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Acta Crystallogr Sect E Struct Rep Online. 2009 January 1; 65(Pt 1): m63.
Published online 2008 December 13. doi:  10.1107/S160053680804172X
PMCID: PMC2967904

{Tris[2-(5-bromo-2-oxidobenzyl­idene­amino)eth­yl]amine}manganese(III)

Abstract

In the title complex, [Mn(C27H24Br3N4O3)], the MnIII ion is six-coordinated in a distorted octa­hedral environment by three N atoms and three O atoms from the trianion of the hexa­dentate ligand tris­[2-(5-bromo-2-oxidobenzyl­idene­amino)eth­yl]amine. All three N (and O) atoms are cis to each other. The three N and the three O atoms are in a fac conformation among each other.

Related literature

For related literature, see: Hwang & Ha (2007 [triangle]); Mitra et al. (2006 [triangle]).

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Object name is e-65-00m63-scheme1.jpg

Experimental

Crystal data

  • [Mn(C27H24Br3N4O3)]
  • M r = 747.17
  • Triclinic, An external file that holds a picture, illustration, etc.
Object name is e-65-00m63-efi1.jpg
  • a = 9.5892 (15) Å
  • b = 11.7558 (18) Å
  • c = 13.417 (2) Å
  • α = 80.041 (3)°
  • β = 78.084 (3)°
  • γ = 89.069 (3)°
  • V = 1457.3 (4) Å3
  • Z = 2
  • Mo Kα radiation
  • μ = 4.60 mm−1
  • T = 293 (2) K
  • 0.25 × 0.15 × 0.10 mm

Data collection

  • Bruker SMART 1000 CCD diffractometer
  • Absorption correction: multi-scan (SADABS; Bruker, 2000 [triangle]) T min = 0.422, T max = 0.631
  • 9621 measured reflections
  • 5820 independent reflections
  • 3794 reflections with I > 2σ(I)
  • R int = 0.025

Refinement

  • R[F 2 > 2σ(F 2)] = 0.067
  • wR(F 2) = 0.238
  • S = 1.04
  • 5820 reflections
  • 343 parameters
  • H-atom parameters constrained
  • Δρmax = 2.66 e Å−3
  • Δρmin = −0.52 e Å−3

Data collection: SMART (Bruker, 2000 [triangle]); cell refinement: SAINT (Bruker, 2000 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: ORTEP-3 (Farrugia, 1997 [triangle]) and PLATON (Spek, 2003 [triangle]); software used to prepare material for publication: SHELXL97.

Table 1
Selected geometric parameters (Å, °)

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S160053680804172X/bt2817sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053680804172X/bt2817Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

This work was supported by the Korea Research Foundation Grant funded by the Korean Government (MOEHRD) (KRF-2007–412-J02001).

supplementary crystallographic information

Comment

In the title complex, [Mn(C27H24Br3N4O3)], the Mn3+ ion is six-coordinated in a distorted octahedral environment by three N atoms and three O atoms from the trianion of the hexadentate ligand N,N',N"-tris(5-bromosalicylidene)tris(2-aminoethyl)amine. All three N (and O) atoms are adjacent and lie in the facial position (Fig.1 and Fig.2). The apical O1—Mn—N2, O2—Mn—N3 and O3—Mn—N1 bond angles are 171.2 (2)°, 169.7 (2)° and 169.35 (19)°, respectively (Table 1). The Mn—N bonds are on average 0.204 Å longer than the Mn—O bonds (mean lengths: Mn—N 2.169 Å, Mn—O 1.965 Å).

Experimental

Mn(CH3COO)3.2H2O (0.50 g, 1.86 mmol) and N,N',N"-tris(5-bromosalicylidene)tris(2-aminoethyl)amine (Brsaltren; 1.30 g, 1.87 mmol) in EtOH (70 ml) were stirred for 3 h at room temparature. The formed precipitate was separated by filtration and washed with acetone, and dried under vacuum, to give a dark green powder (1.16 g). Crystals suitable for X-ray analysis were obtained by slow evaporation from an acetone/EtOH solution. MS (FAB): m/z 746, 748, 750, 752 (Mn(Brsaltren-H)+); IR (KBr): 3448 cm-1 (broad).

Refinement

H atoms were positioned geometrically and allowed to ride on their respective carrier atoms [C—H = 0.93 (CH) or 0.97 Å (CH2) and Uiso(H) = 1.2Ueq(C)]. The CIF check program indicates a high ratio of the maximum and minimum residual density (5.09) in the structure and solvent accessible voids of 142 Å3. All these factors indicate a strong likelihood of disordered solvent molecules acetone or EtOH in the structure. However, the solvent molecule could neither be located nor refined. The distances between the highest difference peak (2.66 e Å-3) and the nearest peaks (1.96, 1.69 and 1.08 e Å-3) are 1.114, 1.540 and 1.137 Å.

Figures

Fig. 1.
The structure of the title compound with the numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity.
Fig. 2.
View of the unit-cell contents of the title complex.

Crystal data

[Mn(C27H24Br3N4O3)]Z = 2
Mr = 747.17F(000) = 736
Triclinic, P1Dx = 1.703 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 9.5892 (15) ÅCell parameters from 2848 reflections
b = 11.7558 (18) Åθ = 2.8–24.2°
c = 13.417 (2) ŵ = 4.60 mm1
α = 80.041 (3)°T = 293 K
β = 78.084 (3)°Plate, black
γ = 89.069 (3)°0.25 × 0.15 × 0.10 mm
V = 1457.3 (4) Å3

Data collection

Bruker SMART 1000 CCD diffractometer5820 independent reflections
Radiation source: fine-focus sealed tube3794 reflections with I > 2σ(I)
graphiteRint = 0.025
[var phi] and ω scansθmax = 26.4°, θmin = 1.6°
Absorption correction: multi-scan (SADABS; Bruker, 2000)h = −11→11
Tmin = 0.422, Tmax = 0.631k = −10→14
9621 measured reflectionsl = −16→16

Refinement

Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.067Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.238H-atom parameters constrained
S = 1.04w = 1/[σ2(Fo2) + (0.1477P)2] where P = (Fo2 + 2Fc2)/3
5820 reflections(Δ/σ)max < 0.001
343 parametersΔρmax = 2.66 e Å3
0 restraintsΔρmin = −0.52 e Å3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
Mn0.89446 (11)0.29092 (8)0.37296 (8)0.0339 (3)
Br10.43752 (9)0.63459 (7)0.07601 (7)0.0562 (3)
Br20.65915 (12)−0.10364 (9)0.06388 (9)0.0773 (4)
Br30.92383 (12)0.21717 (12)0.94128 (7)0.0817 (4)
O10.8231 (6)0.4437 (4)0.3637 (4)0.0440 (13)
O20.7336 (5)0.2435 (4)0.3291 (4)0.0390 (12)
O30.7913 (6)0.2169 (4)0.5240 (4)0.0438 (12)
N10.9821 (6)0.3512 (5)0.1933 (4)0.0379 (14)
N20.9811 (6)0.1304 (5)0.3586 (4)0.0345 (13)
N31.0442 (6)0.3553 (5)0.4404 (5)0.0371 (14)
N41.2302 (6)0.2689 (5)0.2753 (5)0.0421 (14)
C10.7448 (8)0.4866 (6)0.2978 (6)0.0386 (16)
C20.6213 (9)0.5503 (7)0.3293 (6)0.0471 (19)
H20.59940.56180.39760.056*
C30.5340 (9)0.5950 (7)0.2667 (7)0.055 (2)
H30.45400.63540.29170.066*
C40.5650 (8)0.5800 (6)0.1638 (6)0.0423 (18)
C50.6844 (9)0.5206 (7)0.1259 (6)0.0475 (19)
H50.70410.51180.05690.057*
C60.7768 (8)0.4732 (6)0.1912 (6)0.0416 (17)
C70.8986 (8)0.4149 (6)0.1456 (6)0.0434 (18)
H70.91950.42400.07380.052*
C81.0976 (8)0.2977 (7)0.1326 (6)0.0445 (18)
H8A1.10760.33200.06030.053*
H8B1.07540.21610.13950.053*
C91.2362 (8)0.3111 (7)0.1653 (6)0.0462 (19)
H9A1.30900.26950.12510.055*
H9B1.26430.39220.14950.055*
C100.7244 (7)0.1687 (6)0.2679 (5)0.0332 (15)
C110.6176 (8)0.1814 (7)0.2102 (6)0.0440 (18)
H110.55710.24390.21310.053*
C120.6016 (8)0.1000 (7)0.1481 (6)0.0465 (19)
H120.53140.10920.10900.056*
C130.6884 (8)0.0077 (7)0.1451 (6)0.0451 (19)
C140.7932 (8)−0.0056 (6)0.1990 (6)0.0422 (18)
H140.8513−0.06950.19530.051*
C150.8169 (7)0.0738 (6)0.2602 (5)0.0350 (15)
C160.9320 (8)0.0567 (6)0.3142 (6)0.0386 (16)
H160.9751−0.01490.31720.046*
C171.1154 (7)0.0991 (6)0.3940 (6)0.0381 (16)
H17A1.12180.01570.40990.046*
H17B1.11680.13010.45620.046*
C181.2411 (8)0.1481 (6)0.3092 (6)0.0430 (18)
H18A1.32840.13370.33480.052*
H18B1.24660.10850.25090.052*
C190.8246 (8)0.2186 (6)0.6102 (6)0.0398 (17)
C200.7371 (9)0.1565 (7)0.7023 (6)0.0442 (18)
H200.65700.11610.69710.053*
C210.7678 (9)0.1546 (7)0.8001 (6)0.050 (2)
H210.70970.11280.85880.060*
C220.8866 (9)0.2160 (7)0.8083 (6)0.049 (2)
C230.9756 (9)0.2779 (7)0.7228 (6)0.0463 (19)
H231.05420.31870.72990.056*
C240.9449 (8)0.2781 (6)0.6232 (6)0.0382 (16)
C251.0426 (9)0.3453 (6)0.5379 (6)0.0421 (18)
H251.11320.38660.55540.051*
C261.1647 (8)0.4255 (6)0.3728 (6)0.0451 (18)
H26A1.20060.47730.41110.054*
H26B1.13320.47170.31460.054*
C271.2823 (8)0.3454 (7)0.3340 (6)0.0460 (19)
H27A1.36280.39090.29060.055*
H27B1.31440.30020.39230.055*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Mn0.0380 (6)0.0287 (6)0.0393 (6)0.0037 (4)−0.0134 (5)−0.0116 (5)
Br10.0540 (5)0.0463 (5)0.0767 (6)0.0125 (4)−0.0318 (5)−0.0126 (4)
Br20.0940 (8)0.0649 (7)0.0999 (9)0.0106 (6)−0.0553 (7)−0.0468 (6)
Br30.0812 (8)0.1293 (11)0.0422 (6)0.0090 (7)−0.0231 (5)−0.0234 (6)
O10.053 (3)0.035 (3)0.054 (3)0.010 (2)−0.025 (3)−0.020 (2)
O20.037 (3)0.038 (3)0.048 (3)0.008 (2)−0.013 (2)−0.017 (2)
O30.048 (3)0.050 (3)0.037 (3)−0.005 (2)−0.015 (2)−0.012 (2)
N10.039 (3)0.038 (3)0.038 (3)0.005 (3)−0.008 (3)−0.008 (3)
N20.031 (3)0.034 (3)0.041 (3)0.002 (2)−0.010 (3)−0.010 (3)
N30.045 (4)0.028 (3)0.043 (4)0.003 (3)−0.014 (3)−0.012 (3)
N40.039 (3)0.039 (4)0.048 (4)0.000 (3)−0.010 (3)−0.006 (3)
C10.040 (4)0.028 (4)0.050 (4)0.000 (3)−0.012 (3)−0.011 (3)
C20.057 (5)0.044 (4)0.044 (4)0.008 (4)−0.013 (4)−0.017 (4)
C30.043 (5)0.042 (5)0.088 (7)0.014 (4)−0.022 (4)−0.026 (4)
C40.044 (4)0.029 (4)0.059 (5)0.008 (3)−0.023 (4)−0.008 (3)
C50.057 (5)0.043 (5)0.046 (5)0.001 (4)−0.020 (4)−0.005 (4)
C60.042 (4)0.032 (4)0.052 (5)0.004 (3)−0.015 (4)−0.004 (3)
C70.048 (5)0.045 (4)0.039 (4)−0.001 (4)−0.009 (4)−0.014 (3)
C80.049 (5)0.044 (4)0.041 (4)0.008 (4)−0.007 (3)−0.010 (3)
C90.039 (4)0.045 (5)0.052 (5)0.004 (3)−0.006 (4)−0.007 (4)
C100.033 (4)0.030 (4)0.036 (4)−0.008 (3)−0.004 (3)−0.006 (3)
C110.036 (4)0.050 (5)0.051 (5)0.008 (3)−0.011 (3)−0.021 (4)
C120.039 (4)0.048 (5)0.059 (5)0.001 (3)−0.020 (4)−0.017 (4)
C130.050 (5)0.040 (4)0.054 (5)0.000 (4)−0.021 (4)−0.023 (4)
C140.043 (4)0.037 (4)0.050 (5)0.004 (3)−0.011 (4)−0.016 (3)
C150.033 (4)0.031 (4)0.044 (4)0.003 (3)−0.010 (3)−0.011 (3)
C160.040 (4)0.031 (4)0.048 (4)0.008 (3)−0.012 (3)−0.015 (3)
C170.036 (4)0.036 (4)0.046 (4)0.005 (3)−0.016 (3)−0.010 (3)
C180.040 (4)0.041 (4)0.050 (5)0.005 (3)−0.010 (3)−0.014 (4)
C190.044 (4)0.032 (4)0.045 (4)0.004 (3)−0.010 (3)−0.013 (3)
C200.050 (5)0.042 (4)0.044 (4)0.006 (4)−0.009 (4)−0.017 (3)
C210.051 (5)0.054 (5)0.043 (5)0.010 (4)−0.003 (4)−0.012 (4)
C220.058 (5)0.061 (5)0.035 (4)0.016 (4)−0.017 (4)−0.024 (4)
C230.054 (5)0.049 (5)0.042 (4)0.006 (4)−0.020 (4)−0.015 (4)
C240.046 (4)0.030 (4)0.042 (4)0.003 (3)−0.014 (3)−0.012 (3)
C250.056 (5)0.025 (4)0.051 (5)0.005 (3)−0.019 (4)−0.013 (3)
C260.053 (5)0.035 (4)0.047 (5)−0.008 (4)−0.009 (4)−0.008 (3)
C270.037 (4)0.041 (4)0.059 (5)−0.007 (3)−0.005 (4)−0.011 (4)

Geometric parameters (Å, °)

Mn—O21.884 (5)C9—H9A0.9700
Mn—O11.905 (5)C9—H9B0.9700
Mn—N32.064 (6)C10—C111.397 (10)
Mn—N22.073 (6)C10—C151.418 (9)
Mn—O32.105 (5)C11—C121.403 (10)
Mn—N12.369 (6)C11—H110.9300
Br1—C41.898 (7)C12—C131.357 (10)
Br2—C131.901 (7)C12—H120.9300
Br3—C221.892 (7)C13—C141.346 (10)
O1—C11.306 (8)C14—C151.396 (9)
O2—C101.319 (8)C14—H140.9300
O3—C191.265 (8)C15—C161.433 (9)
N1—C71.280 (9)C16—H160.9300
N1—C81.438 (9)C17—C181.519 (10)
N2—C161.278 (9)C17—H17A0.9700
N2—C171.482 (8)C17—H17B0.9700
N3—C251.291 (9)C18—H18A0.9700
N3—C261.476 (10)C18—H18B0.9700
N4—C181.424 (9)C19—C241.416 (10)
N4—C271.449 (9)C19—C201.429 (11)
N4—C91.464 (10)C20—C211.400 (10)
C1—C21.420 (10)C20—H200.9300
C1—C61.435 (10)C21—C221.392 (12)
C2—C31.343 (10)C21—H210.9300
C2—H20.9300C22—C231.379 (12)
C3—C41.392 (12)C23—C241.426 (10)
C3—H30.9300C23—H230.9300
C4—C51.382 (11)C24—C251.442 (11)
C5—C61.414 (10)C25—H250.9300
C5—H50.9300C26—C271.523 (10)
C6—C71.426 (10)C26—H26A0.9700
C7—H70.9300C26—H26B0.9700
C8—C91.501 (10)C27—H27A0.9700
C8—H8A0.9700C27—H27B0.9700
C8—H8B0.9700
O2—Mn—O189.3 (2)C11—C10—C15118.6 (6)
O2—Mn—N3169.7 (2)C10—C11—C12120.0 (7)
O1—Mn—N384.2 (2)C10—C11—H11120.0
O2—Mn—N288.6 (2)C12—C11—H11120.0
O1—Mn—N2171.2 (2)C13—C12—C11120.1 (7)
N3—Mn—N298.9 (2)C13—C12—H12120.0
O2—Mn—O386.9 (2)C11—C12—H12120.0
O1—Mn—O3101.1 (2)C14—C13—C12121.0 (7)
N3—Mn—O386.5 (2)C14—C13—Br2120.2 (6)
N2—Mn—O387.3 (2)C12—C13—Br2118.9 (6)
O2—Mn—N183.2 (2)C13—C14—C15121.8 (7)
O1—Mn—N182.7 (2)C13—C14—H14119.1
N3—Mn—N1103.9 (2)C15—C14—H14119.1
N2—Mn—N188.5 (2)C14—C15—C10118.5 (6)
O3—Mn—N1169.35 (19)C14—C15—C16119.5 (6)
C1—O1—Mn123.1 (4)C10—C15—C16122.0 (6)
C10—O2—Mn129.3 (4)N2—C16—C15126.4 (6)
C19—O3—Mn130.7 (5)N2—C16—H16116.8
C7—N1—C8117.9 (6)C15—C16—H16116.8
C7—N1—Mn115.4 (5)N2—C17—C18109.2 (6)
C8—N1—Mn124.4 (5)N2—C17—H17A109.8
C16—N2—C17115.8 (6)C18—C17—H17A109.8
C16—N2—Mn124.4 (5)N2—C17—H17B109.8
C17—N2—Mn119.6 (4)C18—C17—H17B109.8
C25—N3—C26114.3 (6)H17A—C17—H17B108.3
C25—N3—Mn127.1 (5)N4—C18—C17112.4 (6)
C26—N3—Mn118.5 (5)N4—C18—H18A109.1
C18—N4—C27117.0 (6)C17—C18—H18A109.1
C18—N4—C9118.5 (6)N4—C18—H18B109.1
C27—N4—C9117.8 (6)C17—C18—H18B109.1
O1—C1—C2120.7 (7)H18A—C18—H18B107.9
O1—C1—C6123.1 (6)O3—C19—C24124.5 (7)
C2—C1—C6116.2 (7)O3—C19—C20119.2 (7)
C3—C2—C1124.2 (8)C24—C19—C20116.3 (7)
C3—C2—H2117.9C21—C20—C19122.2 (7)
C1—C2—H2117.9C21—C20—H20118.9
C2—C3—C4119.1 (7)C19—C20—H20118.9
C2—C3—H3120.4C22—C21—C20119.0 (8)
C4—C3—H3120.4C22—C21—H21120.5
C5—C4—C3120.7 (7)C20—C21—H21120.5
C5—C4—Br1119.4 (6)C23—C22—C21121.9 (7)
C3—C4—Br1119.8 (6)C23—C22—Br3119.3 (6)
C4—C5—C6120.6 (8)C21—C22—Br3118.8 (7)
C4—C5—H5119.7C22—C23—C24118.8 (7)
C6—C5—H5119.7C22—C23—H23120.6
C5—C6—C7117.0 (7)C24—C23—H23120.6
C5—C6—C1119.2 (7)C19—C24—C23121.8 (7)
C7—C6—C1123.8 (7)C19—C24—C25122.9 (6)
N1—C7—C6126.7 (7)C23—C24—C25115.3 (7)
N1—C7—H7116.7N3—C25—C24128.0 (7)
C6—C7—H7116.7N3—C25—H25116.0
N1—C8—C9112.1 (6)C24—C25—H25116.0
N1—C8—H8A109.2N3—C26—C27109.1 (6)
C9—C8—H8A109.2N3—C26—H26A109.9
N1—C8—H8B109.2C27—C26—H26A109.9
C9—C8—H8B109.2N3—C26—H26B109.9
H8A—C8—H8B107.9C27—C26—H26B109.9
N4—C9—C8113.7 (7)H26A—C26—H26B108.3
N4—C9—H9A108.8N4—C27—C26110.2 (6)
C8—C9—H9A108.8N4—C27—H27A109.6
N4—C9—H9B108.8C26—C27—H27A109.6
C8—C9—H9B108.8N4—C27—H27B109.6
H9A—C9—H9B107.7C26—C27—H27B109.6
O2—C10—C11119.0 (6)H27A—C27—H27B108.1
O2—C10—C15122.4 (6)
O2—Mn—O1—C1−30.1 (6)C8—N1—C7—C6178.5 (7)
N3—Mn—O1—C1158.0 (6)Mn—N1—C7—C615.1 (10)
O3—Mn—O1—C1−116.8 (6)C5—C6—C7—N1−168.3 (7)
N1—Mn—O1—C153.1 (6)C1—C6—C7—N112.2 (12)
O1—Mn—O2—C10142.7 (6)C7—N1—C8—C9133.5 (7)
N3—Mn—O2—C10−166.1 (11)Mn—N1—C8—C9−64.7 (8)
N2—Mn—O2—C10−28.8 (6)C18—N4—C9—C880.4 (8)
O3—Mn—O2—C10−116.1 (6)C27—N4—C9—C8−129.2 (7)
N1—Mn—O2—C1059.9 (6)N1—C8—C9—N455.0 (9)
O2—Mn—O3—C19−173.2 (6)Mn—O2—C10—C11−152.4 (6)
O1—Mn—O3—C19−84.5 (6)Mn—O2—C10—C1529.2 (9)
N3—Mn—O3—C19−1.1 (6)O2—C10—C11—C12−177.1 (7)
N2—Mn—O3—C1998.0 (6)C15—C10—C11—C121.3 (11)
N1—Mn—O3—C19165.3 (9)C10—C11—C12—C131.0 (12)
O2—Mn—N1—C751.5 (5)C11—C12—C13—C14−1.8 (13)
O1—Mn—N1—C7−38.7 (5)C11—C12—C13—Br2177.8 (6)
N3—Mn—N1—C7−120.9 (5)C12—C13—C14—C150.3 (13)
N2—Mn—N1—C7140.3 (5)Br2—C13—C14—C15−179.4 (6)
O3—Mn—N1—C773.1 (12)C13—C14—C15—C102.1 (12)
O2—Mn—N1—C8−110.7 (6)C13—C14—C15—C16−178.6 (8)
O1—Mn—N1—C8159.1 (6)O2—C10—C15—C14175.6 (7)
N3—Mn—N1—C876.9 (6)C11—C10—C15—C14−2.8 (10)
N2—Mn—N1—C8−21.9 (6)O2—C10—C15—C16−3.6 (11)
O3—Mn—N1—C8−89.1 (12)C11—C10—C15—C16177.9 (7)
O2—Mn—N2—C1611.6 (6)C17—N2—C16—C15−170.2 (7)
N3—Mn—N2—C16−175.5 (6)Mn—N2—C16—C155.0 (11)
O3—Mn—N2—C1698.5 (6)C14—C15—C16—N2167.7 (7)
N1—Mn—N2—C16−71.7 (6)C10—C15—C16—N2−13.1 (12)
O2—Mn—N2—C17−173.4 (5)C16—N2—C17—C1892.1 (7)
N3—Mn—N2—C17−0.5 (5)Mn—N2—C17—C18−83.4 (6)
O3—Mn—N2—C17−86.5 (5)C27—N4—C18—C1785.2 (8)
N1—Mn—N2—C17103.3 (5)C9—N4—C18—C17−124.2 (7)
O2—Mn—N3—C2546.9 (15)N2—C17—C18—N453.6 (8)
O1—Mn—N3—C2598.5 (6)Mn—O3—C19—C242.1 (11)
N2—Mn—N3—C25−89.8 (6)Mn—O3—C19—C20−177.6 (5)
O3—Mn—N3—C25−3.1 (6)O3—C19—C20—C21179.9 (7)
N1—Mn—N3—C25179.5 (6)C24—C19—C20—C210.1 (10)
O2—Mn—N3—C26−130.0 (12)C19—C20—C21—C220.7 (11)
O1—Mn—N3—C26−78.4 (5)C20—C21—C22—C23−0.6 (12)
N2—Mn—N3—C2693.3 (5)C20—C21—C22—Br3177.9 (6)
O3—Mn—N3—C26−180.0 (5)C21—C22—C23—C24−0.3 (12)
N1—Mn—N3—C262.6 (5)Br3—C22—C23—C24−178.8 (5)
Mn—O1—C1—C2135.6 (6)O3—C19—C24—C23179.2 (7)
Mn—O1—C1—C6−44.6 (9)C20—C19—C24—C23−1.1 (10)
O1—C1—C2—C3−178.6 (7)O3—C19—C24—C250.8 (11)
C6—C1—C2—C31.5 (12)C20—C19—C24—C25−179.4 (6)
C1—C2—C3—C4−0.6 (13)C22—C23—C24—C191.2 (11)
C2—C3—C4—C5−0.5 (13)C22—C23—C24—C25179.7 (7)
C2—C3—C4—Br1176.4 (6)C26—N3—C25—C24−176.3 (7)
C3—C4—C5—C60.5 (12)Mn—N3—C25—C246.7 (11)
Br1—C4—C5—C6−176.3 (6)C19—C24—C25—N3−5.6 (12)
C4—C5—C6—C7−179.1 (7)C23—C24—C25—N3176.0 (7)
C4—C5—C6—C10.5 (12)C25—N3—C26—C2797.6 (7)
O1—C1—C6—C5178.8 (7)Mn—N3—C26—C27−85.1 (7)
C2—C1—C6—C5−1.4 (11)C18—N4—C27—C26−123.4 (7)
O1—C1—C6—C7−1.7 (12)C9—N4—C27—C2685.7 (8)
C2—C1—C6—C7178.1 (7)N3—C26—C27—N460.4 (8)

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BT2817).

References

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  • Mitra, K., Biswas, S., Lucas, C. R. & Adhikary, B. (2006). Inorg. Chim. Acta, 359, 1997–2003.
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