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Acta Crystallogr Sect E Struct Rep Online. 2009 September 1; 65(Pt 9): m1031–m1032.
Published online 2009 August 8. doi:  10.1107/S1600536809030153
PMCID: PMC2969948

4,4′-Diazenediyldipyridinium 4-(4-pyridyldiazen­yl)pyridinium octa­cyanidotungstate(V) dihydrate

Abstract

The asymmetric unit of the title complex, (C10H10N4)(C10H9N4)[W(CN)8]·2H2O, contains two 4,4′-diazenediyldipyridinium, [H2(4,4′-azpy)]2+, two 4-(4-pyridyldiazen­yl)pyridinium, [H(4,4′-azpy)]+, cations, two [WV(CN)8]3− anions, and four uncoordinated water mol­ecules. Each of the W centers is coordinated by eight CN groups in a slightly distorted square-anti­prismatic geometry. In the crystal structure, intra- and inter­molecular N—H(...)O, N—H(...)N and O—H(...)N hydrogen bonds link the cations and anions in an alternating fashion, forming a two-dimensional layered structure, in which they are further linked through the very weak π–π stacking inter­actions [shortest distance = 4.640 (2) Å] and van der Waals forces between adjacent layers, forming a three-dimensional supra­molecular network.

Related literature

For general background to heterometallic cyanido-bridged 4f–4d or 4f–5d assemblies, see: Chelebaeva et al. (2008 [triangle]); Ikeda et al. (2005 [triangle]); Kosaka et al. (2007 [triangle]); Matoga et al. (2005 [triangle]); Przychodzeń et al. (2007 [triangle]); Wang et al. (2006 [triangle]). For a related structure, see: Liu et al. (2008 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-65-m1031-scheme1.jpg

Experimental

Crystal data

  • (C10H10N4)(C10H9N4)[W(CN)8]·2H2O
  • M r = 799.46
  • Orthorhombic, An external file that holds a picture, illustration, etc.
Object name is e-65-m1031-efi1.jpg
  • a = 12.7310 (16) Å
  • b = 16.499 (2) Å
  • c = 30.704 (4) Å
  • V = 6449.3 (14) Å3
  • Z = 8
  • Mo Kα radiation
  • μ = 3.64 mm−1
  • T = 291 K
  • 0.28 × 0.22 × 0.20 mm

Data collection

  • Bruker SMART APEX diffractometer
  • Absorption correction: multi-scan (SADABS; Bruker, 2004 [triangle]) T min = 0.391, T max = 0.483
  • 39717 measured reflections
  • 12501 independent reflections
  • 8553 reflections with I > 2σ(I)
  • R int = 0.048

Refinement

  • R[F 2 > 2σ(F 2)] = 0.047
  • wR(F 2) = 0.102
  • S = 1.03
  • 12501 reflections
  • 847 parameters
  • H-atom parameters constrained
  • Δρmax = 1.35 e Å−3
  • Δρmin = −1.71 e Å−3
  • Absolute structure: Flack (1983 [triangle]), 5514 Friedel pairs
  • Flack parameter: 0.045 (10)

Data collection: SMART (Bruker, 2004 [triangle]); cell refinement: SAINT (Bruker, 2004 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: SHELXTL (Sheldrick, 2008 [triangle]) and DIAMOND (Brandenburg, 2006 [triangle]); software used to prepare material for publication: SHELXL97.

Table 1
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809030153/hk2738sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809030153/hk2738Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The work was supported by the University Natural Science Foundation of Jiangsu Province (grant No. 07KJB150030).

supplementary crystallographic information

Comment

Heterometallic cyanido-bridged 4f-4d or 4f-5d assemblies are of high interest in molecular magnetism over the recent years (Chelebaeva et al., 2008; Przychodzeń et al., 2007; Ikeda et al., 2005; Kosaka et al., 2007; Matoga et al., 2005; Wang et al., 2006). The combination of the octacyanometalate [M(CN)8]3-/4- (M = Mo, W, Nb) building blocks with the lanthanide ions are of interest not only in materials science but also in physics and theoretical chemistry, providing interesting cases of investigation. Herein, we employed 4,4'-azpy (4,4'-azobispyridine), [WV(CN)8]3-, and Ce3+ as building blocks in order to obtain a new lanthanide-containing octacyanotungstate(V)-based magnet. However, the unexpected supramolecular title complex without Ce3+ was obtained. We report herein its crystal structure.

The asymmetric unit of the title complex contains two 4,4'-diazenediyldi- pyridinium, [H2(4,4'-azpy)]2+, and two (4-pyridyldiazenyl)pyridinium, [H(4,4'-azpy)]+, cations, two [WV(CN)8]3- anions, and four uncoordinated water molecules (Fig. 1). Each of the W centers is coordinated by eight CN groups in a slightly distorted square antiprism. The average W-C bond distances are 2.153 (8) Å (for W1) and 2.178 (8) Å (for W2).

In the crystal structure, intra- and intermolecular N-H···O, N-H···N and O-H···N hydrogen bonds (Table 1) link the [H2(4,4'-azpy)]2+ and [H(4,4'-azpy)]+ cations and [W(CN)8]3- anions in an alternating fashion to form a two-dimensional layered structure (Fig. 2), in which they are further linked through the highly weak π–π stacking interactions [shortest distance = 4.640 (2) Å] and van der Waals forces between adjacent layers to form a three-dimensional supramolecular network (Fig. 3) as in the similiar complex (C10H10N4)(C10H9N4)[Mo(CN)8].4H2O (Liu et al., 2008).

Experimental

Single crystals of the title complex were prepared at room temperature in the dark by slow diffusion of an acetonitrile solution (2 ml) containing both Ce(NO3)3.6H2O (21.71 mg, 0.05 mmol) and 4,4'-azpy (9.21 mg, 0.05 mmol) in an acetonitrile solution (20 ml) of [HN(n-C4H9)3]3[W(CN)8].4H2O (46.60 mg, 0.05 mmol). After two weeks, pale yellow crystals were obtained.

Refinement

H atoms were positioned geometrically with O-H = 0.85 Å (for H2O), N-H = 0.86 Å (for NH) and C-H = 0.93 Å, for aromatic H atoms, respectively, and constrained to ride on their parent atoms, with Uiso(H) = xUeq(C,N,O), where x = 1.5 for H2O H and x = 1.2 for all other H atoms.

Figures

Fig. 1.
The molecular structure of the title molecule with the partial atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. The atoms of [H2(4,4'-azpy)]2+ and [H(4,4'-azpy)]+ cations are not labelled for clarity.
Fig. 2.
A partial packing digaram viewed down the a axis. Hydrogen bonds are shown as dashed lines.
Fig. 3.
The three-dimensional supramolecular network.

Crystal data

(C10H10N4)(C10H9N4)[W(CN)8]·2H2OF(000) = 3144
Mr = 799.46Dx = 1.647 Mg m3
Orthorhombic, P212121Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2abCell parameters from 3042 reflections
a = 12.7310 (16) Åθ = 2.4–23.3°
b = 16.499 (2) ŵ = 3.64 mm1
c = 30.704 (4) ÅT = 291 K
V = 6449.3 (14) Å3Pale, yellow
Z = 80.28 × 0.22 × 0.20 mm

Data collection

Bruker SMART APEX diffractometer12501 independent reflections
Radiation source: fine-focus sealed tube8553 reflections with I > 2σ(I)
graphiteRint = 0.048
[var phi] and ω scansθmax = 26.0°, θmin = 1.3°
Absorption correction: multi-scan (SADABS; Bruker, 2004)h = −15→15
Tmin = 0.391, Tmax = 0.483k = −20→16
39717 measured reflectionsl = −25→37

Refinement

Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.047H-atom parameters constrained
wR(F2) = 0.102w = 1/[σ2(Fo2) + (0.05P)2] where P = (Fo2 + 2Fc2)/3
S = 1.03(Δ/σ)max < 0.001
12501 reflectionsΔρmax = 1.35 e Å3
847 parametersΔρmin = −1.71 e Å3
0 restraintsAbsolute structure: Flack (1983), 5514 Friedel pairs
Primary atom site location: structure-invariant direct methodsFlack parameter: 0.045 (10)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
C10.6378 (6)0.5473 (4)0.1970 (3)0.0297 (18)
C20.8138 (6)0.6063 (5)0.2335 (3)0.0313 (18)
C30.6200 (5)0.5979 (5)0.2747 (3)0.0336 (19)
C40.7952 (5)0.5479 (5)0.3113 (3)0.0342 (19)
C50.6367 (6)0.4511 (5)0.3072 (3)0.038 (2)
C60.8309 (6)0.4089 (5)0.2733 (3)0.0362 (19)
C70.6359 (7)0.4012 (5)0.2289 (3)0.038 (2)
C80.8104 (6)0.4661 (5)0.1968 (3)0.0324 (18)
C90.6935 (6)1.1035 (5)−0.0145 (3)0.037 (2)
C100.8908 (6)1.0955 (5)0.0232 (3)0.040 (2)
C110.6993 (6)1.0445 (4)0.0620 (3)0.0301 (17)
C120.8724 (6)0.9562 (5)0.0597 (3)0.036 (2)
C130.6913 (6)0.8979 (5)0.0264 (3)0.0353 (19)
C140.8822 (6)0.9009 (5)−0.0216 (3)0.0318 (18)
C150.6849 (6)0.9547 (5)−0.0491 (3)0.0329 (19)
C160.8540 (6)1.0422 (5)−0.0566 (3)0.035 (2)
C170.7019 (6)0.6236 (4)−0.1048 (3)0.0340 (18)
H170.70530.6073−0.13370.041*
C180.6731 (6)0.5699 (5)−0.0733 (3)0.0355 (19)
H180.65680.5168−0.08080.043*
C190.6678 (6)0.5951 (5)−0.0291 (3)0.0339 (18)
C200.6898 (6)0.6746 (5)−0.0179 (3)0.0360 (18)
H200.68520.69160.01090.043*
C210.7189 (6)0.7285 (5)−0.0504 (3)0.0344 (18)
H210.73340.7821−0.04330.041*
C220.6516 (7)0.2790 (5)0.0626 (3)0.043 (2)
H220.65490.22360.05740.052*
C230.6590 (6)0.3321 (5)0.0289 (3)0.038 (2)
H230.66720.31350.00050.045*
C240.6540 (6)0.4142 (5)0.0375 (3)0.038 (2)
C250.6430 (7)0.4397 (6)0.0816 (3)0.047 (2)
H250.64260.49480.08800.056*
C260.6337 (6)0.3887 (5)0.1125 (3)0.040 (2)
H260.62290.40670.14090.048*
C270.3214 (7)0.6179 (5)0.1410 (3)0.043 (2)
H270.31260.60040.11240.051*
C280.3426 (6)0.5650 (5)0.1707 (3)0.039 (2)
H280.35080.51090.16280.047*
C290.3538 (6)0.5877 (5)0.2162 (3)0.037 (2)
C300.3463 (6)0.6675 (5)0.2279 (3)0.0355 (19)
H300.35440.68350.25680.043*
C310.3253 (6)0.7263 (6)0.1939 (3)0.039 (2)
H310.32100.78110.20090.047*
C320.3825 (6)0.2770 (5)0.3084 (3)0.037 (2)
H320.39480.22240.30280.045*
C330.3711 (7)0.3313 (5)0.2739 (3)0.046 (2)
H330.37690.31350.24530.055*
C340.3510 (6)0.4119 (5)0.2828 (3)0.035 (2)
C350.3408 (6)0.4365 (5)0.3262 (3)0.040 (2)
H350.32460.49020.33260.047*
C360.3540 (7)0.3845 (5)0.3579 (4)0.045 (2)
H360.34860.40270.38650.054*
C370.6111 (6)0.7734 (5)0.6976 (3)0.0336 (19)
H370.61480.71790.70290.040*
C380.6055 (6)0.8260 (5)0.7325 (3)0.038 (2)
H380.60450.80640.76080.046*
C390.6013 (6)0.9083 (5)0.7244 (3)0.037 (2)
C400.6034 (6)0.9347 (6)0.6811 (3)0.039 (2)
H400.60160.99010.67570.047*
C410.6078 (6)0.8834 (5)0.6467 (3)0.0330 (18)
H410.60860.90300.61830.040*
C420.6139 (6)1.1089 (5)0.8685 (3)0.037 (2)
H420.61081.09140.89730.045*
C430.6087 (6)1.0550 (5)0.8382 (3)0.038 (2)
H430.60271.00020.84510.046*
C440.6124 (6)1.0821 (5)0.7922 (3)0.035 (2)
C450.6253 (6)1.1616 (5)0.7834 (3)0.036 (2)
H450.63121.17880.75470.043*
C460.6301 (6)1.2177 (5)0.8166 (3)0.036 (2)
H460.63721.27270.81070.043*
C470.4424 (8)0.7636 (6)0.9344 (3)0.048 (2)
H470.45950.70950.93900.058*
C480.4385 (6)0.8192 (5)0.9690 (3)0.043 (2)
H480.45360.80270.99730.052*
C490.4116 (5)0.8998 (5)0.9601 (3)0.035 (2)
C500.3877 (6)0.9236 (6)0.9184 (3)0.043 (2)
H500.36820.97710.91340.052*
C510.3917 (5)0.8720 (5)0.8846 (3)0.036 (2)
H510.37620.88910.85650.043*
C520.3989 (7)1.2149 (6)1.0509 (3)0.040 (2)
H520.39701.27021.04510.048*
C530.4044 (5)1.1586 (4)1.0177 (3)0.0294 (18)
H530.40411.17700.98910.035*
C540.4104 (6)1.0752 (5)1.0252 (3)0.038 (2)
C550.4061 (7)1.0507 (5)1.0724 (3)0.042 (2)
H550.40910.99621.07990.050*
C560.3982 (6)1.1049 (5)1.1021 (3)0.040 (2)
H560.39361.08791.13090.047*
N10.5960 (5)0.5701 (4)0.1664 (2)0.0311 (15)
N20.8569 (6)0.6651 (4)0.2237 (3)0.0438 (18)
N30.5657 (5)0.6483 (5)0.2883 (3)0.0446 (19)
N40.8368 (5)0.5730 (4)0.3427 (2)0.0308 (15)
N50.5944 (5)0.4196 (4)0.3371 (2)0.0376 (17)
N60.8863 (5)0.3586 (4)0.2865 (2)0.0353 (16)
N70.5832 (5)0.3496 (4)0.2153 (2)0.0365 (17)
N80.8538 (5)0.4451 (4)0.1666 (3)0.0368 (17)
N90.6442 (5)1.1600 (4)−0.0255 (2)0.0358 (16)
N100.9452 (5)1.1469 (4)0.0326 (3)0.0400 (18)
N110.6588 (5)1.0669 (4)0.0903 (3)0.0444 (19)
N120.9160 (5)0.9315 (4)0.0883 (2)0.0348 (16)
N130.6466 (6)0.8433 (4)0.0388 (2)0.0411 (18)
N140.9354 (5)0.8508 (4)−0.0345 (2)0.0328 (16)
N150.6319 (5)0.9307 (4)−0.0754 (3)0.0392 (18)
N160.8838 (6)1.0715 (4)−0.0877 (3)0.046 (2)
N170.7265 (5)0.7036 (4)−0.0933 (2)0.0335 (15)
N180.6520 (6)0.5431 (5)0.0041 (3)0.0310 (19)
N190.6672 (7)0.4666 (5)0.0023 (4)0.046 (2)
N200.6395 (6)0.3066 (4)0.1039 (3)0.039 (2)
H20A0.63550.27260.12500.047*
N210.3112 (6)0.7012 (4)0.1502 (3)0.0408 (17)
H21A0.29690.73550.13000.049*
N220.3621 (6)0.5397 (5)0.2529 (3)0.036 (2)
N230.3483 (7)0.4622 (5)0.2472 (4)0.045 (2)
N240.3757 (6)0.3036 (4)0.3505 (3)0.042 (2)
H240.38470.27070.37190.051*
N250.6113 (5)0.8007 (4)0.6551 (3)0.0384 (18)
H25A0.61350.76660.63390.046*
N260.6018 (6)0.9564 (5)0.7602 (3)0.032 (2)
N270.5977 (7)1.0325 (5)0.7605 (3)0.042 (3)
N280.6237 (5)1.1889 (4)0.8611 (3)0.0406 (18)
H28A0.62611.22240.88250.049*
N290.4199 (5)0.7923 (4)0.8931 (2)0.0364 (17)
N300.4065 (5)0.9466 (4)0.9941 (3)0.0328 (18)
N310.4201 (5)1.0249 (4)0.9923 (3)0.0333 (19)
N320.3964 (5)1.1847 (4)1.0941 (2)0.0324 (16)
H32A0.39351.21821.11550.039*
H2B0.56580.15480.15250.049*
H2C0.67390.15180.15810.049*
O10.4023 (4)0.3080 (3)0.15273 (19)0.0362 (14)
H1B0.45890.33470.14950.054*
H1C0.35000.33930.14890.054*
O20.6195 (5)0.1824 (4)0.1591 (2)0.0351 (16)
O30.3947 (4)0.1827 (3)0.4021 (2)0.0330 (15)
H3B0.34700.14810.39690.050*
H3C0.45460.16100.39840.050*
O40.6277 (4)0.3185 (4)0.9132 (2)0.0415 (15)
H4B0.56870.33850.90590.062*
H4C0.67670.34450.90070.062*
W10.721961 (19)0.50218 (3)0.253569 (10)0.03326 (9)
W20.783580 (19)1.00055 (3)0.003054 (9)0.03288 (8)

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
C10.035 (4)0.024 (4)0.030 (5)0.000 (3)−0.011 (4)−0.009 (4)
C20.029 (3)0.034 (4)0.031 (5)−0.006 (3)0.008 (3)−0.013 (4)
C30.025 (4)0.039 (5)0.036 (5)0.010 (3)0.003 (3)−0.011 (4)
C40.025 (4)0.053 (5)0.024 (5)−0.006 (3)0.001 (3)−0.012 (4)
C50.038 (4)0.049 (5)0.026 (5)−0.001 (4)0.005 (4)0.000 (4)
C60.038 (4)0.041 (5)0.030 (5)0.003 (4)0.004 (4)−0.004 (4)
C70.042 (4)0.047 (5)0.025 (5)−0.011 (4)−0.001 (4)0.001 (4)
C80.043 (4)0.023 (4)0.032 (5)0.002 (3)0.005 (4)−0.005 (3)
C90.040 (4)0.033 (4)0.038 (6)0.010 (3)0.010 (4)0.014 (4)
C100.035 (4)0.045 (5)0.039 (6)−0.010 (4)0.003 (4)−0.004 (4)
C110.036 (4)0.025 (4)0.029 (5)0.001 (3)−0.005 (4)0.005 (3)
C120.033 (4)0.039 (5)0.037 (5)0.007 (3)−0.015 (4)−0.008 (4)
C130.040 (4)0.038 (5)0.028 (5)−0.004 (3)−0.001 (3)0.003 (4)
C140.028 (4)0.034 (4)0.033 (5)−0.002 (3)−0.001 (3)0.000 (4)
C150.026 (3)0.047 (5)0.026 (5)−0.001 (3)−0.012 (3)−0.001 (4)
C160.029 (4)0.030 (4)0.045 (6)−0.004 (3)0.002 (4)0.008 (4)
C170.035 (4)0.032 (4)0.035 (5)0.010 (3)−0.001 (3)0.001 (4)
C180.048 (5)0.030 (4)0.029 (5)0.007 (3)0.018 (4)−0.010 (4)
C190.034 (4)0.034 (4)0.033 (5)−0.003 (3)0.005 (3)−0.005 (4)
C200.042 (4)0.037 (4)0.029 (5)−0.005 (3)−0.005 (3)0.000 (4)
C210.035 (4)0.030 (4)0.038 (5)0.011 (4)0.004 (4)0.002 (4)
C220.047 (5)0.034 (5)0.049 (6)−0.004 (4)0.027 (4)0.003 (4)
C230.043 (4)0.027 (4)0.044 (6)−0.012 (3)−0.023 (4)0.008 (4)
C240.029 (4)0.032 (4)0.051 (6)0.008 (3)−0.004 (4)0.010 (4)
C250.058 (5)0.040 (5)0.041 (6)−0.001 (4)0.002 (5)0.001 (5)
C260.025 (4)0.034 (5)0.060 (7)−0.017 (3)0.016 (4)0.002 (4)
C270.046 (4)0.031 (4)0.052 (6)−0.022 (4)−0.023 (4)0.018 (4)
C280.044 (4)0.038 (5)0.036 (5)−0.006 (4)−0.013 (4)0.009 (4)
C290.039 (4)0.040 (5)0.032 (5)0.007 (4)−0.014 (4)0.000 (4)
C300.037 (4)0.041 (5)0.029 (5)−0.004 (3)0.021 (4)−0.005 (4)
C310.030 (4)0.051 (5)0.036 (5)0.004 (4)−0.001 (3)0.007 (4)
C320.034 (4)0.033 (5)0.045 (6)−0.010 (3)−0.002 (4)−0.001 (4)
C330.055 (5)0.029 (5)0.054 (7)0.027 (4)0.007 (4)0.013 (4)
C340.034 (4)0.027 (4)0.045 (6)−0.011 (3)−0.018 (4)0.001 (4)
C350.037 (4)0.031 (4)0.050 (6)−0.014 (3)−0.012 (4)−0.010 (4)
C360.044 (5)0.030 (5)0.061 (7)−0.007 (4)0.027 (5)0.000 (4)
C370.036 (4)0.025 (4)0.040 (6)−0.006 (3)−0.011 (4)−0.002 (4)
C380.033 (4)0.039 (5)0.044 (6)−0.005 (3)0.000 (4)−0.011 (4)
C390.042 (4)0.038 (5)0.032 (5)0.015 (4)0.012 (4)−0.008 (4)
C400.038 (4)0.051 (5)0.029 (5)−0.021 (4)−0.001 (3)−0.004 (4)
C410.041 (4)0.031 (4)0.027 (5)−0.009 (3)−0.003 (3)−0.011 (4)
C420.038 (4)0.034 (5)0.039 (6)−0.001 (3)−0.010 (4)0.010 (4)
C430.033 (4)0.031 (5)0.051 (6)0.011 (3)−0.002 (4)0.006 (4)
C440.030 (4)0.029 (4)0.047 (6)0.010 (3)−0.016 (4)−0.005 (4)
C450.030 (4)0.034 (4)0.044 (6)−0.017 (3)0.004 (3)−0.009 (4)
C460.039 (4)0.035 (5)0.034 (5)−0.021 (3)0.015 (4)−0.004 (4)
C470.068 (6)0.048 (5)0.028 (5)−0.010 (5)0.008 (4)0.004 (4)
C480.042 (4)0.040 (5)0.048 (6)−0.003 (4)−0.017 (4)0.001 (4)
C490.021 (3)0.038 (5)0.046 (6)−0.014 (3)−0.002 (3)0.004 (4)
C500.042 (4)0.048 (5)0.038 (6)0.017 (4)−0.027 (4)−0.003 (4)
C510.019 (3)0.048 (5)0.040 (6)0.015 (3)0.003 (3)−0.002 (4)
C520.048 (5)0.050 (5)0.023 (5)−0.014 (4)0.001 (4)−0.004 (4)
C530.031 (4)0.025 (4)0.033 (5)−0.001 (3)0.005 (3)−0.002 (3)
C540.026 (4)0.043 (5)0.044 (6)−0.020 (3)−0.006 (4)0.008 (4)
C550.052 (5)0.028 (5)0.045 (6)−0.004 (4)0.001 (4)0.006 (4)
C560.041 (4)0.040 (5)0.038 (6)−0.013 (4)0.017 (4)0.005 (4)
N10.035 (3)0.026 (3)0.032 (4)−0.003 (3)0.003 (3)−0.009 (3)
N20.048 (4)0.044 (4)0.040 (5)−0.009 (3)−0.002 (3)0.008 (4)
N30.040 (4)0.048 (5)0.046 (5)0.012 (3)0.001 (3)−0.009 (4)
N40.045 (4)0.028 (3)0.019 (4)−0.013 (3)0.011 (3)0.000 (3)
N50.035 (3)0.039 (4)0.039 (5)0.009 (3)0.013 (3)−0.002 (3)
N60.047 (4)0.036 (4)0.022 (4)0.012 (3)−0.006 (3)−0.018 (3)
N70.038 (3)0.028 (4)0.043 (5)−0.001 (3)0.021 (3)−0.001 (3)
N80.044 (4)0.036 (4)0.030 (4)−0.002 (3)−0.004 (3)−0.011 (3)
N90.035 (3)0.047 (4)0.025 (4)0.012 (3)−0.010 (3)−0.009 (3)
N100.037 (3)0.041 (4)0.042 (5)−0.018 (3)0.001 (3)0.010 (3)
N110.040 (4)0.037 (4)0.057 (6)0.006 (3)0.021 (4)0.003 (4)
N120.026 (3)0.049 (4)0.030 (4)0.009 (3)0.002 (3)−0.003 (3)
N130.064 (4)0.039 (4)0.020 (4)−0.015 (4)0.017 (3)−0.004 (3)
N140.028 (3)0.033 (4)0.038 (4)0.010 (3)−0.012 (3)0.013 (3)
N150.035 (3)0.039 (4)0.044 (5)−0.009 (3)0.004 (3)−0.012 (4)
N160.044 (4)0.034 (4)0.060 (6)−0.011 (3)0.005 (4)0.020 (4)
N170.036 (3)0.036 (4)0.029 (4)−0.002 (3)0.013 (3)−0.002 (3)
N180.021 (3)0.037 (4)0.035 (5)0.002 (3)0.007 (3)0.008 (4)
N190.044 (5)0.038 (4)0.057 (7)−0.009 (3)−0.001 (5)−0.001 (4)
N200.041 (4)0.032 (4)0.044 (5)−0.002 (3)0.007 (4)0.007 (4)
N210.049 (4)0.034 (4)0.039 (5)0.009 (3)0.004 (3)0.004 (3)
N220.033 (4)0.041 (4)0.035 (5)−0.004 (3)0.012 (4)−0.001 (4)
N230.049 (5)0.030 (4)0.056 (6)0.006 (3)−0.028 (5)0.008 (4)
N240.045 (4)0.026 (4)0.055 (6)−0.010 (3)−0.023 (4)−0.006 (4)
N250.039 (4)0.029 (4)0.047 (5)−0.008 (3)−0.011 (3)0.003 (3)
N260.039 (4)0.032 (4)0.026 (5)0.009 (3)−0.001 (4)−0.005 (3)
N270.048 (5)0.035 (4)0.044 (6)−0.016 (3)−0.015 (4)−0.016 (4)
N280.041 (4)0.043 (4)0.038 (5)0.000 (3)−0.010 (3)−0.001 (4)
N290.042 (4)0.032 (4)0.034 (4)−0.012 (3)−0.013 (3)0.003 (3)
N300.032 (3)0.033 (4)0.033 (5)−0.013 (3)0.003 (3)0.002 (4)
N310.028 (3)0.024 (4)0.049 (5)0.004 (2)0.003 (3)0.012 (3)
N320.038 (3)0.039 (4)0.021 (4)−0.012 (3)−0.002 (3)−0.002 (3)
O10.025 (3)0.042 (3)0.042 (4)−0.007 (2)0.002 (2)0.011 (3)
O20.042 (3)0.028 (3)0.036 (4)0.001 (3)0.013 (3)0.004 (3)
O30.033 (3)0.035 (3)0.032 (3)−0.012 (3)−0.017 (3)0.008 (3)
O40.038 (3)0.037 (3)0.050 (4)−0.017 (3)−0.004 (3)−0.003 (3)
W10.03339 (12)0.03505 (16)0.03134 (19)0.0016 (3)−0.00019 (12)−0.0005 (3)
W20.03320 (13)0.03300 (16)0.03245 (19)−0.0027 (3)0.00128 (11)−0.0007 (2)

Geometric parameters (Å, °)

C1—N11.143 (10)C33—H330.9300
C1—W12.173 (8)C34—N231.373 (13)
C2—N21.154 (10)C34—C351.400 (12)
C2—W12.167 (8)C35—C361.308 (13)
C3—N31.159 (10)C35—H350.9300
C3—W12.145 (7)C36—N241.382 (11)
C4—N41.175 (10)C36—H360.9300
C4—W12.140 (8)C37—N251.379 (11)
C5—N51.183 (10)C37—C381.380 (12)
C5—W12.146 (9)C37—H370.9300
C6—N61.162 (10)C38—C391.381 (12)
C6—W12.159 (8)C38—H380.9300
C7—N71.162 (10)C39—N261.355 (11)
C7—W12.133 (8)C39—C401.399 (12)
C8—N81.134 (11)C40—C411.354 (11)
C8—W12.159 (9)C40—H400.9300
C9—N91.174 (10)C41—N251.390 (10)
C9—W22.119 (7)C41—H410.9300
C10—N101.132 (10)C42—C431.289 (12)
C10—W22.168 (8)C42—N281.344 (10)
C11—N111.076 (11)C42—H420.9300
C11—W22.225 (9)C43—C441.483 (13)
C12—N121.115 (10)C43—H430.9300
C12—W22.200 (8)C44—N271.285 (12)
C13—N131.131 (10)C44—C451.349 (11)
C13—W22.183 (8)C45—C461.379 (11)
C14—N141.141 (10)C45—H450.9300
C14—W22.202 (8)C46—N281.449 (11)
C15—N151.125 (10)C46—H460.9300
C15—W22.172 (8)C47—N291.384 (12)
C16—N161.134 (11)C47—C481.404 (13)
C16—W22.152 (9)C47—H470.9300
C17—C181.360 (11)C48—C491.400 (11)
C17—N171.402 (10)C48—H480.9300
C17—H170.9300C49—N301.300 (12)
C18—C191.421 (11)C49—C501.375 (12)
C18—H180.9300C50—C511.343 (12)
C19—N181.349 (12)C50—H500.9300
C19—C201.385 (11)C51—N291.387 (10)
C20—C211.387 (11)C51—H510.9300
C20—H200.9300C52—C531.379 (12)
C21—N171.382 (11)C52—N321.417 (11)
C21—H210.9300C52—H520.9300
C22—N201.355 (12)C53—C541.397 (11)
C22—C231.361 (12)C53—H530.9300
C22—H220.9300C54—N311.316 (12)
C23—C241.381 (11)C54—C551.503 (13)
C23—H230.9300C55—C561.282 (12)
C24—N191.394 (13)C55—H550.9300
C24—C251.426 (13)C56—N321.339 (10)
C25—C261.273 (12)C56—H560.9300
C25—H250.9300N18—N191.278 (9)
C26—N201.382 (10)N20—H20A0.8600
C26—H260.9300N21—H21A0.8600
C27—C281.290 (11)N22—N231.303 (9)
C27—N211.409 (10)N24—H240.8600
C27—H270.9300N25—H25A0.8600
C28—C291.454 (12)N26—N271.257 (8)
C28—H280.9300N28—H28A0.8600
C29—C301.369 (11)N30—N311.303 (10)
C29—N221.383 (12)N32—H32A0.8600
C30—C311.450 (12)O1—H1B0.8499
C30—H300.9300O1—H1C0.8501
C31—N211.416 (11)O2—H2B0.8456
C31—H310.9300O2—H2C0.8576
C32—N241.367 (12)O3—H3B0.8499
C32—C331.396 (12)O3—H3C0.8499
C32—H320.9300O4—H4B0.8501
C33—C341.382 (11)O4—H4C0.8500
N1—C1—W1177.8 (7)N30—C49—C50124.5 (8)
N2—C2—W1175.2 (7)N30—C49—C48114.9 (8)
N3—C3—W1176.5 (8)C50—C49—C48120.5 (9)
N4—C4—W1179.0 (7)C51—C50—C49122.0 (8)
N5—C5—W1176.1 (7)C51—C50—H50119.0
N6—C6—W1175.5 (7)C49—C50—H50119.0
N7—C7—W1175.5 (8)C50—C51—N29117.8 (8)
N8—C8—W1177.3 (7)C50—C51—H51121.1
N9—C9—W2178.0 (8)N29—C51—H51121.1
N10—C10—W2177.6 (8)C53—C52—N32117.1 (8)
N11—C11—W2179.0 (7)C53—C52—H52121.5
N12—C12—W2177.9 (7)N32—C52—H52121.5
N13—C13—W2177.6 (8)C52—C53—C54122.9 (9)
N14—C14—W2178.2 (7)C52—C53—H53118.5
N15—C15—W2178.3 (8)C54—C53—H53118.5
N16—C16—W2172.3 (7)N31—C54—C53120.0 (8)
C18—C17—N17119.7 (8)N31—C54—C55125.0 (8)
C18—C17—H17120.2C53—C54—C55115.0 (8)
N17—C17—H17120.2C56—C55—C54120.0 (8)
C17—C18—C19120.0 (8)C56—C55—H55120.0
C17—C18—H18120.0C54—C55—H55120.0
C19—C18—H18120.0C55—C56—N32123.8 (9)
N18—C19—C20116.4 (8)C55—C56—H56118.1
N18—C19—C18122.9 (8)N32—C56—H56118.1
C20—C19—C18120.4 (8)C21—N17—C17120.2 (7)
C19—C20—C21118.8 (8)N19—N18—C19125.0 (11)
C19—C20—H20120.6N18—N19—C24124.1 (12)
C21—C20—H20120.6C22—N20—C26121.0 (8)
N17—C21—C20121.0 (7)C22—N20—H20A119.5
N17—C21—H21119.5C26—N20—H20A119.5
C20—C21—H21119.5C27—N21—C31117.7 (7)
N20—C22—C23120.2 (8)C27—N21—H21A121.1
N20—C22—H22119.9C31—N21—H21A121.1
C23—C22—H22119.9N23—N22—C29116.2 (11)
C22—C23—C24118.8 (9)N22—N23—C34118.8 (11)
C22—C23—H23120.6C32—N24—C36118.6 (9)
C24—C23—H23120.6C32—N24—H24120.7
C23—C24—N19117.0 (9)C36—N24—H24120.7
C23—C24—C25118.5 (9)C37—N25—C41119.7 (8)
N19—C24—C25124.4 (8)C37—N25—H25A120.1
C26—C25—C24121.4 (9)C41—N25—H25A120.1
C26—C25—H25119.3N27—N26—C39126.3 (10)
C24—C25—H25119.3N26—N27—C44129.6 (11)
C25—C26—N20120.0 (10)C42—N28—C46119.1 (8)
C25—C26—H26120.0C42—N28—H28A120.4
N20—C26—H26120.0C46—N28—H28A120.4
C28—C27—N21122.4 (9)C47—N29—C51123.4 (8)
C28—C27—H27118.8C49—N30—N31123.2 (9)
N21—C27—H27118.8N30—N31—C54125.5 (9)
C27—C28—C29121.7 (9)C56—N32—C52121.1 (8)
C27—C28—H28119.1C56—N32—H32A119.4
C29—C28—H28119.1C52—N32—H32A119.4
C30—C29—N22109.9 (8)H1B—O1—H1C109.5
C30—C29—C28119.6 (8)H2B—O2—H2C109.2
N22—C29—C28130.1 (8)H3B—O3—H3C109.5
C29—C30—C31117.8 (8)H4B—O4—H4C109.5
C29—C30—H30121.1C7—W1—C4142.5 (3)
C31—C30—H30121.1C7—W1—C3111.8 (3)
N21—C31—C30120.6 (8)C4—W1—C375.8 (3)
N21—C31—H31119.7C7—W1—C572.9 (3)
C30—C31—H31119.7C4—W1—C573.9 (3)
N24—C32—C33120.3 (8)C3—W1—C575.6 (3)
N24—C32—H32119.8C7—W1—C682.7 (3)
C33—C32—H32119.8C4—W1—C674.9 (3)
C34—C33—C32119.1 (9)C3—W1—C6146.0 (3)
C34—C33—H33120.4C5—W1—C680.2 (3)
C32—C33—H33120.4C7—W1—C876.5 (3)
N23—C34—C33115.4 (9)C4—W1—C8122.6 (3)
N23—C34—C35125.5 (8)C3—W1—C8139.7 (3)
C33—C34—C35119.0 (8)C5—W1—C8140.8 (3)
C36—C35—C34120.4 (8)C6—W1—C872.2 (3)
C36—C35—H35119.8C7—W1—C2142.7 (3)
C34—C35—H35119.8C4—W1—C273.8 (3)
C35—C36—N24122.4 (10)C3—W1—C280.1 (3)
C35—C36—H36118.8C5—W1—C2143.4 (3)
N24—C36—H36118.8C6—W1—C2107.3 (3)
N25—C37—C38121.8 (8)C8—W1—C273.0 (3)
N25—C37—H37119.1C7—W1—C174.4 (3)
C38—C37—H37119.1C4—W1—C1139.2 (3)
C37—C38—C39118.8 (9)C3—W1—C172.0 (3)
C37—C38—H38120.6C5—W1—C1120.0 (3)
C39—C38—H38120.6C6—W1—C1141.8 (3)
N26—C39—C38115.5 (8)C8—W1—C172.9 (3)
N26—C39—C40126.0 (8)C2—W1—C176.6 (3)
C38—C39—C40118.4 (8)C9—W2—C1675.7 (3)
C41—C40—C39123.2 (9)C9—W2—C1080.4 (3)
C41—C40—H40118.4C16—W2—C1075.5 (3)
C39—C40—H40118.4C9—W2—C1577.2 (3)
C40—C41—N25118.1 (9)C16—W2—C1574.0 (3)
C40—C41—H41121.0C10—W2—C15145.7 (3)
N25—C41—H41121.0C9—W2—C13114.5 (3)
C43—C42—N28124.1 (9)C16—W2—C13138.7 (3)
C43—C42—H42117.9C10—W2—C13143.7 (3)
N28—C42—H42117.9C15—W2—C1370.2 (3)
C42—C43—C44118.5 (8)C9—W2—C12138.2 (3)
C42—C43—H43120.8C16—W2—C12124.4 (3)
C44—C43—H43120.8C10—W2—C1272.0 (3)
N27—C44—C45119.0 (9)C15—W2—C12139.9 (3)
N27—C44—C43121.6 (8)C13—W2—C1276.0 (3)
C45—C44—C43119.3 (8)C9—W2—C14145.0 (3)
C44—C45—C46120.6 (9)C16—W2—C1473.0 (3)
C44—C45—H45119.7C10—W2—C14106.2 (3)
C46—C45—H45119.7C15—W2—C1479.4 (3)
C45—C46—N28118.3 (8)C13—W2—C1480.8 (3)
C45—C46—H46120.8C12—W2—C1474.4 (3)
N28—C46—H46120.8C9—W2—C1171.6 (3)
N29—C47—C48117.5 (9)C16—W2—C11142.1 (3)
N29—C47—H47121.2C10—W2—C1180.6 (3)
C48—C47—H47121.2C15—W2—C11115.7 (3)
C49—C48—C47118.8 (9)C13—W2—C1174.1 (3)
C49—C48—H48120.6C12—W2—C1173.4 (3)
C47—C48—H48120.6C14—W2—C11142.9 (3)

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
N20—H20A···O20.861.832.671 (10)166
N21—H21A···N17i0.861.762.586 (10)162
N24—H24···O30.861.732.560 (10)162
N28—H28A···O4ii0.861.842.670 (10)161
N32—H32A···O1iii0.861.882.719 (10)166
O2—H2B···N3iv0.852.472.914 (10)113
O1—H1B···N70.852.583.076 (10)119
O4—H4C···N4v0.852.252.845 (9)127
O3—H3C···N14v0.852.502.960 (9)115
O4—H4B···N10vi0.852.472.913 (9)114

Symmetry codes: (i) x−1/2, −y+3/2, −z; (ii) x, y+1, z; (iii) x, y+1, z+1; (iv) −x+1, y−1/2, −z+1/2; (v) −x+3/2, −y+1, z+1/2; (vi) x−1/2, −y+3/2, −z+1.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HK2738).

References

  • Brandenburg, K. (2006). DIAMOND Crystal Impact GbR, Bonn, Germany.
  • Bruker (2004). SMART, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
  • Chelebaeva, E., Larionova, J., Guari, Y., Ferreira, R. A. S., Carlos, L. D., Paz, F. A. A., Trifonov, A. & Gueŕin, C. (2008). Inorg. Chem 47, 775–777. [PubMed]
  • Flack, H. D. (1983). Acta Cryst. A39, 876–881.
  • Ikeda, S., Hozumi, T., Hashimoto, K. & Ohkoshi, S. I. (2005). Dalton Trans pp. 2120–2123. [PubMed]
  • Kosaka, W., Hashimoto, K. & Ohkoshi, S. I. (2007). Bull. Chem. Soc. Jpn, 80, 2350–2356.
  • Liu, W.-Y., Zhou, H. & Yuan, A.-H. (2008). Acta Cryst. E64, m1151. [PMC free article] [PubMed]
  • Matoga, D., Mikuriya, M., Handa, M. & Szklarzewicz, J. (2005). Chem. Lett 34, 1550–1551.
  • Przychodzeń, P., Pełka, R., Lewiński, K., Supel, J., Rams, M., Tomala, K. & Sieklucka, B. (2007). Inorg. Chem 46, 8924–8938. [PubMed]
  • Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [PubMed]
  • Wang, Z. X., Shen, X. F., Wang, J., Zhang, P., Li, Y. Z., Nfor, E. N., Song, Y., Ohkoshi, S. I., Hashimoto, K. & You, X. Z. (2006). Angew. Chem. Int. Ed 45, 3287–3291. [PubMed]

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