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Acta Crystallogr Sect E Struct Rep Online. 2008 August 1; 64(Pt 8): o1579–o1580.
Published online 2008 July 23. doi:  10.1107/S1600536808021958
PMCID: PMC2962062
X-ray crystal and computational structural study of (E)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol
Arzu Özek,a* Orhan Büyükgüngör,a Çiğdem Albayrak,b and Mustafa Odabaşoğlub
aDepartment of Physics, Ondokuz Mayıs University, TR-55139 Samsun, Turkey
bDepartment of Chemistry, Ondokuz Mayıs University, TR-55139 Samsun, Turkey
Correspondence e-mail: arzuozek/at/omu.edu.tr
Received July 11, 2008; Accepted July 14, 2008.
Abstract
In the mol­ecule of the title compound, C14H12ClNO, the two aromatic rings are oriented at a dihedral angle of 12.28 (7)°. An intra­molecular O—H(...)N hydrogen bond results in the formation of a nearly planar six-membered ring, which is oriented with respect to the aromatic rings at dihedral angles of 0.18 (5) and 12.10 (6)°. In the crystal structure, weak inter­molecular C—H(...)O hydrogen bonds link the mol­ecules into chains along the c axis. There is a C—H(...)π contact between the methyl group and the chloro­phenyl ring and a π–π contact between the two benzene rings [centroid–centroid distance = 3.866 (1) Å].
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International Union of Crystallography