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Acta Crystallogr Sect E Struct Rep Online. 2008 June 1; 64(Pt 6): m819.
Published online 2008 May 17. doi:  10.1107/S1600536808014128
PMCID: PMC2961517

Bis[1,2-bis­(diphenyl­phosphino)ethane-κ2 P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)(4-chloro­phen­yl)diphenyl­stannate(IV)

Abstract

In the title salt, [Ag(C26H24P2)2][Sn(C2ClF2O2)2(C6H5)2(C6H4Cl)], the AgI atom has a tetra­hedral and the SnIV atom a trans-trigonal-bipyramidal coordination geometry. In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two chloro­difluoro­methyl groups are also disordered over two sites for their halogen atoms (occupancy ratios 0.72:0.28 and 0.70:0.30).

Related literature

For other [1,2-bis­(diphenyl­phosphino)ethane]silver bis­(chloro­­difluoro­acetato)triorganostannates, see: Teo et al. (2007 [triangle]; 2008 [triangle]). The structural chemistry of organotin carboxyl­ates has been reviewed by Tiekink (1991 [triangle], 1994 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-64-0m819-scheme1.jpg

Experimental

Crystal data

  • [Ag(C26H24P2)2][Sn(C2ClF2O2)2(C6H5)2(C6H4Cl)]
  • M r = 1548.03
  • Triclinic, An external file that holds a picture, illustration, etc.
Object name is e-64-0m819-efi1.jpg
  • a = 13.4774 (3) Å
  • b = 15.4957 (5) Å
  • c = 18.1475 (4) Å
  • α = 69.674 (2)°
  • β = 84.646 (2)°
  • γ = 74.030 (2)°
  • V = 3416.8 (2) Å3
  • Z = 2
  • Mo Kα radiation
  • μ = 0.92 mm−1
  • T = 100 (2) K
  • 0.19 × 0.09 × 0.06 mm

Data collection

  • Bruker SMART APEX diffractometer
  • Absorption correction: multi-scan SADABS (Sheldrick, 1996 [triangle]) T min = 0.844, T max = 0.947
  • 37182 measured reflections
  • 16111 independent reflections
  • 10301 reflections with I > 2σ(I)
  • R int = 0.075

Refinement

  • R[F 2 > 2σ(F 2)] = 0.057
  • wR(F 2) = 0.148
  • S = 1.01
  • 16111 reflections
  • 868 parameters
  • 118 restraints
  • H-atom parameters constrained
  • Δρmax = 1.35 e Å−3
  • Δρmin = −1.76 e Å−3

Data collection: APEX2 (Bruker, 2007 [triangle]); cell refinement: SAINT (Bruker, 2007 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: X-SEED (Barbour, 2001 [triangle]); software used to prepare material for publication: publCIF (Westrip, 2008 [triangle]).

Table 1
Selected bond angles (°)

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808014128/bq2076sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808014128/bq2076Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

We thank the University of Malaya for funding this study (SF022155/2007 A) and also for the purchase of the diffractometer.

supplementary crystallographic information

Comment

This study continues with studies on bis[1,2-bis(diphenylphosphine)ethane]silver bis(chlorodifluoroacetato)triorganostannates (Teo et al., 2007, 2008). In the present study, the [Ag(Ph2CH2CH2Ph2)2] cation is the counterion for [Sn(C6H4Cl)Ph2(ClF2CCO2)2] (Scheme I). The silver(I) atom shows tetrahedral and the tin atom trans-trigonal bipyramidal coordination (Fig. 1).

Experimental

(4-Chlorophenyl)diphenyltin hydroxide (0.20 g, 0.5 mmol) and chorodifluoroacetic acid (0.05 ml, 0.5 mmol) were dissolved in dichloromethane/methanol (25 ml). The mixture was heated until the hydroxide dissolved completely. Another solution containing 1,2-bis(diphenylphosphino)ethane (0.40 g, 1.0 mmol) and silver trifluoroacetate (0.11 g, 0.5 mmol) was prepared; this was also heated until the reagents dissolved completely. The two solutions were mixed; crystals were obtained by allowing the solvent to evaporate in about 70% yield.

Refinement

Carbon-bound H-atoms were placed in calculated positions (C—H 0.95 to 0.99 Å) and were included in the refinement in the riding model approximation, with U(H) set to 1.2Ueq(C).The chlorine atom of the phenylene ring is disordered over two rings; the C–Cl distances were restrained to 1.75±0.01 Å. The disorder refined to a 0.81:0.19 ratio. The two chlorodifluoromethyl groups of the chlorodifluoroacetate anion are both disordered. Distance restraints were applied: C–C distances = 1.50±0.01 Å, C–Cl 1.75±0.01 Å; C–F 1.35±0.01 Å; Cl···F 2.52±0.01 Å and F···F 2.21±0.01 Å. Additionally, the six halogen atoms of each anion were restrained to lie in an approximate plane, the atoms being allowed to deviate by a maximum of 0.05 Å. The anisotropic temperature factors of the disordered atoms were restrained to be nearly isotropic. The final difference Fourier map had a large peak/hole (-1.76 e Å3 in the vicinity of one of the two disordered anions.

Figures

Fig. 1.
70% Probability thermal ellipsoid plot (Barbour, 2001) of the [Ag(C26H24P2)2] cation. Hydrogen atoms are drawn as spheres of arbitrary radii.
Fig. 2.
70% Probability thermal ellipsoid plot (Barbour, 2001) of the [Sn(ClC6H4)(C6H5)2(C2ClF2O2)] anion. The disordered atoms are not shown. Hydrogen atoms are drawn as spheres of arbitrary radii.

Crystal data

[Ag(C26H24P2)2][Sn(C2ClF2O2)2(C6H5)2(C6H4Cl)]Z = 2
Mr = 1548.03F000 = 1564
Triclinic, P1Dx = 1.505 Mg m3
Hall symbol: -P 1Mo Kα radiation λ = 0.71073 Å
a = 13.4774 (3) ÅCell parameters from 3393 reflections
b = 15.4957 (5) Åθ = 2.3–21.7º
c = 18.1475 (4) ŵ = 0.92 mm1
α = 69.674 (2)ºT = 100 (2) K
β = 84.646 (2)ºBlock, colorless
γ = 74.030 (2)º0.19 × 0.09 × 0.06 mm
V = 3416.8 (2) Å3

Data collection

Bruker SMART APEX diffractometer16111 independent reflections
Radiation source: fine-focus sealed tube10301 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.076
T = 100(2) Kθmax = 27.5º
ω scansθmin = 1.2º
Absorption correction: Multi-scanSADABS (Sheldrick, 1996)h = −17→17
Tmin = 0.844, Tmax = 0.947k = −20→15
37182 measured reflectionsl = −23→23

Refinement

Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.057H-atom parameters constrained
wR(F2) = 0.148  w = 1/[σ2(Fo2) + (0.0516P)2 + 3.4764P] where P = (Fo2 + 2Fc2)/3
S = 1.01(Δ/σ)max = 0.001
16111 reflectionsΔρmax = 1.36 e Å3
868 parametersΔρmin = −1.76 e Å3
118 restraintsExtinction correction: none
Primary atom site location: structure-invariant direct methods

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/UeqOcc. (<1)
Sn10.18356 (3)0.41136 (3)0.74160 (2)0.02029 (10)
Ag10.34144 (3)−0.12991 (3)0.74626 (2)0.01634 (10)
Cl1−0.16052 (14)0.15843 (14)0.80533 (11)0.0334 (5)0.813 (4)
Cl20.13197 (16)0.43648 (19)1.02140 (12)0.0509 (7)0.813 (4)
Cl30.1026 (3)0.4097 (2)0.45258 (17)0.0712 (12)0.722 (5)
F10.3254 (3)0.3662 (3)1.02756 (19)0.0261 (11)0.813 (4)
F20.2350 (4)0.2721 (3)1.0236 (2)0.0530 (14)0.813 (4)
F30.1652 (5)0.5441 (3)0.4608 (3)0.0505 (17)0.722 (5)
F40.2835 (4)0.4236 (5)0.4476 (3)0.077 (3)0.722 (5)
Cl2'0.2959 (8)0.2388 (5)1.0223 (4)0.0530 (14)0.19
Cl3'0.2789 (5)0.5165 (6)0.4514 (3)0.059 (3)0.278 (5)
F1'0.2994 (11)0.3969 (9)1.0274 (5)0.0261 (11)0.19
F2'0.1466 (7)0.3712 (11)1.0226 (5)0.0509 (7)0.19
F3'0.0957 (6)0.5099 (9)0.4631 (5)0.074 (5)0.278 (5)
F4'0.2082 (12)0.3847 (7)0.4476 (5)0.071 (5)0.278 (5)
P10.43266 (10)−0.27742 (10)0.71408 (7)0.0162 (3)
P20.26737 (10)−0.24426 (10)0.85526 (7)0.0157 (3)
P30.40448 (10)−0.00758 (10)0.77467 (7)0.0170 (3)
P40.22324 (10)0.01273 (10)0.65085 (7)0.0170 (3)
O10.1970 (3)0.3585 (3)0.8728 (2)0.0250 (9)
O20.2980 (3)0.4534 (3)0.8737 (2)0.0236 (8)
O30.1653 (3)0.4574 (3)0.6122 (2)0.0249 (9)
O40.2539 (3)0.3173 (3)0.5987 (2)0.0342 (10)
C10.0862 (4)0.3184 (4)0.7596 (3)0.0210 (12)
C20.0951 (4)0.2341 (4)0.8233 (3)0.0231 (12)
H20.15250.21160.85790.028*
C30.0214 (5)0.1825 (4)0.8372 (3)0.0287 (13)
H30.02910.12440.88000.034*
C4−0.0633 (4)0.2173 (4)0.7876 (3)0.0290 (13)
H4−0.11560.18410.79800.035*0.187 (4)
C5−0.0729 (5)0.2994 (5)0.7231 (4)0.0351 (15)
H5−0.12990.32130.68830.042*
C60.0012 (4)0.3493 (4)0.7100 (3)0.0298 (14)
H6−0.00590.40620.66600.036*
C70.3472 (4)0.3784 (4)0.7282 (3)0.0260 (13)
C80.4138 (5)0.3012 (4)0.7814 (3)0.0297 (14)
H80.38610.25870.82420.036*
C90.5190 (5)0.2854 (5)0.7730 (4)0.0380 (17)
H90.56370.23120.80850.046*
C100.5589 (5)0.3497 (5)0.7120 (4)0.0391 (17)
H100.63160.34070.70760.047*0.813 (4)
Cl1'0.6905 (9)0.3299 (19)0.7021 (15)0.171 (10)0.187 (4)
C110.4963 (5)0.4253 (5)0.6585 (4)0.0346 (15)
H110.52510.46740.61600.042*
C120.3899 (5)0.4407 (5)0.6663 (3)0.0304 (14)
H120.34590.49390.62930.036*
C130.0986 (4)0.5528 (4)0.7339 (3)0.0202 (11)
C140.0815 (5)0.6263 (4)0.6624 (3)0.0287 (13)
H140.10890.61380.61590.034*
C150.0251 (5)0.7179 (4)0.6573 (4)0.0337 (15)
H150.01410.76690.60750.040*
C16−0.0152 (4)0.7388 (4)0.7241 (3)0.0313 (14)
H16−0.05270.80170.72060.038*
C170.0001 (4)0.6661 (4)0.7957 (3)0.0274 (13)
H17−0.02770.67900.84200.033*
C180.0561 (4)0.5738 (4)0.8008 (3)0.0249 (12)
H180.06550.52460.85060.030*
C190.2499 (4)0.3938 (4)0.9047 (3)0.0210 (12)
C200.2436 (4)0.3606 (4)0.9940 (3)0.0322 (14)
C210.2060 (4)0.4013 (4)0.5744 (3)0.0254 (13)
C220.1933 (4)0.4485 (4)0.4850 (3)0.0371 (16)
C230.4185 (4)−0.2828 (4)0.6172 (3)0.0194 (11)
C240.4972 (4)−0.2732 (4)0.5614 (3)0.0277 (13)
H240.5598−0.26440.57380.033*
C250.4830 (6)−0.2766 (5)0.4875 (3)0.0388 (17)
H250.5367−0.27090.44970.047*
C270.3918 (6)−0.2882 (5)0.4686 (3)0.045 (2)
H270.3831−0.29070.41810.054*
C280.3134 (5)−0.2961 (5)0.5227 (3)0.0406 (17)
H280.2507−0.30420.50950.049*
C290.3258 (5)−0.2922 (4)0.5963 (3)0.0286 (13)
H290.2707−0.29600.63300.034*
C300.5692 (4)−0.3352 (4)0.7361 (3)0.0180 (11)
C310.6268 (4)−0.2935 (4)0.7664 (3)0.0205 (11)
H310.5951−0.23470.77450.025*
C320.7299 (4)−0.3368 (5)0.7848 (3)0.0300 (14)
H320.7692−0.30730.80480.036*
C330.7756 (4)−0.4231 (5)0.7742 (3)0.0338 (15)
H330.8464−0.45300.78700.041*
C340.7198 (4)−0.4656 (5)0.7454 (3)0.0327 (15)
H340.7518−0.52500.73830.039*
C350.6161 (4)−0.4223 (4)0.7264 (3)0.0234 (12)
H350.5773−0.45230.70670.028*
C360.3707 (4)−0.3694 (4)0.7792 (3)0.0158 (10)
H36A0.3654−0.41190.75060.019*
H36B0.4160−0.40860.82530.019*
C370.2626 (4)−0.3305 (4)0.8087 (3)0.0178 (11)
H37A0.2381−0.38360.84710.021*
H37B0.2135−0.29940.76410.021*
C380.1386 (4)−0.2200 (4)0.8980 (3)0.0187 (11)
C390.0693 (4)−0.1315 (4)0.8647 (3)0.0233 (12)
H390.0888−0.08560.81970.028*
C40−0.0283 (4)−0.1102 (5)0.8972 (3)0.0309 (14)
H40−0.0753−0.04970.87470.037*
C41−0.0561 (4)−0.1777 (5)0.9623 (3)0.0295 (14)
H41−0.1228−0.16340.98430.035*
C420.0110 (4)−0.2650 (5)0.9956 (3)0.0314 (14)
H42−0.0093−0.31091.04030.038*
C430.1082 (4)−0.2862 (4)0.9639 (3)0.0246 (13)
H430.1548−0.34670.98740.030*
C440.3491 (4)−0.3121 (4)0.9418 (3)0.0193 (11)
C450.3547 (4)−0.4080 (4)0.9852 (3)0.0197 (11)
H450.3225−0.44320.96580.024*
C460.4067 (4)−0.4511 (4)1.0557 (3)0.0254 (13)
H460.4099−0.51591.08500.031*
C470.4545 (4)−0.4003 (4)1.0844 (3)0.0273 (13)
H470.4880−0.42961.13410.033*
C480.4532 (5)−0.3073 (4)1.0405 (3)0.0301 (14)
H480.4882−0.27331.05900.036*
C490.4007 (4)−0.2631 (4)0.9691 (3)0.0209 (12)
H490.4003−0.19920.93900.025*
C500.3564 (4)0.0103 (4)0.8679 (3)0.0183 (11)
C510.2711 (4)−0.0222 (4)0.9024 (3)0.0238 (12)
H510.2355−0.04770.87570.029*
C520.2381 (5)−0.0172 (4)0.9757 (3)0.0312 (14)
H520.1807−0.04070.99970.037*
C530.2886 (5)0.0219 (5)1.0147 (3)0.0371 (17)
H530.26600.02521.06510.044*
C540.3704 (5)0.0554 (5)0.9797 (3)0.0355 (16)
H540.40470.08221.00610.043*
C550.4055 (4)0.0513 (4)0.9055 (3)0.0278 (13)
H550.46200.07630.88130.033*
C560.5389 (4)−0.0037 (4)0.7712 (3)0.0170 (11)
C570.5746 (4)0.0730 (4)0.7224 (3)0.0242 (12)
H570.52680.12910.69190.029*
C580.6785 (4)0.0689 (4)0.7176 (3)0.0268 (13)
H580.70160.12230.68470.032*
C590.7492 (4)−0.0138 (4)0.7611 (3)0.0227 (12)
H590.8211−0.01790.75610.027*
C600.7153 (4)−0.0889 (4)0.8112 (3)0.0228 (12)
H600.7639−0.14390.84230.027*
C610.6111 (4)−0.0863 (4)0.8173 (3)0.0213 (12)
H610.5885−0.13920.85190.026*
C620.3403 (4)0.1056 (4)0.7001 (3)0.0213 (12)
H62A0.34060.15910.71780.026*
H62B0.37950.11320.65030.026*
C630.2292 (4)0.1095 (4)0.6854 (3)0.0210 (11)
H63A0.19730.17160.64560.025*
H63B0.18930.10460.73460.025*
C640.0860 (4)0.0357 (4)0.6307 (3)0.0192 (11)
C650.0534 (4)−0.0335 (4)0.6162 (3)0.0298 (14)
H650.1001−0.09410.62280.036*
C66−0.0472 (5)−0.0158 (5)0.5919 (3)0.0333 (14)
H66−0.0682−0.06360.58070.040*
C67−0.1161 (4)0.0700 (5)0.5841 (3)0.0304 (14)
H67−0.18450.08270.56650.037*
C68−0.0852 (5)0.1373 (5)0.6019 (4)0.0394 (16)
H68−0.13350.19630.59830.047*
C690.0162 (5)0.1213 (5)0.6254 (4)0.0375 (16)
H690.03650.16890.63740.045*
C700.2744 (4)0.0472 (4)0.5509 (3)0.0189 (11)
C710.3469 (5)−0.0209 (4)0.5279 (3)0.0289 (14)
H710.3717−0.08310.56470.035*
C720.3835 (5)0.0010 (5)0.4515 (3)0.0395 (17)
H720.4336−0.04610.43600.047*
C730.3481 (5)0.0902 (5)0.3983 (3)0.0346 (15)
H730.37290.10480.34580.042*
C740.2759 (5)0.1593 (5)0.4209 (3)0.0384 (16)
H740.25200.22170.38420.046*
C750.2390 (5)0.1371 (4)0.4968 (3)0.0324 (15)
H750.18870.18420.51210.039*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Sn10.0262 (2)0.0174 (2)0.01686 (18)−0.00631 (16)−0.00245 (14)−0.00419 (15)
Ag10.0203 (2)0.0146 (2)0.01421 (18)−0.00492 (16)0.00009 (14)−0.00477 (15)
Cl10.0331 (10)0.0287 (11)0.0412 (11)−0.0200 (9)−0.0059 (8)−0.0043 (8)
Cl20.0482 (13)0.0701 (18)0.0350 (11)−0.0151 (12)0.0073 (9)−0.0204 (11)
Cl30.100 (3)0.0479 (19)0.0606 (18)−0.0052 (17)−0.0476 (17)−0.0114 (14)
F10.028 (2)0.028 (3)0.0202 (16)−0.005 (2)−0.0082 (15)−0.0055 (16)
F20.066 (4)0.043 (3)0.043 (2)−0.018 (3)−0.014 (3)0.001 (2)
F30.086 (4)0.035 (3)0.025 (3)−0.022 (3)−0.011 (3)0.004 (2)
F40.059 (4)0.111 (6)0.024 (3)0.016 (4)0.010 (3)−0.009 (3)
Cl2'0.066 (4)0.043 (3)0.043 (2)−0.018 (3)−0.014 (3)0.001 (2)
Cl3'0.066 (5)0.073 (5)0.037 (3)−0.033 (4)0.015 (3)−0.010 (3)
F1'0.028 (2)0.028 (3)0.0202 (16)−0.005 (2)−0.0082 (15)−0.0055 (16)
F2'0.0482 (13)0.0701 (18)0.0350 (11)−0.0151 (12)0.0073 (9)−0.0204 (11)
F3'0.077 (9)0.089 (10)0.045 (7)−0.018 (8)−0.024 (7)−0.004 (7)
F4'0.096 (10)0.076 (9)0.058 (8)−0.036 (8)−0.007 (7)−0.030 (7)
P10.0172 (7)0.0170 (7)0.0140 (6)−0.0032 (6)−0.0009 (5)−0.0056 (5)
P20.0164 (6)0.0152 (7)0.0145 (6)−0.0049 (5)0.0002 (5)−0.0033 (5)
P30.0220 (7)0.0161 (7)0.0131 (6)−0.0056 (6)−0.0007 (5)−0.0046 (5)
P40.0192 (7)0.0164 (7)0.0156 (6)−0.0049 (6)−0.0015 (5)−0.0049 (5)
O10.033 (2)0.028 (2)0.0170 (18)−0.0128 (19)−0.0060 (15)−0.0059 (16)
O20.028 (2)0.019 (2)0.0230 (19)−0.0091 (17)−0.0015 (16)−0.0025 (16)
O30.032 (2)0.024 (2)0.0184 (18)−0.0064 (18)−0.0020 (16)−0.0073 (17)
O40.053 (3)0.017 (2)0.029 (2)−0.004 (2)−0.0024 (19)−0.0054 (18)
C10.026 (3)0.021 (3)0.019 (3)−0.009 (2)0.002 (2)−0.009 (2)
C20.027 (3)0.025 (3)0.017 (3)−0.007 (3)0.000 (2)−0.008 (2)
C30.040 (4)0.025 (3)0.022 (3)−0.017 (3)−0.002 (2)−0.002 (2)
C40.032 (3)0.031 (4)0.030 (3)−0.017 (3)0.000 (2)−0.010 (3)
C50.035 (3)0.035 (4)0.035 (3)−0.012 (3)−0.009 (3)−0.007 (3)
C60.030 (3)0.029 (4)0.027 (3)−0.008 (3)−0.004 (2)−0.004 (3)
C70.029 (3)0.026 (3)0.028 (3)−0.005 (3)−0.005 (2)−0.017 (3)
C80.034 (3)0.026 (3)0.028 (3)−0.002 (3)−0.007 (2)−0.011 (3)
C90.033 (4)0.041 (4)0.046 (4)0.009 (3)−0.014 (3)−0.032 (3)
C100.030 (3)0.060 (5)0.047 (4)−0.014 (3)0.008 (3)−0.041 (4)
Cl1'0.168 (13)0.177 (13)0.183 (12)−0.050 (9)−0.007 (9)−0.074 (9)
C110.036 (4)0.048 (4)0.039 (4)−0.021 (3)0.008 (3)−0.032 (3)
C120.034 (3)0.029 (4)0.034 (3)−0.008 (3)0.002 (3)−0.019 (3)
C130.020 (3)0.023 (3)0.020 (3)−0.009 (2)−0.001 (2)−0.007 (2)
C140.037 (3)0.023 (3)0.025 (3)−0.006 (3)0.002 (2)−0.008 (2)
C150.039 (4)0.019 (3)0.036 (3)−0.006 (3)−0.004 (3)−0.003 (3)
C160.024 (3)0.023 (3)0.044 (4)0.001 (3)−0.004 (3)−0.012 (3)
C170.019 (3)0.031 (4)0.038 (3)−0.005 (3)0.002 (2)−0.019 (3)
C180.018 (3)0.030 (3)0.027 (3)−0.007 (3)−0.002 (2)−0.010 (3)
C190.021 (3)0.022 (3)0.018 (3)−0.002 (2)−0.004 (2)−0.006 (2)
C200.043 (4)0.034 (4)0.024 (3)−0.021 (3)−0.009 (3)−0.004 (3)
C210.035 (3)0.028 (3)0.017 (3)−0.016 (3)0.000 (2)−0.006 (2)
C220.044 (4)0.038 (4)0.021 (3)−0.002 (3)−0.001 (3)−0.007 (3)
C230.026 (3)0.012 (3)0.015 (2)0.005 (2)−0.004 (2)−0.003 (2)
C240.030 (3)0.025 (3)0.024 (3)−0.001 (3)0.005 (2)−0.008 (2)
C250.060 (5)0.026 (4)0.015 (3)0.007 (3)0.004 (3)−0.004 (3)
C270.083 (6)0.026 (4)0.019 (3)0.010 (4)−0.020 (3)−0.011 (3)
C280.054 (4)0.040 (4)0.026 (3)−0.006 (3)−0.018 (3)−0.009 (3)
C290.032 (3)0.026 (3)0.027 (3)−0.005 (3)−0.008 (2)−0.008 (3)
C300.017 (3)0.022 (3)0.014 (2)−0.006 (2)0.0019 (19)−0.004 (2)
C310.018 (3)0.022 (3)0.022 (3)−0.007 (2)−0.002 (2)−0.007 (2)
C320.023 (3)0.045 (4)0.023 (3)−0.017 (3)−0.003 (2)−0.006 (3)
C330.016 (3)0.045 (4)0.032 (3)−0.002 (3)0.002 (2)−0.008 (3)
C340.027 (3)0.037 (4)0.030 (3)0.002 (3)0.002 (2)−0.016 (3)
C350.021 (3)0.026 (3)0.026 (3)−0.001 (2)−0.004 (2)−0.015 (2)
C360.018 (3)0.011 (3)0.019 (2)−0.005 (2)−0.0043 (19)−0.003 (2)
C370.019 (3)0.017 (3)0.017 (2)−0.004 (2)−0.003 (2)−0.006 (2)
C380.017 (3)0.020 (3)0.020 (3)−0.003 (2)−0.003 (2)−0.009 (2)
C390.018 (3)0.027 (3)0.021 (3)−0.002 (2)−0.002 (2)−0.005 (2)
C400.022 (3)0.034 (4)0.037 (3)−0.001 (3)−0.004 (2)−0.017 (3)
C410.019 (3)0.040 (4)0.032 (3)−0.003 (3)0.004 (2)−0.020 (3)
C420.028 (3)0.042 (4)0.024 (3)−0.008 (3)0.008 (2)−0.014 (3)
C430.024 (3)0.022 (3)0.022 (3)0.000 (2)0.004 (2)−0.006 (2)
C440.020 (3)0.018 (3)0.015 (2)−0.003 (2)0.002 (2)−0.002 (2)
C450.021 (3)0.018 (3)0.020 (3)−0.004 (2)0.003 (2)−0.008 (2)
C460.033 (3)0.020 (3)0.020 (3)−0.003 (3)−0.003 (2)−0.004 (2)
C470.028 (3)0.029 (3)0.023 (3)0.001 (3)−0.004 (2)−0.012 (3)
C480.034 (3)0.030 (4)0.027 (3)−0.008 (3)−0.007 (2)−0.010 (3)
C490.018 (3)0.028 (3)0.020 (3)−0.009 (2)−0.002 (2)−0.009 (2)
C500.021 (3)0.013 (3)0.019 (2)0.002 (2)−0.004 (2)−0.007 (2)
C510.028 (3)0.024 (3)0.021 (3)−0.004 (3)0.000 (2)−0.011 (2)
C520.033 (3)0.031 (4)0.025 (3)−0.003 (3)0.007 (2)−0.010 (3)
C530.035 (4)0.047 (4)0.021 (3)0.012 (3)−0.006 (3)−0.018 (3)
C540.033 (3)0.048 (4)0.032 (3)0.005 (3)−0.010 (3)−0.032 (3)
C550.028 (3)0.032 (4)0.027 (3)−0.004 (3)−0.005 (2)−0.016 (3)
C560.024 (3)0.017 (3)0.015 (2)−0.008 (2)−0.001 (2)−0.011 (2)
C570.032 (3)0.019 (3)0.020 (3)−0.005 (3)0.001 (2)−0.006 (2)
C580.031 (3)0.025 (3)0.027 (3)−0.014 (3)0.000 (2)−0.006 (3)
C590.024 (3)0.029 (3)0.024 (3)−0.013 (3)0.001 (2)−0.014 (2)
C600.031 (3)0.019 (3)0.017 (3)−0.004 (2)−0.005 (2)−0.004 (2)
C610.027 (3)0.024 (3)0.017 (2)−0.012 (2)−0.001 (2)−0.006 (2)
C620.029 (3)0.016 (3)0.018 (3)−0.004 (2)−0.007 (2)−0.004 (2)
C630.025 (3)0.015 (3)0.023 (3)−0.004 (2)−0.003 (2)−0.008 (2)
C640.019 (3)0.021 (3)0.016 (2)−0.003 (2)0.000 (2)−0.006 (2)
C650.026 (3)0.019 (3)0.039 (3)0.000 (3)−0.010 (3)−0.005 (3)
C660.032 (3)0.035 (4)0.037 (3)−0.012 (3)−0.009 (3)−0.013 (3)
C670.020 (3)0.038 (4)0.033 (3)−0.008 (3)−0.001 (2)−0.011 (3)
C680.022 (3)0.037 (4)0.059 (4)0.005 (3)−0.008 (3)−0.024 (3)
C690.031 (3)0.034 (4)0.055 (4)−0.004 (3)−0.008 (3)−0.025 (3)
C700.021 (3)0.023 (3)0.013 (2)−0.008 (2)0.0004 (19)−0.003 (2)
C710.045 (4)0.016 (3)0.019 (3)−0.005 (3)0.003 (2)−0.001 (2)
C720.057 (4)0.026 (4)0.030 (3)−0.004 (3)0.012 (3)−0.011 (3)
C730.054 (4)0.037 (4)0.015 (3)−0.020 (3)0.009 (3)−0.007 (3)
C740.051 (4)0.032 (4)0.022 (3)−0.008 (3)0.004 (3)−0.001 (3)
C750.033 (3)0.027 (4)0.022 (3)0.004 (3)0.006 (2)0.000 (3)

Geometric parameters (Å, °)

Sn1—C12.131 (6)C30—C351.389 (7)
Sn1—C72.133 (6)C31—C321.382 (7)
Sn1—C132.138 (5)C31—H310.9500
Sn1—O12.239 (3)C32—C331.382 (9)
Sn1—O32.221 (3)C32—H320.9500
Ag1—P12.515 (1)C33—C341.363 (9)
Ag1—P22.494 (1)C33—H330.9500
Ag1—P32.495 (2)C34—C351.391 (7)
Ag1—P42.518 (1)C34—H340.9500
Cl1—C41.740 (5)C35—H350.9500
Cl2—C201.785 (5)C36—C371.539 (7)
Cl3—C221.728 (6)C36—H36A0.9900
F1—C201.345 (6)C36—H36B0.9900
F2—C201.322 (6)C37—H37A0.9900
F3—C221.343 (6)C37—H37B0.9900
F4—C221.363 (6)C38—C431.392 (7)
Cl2'—C201.728 (7)C38—C391.394 (7)
Cl3'—C221.704 (7)C39—C401.392 (7)
F1'—C201.343 (8)C39—H390.9500
F2'—C201.349 (8)C40—C411.381 (8)
F3'—C221.393 (8)C40—H400.9500
F4'—C221.345 (8)C41—C421.369 (8)
P1—C231.819 (5)C41—H410.9500
P1—C301.825 (5)C42—C431.381 (7)
P1—C361.851 (5)C42—H420.9500
P2—C441.823 (5)C43—H430.9500
P2—C371.828 (5)C44—C491.387 (7)
P2—C381.829 (5)C44—C451.403 (7)
P3—C561.824 (5)C45—C461.375 (7)
P3—C501.839 (5)C45—H450.9500
P3—C621.841 (5)C46—C471.389 (8)
P4—C701.829 (5)C46—H460.9500
P4—C641.832 (5)C47—C481.380 (8)
P4—C631.838 (5)C47—H470.9500
O1—C191.286 (6)C48—C491.390 (7)
O2—C191.221 (6)C48—H480.9500
O3—C211.267 (7)C49—H490.9500
O4—C211.224 (7)C50—C551.387 (8)
C1—C61.394 (7)C50—C511.390 (7)
C1—C21.395 (7)C51—C521.384 (7)
C2—C31.393 (8)C51—H510.9500
C2—H20.9500C52—C531.395 (9)
C3—C41.386 (8)C52—H520.9500
C3—H30.9500C53—C541.357 (9)
C4—C51.382 (8)C53—H530.9500
C4—H40.9500C54—C551.401 (7)
C5—C61.379 (8)C54—H540.9500
C5—H50.9500C55—H550.9500
C6—H60.9500C56—C571.390 (7)
C7—C81.392 (8)C56—C611.416 (7)
C7—C121.400 (8)C57—C581.379 (8)
C8—C91.373 (8)C57—H570.9500
C8—H80.9500C58—C591.393 (8)
C9—C101.388 (10)C58—H580.9500
C9—H90.9500C59—C601.368 (8)
C10—C111.359 (9)C59—H590.9500
C10—Cl1'1.718 (10)C60—C611.390 (7)
C10—H100.9500C60—H600.9500
C11—C121.389 (8)C61—H610.9500
C11—H110.9500C62—C631.526 (7)
C12—H120.9500C62—H62A0.9900
C13—C141.384 (7)C62—H62B0.9900
C13—C181.397 (7)C63—H63A0.9900
C14—C151.390 (8)C63—H63B0.9900
C14—H140.9500C64—C651.376 (8)
C15—C161.386 (8)C64—C691.376 (8)
C15—H150.9500C65—C661.389 (8)
C16—C171.380 (8)C65—H650.9500
C16—H160.9500C66—C671.365 (8)
C17—C181.397 (8)C66—H660.9500
C17—H170.9500C67—C681.366 (9)
C18—H180.9500C67—H670.9500
C19—C201.523 (6)C68—C691.398 (8)
C21—C221.534 (6)C68—H680.9500
C23—C241.397 (7)C69—H690.9500
C23—C291.397 (8)C70—C751.379 (8)
C24—C251.394 (8)C70—C711.380 (7)
C24—H240.9500C71—C721.387 (7)
C25—C271.379 (10)C71—H710.9500
C25—H250.9500C72—C731.366 (8)
C27—C281.373 (9)C72—H720.9500
C27—H270.9500C73—C741.385 (9)
C28—C291.386 (8)C73—H730.9500
C28—H280.9500C74—C751.380 (7)
C29—H290.9500C74—H740.9500
C30—C311.386 (7)C75—H750.9500
C1—Sn1—C7127.5 (2)C31—C30—P1119.6 (4)
C1—Sn1—C13112.4 (2)C35—C30—P1121.4 (4)
C1—Sn1—O391.1 (2)C32—C31—C30120.6 (5)
C1—Sn1—O185.5 (2)C32—C31—H31119.7
C7—Sn1—O191.8 (2)C30—C31—H31119.7
C7—Sn1—C13120.1 (2)C33—C32—C31119.7 (6)
C7—Sn1—O389.9 (2)C33—C32—H32120.1
C13—Sn1—O387.2 (2)C31—C32—H32120.1
C13—Sn1—O194.5 (2)C34—C33—C32120.5 (6)
O1—Sn1—O3176.6 (1)C34—C33—H33119.8
P1—Ag1—P282.98 (4)C32—C33—H33119.8
P1—Ag1—P3132.80 (5)C33—C34—C35120.1 (6)
P1—Ag1—P4122.85 (4)C33—C34—H34119.9
P2—Ag1—P3119.12 (4)C35—C34—H34119.9
P2—Ag1—P4119.90 (4)C30—C35—C34120.1 (6)
P3—Ag1—P483.87 (5)C30—C35—H35119.9
C23—P1—C30103.0 (2)C34—C35—H35119.9
C23—P1—C36103.0 (2)C37—C36—P1115.0 (4)
C30—P1—C36101.9 (2)C37—C36—H36A108.5
C23—P1—Ag1120.14 (17)P1—C36—H36A108.5
C30—P1—Ag1121.86 (18)C37—C36—H36B108.5
C36—P1—Ag1103.86 (16)P1—C36—H36B108.5
C44—P2—C37105.6 (2)H36A—C36—H36B107.5
C44—P2—C38102.5 (2)C36—C37—P2109.8 (3)
C37—P2—C38103.0 (2)C36—C37—H37A109.7
C44—P2—Ag1115.96 (17)P2—C37—H37A109.7
C37—P2—Ag1100.48 (16)C36—C37—H37B109.7
C38—P2—Ag1126.80 (18)P2—C37—H37B109.7
C56—P3—C50104.1 (2)H37A—C37—H37B108.2
C56—P3—C62103.9 (2)C43—C38—C39118.7 (5)
C50—P3—C62103.3 (2)C43—C38—P2122.2 (4)
C56—P3—Ag1125.32 (17)C39—C38—P2119.0 (4)
C50—P3—Ag1113.64 (18)C40—C39—C38120.3 (5)
C62—P3—Ag1104.17 (18)C40—C39—H39119.8
C70—P4—C64100.8 (2)C38—C39—H39119.8
C70—P4—C63103.5 (3)C41—C40—C39119.4 (6)
C64—P4—C63104.2 (2)C41—C40—H40120.3
C70—P4—Ag1113.72 (17)C39—C40—H40120.3
C64—P4—Ag1129.67 (18)C42—C41—C40121.0 (5)
C63—P4—Ag1102.04 (17)C42—C41—H41119.5
C19—O1—Sn1118.7 (3)C40—C41—H41119.5
C21—O3—Sn1121.1 (3)C41—C42—C43119.7 (6)
C6—C1—C2117.9 (5)C41—C42—H42120.1
C6—C1—Sn1117.7 (4)C43—C42—H42120.1
C2—C1—Sn1123.9 (4)C42—C43—C38120.8 (5)
C3—C2—C1121.1 (5)C42—C43—H43119.6
C3—C2—H2119.4C38—C43—H43119.6
C1—C2—H2119.4C49—C44—C45119.1 (5)
C4—C3—C2119.0 (5)C49—C44—P2117.4 (4)
C4—C3—H3120.5C45—C44—P2123.3 (4)
C2—C3—H3120.5C46—C45—C44120.2 (5)
C5—C4—C3121.0 (5)C46—C45—H45119.9
C5—C4—Cl1118.4 (5)C44—C45—H45119.9
C3—C4—Cl1120.6 (4)C45—C46—C47120.4 (5)
C5—C4—H4119.5C45—C46—H46119.8
C3—C4—H4119.5C47—C46—H46119.8
C6—C5—C4119.2 (6)C48—C47—C46119.8 (5)
C6—C5—H5120.4C48—C47—H47120.1
C4—C5—H5120.4C46—C47—H47120.1
C5—C6—C1121.7 (6)C47—C48—C49120.2 (6)
C5—C6—H6119.1C47—C48—H48119.9
C1—C6—H6119.1C49—C48—H48119.9
C8—C7—C12118.3 (5)C44—C49—C48120.3 (5)
C8—C7—Sn1122.9 (4)C44—C49—H49119.9
C12—C7—Sn1118.6 (4)C48—C49—H49119.9
C9—C8—C7121.1 (6)C55—C50—C51119.9 (5)
C9—C8—H8119.4C55—C50—P3121.7 (4)
C7—C8—H8119.4C51—C50—P3118.3 (4)
C8—C9—C10119.1 (6)C52—C51—C50119.8 (5)
C8—C9—H9120.4C52—C51—H51120.1
C10—C9—H9120.4C50—C51—H51120.1
C11—C10—C9121.4 (6)C51—C52—C53120.5 (6)
C11—C10—Cl1'119.6 (11)C51—C52—H52119.7
C9—C10—Cl1'118.9 (11)C53—C52—H52119.7
C11—C10—H10119.3C54—C53—C52119.1 (5)
C9—C10—H10119.3C54—C53—H53120.4
C10—C11—C12119.5 (6)C52—C53—H53120.4
C10—C11—H11120.3C53—C54—C55121.6 (6)
C12—C11—H11120.3C53—C54—H54119.2
C11—C12—C7120.5 (6)C55—C54—H54119.2
C11—C12—H12119.8C50—C55—C54118.9 (6)
C7—C12—H12119.8C50—C55—H55120.6
C14—C13—C18117.6 (5)C54—C55—H55120.6
C14—C13—Sn1121.4 (4)C57—C56—C61118.8 (5)
C18—C13—Sn1121.0 (4)C57—C56—P3123.6 (4)
C13—C14—C15121.4 (5)C61—C56—P3117.5 (4)
C13—C14—H14119.3C58—C57—C56121.1 (5)
C15—C14—H14119.3C58—C57—H57119.5
C16—C15—C14120.8 (6)C56—C57—H57119.5
C16—C15—H15119.6C57—C58—C59119.7 (5)
C14—C15—H15119.6C57—C58—H58120.1
C17—C16—C15118.6 (6)C59—C58—H58120.1
C17—C16—H16120.7C60—C59—C58120.0 (5)
C15—C16—H16120.7C60—C59—H59120.0
C16—C17—C18120.7 (5)C58—C59—H59120.0
C16—C17—H17119.7C59—C60—C61121.2 (5)
C18—C17—H17119.7C59—C60—H60119.4
C17—C18—C13121.0 (5)C61—C60—H60119.4
C17—C18—H18119.5C60—C61—C56119.1 (5)
C13—C18—H18119.5C60—C61—H61120.4
O2—C19—O1129.4 (5)C56—C61—H61120.4
O2—C19—C20116.6 (5)C63—C62—P3111.8 (4)
O1—C19—C20113.8 (5)C63—C62—H62A109.2
F2—C20—F1108.5 (4)P3—C62—H62A109.2
F1'—C20—F2'110.9 (7)C63—C62—H62B109.2
F2—C20—C19111.7 (4)P3—C62—H62B109.2
F1'—C20—C19113.9 (6)H62A—C62—H62B107.9
F1—C20—C19112.8 (4)C62—C63—P4111.5 (4)
F2'—C20—C19114.3 (6)C62—C63—H63A109.3
F1'—C20—Cl2'108.2 (6)P4—C63—H63A109.3
F2'—C20—Cl2'104.7 (6)C62—C63—H63B109.3
C19—C20—Cl2'103.9 (4)P4—C63—H63B109.3
F2—C20—Cl2108.3 (4)H63A—C63—H63B108.0
F1—C20—Cl2107.1 (4)C65—C64—C69119.2 (5)
C19—C20—Cl2108.4 (3)C65—C64—P4118.3 (4)
O4—C21—O3129.7 (5)C69—C64—P4122.4 (5)
O4—C21—C22116.7 (5)C64—C65—C66120.7 (6)
O3—C21—C22113.6 (5)C64—C65—H65119.7
F3—C22—F4106.3 (5)C66—C65—H65119.7
F4'—C22—F3'106.6 (7)C67—C66—C65120.4 (6)
F3—C22—C21113.8 (5)C67—C66—H66119.8
F4'—C22—C21112.7 (6)C65—C66—H66119.8
F4—C22—C21110.9 (5)C66—C67—C68119.0 (6)
F3'—C22—C21112.7 (5)C66—C67—H67120.5
F4'—C22—Cl3'109.7 (6)C68—C67—H67120.5
F3'—C22—Cl3'106.3 (6)C67—C68—C69121.4 (6)
C21—C22—Cl3'108.5 (4)C67—C68—H68119.3
F3—C22—Cl3108.7 (4)C69—C68—H68119.3
F4—C22—Cl3107.1 (4)C64—C69—C68119.2 (6)
C21—C22—Cl3109.7 (4)C64—C69—H69120.4
C24—C23—C29118.9 (5)C68—C69—H69120.4
C24—C23—P1121.2 (4)C75—C70—C71119.1 (5)
C29—C23—P1119.8 (4)C75—C70—P4122.3 (4)
C25—C24—C23119.6 (6)C71—C70—P4118.5 (4)
C25—C24—H24120.2C70—C71—C72120.2 (5)
C23—C24—H24120.2C70—C71—H71119.9
C27—C25—C24120.6 (6)C72—C71—H71119.9
C27—C25—H25119.7C73—C72—C71120.3 (6)
C24—C25—H25119.7C73—C72—H72119.9
C28—C27—C25120.3 (6)C71—C72—H72119.9
C28—C27—H27119.9C72—C73—C74120.0 (5)
C25—C27—H27119.9C72—C73—H73120.0
C27—C28—C29119.9 (6)C74—C73—H73120.0
C27—C28—H28120.0C75—C74—C73119.6 (6)
C29—C28—H28120.0C75—C74—H74120.2
C28—C29—C23120.7 (6)C73—C74—H74120.2
C28—C29—H29119.6C70—C75—C74120.7 (5)
C23—C29—H29119.6C70—C75—H75119.6
C31—C30—C35119.0 (5)C74—C75—H75119.6
P2—Ag1—P1—C23123.5 (2)Ag1—P1—C23—C24103.9 (4)
P3—Ag1—P1—C23−112.8 (2)C30—P1—C23—C29147.4 (5)
P4—Ag1—P1—C232.3 (2)C36—P1—C23—C2941.6 (5)
P2—Ag1—P1—C30−104.56 (19)Ag1—P1—C23—C29−73.1 (5)
P3—Ag1—P1—C3019.1 (2)C29—C23—C24—C25−2.3 (8)
P4—Ag1—P1—C30134.22 (19)P1—C23—C24—C25−179.3 (4)
P2—Ag1—P1—C369.28 (17)C23—C24—C25—C270.8 (9)
P3—Ag1—P1—C36132.94 (17)C24—C25—C27—C280.3 (10)
P4—Ag1—P1—C36−111.93 (17)C25—C27—C28—C290.2 (10)
P3—Ag1—P2—C44−54.5 (2)C27—C28—C29—C23−1.7 (9)
P1—Ag1—P2—C4481.1 (2)C24—C23—C29—C282.7 (9)
P4—Ag1—P2—C44−154.87 (19)P1—C23—C29—C28179.7 (5)
P3—Ag1—P2—C37−167.73 (16)C23—P1—C30—C31134.0 (4)
P1—Ag1—P2—C37−32.09 (17)C36—P1—C30—C31−119.4 (4)
P4—Ag1—P2—C3791.94 (17)Ag1—P1—C30—C31−4.6 (5)
P3—Ag1—P2—C3877.2 (2)C23—P1—C30—C35−48.7 (5)
P1—Ag1—P2—C38−147.1 (2)C36—P1—C30—C3557.8 (5)
P4—Ag1—P2—C38−23.1 (2)Ag1—P1—C30—C35172.6 (3)
P2—Ag1—P3—C56112.5 (2)C35—C30—C31—C321.5 (7)
P1—Ag1—P3—C563.5 (2)P1—C30—C31—C32178.8 (4)
P4—Ag1—P3—C56−126.6 (2)C30—C31—C32—C33−1.0 (8)
P2—Ag1—P3—C50−17.01 (19)C31—C32—C33—C340.2 (9)
P1—Ag1—P3—C50−125.98 (18)C32—C33—C34—C350.1 (9)
P4—Ag1—P3—C50103.92 (18)C31—C30—C35—C34−1.3 (8)
P2—Ag1—P3—C62−128.67 (18)P1—C30—C35—C34−178.5 (4)
P1—Ag1—P3—C62122.37 (18)C33—C34—C35—C300.5 (8)
P4—Ag1—P3—C62−7.73 (18)C23—P1—C36—C37−104.1 (4)
P2—Ag1—P4—C70−146.3 (2)C30—P1—C36—C37149.3 (4)
P3—Ag1—P4—C7093.6 (2)Ag1—P1—C36—C3721.9 (4)
P1—Ag1—P4—C70−44.5 (2)P1—C36—C37—P2−53.8 (4)
P2—Ag1—P4—C64−17.2 (2)C44—P2—C37—C36−65.0 (4)
P3—Ag1—P4—C64−137.3 (2)C38—P2—C37—C36−172.2 (3)
P1—Ag1—P4—C6484.6 (2)Ag1—P2—C37—C3655.9 (3)
P2—Ag1—P4—C63102.96 (18)C44—P2—C38—C43−37.0 (5)
P3—Ag1—P4—C63−17.22 (18)C37—P2—C38—C4372.5 (5)
P1—Ag1—P4—C63−155.30 (17)Ag1—P2—C38—C43−173.6 (4)
C1—Sn1—O1—C19−177.6 (4)C44—P2—C38—C39141.4 (4)
C7—Sn1—O1—C1955.0 (4)C37—P2—C38—C39−109.1 (5)
C13—Sn1—O1—C19−65.3 (4)Ag1—P2—C38—C394.8 (5)
C1—Sn1—O3—C21−70.4 (4)C43—C38—C39—C400.1 (8)
C7—Sn1—O3—C2157.1 (4)P2—C38—C39—C40−178.4 (4)
C13—Sn1—O3—C21177.2 (4)C38—C39—C40—C41−0.5 (9)
C7—Sn1—C1—C6−128.5 (4)C39—C40—C41—C420.4 (9)
C13—Sn1—C1—C649.7 (5)C40—C41—C42—C430.1 (9)
O3—Sn1—C1—C6−37.8 (4)C41—C42—C43—C38−0.5 (9)
O1—Sn1—C1—C6142.7 (4)C39—C38—C43—C420.4 (8)
C7—Sn1—C1—C259.6 (5)P2—C38—C43—C42178.9 (4)
C13—Sn1—C1—C2−122.3 (4)C37—P2—C44—C49153.7 (4)
O3—Sn1—C1—C2150.3 (4)C38—P2—C44—C49−98.8 (4)
O1—Sn1—C1—C2−29.3 (4)Ag1—P2—C44—C4943.5 (4)
C6—C1—C2—C3−0.1 (8)C37—P2—C44—C45−32.1 (5)
Sn1—C1—C2—C3171.8 (4)C38—P2—C44—C4575.4 (5)
C1—C2—C3—C4−1.6 (9)Ag1—P2—C44—C45−142.3 (4)
C2—C3—C4—C52.9 (9)C49—C44—C45—C463.1 (7)
C2—C3—C4—Cl1−176.8 (4)P2—C44—C45—C46−171.1 (4)
C3—C4—C5—C6−2.5 (10)C44—C45—C46—C47−0.3 (8)
Cl1—C4—C5—C6177.3 (5)C45—C46—C47—C48−2.5 (8)
C4—C5—C6—C10.7 (10)C46—C47—C48—C492.5 (8)
C2—C1—C6—C50.6 (9)C45—C44—C49—C48−3.0 (7)
Sn1—C1—C6—C5−171.9 (5)P2—C44—C49—C48171.5 (4)
C1—Sn1—C7—C8−52.3 (5)C47—C48—C49—C440.2 (8)
C13—Sn1—C7—C8129.6 (5)C56—P3—C50—C5520.3 (5)
O3—Sn1—C7—C8−143.7 (5)C62—P3—C50—C55−88.0 (5)
O1—Sn1—C7—C833.4 (5)Ag1—P3—C50—C55159.8 (4)
C1—Sn1—C7—C12132.2 (4)C56—P3—C50—C51−157.0 (4)
C13—Sn1—C7—C12−45.8 (5)C62—P3—C50—C5194.7 (4)
O3—Sn1—C7—C1240.9 (4)Ag1—P3—C50—C51−17.5 (5)
O1—Sn1—C7—C12−142.0 (4)C55—C50—C51—C52−2.8 (8)
C12—C7—C8—C9−0.9 (8)P3—C50—C51—C52174.6 (4)
Sn1—C7—C8—C9−176.4 (4)C50—C51—C52—C531.3 (9)
C7—C8—C9—C102.4 (9)C51—C52—C53—C540.2 (9)
C8—C9—C10—C11−3.1 (9)C52—C53—C54—C55−0.1 (10)
C8—C9—C10—Cl1'179.7 (10)C51—C50—C55—C542.8 (8)
C9—C10—C11—C122.3 (9)P3—C50—C55—C54−174.5 (4)
Cl1'—C10—C11—C12179.5 (11)C53—C54—C55—C50−1.3 (9)
C10—C11—C12—C7−0.8 (9)C50—P3—C56—C57−106.0 (5)
C8—C7—C12—C110.1 (8)C62—P3—C56—C571.8 (5)
Sn1—C7—C12—C11175.7 (4)Ag1—P3—C56—C57120.8 (4)
C1—Sn1—C13—C14−104.0 (5)C50—P3—C56—C6178.2 (4)
C7—Sn1—C13—C1474.3 (5)C62—P3—C56—C61−174.0 (4)
O3—Sn1—C13—C14−14.0 (5)Ag1—P3—C56—C61−55.0 (4)
O1—Sn1—C13—C14168.9 (5)C61—C56—C57—C581.0 (8)
C1—Sn1—C13—C1874.4 (5)P3—C56—C57—C58−174.7 (4)
C7—Sn1—C13—C18−107.3 (4)C56—C57—C58—C591.1 (8)
O3—Sn1—C13—C18164.4 (4)C57—C58—C59—C60−3.0 (8)
O1—Sn1—C13—C18−12.6 (4)C58—C59—C60—C612.7 (8)
C18—C13—C14—C150.6 (9)C59—C60—C61—C56−0.6 (8)
Sn1—C13—C14—C15179.1 (5)C57—C56—C61—C60−1.3 (7)
C13—C14—C15—C160.5 (10)P3—C56—C61—C60174.7 (4)
C14—C15—C16—C17−1.2 (9)C56—P3—C62—C63171.6 (4)
C15—C16—C17—C180.7 (9)C50—P3—C62—C63−80.0 (4)
C16—C17—C18—C130.5 (9)Ag1—P3—C62—C6339.0 (4)
C14—C13—C18—C17−1.1 (8)P3—C62—C63—P4−59.8 (4)
Sn1—C13—C18—C17−179.6 (4)C70—P4—C63—C62−71.2 (4)
Sn1—O1—C19—O2−1.4 (8)C64—P4—C63—C62−176.2 (4)
Sn1—O1—C19—C20173.5 (3)Ag1—P4—C63—C6247.1 (4)
O2—C19—C20—F2−151.0 (5)C70—P4—C64—C6583.6 (5)
O1—C19—C20—F233.5 (6)C63—P4—C64—C65−169.3 (4)
O2—C19—C20—F1'−4.8 (9)Ag1—P4—C64—C65−50.1 (5)
O1—C19—C20—F1'179.6 (8)C70—P4—C64—C69−92.7 (5)
O2—C19—C20—F1−28.5 (7)C63—P4—C64—C6914.4 (5)
O1—C19—C20—F1155.9 (5)Ag1—P4—C64—C69133.6 (4)
O2—C19—C20—F2'124.1 (9)C69—C64—C65—C663.7 (9)
O1—C19—C20—F2'−51.5 (9)P4—C64—C65—C66−172.7 (4)
O2—C19—C20—Cl2'−122.3 (6)C64—C65—C66—C67−1.7 (9)
O1—C19—C20—Cl2'62.1 (6)C65—C66—C67—C68−1.2 (9)
O2—C19—C20—Cl289.9 (5)C66—C67—C68—C692.1 (10)
O1—C19—C20—Cl2−85.7 (5)C65—C64—C69—C68−2.8 (9)
Sn1—O3—C21—O44.4 (9)P4—C64—C69—C68173.5 (5)
Sn1—O3—C21—C22−174.8 (3)C67—C68—C69—C64−0.1 (10)
O4—C21—C22—F3−163.4 (5)C64—P4—C70—C7557.7 (6)
O3—C21—C22—F315.8 (7)C63—P4—C70—C75−49.9 (5)
O4—C21—C22—F4'19.4 (9)Ag1—P4—C70—C75−159.8 (5)
O3—C21—C22—F4'−161.3 (8)C64—P4—C70—C71−118.8 (5)
O4—C21—C22—F4−43.6 (8)C63—P4—C70—C71133.6 (5)
O3—C21—C22—F4135.6 (6)Ag1—P4—C70—C7123.8 (5)
O4—C21—C22—F3'140.2 (8)C75—C70—C71—C720.1 (9)
O3—C21—C22—F3'−40.6 (9)P4—C70—C71—C72176.7 (5)
O4—C21—C22—Cl3'−102.3 (6)C70—C71—C72—C73−0.1 (10)
O3—C21—C22—Cl3'76.9 (6)C71—C72—C73—C740.6 (11)
O4—C21—C22—Cl374.5 (6)C72—C73—C74—C75−1.1 (11)
O3—C21—C22—Cl3−106.2 (5)C71—C70—C75—C74−0.5 (9)
C30—P1—C23—C24−35.7 (5)P4—C70—C75—C74−177.0 (5)
C36—P1—C23—C24−141.4 (4)C73—C74—C75—C701.1 (10)

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BQ2076).

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