
C180.065 (4)0.063 (3)0.065 (3)0.006 (3)−0.011 (3)0.008 (3)
C190.047 (3)0.053 (3)0.053 (3)0.003 (2)−0.008 (2)0.004 (2)
C200.063 (3)0.054 (3)0.054 (3)−0.001 (3)−0.004 (3)0.008 (2)
C210.062 (3)0.057 (3)0.064 (3)−0.011 (3)−0.009 (3)0.011 (3)
C220.049 (3)0.088 (4)0.106 (5)−0.009 (3)0.004 (3)−0.027 (4)
C230.060 (4)0.106 (5)0.121 (6)−0.015 (4)0.001 (4)−0.031 (5)
C240.075 (5)0.113 (6)0.100 (5)−0.030 (4)0.000 (4)−0.034 (5)
C250.087 (5)0.092 (5)0.130 (6)−0.020 (4)0.012 (5)−0.046 (5)
C260.066 (4)0.082 (4)0.103 (5)−0.005 (3)0.002 (4)−0.034 (4)
C270.153 (9)0.122 (7)0.115 (7)−0.018 (6)0.055 (6)−0.023 (6)
C280.092 (6)0.104 (7)0.146 (8)−0.022 (5)0.003 (5)0.023 (6)
N10.051 (2)0.055 (2)0.050 (2)0.0023 (19)−0.001 (2)−0.0058 (19)
N20.047 (2)0.055 (2)0.052 (2)−0.0031 (19)−0.005 (2)0.0063 (19)
N30.138 (8)0.126 (7)0.326 (17)−0.033 (6)−0.034 (9)0.068 (9)
O10.066 (2)0.075 (2)0.048 (2)0.0262 (19)−0.0044 (18)−0.0012 (17)
O20.051 (2)0.062 (2)0.066 (2)−0.0037 (17)−0.0102 (18)0.0153 (18)

Geometric parameters (Å, °)

Co1—O11.904 (3)C12—H12B0.9700
Co1—O21.916 (3)C13—H13A0.9700
Co1—N11.999 (4)C13—H13B0.9700
Co1—N21.999 (4)C14—O21.293 (6)
Se1—C21.901 (5)C14—C151.414 (7)
Se1—H10.8200C14—C191.415 (7)
Se2—C41.910 (5)C15—C161.377 (7)
Se2—H20.8200C16—C171.368 (8)
Se3—C151.890 (6)C16—H160.9300
Se3—H3A0.8200C17—C181.351 (8)
Se4—C171.896 (5)C18—C191.405 (7)
Se4—H40.8200C18—H180.9300
C1—O11.293 (6)C19—C201.452 (7)
C1—C21.408 (7)C20—N21.273 (6)
C1—C61.419 (7)C20—H200.9300
C2—C31.359 (7)C21—N21.477 (6)
C3—C41.379 (8)C21—C261.504 (8)
C3—H30.9300C21—C221.516 (8)
C4—C51.367 (7)C21—H210.9800
C5—C61.413 (7)C22—C231.532 (8)
C5—H50.9300C22—H22A0.9700
C6—C71.439 (7)C22—H22B0.9700
C7—N11.283 (6)C23—C241.486 (10)
C7—H70.9300C23—H23A0.9700
C8—N11.487 (6)C23—H23B0.9700
C8—C91.505 (8)C24—C251.511 (10)
C8—C131.508 (8)C24—H24A0.9700
C8—H80.9800C24—H24B0.9700
C9—C101.511 (9)C25—C261.524 (9)
C9—H9A0.9700C25—H25A0.9700
C9—H9B0.9700C25—H25B0.9700
C10—C111.517 (10)C26—H26A0.9700
C10—H10A0.9700C26—H26B0.9700
C10—H10B0.9700C27—C281.391 (13)
C11—C121.520 (9)C27—H27A0.9600
C11—H11A0.9700C27—H27B0.9600
C11—H11B0.9700C27—H27C0.9600
C12—C131.536 (9)C28—N31.082 (11)
C12—H12A0.9700
O1—Co1—O2115.82 (16)C16—C15—C14122.5 (5)
O1—Co1—N196.32 (16)C16—C15—Se3119.8 (4)
O2—Co1—N1111.45 (16)C14—C15—Se3117.6 (4)
O1—Co1—N2111.50 (16)C17—C16—C15119.6 (5)
O2—Co1—N296.55 (15)C17—C16—H16120.2
N1—Co1—N2126.51 (17)C15—C16—H16120.2
C2—Se1—H1109.5C18—C17—C16120.6 (5)
C4—Se2—H2109.5C18—C17—Se4120.9 (4)
C15—Se3—H3A109.5C16—C17—Se4118.4 (4)
C17—Se4—H4109.5C17—C18—C19121.2 (5)
O1—C1—C2119.6 (5)C17—C18—H18119.4
O1—C1—C6124.7 (4)C19—C18—H18119.4
C2—C1—C6115.8 (4)C18—C19—C14120.0 (5)
C3—C2—C1124.9 (5)C18—C19—C20116.2 (5)
C3—C2—Se1118.6 (4)C14—C19—C20123.8 (4)
C1—C2—Se1116.5 (4)N2—C20—C19128.4 (5)
C2—C3—C4117.6 (5)N2—C20—H20115.8
C2—C3—H3121.2C19—C20—H20115.8
C4—C3—H3121.2N2—C21—C26110.9 (5)
C5—C4—C3121.7 (5)N2—C21—C22110.8 (5)
C5—C4—Se2120.4 (4)C26—C21—C22110.2 (5)
C3—C4—Se2117.9 (4)N2—C21—H21108.3
C4—C5—C6120.4 (5)C26—C21—H21108.3
C4—C5—H5119.8C22—C21—H21108.3
C6—C5—H5119.8C21—C22—C23110.8 (6)
C5—C6—C1119.5 (5)C21—C22—H22A109.5
C5—C6—C7115.8 (4)C23—C22—H22A109.5
C1—C6—C7124.6 (4)C21—C22—H22B109.5
N1—C7—C6127.1 (5)C23—C22—H22B109.5
N1—C7—H7116.5H22A—C22—H22B108.1
C6—C7—H7116.5C24—C23—C22111.1 (6)
N1—C8—C9110.0 (4)C24—C23—H23A109.4
N1—C8—C13110.3 (5)C22—C23—H23A109.4
C9—C8—C13110.3 (5)C24—C23—H23B109.4
N1—C8—H8108.7C22—C23—H23B109.4
C9—C8—H8108.7H23A—C23—H23B108.0
C13—C8—H8108.7C23—C24—C25111.0 (6)
C8—C9—C10111.5 (5)C23—C24—H24A109.4
C8—C9—H9A109.3C25—C24—H24A109.4
C10—C9—H9A109.3C23—C24—H24B109.4
C8—C9—H9B109.3C25—C24—H24B109.4
C10—C9—H9B109.3H24A—C24—H24B108.0
H9A—C9—H9B108.0C24—C25—C26110.8 (6)
C9—C10—C11110.8 (6)C24—C25—H25A109.5
C9—C10—H10A109.5C26—C25—H25A109.5
C11—C10—H10A109.5C24—C25—H25B109.5
C9—C10—H10B109.5C26—C25—H25B109.5
C11—C10—H10B109.5H25A—C25—H25B108.1
H10A—C10—H10B108.1C21—C26—C25110.8 (6)
C10—C11—C12110.9 (6)C21—C26—H26A109.5
C10—C11—H11A109.5C25—C26—H26A109.5
C12—C11—H11A109.5C21—C26—H26B109.5
C10—C11—H11B109.5C25—C26—H26B109.5
C12—C11—H11B109.5H26A—C26—H26B108.1
H11A—C11—H11B108.1C28—C27—H27A109.5
C11—C12—C13110.8 (6)C28—C27—H27B109.5
C11—C12—H12A109.5H27A—C27—H27B109.5
C13—C12—H12A109.5C28—C27—H27C109.5
C11—C12—H12B109.5H27A—C27—H27C109.5
C13—C12—H12B109.5H27B—C27—H27C109.5
H12A—C12—H12B108.1N3—C28—C27178.6 (14)
C8—C13—C12111.1 (5)C7—N1—C8118.9 (4)
C8—C13—H13A109.4C7—N1—Co1120.7 (3)
C12—C13—H13A109.4C8—N1—Co1120.5 (3)
C8—C13—H13B109.4C20—N2—C21118.0 (4)
C12—C13—H13B109.4C20—N2—Co1120.3 (4)
H13A—C13—H13B108.0C21—N2—Co1121.6 (3)
O2—C14—C15118.6 (4)C1—O1—Co1124.3 (3)
O2—C14—C19125.4 (4)C14—O2—Co1124.7 (3)
C15—C14—C19116.0 (4)
O1—C1—C2—C3178.5 (5)C14—C19—C20—N23.8 (9)
C6—C1—C2—C3−2.0 (8)N2—C21—C22—C23−179.5 (5)
O1—C1—C2—Se1−3.1 (7)C26—C21—C22—C23−56.4 (8)
C6—C1—C2—Se1176.4 (4)C21—C22—C23—C2456.5 (9)
C1—C2—C3—C40.4 (9)C22—C23—C24—C25−56.3 (9)
Se1—C2—C3—C4−177.9 (4)C23—C24—C25—C2656.7 (9)
C2—C3—C4—C50.4 (8)N2—C21—C26—C25179.9 (6)
C2—C3—C4—Se2179.3 (4)C22—C21—C26—C2556.9 (8)
C3—C4—C5—C60.5 (8)C24—C25—C26—C21−57.0 (9)
Se2—C4—C5—C6−178.4 (4)C6—C7—N1—C8178.1 (5)
C4—C5—C6—C1−2.1 (8)C6—C7—N1—Co1−2.2 (7)
C4—C5—C6—C7176.8 (5)C9—C8—N1—C7−139.0 (5)
O1—C1—C6—C5−177.8 (5)C13—C8—N1—C799.1 (6)
C2—C1—C6—C52.7 (7)C9—C8—N1—Co141.3 (6)
O1—C1—C6—C73.4 (8)C13—C8—N1—Co1−80.6 (5)
C2—C1—C6—C7−176.1 (5)O1—Co1—N1—C7−7.3 (4)
C5—C6—C7—N1−171.9 (5)O2—Co1—N1—C7−128.3 (4)
C1—C6—C7—N17.0 (8)N2—Co1—N1—C7115.4 (4)
N1—C8—C9—C10−179.6 (6)O1—Co1—N1—C8172.4 (4)
C13—C8—C9—C10−57.7 (7)O2—Co1—N1—C851.4 (4)
C8—C9—C10—C1157.4 (9)N2—Co1—N1—C8−64.9 (4)
C9—C10—C11—C12−55.7 (9)C19—C20—N2—C21−177.5 (5)
C10—C11—C12—C1354.8 (10)C19—C20—N2—Co10.2 (8)
N1—C8—C13—C12178.2 (5)C26—C21—N2—C2088.0 (6)
C9—C8—C13—C1256.5 (7)C22—C21—N2—C20−149.2 (5)
C11—C12—C13—C8−55.6 (9)C26—C21—N2—Co1−89.7 (5)
O2—C14—C15—C16179.5 (5)C22—C21—N2—Co133.0 (6)
C19—C14—C15—C16−0.6 (8)O1—Co1—N2—C20−126.7 (4)
O2—C14—C15—Se3−1.9 (6)O2—Co1—N2—C20−5.6 (4)
C19—C14—C15—Se3177.9 (4)N1—Co1—N2—C20117.3 (4)
C14—C15—C16—C17−0.6 (9)O1—Co1—N2—C2151.0 (4)
Se3—C15—C16—C17−179.2 (4)O2—Co1—N2—C21172.0 (4)
C15—C16—C17—C180.9 (9)N1—Co1—N2—C21−65.1 (4)
C15—C16—C17—Se4−179.6 (4)C2—C1—O1—Co1162.9 (4)
C16—C17—C18—C190.1 (9)C6—C1—O1—Co1−16.6 (7)
Se4—C17—C18—C19−179.4 (4)O2—Co1—O1—C1134.1 (4)
C17—C18—C19—C14−1.4 (8)N1—Co1—O1—C116.5 (4)
C17—C18—C19—C20178.9 (5)N2—Co1—O1—C1−116.9 (4)
O2—C14—C19—C18−178.6 (5)C15—C14—O2—Co1170.8 (4)
C15—C14—C19—C181.6 (7)C19—C14—O2—Co1−9.0 (7)
O2—C14—C19—C201.0 (8)O1—Co1—O2—C14127.7 (4)
C15—C14—C19—C20−178.8 (5)N1—Co1—O2—C14−123.5 (4)
C18—C19—C20—N2−176.6 (6)N2—Co1—O2—C1410.0 (4)

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HB5080).

References

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