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Acta Crystallogr Sect E Struct Rep Online. 2008 August 1; 64(Pt 8): m1100–m1101.
Published online 2008 July 31. doi:  10.1107/S1600536808023696
PMCID: PMC2962003

catena-Poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(III)] hexa-μ3-sulfido-dodeca-μ2-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum]

Abstract

The title compound, {[Pr(C2H6OS)8]2[Mo6Ag6S24]}n, contains polymeric Mo6S24Ag6 2− anions and [Pr(Me2SO)8]3+ cations, forming a one-dimensional polymeric Mo/S/Ag cluster. The anion assumes the conformation of a zigzag chain. The trivalent cations are arrayed amongst the anionic chains and are well separated from each other. Each Mo and Ag atom is coordinated by four S atoms in a distorted tetra­hedral geometry. The Pr3+ atom is coordinated by eight dimethyl sulfoxide ligands, forming a polyhedron-shaped distorted square anti­prism.

Related literature

The two most relevant known analogs are {[Ca(dmf)6][Mo2S8Ag2]}n (Yu et al., 1998 [triangle]) and {[Ca(dmso)6]2[W4S16Ag4]}n (Huang et al., 1996 [triangle]). For related literature, see: Du et al. (1992 [triangle]); Holloway & Melnik (1993 [triangle]); Holm (1992 [triangle]); Hou et al. (1996 [triangle]); Naruta et al. (1994 [triangle]); Niu et al. (2004 [triangle]); Plotnikova et al. (2004 [triangle]); Zhang et al. (2001 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-64-m1100-scheme1.jpg

Experimental

Crystal data

  • [Pr(C2H6OS)8]2[Mo6Ag6S24]
  • M r = 3524.17
  • Triclinic, An external file that holds a picture, illustration, etc.
Object name is e-64-m1100-efi1.jpg
  • a = 15.1808 (15) Å
  • b = 17.6200 (17) Å
  • c = 19.960 (2) Å
  • α = 89.912 (2)°
  • β = 89.768 (3)°
  • γ = 87.616 (3)°
  • V = 5334.4 (9) Å3
  • Z = 2
  • Mo Kα radiation
  • μ = 3.47 mm−1
  • T = 291 (2) K
  • 0.30 × 0.26 × 0.24 mm

Data collection

  • Bruker SMART APEXII CCD diffractometer
  • Absorption correction: multi-scan (SADABS; Bruker, 2000 [triangle]) T min = 0.375, T max = 0.435
  • 63226 measured reflections
  • 19555 independent reflections
  • 16163 reflections with I > 2σ(I)
  • R int = 0.040

Refinement

  • R[F 2 > 2σ(F 2)] = 0.049
  • wR(F 2) = 0.111
  • S = 1.03
  • 19555 reflections
  • 951 parameters
  • Δρmax = 0.87 e Å−3
  • Δρmin = −1.56 e Å−3

Data collection: APEX2 (Bruker, 2004 [triangle]); cell refinement: SAINT (Bruker, 2004 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: SHELXL97; software used to prepare material for publication: SHELXL97 and PLATON (Spek, 2003 [triangle]).

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808023696/pv2090sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808023696/pv2090Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

This work was financially supported by the Natural Science Foundation of Jiangsu Province Education office (No. 04KJB150015). We thank Dr Zaichao Zhang for his support.

supplementary crystallographic information

Comment

The thiometalates, such as tetrathiotungstate and tetrathiomolybdate, have been extensively used in the synthesis of transition metal sulfides (Holloway et al., 1993), since these moities can surve as multidentate ligands to coordinate with various transithion metals, including Cu, Ag, Au, Zn, Cd, Hg, Fe, Co, Ni, Pd, Pt, Sn and Ru to form a wide range novel structure complexes (Hou et al., 1996; Niu et al., 2004). Up to now, more than 300 heterothiometallic cluster compounds containing these moieties have been synthesized and studied extensively (Zhang et al., 2001). These complexes play a special role in catalysis reactions (Du et al., 1992), biological processes (Holm et al., 1992) and advanced materials (Naruta et al., 1994). Herein, the synthesis and structure of a novel polymeric Mo—Ag—S complex, [Mo6S24Ag6][Pr(dmso)8]2 (dmso= dimethylsulfoxide) (I), is reported.

The asymmetric unit of (I) comprises polymeric anion (Mo6S24Ag6)n6n- and two [Pr(Me2SO)8]3+ cations to form a Mo/S/Ag cluster (Fig. 1). The repeat unit in the anionic chain consists of six butterfly-shaped sub-units joined together by shared silver atoms, which can be viewed as a zigzag chain propagated by cell translation along the c -axis. Each Mo atom is coordinated by one terminal S, two µ2-S and one µ3-S to form a distorted tetrahedron with S—Mo—S angles varying from 106.70 (7) to 113.42 (6) °. Each Ag atom is coordinated by twoµ2-S, and twoµ3-S to form a distorted tetrahedron, with S—Ag—S angles in the range 89.13 (5) to 142.30 (5) °. The bond distances Mo—S and Ag—S are 2.1156 (18) to 2.2611 (17) Å and 2.4893 (17) to 2.7032 (16) Å, respectively, which are comparable to the values observed in similar compounds (Yu et al., 1998). The Pr3+ is coordinated with eight dmso molecules to form a polyhedron shaped like distorted square antiprism, with Pr—O bond lengths in the range 2.379 (5)–2.521 (4) Å, which are similar to the reported values, 2.432 (6) to 2.476 (6) Å, for the related compound (Plotnikova et al., 2004).

Experimental

AgI (0.235 g, 1 mmol) was added to a solution of (NH4)2MoS4 (0.260 g, 1 mmol in 10 ml dmso) with thorough stir for 20 minutes. The solution underwent an additional stirring for one minute after 0.5 mmol Pr(NO3)3 . 6H2O was added. After filtration the dark-red filtrate was carefully laid on the surface with 10 ml i-PrOH. Dark-red crystals were obtained after two weeks.

Refinement

H atoms were positioned geometrically in a riding mode with C—H = 0.96 Å and Uiso = 1.5Ueq times the methyl C atoms. The highest electron density peak in the final difference map was located close to Pr2 and was deemed meaningless.

Figures

Fig. 1.
The molecular structure of (I), with atom labels and 30% probability displacement ellipsoids. All H atoms have been omitted.

Crystal data

[Pr(C2H6OS)8]2[Mo6Ag6S24]Z = 2
Mr = 3524.17F000 = 3416
Triclinic, P1Dx = 2.194 Mg m3
Hall symbol: -P 1Mo Kα radiation λ = 0.71073 Å
a = 15.1808 (15) ÅCell parameters from 19555 reflections
b = 17.6200 (17) Åθ = 2.1–25.5º
c = 19.960 (2) ŵ = 3.47 mm1
α = 89.912 (2)ºT = 291 (2) K
β = 89.768 (3)ºBlock, black-red
γ = 87.616 (3)º0.30 × 0.26 × 0.24 mm
V = 5334.4 (9) Å3

Data collection

Bruker SMART ApexII CCD diffractometer19555 independent reflections
Radiation source: fine-focus sealed tube16163 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.040
T = 291(2) Kθmax = 25.5º
phi and ω scansθmin = 1.2º
Absorption correction: multi-scan(SADABS; Bruker, 2000)h = −18→18
Tmin = 0.375, Tmax = 0.435k = −21→21
63226 measured reflectionsl = −24→21

Refinement

Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: full with fixed elements per cycleHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.049H-atom parameters constrained
wR(F2) = 0.111  w = 1/[σ2(Fo2) + (0.070P)2] where P = (Fo2 + 2Fc2)/3
S = 1.03(Δ/σ)max < 0.001
19555 reflectionsΔρmax = 0.87 e Å3
951 parametersΔρmin = −1.56 e Å3
Primary atom site location: structure-invariant direct methodsExtinction correction: none

Special details

Experimental. Yield: 0.377 g in pure form, 63.6% (based on Mo). Analysis calculated for C32H96Ag6Mo6O16Pr2S40: C 10.91, H 2.75%; found: C 10.82, H 2.86%.
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
Ag10.78546 (3)0.27180 (3)0.04430 (3)0.02200 (10)
Ag20.87061 (3)0.43334 (3)0.18316 (2)0.01931 (10)
Ag30.84246 (3)0.37447 (3)0.38218 (2)0.02125 (10)
Ag40.70699 (3)0.22873 (3)0.54426 (3)0.02098 (10)
Ag50.62965 (3)0.06681 (3)0.68251 (2)0.01838 (10)
Ag60.65666 (3)0.12879 (3)0.88251 (3)0.02199 (10)
C10.8958 (5)0.9234 (5)−0.0213 (4)0.0334 (18)
H1A0.94660.9536−0.01690.050*
H1B0.86910.9328−0.06430.050*
H1C0.91330.8705−0.01770.050*
C20.8145 (4)1.0521 (4)0.0348 (4)0.0246 (14)
H2A0.75571.07020.02390.037*
H2B0.85401.0653−0.00060.037*
H2C0.83251.07490.07580.037*
C30.9335 (5)1.1728 (5)0.2546 (5)0.045 (2)
H3A0.98681.14150.25630.068*
H3B0.93441.21040.28930.068*
H3C0.92931.19750.21170.068*
C40.7575 (5)1.1766 (4)0.2372 (5)0.0369 (19)
H4A0.72821.15350.20040.055*
H4B0.78241.22300.22250.055*
H4C0.71581.18740.27260.055*
C50.5570 (6)1.0542 (4)0.1992 (4)0.0377 (19)
H5A0.60211.07420.22700.056*
H5B0.50831.04030.22680.056*
H5C0.53741.09220.16750.056*
C60.5746 (4)1.0049 (4)0.0764 (3)0.0239 (14)
H6A0.57651.05930.07540.036*
H6B0.51650.99010.06480.036*
H6C0.61650.98350.04480.036*
C70.6163 (5)1.0313 (4)0.4018 (4)0.0328 (17)
H7A0.64471.07890.40000.049*
H7B0.59591.02250.44670.049*
H7C0.56701.03270.37170.049*
C80.7746 (5)0.9889 (4)0.4284 (4)0.0312 (16)
H8A0.83070.97020.41150.047*
H8B0.76660.97060.47320.047*
H8C0.77271.04340.42850.047*
C91.0710 (6)1.0131 (5)0.3723 (5)0.044 (2)
H9A1.11601.00950.33830.066*
H9B1.09761.00740.41560.066*
H9C1.04041.06180.36940.066*
C101.0723 (5)0.8691 (5)0.3279 (4)0.039 (2)
H10A1.05740.85620.28270.059*
H10B1.07250.82440.35540.059*
H10C1.12970.89010.32850.059*
C110.7288 (5)0.7341 (5)0.3713 (5)0.042 (2)
H11A0.72360.68020.37560.063*
H11B0.67980.75510.34610.063*
H11C0.72890.75680.41500.063*
C120.9034 (5)0.7244 (5)0.3821 (4)0.0343 (18)
H12A0.94430.76360.38970.051*
H12B0.93450.67980.36530.051*
H12C0.87460.71240.42350.051*
C130.6233 (5)0.7258 (4)0.1818 (4)0.0349 (18)
H13A0.65550.69920.21650.052*
H13B0.59960.68970.15140.052*
H13C0.57600.75620.20140.052*
C140.7488 (5)0.7190 (4)0.0897 (4)0.0303 (16)
H14A0.78400.74340.05660.045*
H14B0.70650.68860.06770.045*
H14C0.78610.68720.11760.045*
C151.0379 (5)0.7185 (4)0.1564 (4)0.0327 (17)
H15A1.08470.71100.12430.049*
H15B1.00140.67530.15610.049*
H15C1.06250.72420.20020.049*
C161.0620 (5)0.8539 (5)0.1084 (5)0.041 (2)
H16A1.03950.90450.09900.061*
H16B1.08760.83210.06840.061*
H16C1.10620.85560.14260.061*
C170.4200 (5)0.6293 (5)0.8322 (4)0.0332 (18)
H17A0.45250.67480.83480.050*
H17B0.39850.61660.87600.050*
H17C0.37110.63730.80230.050*
C180.4629 (6)0.4856 (5)0.8743 (5)0.050 (2)
H18A0.50050.44050.87140.075*
H18B0.40240.47220.87130.075*
H18C0.47240.51030.91640.075*
C190.6012 (6)0.7740 (5)0.8559 (5)0.052 (2)
H19A0.61920.81710.83060.078*
H19B0.57960.79050.89900.078*
H19C0.55530.74940.83230.078*
C200.7616 (5)0.7735 (5)0.8928 (4)0.038 (2)
H20A0.81870.74820.89600.058*
H20B0.74400.79260.93610.058*
H20C0.76420.81500.86170.058*
C210.7209 (4)0.5185 (4)0.9328 (3)0.0260 (15)
H21A0.67350.55620.92990.039*
H21B0.74150.51540.97820.039*
H21C0.70020.47010.91940.039*
C220.8955 (4)0.4710 (4)0.9029 (4)0.0259 (15)
H22A0.88790.42560.87740.039*
H22B0.89060.45970.94980.039*
H22C0.95270.49000.89370.039*
C230.9432 (6)0.4461 (4)0.7015 (4)0.037 (2)
H23A0.93310.45470.74850.055*
H23B1.00540.44080.69310.055*
H23C0.91550.40050.68820.055*
C240.9197 (5)0.4921 (4)0.5702 (4)0.0351 (18)
H24A0.97710.46710.56780.053*
H24B0.91750.53500.54050.053*
H24C0.87590.45720.55720.053*
C250.6809 (4)0.4519 (4)0.5293 (4)0.0243 (15)
H25A0.72300.42410.55650.036*
H25B0.69400.44270.48280.036*
H25C0.62270.43560.53920.036*
C260.6145 (5)0.5818 (5)0.4818 (4)0.041 (2)
H26A0.57830.62380.49830.061*
H26B0.57760.54180.46810.061*
H26C0.64850.59820.44430.061*
C270.4390 (4)0.6424 (4)0.6146 (4)0.0276 (16)
H27A0.46160.59650.59360.041*
H27B0.39950.66910.58440.041*
H27C0.40790.63000.65490.041*
C280.4711 (6)0.7858 (4)0.6537 (4)0.0350 (18)
H28A0.41640.77490.67530.053*
H28B0.45930.81380.61320.053*
H28C0.50570.81550.68310.053*
C290.7501 (5)0.3295 (5)0.7443 (4)0.0303 (16)
H29A0.80120.33960.71780.045*
H29B0.74230.27570.74580.045*
H29C0.75780.34820.78890.045*
C300.5723 (5)0.3183 (4)0.7461 (4)0.0372 (19)
H30A0.59970.29240.78340.056*
H30B0.55260.28170.71450.056*
H30C0.52280.34920.76170.056*
C310.7678 (5)0.7931 (4)0.5788 (4)0.0330 (17)
H31A0.80250.75610.55370.050*
H31B0.79800.83980.58050.050*
H31C0.71170.80160.55750.050*
C320.8554 (5)0.7855 (5)0.6919 (4)0.042 (2)
H32A0.86720.76310.73500.063*
H32B0.85540.83980.69550.063*
H32C0.90020.76840.66070.063*
Mo10.61048 (4)0.24994 (3)−0.01700 (3)0.02195 (12)
Mo20.95462 (4)0.33692 (3)0.07937 (3)0.02121 (12)
Mo30.77241 (4)0.50147 (3)0.29754 (3)0.01952 (11)
Mo40.88146 (3)0.24889 (3)0.48144 (3)0.01828 (11)
Mo50.53974 (4)0.15946 (3)0.57924 (3)0.02027 (12)
Mo60.73016 (3)0.00388 (3)0.79719 (3)0.01753 (11)
O10.7860 (3)0.5247 (3)0.8064 (3)0.0288 (11)
O20.6332 (3)0.4512 (3)0.7360 (3)0.0345 (12)
O30.7990 (3)0.5091 (3)0.6592 (2)0.0267 (10)
O40.6308 (3)0.5630 (3)0.6109 (3)0.0321 (12)
O50.7596 (4)0.6741 (3)0.6534 (3)0.0329 (12)
O60.5575 (3)0.6695 (3)0.7031 (2)0.0272 (11)
O70.7184 (3)0.6894 (3)0.7999 (3)0.0278 (11)
O80.5866 (3)0.5777 (3)0.8189 (3)0.0317 (12)
O90.6996 (3)0.9815 (3)0.1620 (3)0.0352 (12)
O100.8465 (3)1.0588 (3)0.2127 (3)0.0341 (12)
O110.7216 (3)0.9764 (3)0.3074 (3)0.0300 (11)
O120.9460 (3)0.9716 (3)0.2996 (3)0.0313 (11)
O130.8328 (3)0.8390 (3)0.3232 (3)0.0281 (11)
O140.9421 (3)0.8320 (3)0.2026 (2)0.0294 (11)
O150.7539 (3)0.8055 (3)0.1910 (3)0.0347 (12)
O160.8656 (3)0.9315 (3)0.1070 (3)0.0330 (12)
Pr10.68424 (3)0.57914 (2)0.72542 (2)0.02548 (8)
Pr20.82416 (3)0.92341 (2)0.22508 (2)0.02798 (9)
S10.80876 (11)0.54420 (9)0.87912 (9)0.0248 (3)
S20.65104 (11)0.37779 (10)0.70611 (9)0.0258 (4)
S30.89809 (11)0.52398 (10)0.65518 (9)0.0241 (3)
S40.68607 (10)0.54836 (9)0.54593 (9)0.0216 (3)
S50.75131 (11)0.75815 (9)0.66337 (10)0.0273 (4)
S60.52875 (10)0.70130 (9)0.63470 (8)0.0204 (3)
S70.68841 (11)0.71208 (10)0.86610 (10)0.0268 (4)
S80.49025 (11)0.55351 (10)0.80179 (9)0.0283 (4)
S90.60037 (11)0.97252 (9)0.15556 (8)0.0222 (3)
S100.84069 (12)1.11499 (10)0.26649 (10)0.0304 (4)
S110.69190 (12)0.95725 (9)0.37809 (9)0.0253 (3)
S120.99262 (11)0.93770 (10)0.35972 (9)0.0270 (4)
S130.83075 (11)0.75346 (10)0.32827 (10)0.0280 (4)
S140.97585 (10)0.79828 (9)0.13613 (8)0.0218 (3)
S150.69540 (11)0.78562 (11)0.13722 (10)0.0298 (4)
S160.81670 (11)0.94834 (9)0.04462 (8)0.0222 (3)
S170.54376 (12)0.35754 (9)−0.01073 (9)0.0262 (4)
S180.73261 (11)0.25822 (9)−0.08048 (9)0.0228 (3)
S190.64721 (10)0.21231 (9)0.08602 (9)0.0221 (3)
S200.93337 (11)0.21408 (9)0.07184 (10)0.0273 (4)
S210.82979 (10)0.40873 (9)0.06364 (8)0.0212 (3)
S221.01469 (11)0.35874 (10)0.17709 (9)0.0255 (4)
S230.84212 (12)0.56812 (9)0.22337 (9)0.0276 (4)
S240.76903 (11)0.37773 (9)0.27082 (9)0.0229 (3)
S250.82802 (11)0.51972 (10)0.39758 (9)0.0255 (4)
S260.97938 (11)0.32594 (10)0.43910 (9)0.0257 (4)
S270.76187 (11)0.24381 (9)0.41848 (9)0.0228 (3)
S280.84592 (11)0.28735 (9)0.58351 (9)0.0230 (3)
S290.55611 (11)0.28247 (9)0.57021 (9)0.0234 (3)
S300.66753 (10)0.09053 (9)0.56254 (8)0.0211 (3)
S310.48045 (10)0.13744 (9)0.67810 (9)0.0227 (3)
S320.66278 (12)−0.06600 (9)0.72356 (9)0.0265 (4)
S330.72800 (10)0.12826 (9)0.76892 (9)0.0220 (3)
S340.67491 (10)−0.01717 (9)0.89779 (8)0.0178 (3)
S350.51836 (10)0.16917 (9)−0.05732 (9)0.0220 (3)
S361.04706 (12)0.36546 (11)0.00374 (10)0.0309 (4)
S370.63694 (10)0.54508 (10)0.29967 (9)0.0253 (4)
S380.94174 (12)0.13672 (10)0.48825 (9)0.0280 (4)
S390.44672 (12)0.12648 (11)0.50451 (10)0.0304 (4)
S400.86602 (10)−0.03442 (10)0.79993 (9)0.0250 (4)

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Ag10.0213 (2)0.0185 (2)0.0261 (3)0.00145 (18)−0.0051 (2)−0.00202 (19)
Ag20.0233 (2)0.0186 (2)0.0162 (2)−0.00268 (18)0.00113 (18)−0.00311 (18)
Ag30.0201 (2)0.0245 (2)0.0188 (2)0.00338 (18)−0.00084 (19)0.00360 (19)
Ag40.0194 (2)0.0228 (2)0.0205 (3)0.00222 (18)0.00016 (19)0.00386 (19)
Ag50.0162 (2)0.0221 (2)0.0168 (2)−0.00022 (17)−0.00191 (18)0.00371 (19)
Ag60.0211 (2)0.0185 (2)0.0262 (3)0.00178 (18)−0.0051 (2)−0.0019 (2)
C10.022 (3)0.055 (5)0.022 (4)0.015 (3)−0.010 (3)−0.019 (3)
C20.023 (3)0.024 (3)0.027 (4)−0.002 (3)0.009 (3)−0.010 (3)
C30.028 (4)0.053 (5)0.055 (6)−0.001 (4)−0.011 (4)0.005 (4)
C40.031 (4)0.024 (4)0.056 (5)0.000 (3)−0.021 (4)−0.005 (3)
C50.049 (5)0.030 (4)0.033 (4)0.003 (3)0.007 (4)−0.021 (3)
C60.024 (3)0.026 (3)0.022 (4)−0.008 (3)0.004 (3)−0.003 (3)
C70.037 (4)0.035 (4)0.026 (4)0.008 (3)−0.015 (3)−0.018 (3)
C80.034 (4)0.035 (4)0.024 (4)0.012 (3)0.001 (3)−0.014 (3)
C90.042 (5)0.047 (5)0.044 (5)−0.019 (4)0.007 (4)0.015 (4)
C100.033 (4)0.049 (5)0.034 (5)0.017 (4)0.019 (3)0.017 (4)
C110.037 (4)0.042 (5)0.048 (5)−0.010 (4)0.014 (4)0.003 (4)
C120.021 (3)0.045 (4)0.038 (4)−0.009 (3)−0.001 (3)0.019 (4)
C130.024 (3)0.026 (4)0.054 (5)−0.005 (3)0.023 (3)−0.005 (3)
C140.035 (4)0.019 (3)0.037 (4)0.001 (3)0.009 (3)−0.002 (3)
C150.030 (4)0.022 (3)0.046 (5)0.007 (3)−0.010 (3)−0.006 (3)
C160.030 (4)0.042 (5)0.053 (5)−0.016 (3)−0.014 (4)0.006 (4)
C170.025 (4)0.049 (5)0.026 (4)−0.008 (3)−0.012 (3)0.017 (3)
C180.051 (5)0.048 (5)0.054 (6)−0.027 (4)−0.002 (4)0.004 (4)
C190.038 (5)0.054 (5)0.060 (6)0.033 (4)0.012 (4)0.015 (5)
C200.046 (5)0.045 (5)0.026 (4)−0.025 (4)0.019 (3)−0.014 (3)
C210.028 (3)0.033 (4)0.017 (3)−0.013 (3)0.001 (3)0.011 (3)
C220.019 (3)0.037 (4)0.021 (4)−0.001 (3)−0.008 (3)−0.001 (3)
C230.052 (5)0.020 (3)0.039 (5)−0.016 (3)−0.030 (4)0.008 (3)
C240.038 (4)0.033 (4)0.032 (4)0.018 (3)0.007 (3)−0.011 (3)
C250.021 (3)0.028 (3)0.026 (4)−0.019 (3)0.006 (3)−0.006 (3)
C260.032 (4)0.057 (5)0.034 (5)−0.016 (4)0.011 (3)0.019 (4)
C270.019 (3)0.032 (4)0.032 (4)−0.012 (3)−0.011 (3)0.000 (3)
C280.063 (5)0.012 (3)0.029 (4)0.012 (3)0.017 (4)0.003 (3)
C290.026 (3)0.042 (4)0.022 (4)0.007 (3)0.001 (3)0.013 (3)
C300.033 (4)0.033 (4)0.046 (5)−0.002 (3)−0.020 (4)0.016 (4)
C310.041 (4)0.016 (3)0.043 (5)0.001 (3)−0.005 (3)−0.001 (3)
C320.026 (4)0.061 (5)0.039 (5)0.016 (4)−0.021 (3)−0.024 (4)
Mo10.0212 (3)0.0183 (3)0.0262 (3)0.0016 (2)−0.0051 (2)−0.0019 (2)
Mo20.0216 (3)0.0202 (3)0.0215 (3)0.0035 (2)−0.0024 (2)0.0008 (2)
Mo30.0198 (3)0.0192 (3)0.0195 (3)−0.0004 (2)−0.0046 (2)0.0017 (2)
Mo40.0179 (3)0.0178 (3)0.0190 (3)0.0024 (2)0.0007 (2)0.0024 (2)
Mo50.0198 (3)0.0196 (3)0.0210 (3)0.0037 (2)−0.0003 (2)0.0017 (2)
Mo60.0201 (3)0.0186 (3)0.0136 (3)0.0026 (2)0.0000 (2)0.0006 (2)
O10.034 (3)0.016 (2)0.035 (3)0.0028 (19)−0.002 (2)−0.001 (2)
O20.030 (3)0.036 (3)0.038 (3)−0.009 (2)−0.007 (2)0.003 (2)
O30.026 (2)0.032 (3)0.022 (3)−0.004 (2)−0.001 (2)−0.004 (2)
O40.031 (3)0.044 (3)0.020 (3)0.006 (2)−0.002 (2)−0.015 (2)
O50.044 (3)0.022 (2)0.033 (3)0.001 (2)0.004 (2)0.005 (2)
O60.027 (2)0.028 (2)0.026 (3)0.007 (2)−0.017 (2)−0.009 (2)
O70.025 (2)0.025 (2)0.033 (3)0.0097 (19)−0.018 (2)−0.009 (2)
O80.025 (2)0.044 (3)0.027 (3)−0.006 (2)−0.006 (2)0.004 (2)
O90.035 (3)0.032 (3)0.039 (3)−0.002 (2)−0.011 (2)0.008 (2)
O100.022 (2)0.032 (3)0.047 (4)0.000 (2)−0.001 (2)0.004 (2)
O110.036 (3)0.026 (3)0.028 (3)−0.004 (2)0.003 (2)0.006 (2)
O120.034 (3)0.028 (3)0.031 (3)0.010 (2)−0.006 (2)−0.004 (2)
O130.033 (3)0.019 (2)0.032 (3)0.0003 (19)0.003 (2)0.008 (2)
O140.028 (3)0.043 (3)0.017 (3)0.000 (2)−0.004 (2)−0.013 (2)
O150.033 (3)0.035 (3)0.035 (3)0.009 (2)0.005 (2)−0.009 (2)
O160.032 (3)0.039 (3)0.027 (3)0.008 (2)−0.008 (2)0.004 (2)
Pr10.02798 (19)0.02676 (19)0.0212 (2)0.00459 (15)−0.00136 (15)0.00115 (15)
Pr20.0321 (2)0.02562 (19)0.0257 (2)0.00574 (16)−0.00071 (16)−0.00028 (16)
S10.0262 (8)0.0230 (8)0.0251 (9)−0.0015 (6)−0.0049 (7)0.0015 (7)
S20.0244 (8)0.0251 (8)0.0284 (10)−0.0082 (7)−0.0040 (7)0.0006 (7)
S30.0207 (8)0.0279 (8)0.0233 (9)0.0053 (6)−0.0046 (6)−0.0015 (7)
S40.0202 (7)0.0227 (8)0.0218 (8)0.0017 (6)−0.0002 (6)−0.0022 (6)
S50.0287 (9)0.0208 (8)0.0327 (10)−0.0032 (7)−0.0028 (7)−0.0023 (7)
S60.0219 (8)0.0212 (7)0.0180 (8)0.0010 (6)−0.0008 (6)0.0028 (6)
S70.0173 (8)0.0297 (9)0.0334 (10)0.0008 (6)−0.0076 (7)0.0049 (7)
S80.0236 (8)0.0350 (9)0.0273 (10)−0.0140 (7)−0.0017 (7)−0.0016 (7)
S90.0266 (8)0.0192 (7)0.0203 (8)0.0062 (6)−0.0021 (6)0.0006 (6)
S100.0344 (9)0.0290 (9)0.0280 (10)−0.0033 (7)−0.0056 (8)0.0063 (7)
S110.0310 (9)0.0228 (8)0.0217 (9)0.0033 (7)0.0042 (7)−0.0074 (7)
S120.0174 (8)0.0342 (9)0.0297 (10)−0.0041 (7)0.0018 (7)0.0030 (7)
S130.0213 (8)0.0292 (9)0.0339 (10)−0.0074 (7)−0.0033 (7)0.0076 (8)
S140.0226 (8)0.0272 (8)0.0153 (8)0.0022 (6)0.0037 (6)0.0017 (6)
S150.0209 (8)0.0320 (9)0.0366 (11)−0.0013 (7)−0.0033 (7)0.0024 (8)
S160.0253 (8)0.0223 (8)0.0193 (8)−0.0040 (6)−0.0031 (6)0.0006 (6)
S170.0351 (9)0.0212 (8)0.0212 (9)0.0100 (7)−0.0031 (7)−0.0023 (7)
S180.0228 (8)0.0234 (8)0.0219 (9)0.0035 (6)−0.0010 (6)−0.0073 (7)
S190.0213 (8)0.0186 (7)0.0263 (9)0.0015 (6)−0.0050 (6)−0.0018 (6)
S200.0270 (8)0.0195 (8)0.0344 (10)0.0094 (6)−0.0046 (7)−0.0027 (7)
S210.0223 (8)0.0189 (7)0.0220 (9)0.0054 (6)−0.0054 (6)−0.0059 (6)
S220.0211 (8)0.0324 (9)0.0230 (9)−0.0001 (7)−0.0045 (7)0.0024 (7)
S230.0349 (9)0.0207 (8)0.0272 (9)−0.0025 (7)0.0124 (7)−0.0014 (7)
S240.0251 (8)0.0219 (8)0.0221 (9)−0.0071 (6)−0.0052 (7)0.0035 (6)
S250.0266 (8)0.0284 (8)0.0216 (9)0.0002 (7)−0.0084 (7)−0.0047 (7)
S260.0179 (7)0.0302 (9)0.0291 (10)−0.0012 (6)−0.0018 (7)0.0068 (7)
S270.0206 (7)0.0274 (8)0.0200 (8)0.0033 (6)−0.0009 (6)0.0006 (7)
S280.0274 (8)0.0203 (8)0.0211 (9)0.0011 (6)−0.0011 (7)−0.0036 (6)
S290.0236 (8)0.0195 (8)0.0262 (9)0.0071 (6)0.0034 (7)0.0077 (7)
S300.0213 (7)0.0225 (8)0.0192 (8)0.0022 (6)0.0027 (6)−0.0013 (6)
S310.0210 (8)0.0233 (8)0.0232 (9)0.0071 (6)0.0015 (6)−0.0030 (7)
S320.0344 (9)0.0199 (8)0.0255 (9)−0.0028 (7)−0.0063 (7)−0.0032 (7)
S330.0214 (8)0.0184 (7)0.0262 (9)0.0016 (6)−0.0050 (7)−0.0019 (6)
S340.0201 (7)0.0189 (7)0.0142 (8)0.0026 (6)0.0001 (6)0.0006 (6)
S350.0214 (8)0.0188 (7)0.0257 (9)0.0019 (6)−0.0050 (6)−0.0020 (7)
S360.0289 (9)0.0324 (9)0.0312 (10)0.0002 (7)0.0071 (8)−0.0019 (8)
S370.0173 (7)0.0369 (9)0.0215 (9)0.0016 (7)−0.0041 (6)−0.0051 (7)
S380.0360 (9)0.0276 (9)0.0190 (9)0.0155 (7)0.0066 (7)−0.0004 (7)
S390.0285 (9)0.0338 (9)0.0291 (10)−0.0009 (7)−0.0083 (7)−0.0068 (8)
S400.0185 (8)0.0364 (9)0.0190 (9)0.0101 (7)0.0043 (6)0.0034 (7)

Geometric parameters (Å, °)

Ag1—S202.4893 (17)C20—S71.673 (7)
Ag1—S192.5226 (16)C20—H20A0.9600
Ag1—S212.5619 (16)C20—H20B0.9600
Ag1—S182.6341 (17)C20—H20C0.9600
Ag1—Mo22.9433 (6)C21—S11.781 (6)
Ag1—Mo12.9690 (6)C21—H21A0.9600
Ag2—S222.5072 (17)C21—H21B0.9600
Ag2—S212.5101 (17)C21—H21C0.9600
Ag2—S232.5274 (17)C22—S11.867 (7)
Ag2—S242.5492 (16)C22—H22A0.9600
Ag2—Mo22.9349 (6)C22—H22B0.9600
Ag2—Mo32.9509 (6)C22—H22C0.9600
Ag3—S242.4901 (17)C23—S31.769 (7)
Ag3—S262.4921 (17)C23—H23A0.9600
Ag3—S252.5783 (18)C23—H23B0.9600
Ag3—S272.7465 (17)C23—H23C0.9600
Ag3—Mo32.9660 (6)C24—S31.813 (7)
Ag3—Mo43.0099 (6)C24—H24A0.9600
Ag4—S292.4946 (16)C24—H24B0.9600
Ag4—S282.5151 (16)C24—H24C0.9600
Ag4—S302.5571 (16)C25—S41.737 (6)
Ag4—S272.6584 (17)C25—H25A0.9600
Ag4—Mo52.9436 (6)C25—H25B0.9600
Ag4—Mo42.9602 (6)C25—H25C0.9600
Ag5—S302.4992 (17)C26—S41.767 (8)
Ag5—S322.5100 (17)C26—H26A0.9600
Ag5—S312.5404 (16)C26—H26B0.9600
Ag5—S332.5568 (16)C26—H26C0.9600
Ag5—Mo52.9333 (6)C27—S61.794 (6)
Ag5—Mo62.9457 (6)C27—H27A0.9600
Ag6—S35i2.4929 (17)C27—H27B0.9600
Ag6—S332.5085 (18)C27—H27C0.9600
Ag6—S342.5929 (15)C28—S61.737 (7)
Ag6—S18i2.7032 (16)C28—H28A0.9600
Ag6—Mo62.9632 (6)C28—H28B0.9600
Ag6—Mo1i2.9915 (6)C28—H28C0.9600
C1—S161.820 (7)C29—S21.862 (7)
C1—H1A0.9600C29—H29A0.9600
C1—H1B0.9600C29—H29B0.9600
C1—H1C0.9600C29—H29C0.9600
C2—S161.837 (7)C30—S21.805 (8)
C2—H2A0.9600C30—H30A0.9600
C2—H2B0.9600C30—H30B0.9600
C2—H2C0.9600C30—H30C0.9600
C3—S101.788 (8)C31—S51.815 (8)
C3—H3A0.9600C31—H31A0.9600
C3—H3B0.9600C31—H31B0.9600
C3—H3C0.9600C31—H31C0.9600
C4—S101.733 (7)C32—S51.768 (7)
C4—H4A0.9600C32—H32A0.9600
C4—H4B0.9600C32—H32B0.9600
C4—H4C0.9600C32—H32C0.9600
C5—S91.785 (7)Mo1—S172.1156 (18)
C5—H5A0.9600Mo1—S352.1925 (16)
C5—H5B0.9600Mo1—S192.2256 (18)
C5—H5C0.9600Mo1—S182.2512 (18)
C6—S91.720 (7)Mo1—Ag6ii2.9915 (6)
C6—H6A0.9600Mo2—S362.1308 (19)
C6—H6B0.9600Mo2—S222.1977 (18)
C6—H6C0.9600Mo2—S202.2070 (18)
C7—S111.765 (7)Mo2—S212.2572 (17)
C7—H7A0.9600Mo3—S372.1655 (17)
C7—H7B0.9600Mo3—S232.1855 (18)
C7—H7C0.9600Mo3—S252.2004 (18)
C8—S111.722 (7)Mo3—S242.2480 (17)
C8—H8A0.9600Mo4—S382.1475 (18)
C8—H8B0.9600Mo4—S282.2058 (18)
C8—H8C0.9600Mo4—S272.2172 (17)
C9—S121.838 (8)Mo4—S262.2183 (17)
C9—H9A0.9600Mo5—S392.1552 (18)
C9—H9B0.9600Mo5—S292.1988 (17)
C9—H9C0.9600Mo5—S312.2061 (18)
C10—S121.789 (7)Mo5—S302.2693 (17)
C10—H10A0.9600Mo6—S402.1440 (17)
C10—H10B0.9600Mo6—S322.2011 (18)
C10—H10C0.9600Mo6—S342.2098 (17)
C11—S131.812 (7)Mo6—S332.2611 (17)
C11—H11A0.9600O1—S11.536 (5)
C11—H11B0.9600O1—Pr12.411 (5)
C11—H11C0.9600O2—S21.441 (6)
C12—S131.611 (7)O2—Pr12.423 (5)
C12—H12A0.9600O3—S31.540 (5)
C12—H12B0.9600O3—Pr12.472 (5)
C12—H12C0.9600O4—S41.558 (5)
C13—S151.785 (7)O4—Pr12.449 (5)
C13—H13A0.9600O5—S51.495 (5)
C13—H13B0.9600O5—Pr12.513 (5)
C13—H13C0.9600O6—S61.534 (5)
C14—S151.689 (7)O6—Pr12.486 (5)
C14—H14A0.9600O7—S71.446 (6)
C14—H14B0.9600O7—Pr12.521 (5)
C14—H14C0.9600O8—S81.580 (5)
C15—S141.709 (7)O8—Pr12.379 (5)
C15—H15A0.9600O9—S91.527 (5)
C15—H15B0.9600O9—Pr22.462 (5)
C15—H15C0.9600O10—S101.461 (6)
C16—S141.755 (7)O10—Pr22.436 (5)
C16—H16A0.9600O11—S111.522 (5)
C16—H16B0.9600O11—Pr22.420 (5)
C16—H16C0.9600O12—S121.506 (5)
C17—S81.780 (8)O12—Pr22.551 (5)
C17—H17A0.9600O13—S131.512 (5)
C17—H17B0.9600O13—Pr22.458 (5)
C17—H17C0.9600O14—S141.532 (5)
C18—S81.932 (9)O14—Pr22.399 (5)
C18—H18A0.9600O15—S151.449 (6)
C18—H18B0.9600O15—Pr22.472 (5)
C18—H18C0.9600O16—S161.476 (5)
C19—S71.692 (7)O16—Pr22.442 (5)
C19—H19A0.9600S18—Ag6ii2.7032 (16)
C19—H19B0.9600S35—Ag6ii2.4929 (17)
C19—H19C0.9600
S20—Ag1—S19120.61 (6)S2—C29—H29C109.5
S20—Ag1—S2194.74 (5)H29A—C29—H29C109.5
S19—Ag1—S21126.66 (5)H29B—C29—H29C109.5
S20—Ag1—S18116.60 (6)S2—C30—H30A109.5
S19—Ag1—S1890.53 (5)S2—C30—H30B109.5
S21—Ag1—S18108.88 (5)H30A—C30—H30B109.5
S20—Ag1—Mo247.03 (4)S2—C30—H30C109.5
S19—Ag1—Mo2146.88 (4)H30A—C30—H30C109.5
S21—Ag1—Mo247.79 (4)H30B—C30—H30C109.5
S18—Ag1—Mo2122.58 (4)S5—C31—H31A109.5
S20—Ag1—Mo1146.81 (4)S5—C31—H31B109.5
S19—Ag1—Mo146.95 (4)H31A—C31—H31B109.5
S21—Ag1—Mo1117.22 (4)S5—C31—H31C109.5
S18—Ag1—Mo146.91 (4)H31A—C31—H31C109.5
Mo2—Ag1—Mo1161.995 (19)H31B—C31—H31C109.5
S22—Ag2—S2194.72 (5)S5—C32—H32A109.5
S22—Ag2—S23128.21 (6)S5—C32—H32B109.5
S21—Ag2—S23115.56 (6)H32A—C32—H32B109.5
S22—Ag2—S24110.98 (6)S5—C32—H32C109.5
S21—Ag2—S24115.23 (5)H32A—C32—H32C109.5
S23—Ag2—S2493.50 (5)H32B—C32—H32C109.5
S22—Ag2—Mo246.82 (4)S17—Mo1—S35107.99 (7)
S21—Ag2—Mo248.21 (4)S17—Mo1—S19108.51 (7)
S23—Ag2—Mo2145.24 (4)S35—Mo1—S19107.94 (6)
S24—Ag2—Mo2120.96 (4)S17—Mo1—S18109.85 (7)
S22—Ag2—Mo3131.56 (4)S35—Mo1—S18112.58 (7)
S21—Ag2—Mo3132.93 (4)S19—Mo1—S18109.86 (7)
S23—Ag2—Mo346.23 (4)S17—Mo1—Ag1104.89 (5)
S24—Ag2—Mo347.56 (4)S35—Mo1—Ag1146.79 (5)
Mo2—Ag2—Mo3168.497 (18)S19—Mo1—Ag155.92 (4)
S24—Ag3—S26141.66 (6)S18—Mo1—Ag158.70 (4)
S24—Ag3—S2593.75 (5)S17—Mo1—Ag6ii140.18 (5)
S26—Ag3—S25108.70 (5)S35—Mo1—Ag6ii54.91 (5)
S24—Ag3—S2792.18 (5)S19—Mo1—Ag6ii111.04 (5)
S26—Ag3—S2789.26 (5)S18—Mo1—Ag6ii60.12 (4)
S25—Ag3—S27141.10 (5)Ag1—Mo1—Ag6ii100.784 (18)
S24—Ag3—Mo347.68 (4)S36—Mo2—S22107.70 (7)
S26—Ag3—Mo3142.00 (4)S36—Mo2—S20107.85 (7)
S25—Ag3—Mo346.11 (4)S22—Mo2—S20108.22 (7)
S27—Ag3—Mo3128.52 (4)S36—Mo2—S21108.27 (7)
S24—Ag3—Mo4132.81 (4)S22—Mo2—S21111.88 (7)
S26—Ag3—Mo446.38 (4)S20—Mo2—S21112.73 (6)
S25—Ag3—Mo4131.03 (4)S36—Mo2—Ag2129.44 (6)
S27—Ag3—Mo445.02 (4)S22—Mo2—Ag256.30 (5)
Mo3—Ag3—Mo4169.415 (18)S20—Mo2—Ag2122.65 (5)
S29—Ag4—S28123.51 (6)S21—Mo2—Ag256.00 (4)
S29—Ag4—S3094.87 (5)S36—Mo2—Ag1121.01 (6)
S28—Ag4—S30125.49 (5)S22—Mo2—Ag1131.19 (5)
S29—Ag4—S27116.20 (5)S20—Mo2—Ag155.61 (5)
S28—Ag4—S2789.13 (5)S21—Mo2—Ag157.22 (4)
S30—Ag4—S27108.32 (5)Ag2—Mo2—Ag191.783 (17)
S29—Ag4—Mo546.80 (4)S37—Mo3—S23107.12 (7)
S28—Ag4—Mo5148.13 (4)S37—Mo3—S25107.32 (7)
S30—Ag4—Mo548.10 (4)S23—Mo3—S25109.73 (7)
S27—Ag4—Mo5122.72 (4)S37—Mo3—S24106.76 (7)
S29—Ag4—Mo4148.46 (4)S23—Mo3—S24113.03 (7)
S28—Ag4—Mo446.64 (4)S25—Mo3—S24112.54 (7)
S30—Ag4—Mo4114.79 (4)S37—Mo3—Ag2127.82 (5)
S27—Ag4—Mo446.10 (4)S23—Mo3—Ag256.62 (5)
Mo5—Ag4—Mo4159.892 (19)S25—Mo3—Ag2124.84 (5)
S30—Ag5—S32115.41 (6)S24—Mo3—Ag256.81 (5)
S30—Ag5—S3195.10 (5)S37—Mo3—Ag3124.32 (5)
S32—Ag5—S31127.52 (6)S23—Mo3—Ag3128.57 (5)
S30—Ag5—S33115.80 (5)S25—Mo3—Ag357.62 (5)
S32—Ag5—S3394.37 (5)S24—Mo3—Ag354.99 (4)
S31—Ag5—S33110.02 (5)Ag2—Mo3—Ag388.511 (17)
S30—Ag5—Mo548.58 (4)S38—Mo4—S28108.27 (7)
S32—Ag5—Mo5144.96 (4)S38—Mo4—S27108.51 (7)
S31—Ag5—Mo546.86 (4)S28—Mo4—S27110.40 (7)
S33—Ag5—Mo5120.50 (4)S38—Mo4—S26108.45 (7)
S30—Ag5—Mo6133.54 (4)S28—Mo4—S26108.77 (7)
S32—Ag5—Mo646.75 (4)S27—Mo4—S26112.34 (7)
S31—Ag5—Mo6130.61 (4)S38—Mo4—Ag4102.24 (5)
S33—Ag5—Mo647.88 (4)S28—Mo4—Ag456.00 (4)
Mo5—Ag5—Mo6168.289 (18)S27—Mo4—Ag459.76 (5)
S35i—Ag6—S33142.30 (5)S26—Mo4—Ag4149.03 (5)
S35i—Ag6—S34106.34 (5)S38—Mo4—Ag3141.42 (5)
S33—Ag6—S3494.19 (5)S28—Mo4—Ag3110.08 (5)
S35i—Ag6—S18i90.61 (5)S27—Mo4—Ag361.19 (5)
S33—Ag6—S18i93.05 (5)S26—Mo4—Ag354.42 (5)
S34—Ag6—S18i140.62 (5)Ag4—Mo4—Ag3102.397 (17)
S35i—Ag6—Mo6140.68 (4)S39—Mo5—S29108.20 (7)
S33—Ag6—Mo647.93 (4)S39—Mo5—S31107.24 (7)
S34—Ag6—Mo646.28 (4)S29—Mo5—S31107.97 (7)
S18i—Ag6—Mo6128.66 (4)S39—Mo5—S30108.09 (7)
S35i—Ag6—Mo1i46.02 (4)S29—Mo5—S30112.76 (6)
S33—Ag6—Mo1i134.10 (4)S31—Mo5—S30112.37 (6)
S34—Ag6—Mo1i129.93 (4)S39—Mo5—Ag5129.35 (6)
S18i—Ag6—Mo1i46.23 (4)S29—Mo5—Ag5122.40 (5)
Mo6—Ag6—Mo1i170.066 (18)S31—Mo5—Ag557.17 (4)
S16—C1—H1A109.5S30—Mo5—Ag555.67 (4)
S16—C1—H1B109.5S39—Mo5—Ag4122.40 (6)
H1A—C1—H1B109.5S29—Mo5—Ag455.80 (4)
S16—C1—H1C109.5S31—Mo5—Ag4130.26 (5)
H1A—C1—H1C109.5S30—Mo5—Ag457.00 (4)
H1B—C1—H1C109.5Ag5—Mo5—Ag490.310 (16)
S16—C2—H2A109.5S40—Mo6—S32107.85 (7)
S16—C2—H2B109.5S40—Mo6—S34106.73 (6)
H2A—C2—H2B109.5S32—Mo6—S34109.00 (7)
S16—C2—H2C109.5S40—Mo6—S33106.70 (7)
H2A—C2—H2C109.5S32—Mo6—S33112.80 (7)
H2B—C2—H2C109.5S34—Mo6—S33113.42 (6)
S10—C3—H3A109.5S40—Mo6—Ag5128.13 (5)
S10—C3—H3B109.5S32—Mo6—Ag556.16 (5)
H3A—C3—H3B109.5S34—Mo6—Ag5125.10 (5)
S10—C3—H3C109.5S33—Mo6—Ag557.01 (4)
H3A—C3—H3C109.5S40—Mo6—Ag6123.01 (5)
H3B—C3—H3C109.5S32—Mo6—Ag6129.13 (5)
S10—C4—H4A109.5S34—Mo6—Ag657.99 (4)
S10—C4—H4B109.5S33—Mo6—Ag655.45 (5)
H4A—C4—H4B109.5Ag5—Mo6—Ag689.684 (16)
S10—C4—H4C109.5S1—O1—Pr1133.9 (3)
H4A—C4—H4C109.5S2—O2—Pr1138.2 (3)
H4B—C4—H4C109.5S3—O3—Pr1127.9 (3)
S9—C5—H5A109.5S4—O4—Pr1128.1 (3)
S9—C5—H5B109.5S5—O5—Pr1124.1 (3)
H5A—C5—H5B109.5S6—O6—Pr1126.6 (3)
S9—C5—H5C109.5S7—O7—Pr1132.9 (3)
H5A—C5—H5C109.5S8—O8—Pr1114.5 (3)
H5B—C5—H5C109.5S9—O9—Pr2138.3 (3)
S9—C6—H6A109.5S10—O10—Pr2125.7 (3)
S9—C6—H6B109.5S11—O11—Pr2137.1 (3)
H6A—C6—H6B109.5S12—O12—Pr2132.2 (3)
S9—C6—H6C109.5S13—O13—Pr2130.7 (3)
H6A—C6—H6C109.5S14—O14—Pr2130.4 (3)
H6B—C6—H6C109.5S15—O15—Pr2134.5 (3)
S11—C7—H7A109.5S16—O16—Pr2134.3 (3)
S11—C7—H7B109.5O8—Pr1—O181.92 (17)
H7A—C7—H7B109.5O8—Pr1—O272.56 (19)
S11—C7—H7C109.5O1—Pr1—O278.30 (16)
H7A—C7—H7C109.5O8—Pr1—O4121.32 (17)
H7B—C7—H7C109.5O1—Pr1—O4142.40 (17)
S11—C8—H8A109.5O2—Pr1—O481.43 (18)
S11—C8—H8B109.5O8—Pr1—O3146.88 (17)
H8A—C8—H8B109.5O1—Pr1—O374.52 (17)
S11—C8—H8C109.5O2—Pr1—O380.02 (17)
H8A—C8—H8C109.5O4—Pr1—O370.98 (16)
H8B—C8—H8C109.5O8—Pr1—O671.49 (18)
S12—C9—H9A109.5O1—Pr1—O6147.39 (17)
S12—C9—H9B109.5O2—Pr1—O6110.03 (17)
H9A—C9—H9B109.5O4—Pr1—O669.76 (16)
S12—C9—H9C109.5O3—Pr1—O6137.17 (16)
H9A—C9—H9C109.5O8—Pr1—O5138.89 (18)
H9B—C9—H9C109.5O1—Pr1—O5110.22 (17)
S12—C10—H10A109.5O2—Pr1—O5147.11 (18)
S12—C10—H10B109.5O4—Pr1—O572.98 (18)
H10A—C10—H10B109.5O3—Pr1—O572.42 (17)
S12—C10—H10C109.5O6—Pr1—O580.34 (17)
H10A—C10—H10C109.5O8—Pr1—O772.15 (18)
H10B—C10—H10C109.5O1—Pr1—O776.09 (15)
S13—C11—H11A109.5O2—Pr1—O7138.67 (18)
S13—C11—H11B109.5O4—Pr1—O7136.26 (17)
H11A—C11—H11B109.5O3—Pr1—O7122.48 (15)
S13—C11—H11C109.5O6—Pr1—O777.98 (14)
H11A—C11—H11C109.5O5—Pr1—O773.15 (18)
H11B—C11—H11C109.5O14—Pr2—O11146.54 (17)
S13—C12—H12A109.5O14—Pr2—O10120.58 (17)
S13—C12—H12B109.5O11—Pr2—O1078.64 (17)
H12A—C12—H12B109.5O14—Pr2—O1670.99 (17)
S13—C12—H12C109.5O11—Pr2—O16142.44 (17)
H12A—C12—H12C109.5O10—Pr2—O1678.48 (19)
H12B—C12—H12C109.5O14—Pr2—O1373.84 (17)
S15—C13—H13A109.5O11—Pr2—O1373.25 (17)
S15—C13—H13B109.5O10—Pr2—O13131.73 (18)
H13A—C13—H13B109.5O16—Pr2—O13142.69 (17)
S15—C13—H13C109.5O14—Pr2—O9136.28 (18)
H13A—C13—H13C109.5O11—Pr2—O973.54 (19)
H13B—C13—H13C109.5O10—Pr2—O971.19 (17)
S15—C14—H14A109.5O16—Pr2—O971.07 (18)
S15—C14—H14B109.5O13—Pr2—O9132.93 (17)
H14A—C14—H14B109.5O14—Pr2—O1573.77 (16)
S15—C14—H14C109.5O11—Pr2—O15102.65 (17)
H14A—C14—H14C109.5O10—Pr2—O15151.40 (18)
H14B—C14—H14C109.5O16—Pr2—O1584.38 (18)
S14—C15—H15A109.5O13—Pr2—O1574.16 (18)
S14—C15—H15B109.5O9—Pr2—O1581.69 (18)
H15A—C15—H15B109.5O14—Pr2—O1278.50 (16)
S14—C15—H15C109.5O11—Pr2—O1286.49 (17)
H15A—C15—H15C109.5O10—Pr2—O1266.42 (17)
H15B—C15—H15C109.5O16—Pr2—O12110.71 (17)
S14—C16—H16A109.5O13—Pr2—O1273.36 (17)
S14—C16—H16B109.5O9—Pr2—O12135.87 (17)
H16A—C16—H16B109.5O15—Pr2—O12141.90 (17)
S14—C16—H16C109.5O1—S1—C21109.4 (2)
H16A—C16—H16C109.5O1—S1—C22104.3 (2)
H16B—C16—H16C109.5C21—S1—C22100.7 (3)
S8—C17—H17A109.5O2—S2—C30103.6 (3)
S8—C17—H17B109.5O2—S2—C29110.9 (3)
H17A—C17—H17B109.5C30—S2—C2995.5 (3)
S8—C17—H17C109.5O3—S3—C23101.1 (3)
H17A—C17—H17C109.5O3—S3—C2499.1 (3)
H17B—C17—H17C109.5C23—S3—C24101.0 (4)
S8—C18—H18A109.5O4—S4—C25106.0 (2)
S8—C18—H18B109.5O4—S4—C26103.2 (3)
H18A—C18—H18B109.5C25—S4—C2697.7 (4)
S8—C18—H18C109.5O5—S5—C32105.9 (3)
H18A—C18—H18C109.5O5—S5—C31101.7 (2)
H18B—C18—H18C109.5C32—S5—C3194.2 (4)
S7—C19—H19A109.5O6—S6—C28104.2 (3)
S7—C19—H19B109.5O6—S6—C27101.7 (2)
H19A—C19—H19B109.5C28—S6—C27100.2 (4)
S7—C19—H19C109.5O7—S7—C20105.3 (3)
H19A—C19—H19C109.5O7—S7—C19107.1 (4)
H19B—C19—H19C109.5C20—S7—C1998.4 (5)
S7—C20—H20A109.5O8—S8—C17104.8 (2)
S7—C20—H20B109.5O8—S8—C18103.2 (3)
H20A—C20—H20B109.5C17—S8—C1894.2 (4)
S7—C20—H20C109.5O9—S9—C6105.0 (2)
H20A—C20—H20C109.5O9—S9—C5101.8 (3)
H20B—C20—H20C109.5C6—S9—C596.3 (4)
S1—C21—H21A109.5O10—S10—C4101.4 (3)
S1—C21—H21B109.5O10—S10—C3105.3 (3)
H21A—C21—H21B109.5C4—S10—C399.8 (4)
S1—C21—H21C109.5O11—S11—C8104.2 (3)
H21A—C21—H21C109.5O11—S11—C7105.8 (3)
H21B—C21—H21C109.5C8—S11—C793.7 (3)
S1—C22—H22A109.5O12—S12—C10106.2 (3)
S1—C22—H22B109.5O12—S12—C997.6 (3)
H22A—C22—H22B109.5C10—S12—C995.6 (4)
S1—C22—H22C109.5O13—S13—C12108.6 (3)
H22A—C22—H22C109.5O13—S13—C11105.7 (3)
H22B—C22—H22C109.5C12—S13—C11101.8 (4)
S3—C23—H23A109.5O14—S14—C15106.1 (3)
S3—C23—H23B109.5O14—S14—C16107.3 (3)
H23A—C23—H23B109.5C15—S14—C1697.8 (4)
S3—C23—H23C109.5O15—S15—C14107.7 (3)
H23A—C23—H23C109.5O15—S15—C1399.9 (3)
H23B—C23—H23C109.5C14—S15—C1399.0 (3)
S3—C24—H24A109.5O16—S16—C1103.9 (2)
S3—C24—H24B109.5O16—S16—C2106.1 (2)
H24A—C24—H24B109.5C1—S16—C298.6 (4)
S3—C24—H24C109.5Mo1—S18—Ag174.39 (5)
H24A—C24—H24C109.5Mo1—S18—Ag6ii73.65 (5)
H24B—C24—H24C109.5Ag1—S18—Ag6ii118.71 (6)
S4—C25—H25A109.5Mo1—S19—Ag177.13 (5)
S4—C25—H25B109.5Mo2—S20—Ag177.36 (5)
H25A—C25—H25B109.5Mo2—S21—Ag275.79 (5)
S4—C25—H25C109.5Mo2—S21—Ag174.99 (5)
H25A—C25—H25C109.5Ag2—S21—Ag1112.64 (6)
H25B—C25—H25C109.5Mo2—S22—Ag276.88 (5)
S4—C26—H26A109.5Mo3—S23—Ag277.15 (5)
S4—C26—H26B109.5Mo3—S24—Ag377.32 (5)
H26A—C26—H26B109.5Mo3—S24—Ag275.63 (5)
S4—C26—H26C109.5Ag3—S24—Ag2110.04 (6)
H26A—C26—H26C109.5Mo3—S25—Ag376.27 (5)
H26B—C26—H26C109.5Mo4—S26—Ag379.20 (5)
S6—C27—H27A109.5Mo4—S27—Ag474.15 (5)
S6—C27—H27B109.5Mo4—S27—Ag373.79 (5)
H27A—C27—H27B109.5Ag4—S27—Ag3118.81 (6)
S6—C27—H27C109.5Mo4—S28—Ag477.36 (5)
H27A—C27—H27C109.5Mo5—S29—Ag477.40 (5)
H27B—C27—H27C109.5Mo5—S30—Ag575.75 (5)
S6—C28—H28A109.5Mo5—S30—Ag474.90 (5)
S6—C28—H28B109.5Ag5—S30—Ag4110.99 (6)
H28A—C28—H28B109.5Mo5—S31—Ag575.98 (5)
S6—C28—H28C109.5Mo6—S32—Ag577.10 (5)
H28A—C28—H28C109.5Mo6—S33—Ag676.62 (5)
H28B—C28—H28C109.5Mo6—S33—Ag575.10 (5)
S2—C29—H29A109.5Ag6—S33—Ag5110.69 (6)
S2—C29—H29B109.5Mo6—S34—Ag675.73 (5)
H29A—C29—H29B109.5Mo1—S35—Ag6ii79.07 (5)

Symmetry codes: (i) x, y, z+1; (ii) x, y, z−1.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: PV2090).

References

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