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Acta Crystallogr Sect E Struct Rep Online. 2008 May 1; 64(Pt 5): m703.
Published online 2008 April 23. doi:  10.1107/S1600536808010763
PMCID: PMC2961205

Bis[1,3-bis­(diphenyl­phosphino)propane-κ2 P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)triphenyl­stannate(IV)

Abstract

In the title salt, [Ag(C27H26P2)2][Sn(C6H5)3(C2ClF2O2)], the AgI atom exists in a tetra­hedral coordination geometry formed by four P atoms [Ag—P = 2.460 (1)–2.501 (1) Å], whereas the SnIV atom exists in a trans-trigonal–bipyramidal coordination geometry formed by two O [Sn—O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn—C = 2.115 (4)–2.128 (4) Å;(Σ C—Sn—C)= 360.0 (6)°].

Related literature

For the crystal structures of other bis­(chloro­difluoro­acetato)triorganostannates, see: Ng & Hook (1999 [triangle]); Teo et al. (2004 [triangle], 2007 [triangle], 2008 [triangle]). The structural chemistry of organotin carboxyl­ates has been reviewed by Tiekink (1991 [triangle], 1994 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-64-0m703-scheme1.jpg

Experimental

Crystal data

  • [Ag(C27H26P2)2][Sn(C6H5)3(C2ClF2O2)]
  • M r = 1541.64
  • Triclinic, An external file that holds a picture, illustration, etc.
Object name is e-64-0m703-efi1.jpg
  • a = 10.5554 (2) Å
  • b = 17.6600 (4) Å
  • c = 19.1383 (4) Å
  • α = 91.581 (1)°
  • β = 94.931 (1)°
  • γ = 104.535 (1)°
  • V = 3436.1 (1) Å3
  • Z = 2
  • Mo Kα radiation
  • μ = 0.88 mm−1
  • T = 100 (2) K
  • 0.18 × 0.12 × 0.05 mm

Data collection

  • Bruker SMART APEXII diffractometer
  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996 [triangle]) T min = 0.858, T max = 0.957
  • 35712 measured reflections
  • 15398 independent reflections
  • 10993 reflections with I > 2σ(I)
  • R int = 0.065

Refinement

  • R[F 2 > 2σ(F 2)] = 0.049
  • wR(F 2) = 0.112
  • S = 1.05
  • 15398 reflections
  • 829 parameters
  • 48 restraints
  • H-atom parameters constrained
  • Δρmax = 0.86 e Å−3
  • Δρmin = −0.76 e Å−3

Data collection: APEX2 (Bruker, 2007 [triangle]); cell refinement: SAINT (Bruker, 2007 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: X-SEED (Barbour, 2001 [triangle]); software used to prepare material for publication: publCIF (Westrip, 2008 [triangle]).

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808010763/cv2399sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808010763/cv2399Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The authors thank the University of Malaya for funding this study (grant No. SF022155/2007 A) and also for the purchase of the diffractometer.

supplementary crystallographic information

Comment

The structural chemistry of di(carboxylato)triorganostannates has been reviewed by Tiekink (1991, 1994). This study continues our studies on bis(chlorodifluoroacetato)triorganostannates (Ng & Hook, 1999; Teo et al., 2004, 2007, 2008). One of these studies used the bis[1,3-bis(diphenylphosphine)ethane]silver cation as counterion. Herewith we present the crystal structure of the title compound, (I), where [Ag(Ph2(CH2)3Ph2)2] cation is the counterion for [SnPh3(ClF2CCO2)2] anion (Scheme I).

In (I) (Fig. 1), the silver(I) and tin(IV) atoms show tetrahedral and trans-trigonal bipyramidal coordinations, respectively.

Experimental

Triphenyltin hydroxide (0.18 g, 0.5 mmol) and chorodifluoroacetic acid (0.05 ml, 0.5 mmol) were dissolved in dichloromethane/methanol (25 ml). The mixture was heated until the hydroxide dissolved completely. Another solution containing 1,3-bis(diphenylphosphino)propane (0.41 g, 1.0 mmol) and silver trifluoroacetate (0.11 g, 0.5 mmol) was prepared; this was also heated until the reagents dissolved completely. The two solutions were mixed; crystals were obtained by allowing the solvent to evaporate in about 70% yield.

Refinement

Carbon-bound H-atoms were placed in calculated positions (C—H 0.95 to 0.99 Å) and were included in the refinement in the riding model approximation, with U(H) set to 1.2Ueq(C).

One of the phenyl rings shows large displacement ellipsoids. This ring, C44-C49, was restrained to be nearly planar; the bonded C-atoms were restrained to 1.39 (1) Å and 1,4-related ones to 2.78 (1) Å. The anisotropic displacement parameters of atoms C44-C49 were restrained to be nearly isotropic.

Figures

Fig. 1.
The 70% probability displacement ellipsoids plot (Barbour, 2001) of (I). Hydrogen atoms are drawn as spheres of arbitrary radii.

Crystal data

[Ag(C27H26P2)2][Sn(C6H5)3(C2ClF2O2)]Z = 2
Mr = 1541.64F000 = 1564
Triclinic, P1Dx = 1.490 Mg m3
Hall symbol: -P 1Mo Kα radiation λ = 0.71073 Å
a = 10.5554 (2) ÅCell parameters from 4777 reflections
b = 17.6600 (4) Åθ = 2.2–24º
c = 19.1383 (4) ŵ = 0.88 mm1
α = 91.581 (1)ºT = 100 (2) K
β = 94.931 (1)ºBlock, colourless
γ = 104.535 (1)º0.18 × 0.12 × 0.05 mm
V = 3436.1 (1) Å3

Data collection

Bruker SMART APEX diffractometer15398 independent reflections
Radiation source: fine-focus sealed tube10993 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.065
T = 100(2) Kθmax = 27.5º
ω scansθmin = 1.1º
Absorption correction: multi-scan(SADABS; Sheldrick, 1996)h = −13→13
Tmin = 0.858, Tmax = 0.957k = −22→18
35712 measured reflectionsl = −24→24

Refinement

Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.049H-atom parameters constrained
wR(F2) = 0.112  w = 1/[σ2(Fo2) + 1.3097P] where P = (Fo2 + 2Fc2)/3
S = 1.05(Δ/σ)max = 0.001
15398 reflectionsΔρmax = 0.86 e Å3
829 parametersΔρmin = −0.76 e Å3
48 restraintsExtinction correction: none
Primary atom site location: structure-invariant direct methods

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
Sn10.02753 (3)0.730942 (18)0.273935 (14)0.01420 (8)
Ag10.41787 (3)0.227571 (19)0.254989 (15)0.01370 (8)
Cl1−0.23532 (11)0.56238 (7)0.09181 (6)0.0289 (3)
Cl20.08334 (11)0.88104 (8)0.50499 (6)0.0294 (3)
P10.21513 (10)0.14129 (7)0.19532 (5)0.0140 (2)
P20.30050 (10)0.27516 (7)0.34838 (5)0.0164 (2)
P30.56274 (10)0.32427 (7)0.18763 (6)0.0154 (2)
P40.59289 (10)0.17736 (7)0.31680 (6)0.0153 (2)
F1−0.0366 (3)0.56467 (16)0.02666 (12)0.0289 (6)
F2−0.0553 (3)0.49132 (16)0.11555 (13)0.0301 (6)
F3−0.1207 (3)0.92144 (19)0.46015 (14)0.0399 (8)
F40.0540 (3)0.97475 (16)0.41018 (14)0.0335 (7)
O1−0.0013 (3)0.62288 (17)0.20477 (14)0.0173 (6)
O20.0963 (3)0.68053 (19)0.11296 (15)0.0253 (7)
O30.0474 (3)0.83204 (18)0.34826 (14)0.0202 (7)
O4−0.1681 (3)0.8079 (2)0.36239 (16)0.0278 (8)
C1−0.0392 (4)0.6519 (3)0.3528 (2)0.0168 (9)
C2−0.1432 (4)0.5862 (3)0.3396 (2)0.0245 (10)
H2−0.18910.57590.29400.029*
C3−0.1815 (4)0.5347 (3)0.3923 (2)0.0291 (11)
H3−0.25410.49020.38290.035*
C4−0.1132 (5)0.5486 (3)0.4585 (2)0.0265 (11)
H4−0.13820.51360.49470.032*
C5−0.0085 (5)0.6138 (3)0.4714 (2)0.0277 (11)
H50.03940.62320.51640.033*
C60.0270 (4)0.6650 (3)0.4197 (2)0.0237 (10)
H60.09820.71010.42970.028*
C70.2352 (4)0.7673 (3)0.2721 (2)0.0147 (9)
C80.3074 (4)0.7132 (3)0.2625 (2)0.0228 (10)
H80.26380.65920.25480.027*
C90.4436 (4)0.7373 (3)0.2641 (2)0.0243 (10)
H90.49270.69940.25990.029*
C100.5081 (4)0.8157 (3)0.2717 (2)0.0223 (10)
H100.60090.83190.27140.027*
C110.4365 (4)0.8706 (3)0.2799 (2)0.0211 (10)
H110.47950.92490.28430.025*
C120.3011 (4)0.8455 (3)0.2815 (2)0.0185 (9)
H120.25260.88310.28930.022*
C13−0.0893 (4)0.7739 (3)0.1972 (2)0.0152 (9)
C14−0.2241 (4)0.7448 (3)0.1842 (2)0.0241 (10)
H14−0.26830.70570.21300.029*
C15−0.2964 (4)0.7710 (3)0.1308 (2)0.0263 (11)
H15−0.38900.75040.12360.032*
C16−0.2335 (4)0.8270 (3)0.0883 (2)0.0286 (12)
H16−0.28240.84420.05070.034*
C17−0.0999 (5)0.8582 (3)0.1001 (2)0.0344 (13)
H17−0.05680.89770.07120.041*
C18−0.0276 (4)0.8320 (3)0.1543 (2)0.0277 (11)
H180.06460.85380.16220.033*
C190.0206 (4)0.6297 (3)0.1401 (2)0.0171 (9)
C20−0.0680 (4)0.5614 (3)0.0928 (2)0.0212 (10)
C21−0.0532 (4)0.8413 (3)0.3756 (2)0.0185 (9)
C22−0.0145 (4)0.9070 (3)0.4342 (2)0.0228 (10)
C230.1159 (4)0.1904 (3)0.1391 (2)0.0155 (9)
C240.1817 (4)0.2448 (3)0.0947 (2)0.0197 (10)
H240.27490.25670.09670.024*
C250.1131 (4)0.2815 (3)0.0481 (2)0.0256 (11)
H250.15880.31800.01750.031*
C26−0.0226 (4)0.2651 (3)0.0458 (2)0.0264 (11)
H26−0.07000.29040.01360.032*
C27−0.0893 (4)0.2119 (3)0.0902 (2)0.0229 (10)
H27−0.18230.20170.08920.028*
C28−0.0209 (4)0.1735 (3)0.1364 (2)0.0192 (9)
H28−0.06700.13600.16600.023*
C290.2263 (4)0.0595 (3)0.1382 (2)0.0158 (9)
C300.1691 (4)0.0471 (3)0.0691 (2)0.0195 (10)
H300.11660.08000.05120.023*
C310.1881 (4)−0.0129 (3)0.0260 (2)0.0251 (11)
H310.1506−0.0197−0.02140.030*
C320.2605 (4)−0.0625 (3)0.0513 (2)0.0246 (10)
H320.2705−0.10450.02200.030*
C330.3193 (4)−0.0510 (3)0.1201 (2)0.0249 (11)
H330.3708−0.08460.13760.030*
C340.3023 (4)0.0096 (3)0.1626 (2)0.0223 (10)
H340.34310.01740.20940.027*
C350.1064 (4)0.0964 (3)0.2607 (2)0.0182 (9)
H350.07740.04130.26410.022*
C360.0654 (4)0.1549 (3)0.3099 (2)0.0204 (10)
H36A0.04310.19630.28100.025*
H36B−0.01590.12690.32980.025*
C370.1649 (4)0.1948 (3)0.3706 (2)0.0193 (10)
H37A0.20290.15460.39310.023*
H37B0.11720.21540.40600.023*
C380.2178 (4)0.3504 (3)0.3206 (2)0.0174 (9)
C390.2053 (4)0.3658 (3)0.2501 (2)0.0208 (10)
H390.24140.33800.21710.025*
C400.1405 (4)0.4214 (3)0.2269 (2)0.0220 (10)
H400.13030.43030.17820.026*
C410.0911 (4)0.4635 (3)0.2747 (2)0.0260 (11)
H410.04820.50220.25930.031*
C420.1047 (5)0.4489 (3)0.3456 (2)0.0372 (14)
H420.07150.47810.37880.045*
C430.1659 (5)0.3927 (3)0.3679 (2)0.0324 (13)
H430.17280.38250.41640.039*
C440.3843 (4)0.3140 (3)0.4337 (2)0.0210 (10)
C450.4909 (5)0.3775 (3)0.4357 (2)0.0566 (18)
H45A0.46070.41950.41140.068*
H45B0.55500.36250.40690.068*
C460.5602 (5)0.4111 (3)0.4991 (3)0.085 (3)
H460.63360.45520.49940.102*
C470.5213 (5)0.3798 (3)0.5610 (2)0.0516 (16)
H470.56830.40220.60440.062*
C480.4156 (4)0.3168 (3)0.5608 (2)0.0359 (13)
H480.38900.29550.60380.043*
C490.3468 (4)0.2837 (3)0.4974 (2)0.0298 (11)
H490.27330.23980.49760.036*
C500.6527 (4)0.0962 (3)0.2826 (2)0.0179 (9)
C510.6416 (4)0.0806 (3)0.2098 (2)0.0214 (10)
H510.59980.11030.17920.026*
C520.6915 (4)0.0218 (3)0.1824 (3)0.0275 (11)
H520.68500.01190.13310.033*
C530.7504 (4)−0.0222 (3)0.2263 (3)0.0293 (12)
H530.7842−0.06240.20710.035*
C540.7605 (4)−0.0080 (3)0.2983 (3)0.0295 (12)
H540.8009−0.03880.32850.035*
C550.7116 (4)0.0513 (3)0.3266 (2)0.0220 (10)
H550.71880.06090.37610.026*
C560.5544 (4)0.1494 (3)0.4043 (2)0.0180 (9)
C570.4425 (4)0.0884 (3)0.4092 (2)0.0232 (10)
H570.39460.06170.36760.028*
C580.4006 (4)0.0663 (3)0.4738 (2)0.0278 (11)
H580.32550.02390.47630.033*
C590.4674 (5)0.1057 (3)0.5348 (2)0.0315 (12)
H590.43720.09110.57910.038*
C600.5778 (5)0.1660 (3)0.5311 (2)0.0327 (12)
H600.62460.19280.57300.039*
C610.6211 (4)0.1882 (3)0.4658 (2)0.0245 (10)
H610.69700.23010.46370.029*
C620.7435 (4)0.2573 (3)0.3283 (2)0.0179 (9)
H62A0.72770.30020.35790.022*
H62B0.81410.23810.35360.022*
C630.7910 (4)0.2905 (3)0.2587 (2)0.0165 (9)
H63A0.88780.31070.26520.020*
H63B0.77030.24700.22240.020*
C640.7316 (4)0.3561 (3)0.2311 (2)0.0183 (9)
H64A0.78930.38520.19740.022*
H64B0.73210.39310.27100.022*
C650.5173 (4)0.4162 (3)0.1735 (2)0.0160 (9)
C660.4562 (4)0.4311 (3)0.1095 (2)0.0223 (10)
H660.44270.39410.07090.027*
C670.4145 (4)0.5001 (3)0.1019 (2)0.0245 (11)
H670.37480.51050.05800.029*
C680.4318 (5)0.5522 (3)0.1582 (3)0.0305 (12)
H680.40230.59850.15330.037*
C690.4916 (5)0.5385 (3)0.2223 (2)0.0310 (12)
H690.50440.57550.26090.037*
C700.5325 (4)0.4702 (3)0.2293 (2)0.0227 (10)
H700.57200.46030.27340.027*
C710.5872 (4)0.2907 (3)0.0999 (2)0.0154 (9)
C720.6675 (4)0.3406 (3)0.0568 (2)0.0187 (9)
H720.71130.39250.07350.022*
C730.6833 (4)0.3150 (3)−0.0097 (2)0.0214 (10)
H730.73630.3496−0.03900.026*
C740.6222 (4)0.2389 (3)−0.0339 (2)0.0245 (11)
H740.63490.2212−0.07940.029*
C750.5432 (4)0.1889 (3)0.0076 (2)0.0225 (10)
H750.50110.1367−0.00920.027*
C760.5250 (4)0.2150 (3)0.0746 (2)0.0180 (9)
H760.46960.18070.10310.022*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Sn10.01322 (14)0.01595 (17)0.01312 (15)0.00299 (12)0.00177 (11)0.00034 (12)
Ag10.01216 (15)0.01514 (18)0.01399 (16)0.00362 (13)0.00165 (12)0.00158 (13)
Cl10.0229 (6)0.0264 (7)0.0336 (7)0.0011 (5)−0.0020 (5)0.0000 (5)
Cl20.0327 (6)0.0326 (7)0.0199 (6)0.0051 (5)−0.0038 (5)−0.0009 (5)
P10.0130 (5)0.0145 (6)0.0143 (5)0.0029 (4)0.0007 (4)0.0020 (5)
P20.0162 (5)0.0194 (6)0.0145 (5)0.0057 (5)0.0034 (4)0.0006 (5)
P30.0160 (5)0.0140 (6)0.0155 (6)0.0025 (5)0.0017 (4)0.0011 (5)
P40.0131 (5)0.0161 (6)0.0164 (6)0.0036 (5)0.0001 (4)0.0023 (5)
F10.0449 (16)0.0296 (17)0.0143 (13)0.0131 (14)0.0064 (12)−0.0045 (12)
F20.0426 (16)0.0179 (16)0.0309 (15)0.0121 (13)−0.0032 (12)0.0003 (12)
F30.0325 (16)0.055 (2)0.0360 (17)0.0216 (15)0.0027 (13)−0.0212 (15)
F40.0470 (17)0.0209 (17)0.0308 (16)0.0071 (14)−0.0009 (13)−0.0018 (13)
O10.0225 (15)0.0171 (17)0.0119 (14)0.0036 (13)0.0036 (12)−0.0004 (13)
O20.0261 (17)0.026 (2)0.0215 (17)−0.0005 (15)0.0089 (13)0.0020 (15)
O30.0196 (15)0.0210 (18)0.0205 (16)0.0057 (13)0.0043 (12)−0.0019 (14)
O40.0175 (16)0.034 (2)0.0298 (18)0.0040 (15)0.0013 (13)−0.0066 (16)
C10.019 (2)0.020 (3)0.013 (2)0.0068 (19)0.0038 (16)0.0006 (19)
C20.025 (2)0.029 (3)0.017 (2)0.003 (2)0.0011 (18)0.002 (2)
C30.025 (2)0.026 (3)0.031 (3)−0.005 (2)0.005 (2)0.005 (2)
C40.037 (3)0.027 (3)0.020 (2)0.013 (2)0.012 (2)0.010 (2)
C50.036 (3)0.028 (3)0.019 (2)0.008 (2)−0.002 (2)0.006 (2)
C60.028 (2)0.022 (3)0.019 (2)0.003 (2)−0.0019 (19)−0.003 (2)
C70.0094 (18)0.018 (2)0.014 (2)−0.0011 (17)−0.0001 (15)0.0000 (18)
C80.018 (2)0.018 (3)0.031 (3)0.0037 (19)0.0032 (19)−0.004 (2)
C90.016 (2)0.019 (3)0.038 (3)0.007 (2)0.0031 (19)−0.003 (2)
C100.014 (2)0.028 (3)0.024 (2)0.005 (2)0.0010 (18)0.000 (2)
C110.017 (2)0.017 (3)0.027 (2)−0.0002 (19)−0.0009 (18)0.003 (2)
C120.017 (2)0.017 (2)0.023 (2)0.0062 (19)0.0043 (17)0.004 (2)
C130.019 (2)0.014 (2)0.012 (2)0.0052 (18)−0.0009 (16)−0.0007 (18)
C140.020 (2)0.021 (3)0.032 (3)0.004 (2)0.0048 (19)0.009 (2)
C150.014 (2)0.028 (3)0.035 (3)0.004 (2)−0.0036 (19)0.003 (2)
C160.026 (2)0.040 (3)0.022 (2)0.014 (2)−0.0053 (19)0.004 (2)
C170.027 (3)0.044 (4)0.032 (3)0.006 (2)0.003 (2)0.021 (3)
C180.020 (2)0.030 (3)0.030 (3)0.000 (2)0.0010 (19)0.013 (2)
C190.020 (2)0.018 (3)0.015 (2)0.0077 (19)0.0034 (17)0.0015 (19)
C200.027 (2)0.014 (2)0.023 (2)0.006 (2)0.0040 (19)0.003 (2)
C210.025 (2)0.020 (3)0.014 (2)0.010 (2)0.0025 (17)0.0058 (19)
C220.020 (2)0.022 (3)0.027 (3)0.008 (2)−0.0014 (19)−0.002 (2)
C230.019 (2)0.013 (2)0.014 (2)0.0039 (18)−0.0011 (16)−0.0006 (18)
C240.017 (2)0.022 (3)0.021 (2)0.0057 (19)0.0027 (17)0.002 (2)
C250.028 (2)0.026 (3)0.027 (3)0.011 (2)0.005 (2)0.015 (2)
C260.024 (2)0.038 (3)0.022 (2)0.016 (2)0.0017 (19)0.004 (2)
C270.018 (2)0.036 (3)0.016 (2)0.012 (2)−0.0037 (17)−0.002 (2)
C280.018 (2)0.020 (3)0.018 (2)0.0033 (19)0.0011 (17)0.000 (2)
C290.017 (2)0.016 (2)0.013 (2)0.0013 (18)0.0039 (16)0.0049 (18)
C300.018 (2)0.020 (3)0.022 (2)0.0084 (19)−0.0018 (17)0.001 (2)
C310.027 (2)0.031 (3)0.018 (2)0.010 (2)−0.0003 (19)0.001 (2)
C320.027 (2)0.020 (3)0.027 (3)0.006 (2)0.006 (2)−0.007 (2)
C330.025 (2)0.021 (3)0.031 (3)0.010 (2)0.004 (2)0.003 (2)
C340.021 (2)0.027 (3)0.019 (2)0.010 (2)−0.0058 (18)0.000 (2)
C350.022 (2)0.014 (2)0.018 (2)−0.0008 (18)0.0095 (17)0.0034 (19)
C360.017 (2)0.026 (3)0.018 (2)0.0040 (19)0.0037 (17)0.002 (2)
C370.023 (2)0.024 (3)0.012 (2)0.009 (2)0.0033 (17)0.0010 (19)
C380.020 (2)0.018 (2)0.016 (2)0.0072 (19)0.0037 (17)0.0048 (19)
C390.023 (2)0.024 (3)0.017 (2)0.008 (2)0.0058 (18)0.000 (2)
C400.028 (2)0.024 (3)0.013 (2)0.006 (2)−0.0013 (18)0.001 (2)
C410.028 (2)0.018 (3)0.036 (3)0.011 (2)0.004 (2)0.008 (2)
C420.061 (4)0.038 (4)0.024 (3)0.033 (3)0.004 (2)−0.003 (2)
C430.052 (3)0.037 (3)0.018 (2)0.026 (3)0.010 (2)0.007 (2)
C440.021 (2)0.029 (3)0.014 (2)0.008 (2)0.0034 (17)−0.0028 (19)
C450.056 (4)0.068 (5)0.026 (3)−0.022 (3)0.007 (3)−0.002 (3)
C460.073 (4)0.108 (6)0.034 (3)−0.047 (4)0.003 (3)−0.011 (4)
C470.045 (3)0.072 (5)0.023 (3)−0.007 (3)−0.003 (2)−0.010 (3)
C480.045 (3)0.040 (3)0.021 (3)0.008 (3)0.001 (2)0.008 (2)
C490.037 (3)0.032 (3)0.019 (2)0.008 (2)−0.001 (2)0.003 (2)
C500.0111 (19)0.015 (2)0.027 (2)0.0020 (17)0.0006 (17)0.0003 (19)
C510.019 (2)0.023 (3)0.024 (2)0.004 (2)0.0077 (18)0.006 (2)
C520.029 (3)0.019 (3)0.032 (3)−0.001 (2)0.014 (2)−0.005 (2)
C530.019 (2)0.015 (3)0.053 (3)0.000 (2)0.011 (2)−0.007 (2)
C540.012 (2)0.016 (3)0.059 (4)0.0017 (19)−0.004 (2)0.005 (2)
C550.013 (2)0.025 (3)0.025 (2)0.0022 (19)−0.0049 (17)0.001 (2)
C560.014 (2)0.021 (3)0.022 (2)0.0112 (19)0.0004 (17)0.007 (2)
C570.021 (2)0.024 (3)0.024 (2)0.006 (2)−0.0025 (18)0.004 (2)
C580.026 (2)0.029 (3)0.031 (3)0.007 (2)0.011 (2)0.018 (2)
C590.040 (3)0.040 (3)0.018 (2)0.013 (3)0.010 (2)0.011 (2)
C600.040 (3)0.039 (3)0.020 (3)0.010 (3)0.004 (2)0.007 (2)
C610.025 (2)0.026 (3)0.020 (2)0.003 (2)0.0018 (19)0.008 (2)
C620.019 (2)0.016 (2)0.018 (2)0.0033 (18)−0.0002 (17)0.0016 (19)
C630.0113 (19)0.017 (2)0.020 (2)0.0021 (17)0.0008 (16)−0.0005 (19)
C640.020 (2)0.018 (2)0.014 (2)0.0021 (19)0.0011 (17)−0.0015 (19)
C650.016 (2)0.016 (2)0.015 (2)0.0003 (18)0.0032 (16)0.0011 (18)
C660.022 (2)0.022 (3)0.020 (2)0.002 (2)0.0018 (18)−0.008 (2)
C670.030 (2)0.020 (3)0.026 (3)0.012 (2)0.000 (2)−0.001 (2)
C680.038 (3)0.021 (3)0.036 (3)0.012 (2)0.005 (2)0.006 (2)
C690.046 (3)0.026 (3)0.022 (3)0.012 (3)0.002 (2)−0.004 (2)
C700.031 (2)0.016 (3)0.021 (2)0.006 (2)0.0006 (19)0.000 (2)
C710.0111 (19)0.019 (2)0.016 (2)0.0042 (18)−0.0014 (16)0.0001 (19)
C720.018 (2)0.017 (2)0.021 (2)0.0038 (19)0.0001 (17)0.005 (2)
C730.021 (2)0.028 (3)0.021 (2)0.012 (2)0.0069 (18)0.008 (2)
C740.025 (2)0.039 (3)0.017 (2)0.022 (2)0.0037 (18)0.001 (2)
C750.022 (2)0.023 (3)0.024 (2)0.013 (2)−0.0079 (18)−0.010 (2)
C760.0110 (19)0.021 (3)0.022 (2)0.0046 (18)0.0010 (17)0.002 (2)

Geometric parameters (Å, °)

Sn1—C12.128 (4)C33—C341.384 (6)
Sn1—C72.128 (4)C33—H330.9500
Sn1—C132.115 (4)C34—H340.9500
Sn1—O12.233 (3)C35—C361.543 (6)
Sn1—O32.208 (3)C35—H350.9500
Ag1—P12.460 (1)C36—C371.524 (6)
Ag1—P22.501 (1)C36—H36A0.9900
Ag1—P32.463 (1)C36—H36B0.9900
Ag1—P42.470 (1)C37—H37A0.9900
Cl1—C201.769 (4)C37—H37B0.9900
Cl2—C221.773 (4)C38—C391.385 (5)
P1—C291.821 (4)C38—C431.390 (6)
P1—C231.822 (4)C39—C401.392 (6)
P1—C351.833 (4)C39—H390.9500
P2—C441.818 (4)C40—C411.379 (6)
P2—C381.831 (4)C40—H400.9500
P2—C371.834 (5)C41—C421.390 (6)
P3—C651.825 (4)C41—H410.9500
P3—C711.827 (4)C42—C431.373 (6)
P3—C641.845 (4)C42—H420.9500
P4—C561.810 (4)C43—H430.9500
P4—C501.831 (4)C44—C451.373 (6)
P4—C621.835 (4)C44—C491.394 (6)
F1—C201.334 (5)C45—C461.396 (6)
F2—C201.358 (5)C45—H45A0.9900
F3—C221.342 (4)C45—H45B0.9900
F4—C221.348 (5)C46—C471.373 (6)
O1—C191.282 (4)C46—H460.9500
O2—C191.204 (5)C47—C481.363 (6)
O3—C211.268 (4)C47—H470.9500
O4—C211.209 (5)C48—C491.391 (5)
C1—C21.382 (6)C48—H480.9500
C1—C61.390 (6)C49—H490.9500
C2—C31.395 (6)C50—C551.386 (5)
C2—H20.9500C50—C511.403 (6)
C3—C41.386 (6)C51—C521.386 (6)
C3—H30.9500C51—H510.9500
C4—C51.381 (7)C52—C531.371 (6)
C4—H40.9500C52—H520.9500
C5—C61.371 (6)C53—C541.385 (7)
C5—H50.9500C53—H530.9500
C6—H60.9500C54—C551.396 (6)
C7—C121.380 (6)C54—H540.9500
C7—C81.382 (5)C55—H550.9500
C8—C91.391 (6)C56—C611.386 (6)
C8—H80.9500C56—C571.396 (6)
C9—C101.378 (6)C57—C581.381 (6)
C9—H90.9500C57—H570.9500
C10—C111.384 (6)C58—C591.382 (7)
C10—H100.9500C58—H580.9500
C11—C121.390 (5)C59—C601.376 (7)
C11—H110.9500C59—H590.9500
C12—H120.9500C60—C611.399 (6)
C13—C141.384 (6)C60—H600.9500
C13—C181.398 (6)C61—H610.9500
C14—C151.382 (6)C62—C631.542 (5)
C14—H140.9500C62—H62A0.9900
C15—C161.375 (7)C62—H62B0.9900
C15—H150.9500C63—C641.535 (5)
C16—C171.376 (6)C63—H63A0.9900
C16—H160.9500C63—H63B0.9900
C17—C181.393 (6)C64—H64A0.9900
C17—H170.9500C64—H64B0.9900
C18—H180.9500C65—C701.383 (6)
C19—C201.543 (6)C65—C661.396 (6)
C21—C221.544 (6)C66—C671.402 (6)
C23—C241.392 (6)C66—H660.9500
C23—C281.394 (5)C67—C681.368 (6)
C24—C251.378 (5)C67—H670.9500
C24—H240.9500C68—C691.386 (6)
C25—C261.385 (6)C68—H680.9500
C25—H250.9500C69—C701.385 (6)
C26—C271.385 (6)C69—H690.9500
C26—H260.9500C70—H700.9500
C27—C281.390 (5)C71—C761.385 (6)
C27—H270.9500C71—C721.400 (6)
C28—H280.9500C72—C731.375 (6)
C29—C301.394 (6)C72—H720.9500
C29—C341.396 (5)C73—C741.384 (7)
C30—C311.389 (6)C73—H730.9500
C30—H300.9500C74—C751.375 (7)
C31—C321.371 (6)C74—H740.9500
C31—H310.9500C75—C761.396 (5)
C32—C331.393 (6)C75—H750.9500
C32—H320.9500C76—H760.9500
C1—Sn1—C7115.2 (2)C33—C34—C29121.3 (4)
C1—Sn1—C13127.2 (2)C33—C34—H34119.4
C1—Sn1—O184.9 (1)C29—C34—H34119.4
C1—Sn1—O390.8 (1)C36—C35—P1114.9 (3)
C7—Sn1—C13117.6 (2)C36—C35—H35122.5
C7—Sn1—O195.8 (1)P1—C35—H35122.5
C7—Sn1—O386.9 (1)C37—C36—C35117.3 (3)
C13—Sn1—O393.2 (1)C37—C36—H36A108.0
C13—Sn1—O188.7 (1)C35—C36—H36A108.0
O1—Sn1—O3175.6 (1)C37—C36—H36B108.0
P1—Ag1—P293.58 (4)C35—C36—H36B108.0
P1—Ag1—P3119.54 (4)H36A—C36—H36B107.2
P1—Ag1—P4122.91 (4)C36—C37—P2116.3 (3)
P2—Ag1—P3118.95 (4)C36—C37—H37A108.2
P2—Ag1—P4106.23 (4)P2—C37—H37A108.2
P3—Ag1—P496.64 (4)C36—C37—H37B108.2
C29—P1—C23102.35 (18)P2—C37—H37B108.2
C29—P1—C35104.7 (2)H37A—C37—H37B107.4
C23—P1—C35104.52 (18)C39—C38—C43118.5 (4)
C29—P1—Ag1119.20 (13)C39—C38—P2119.3 (3)
C23—P1—Ag1115.03 (15)C43—C38—P2122.2 (3)
C35—P1—Ag1109.63 (14)C38—C39—C40120.9 (4)
C44—P2—C38103.21 (19)C38—C39—H39119.6
C44—P2—C37103.13 (19)C40—C39—H39119.6
C38—P2—C37103.20 (19)C41—C40—C39119.9 (4)
C44—P2—Ag1121.75 (12)C41—C40—H40120.1
C38—P2—Ag1114.10 (13)C39—C40—H40120.1
C37—P2—Ag1109.46 (14)C40—C41—C42119.5 (4)
C65—P3—C71103.91 (18)C40—C41—H41120.3
C65—P3—C64103.5 (2)C42—C41—H41120.3
C71—P3—C64103.10 (18)C43—C42—C41120.4 (4)
C65—P3—Ag1116.75 (13)C43—C42—H42119.8
C71—P3—Ag1115.99 (15)C41—C42—H42119.8
C64—P3—Ag1112.00 (14)C42—C43—C38120.9 (4)
C56—P4—C50103.42 (19)C42—C43—H43119.6
C56—P4—C62106.1 (2)C38—C43—H43119.6
C50—P4—C62102.09 (19)C45—C44—C49117.7 (4)
C56—P4—Ag1111.49 (12)C45—C44—P2118.1 (3)
C50—P4—Ag1124.14 (14)C49—C44—P2124.3 (3)
C62—P4—Ag1108.08 (13)C44—C45—C46121.6 (4)
C19—O1—Sn1119.0 (3)C44—C45—H45A106.9
C21—O3—Sn1119.3 (3)C46—C45—H45A106.9
C2—C1—C6118.3 (4)C44—C45—H45B106.9
C2—C1—Sn1122.7 (3)C46—C45—H45B106.9
C6—C1—Sn1118.9 (3)H45A—C45—H45B106.7
C1—C2—C3120.9 (4)C47—C46—C45119.3 (5)
C1—C2—H2119.6C47—C46—H46120.3
C3—C2—H2119.6C45—C46—H46120.3
C4—C3—C2119.8 (5)C48—C47—C46120.4 (5)
C4—C3—H3120.1C48—C47—H47119.8
C2—C3—H3120.1C46—C47—H47119.8
C5—C4—C3119.3 (4)C47—C48—C49119.9 (4)
C5—C4—H4120.4C47—C48—H48120.0
C3—C4—H4120.4C49—C48—H48120.0
C6—C5—C4120.6 (4)C48—C49—C44121.0 (4)
C6—C5—H5119.7C48—C49—H49119.5
C4—C5—H5119.7C44—C49—H49119.5
C5—C6—C1121.1 (5)C55—C50—C51119.2 (4)
C5—C6—H6119.5C55—C50—P4121.8 (3)
C1—C6—H6119.5C51—C50—P4119.0 (3)
C12—C7—C8118.5 (4)C52—C51—C50120.1 (4)
C12—C7—Sn1120.7 (3)C52—C51—H51120.0
C8—C7—Sn1120.8 (3)C50—C51—H51120.0
C7—C8—C9120.3 (4)C53—C52—C51120.4 (4)
C7—C8—H8119.8C53—C52—H52119.8
C9—C8—H8119.8C51—C52—H52119.8
C10—C9—C8120.7 (4)C52—C53—C54120.1 (4)
C10—C9—H9119.7C52—C53—H53119.9
C8—C9—H9119.7C54—C53—H53119.9
C9—C10—C11119.4 (4)C53—C54—C55120.2 (4)
C9—C10—H10120.3C53—C54—H54119.9
C11—C10—H10120.3C55—C54—H54119.9
C10—C11—C12119.3 (4)C50—C55—C54120.0 (4)
C10—C11—H11120.3C50—C55—H55120.0
C12—C11—H11120.3C54—C55—H55120.0
C7—C12—C11121.6 (4)C61—C56—C57118.3 (4)
C7—C12—H12119.2C61—C56—P4124.7 (4)
C11—C12—H12119.2C57—C56—P4116.7 (3)
C14—C13—C18117.4 (4)C58—C57—C56120.9 (4)
C14—C13—Sn1123.6 (3)C58—C57—H57119.6
C18—C13—Sn1118.9 (3)C56—C57—H57119.6
C15—C14—C13122.1 (4)C57—C58—C59120.4 (5)
C15—C14—H14118.9C57—C58—H58119.8
C13—C14—H14118.9C59—C58—H58119.8
C16—C15—C14119.6 (4)C60—C59—C58119.6 (4)
C16—C15—H15120.2C60—C59—H59120.2
C14—C15—H15120.2C58—C59—H59120.2
C15—C16—C17120.1 (4)C59—C60—C61120.1 (5)
C15—C16—H16120.0C59—C60—H60119.9
C17—C16—H16120.0C61—C60—H60119.9
C16—C17—C18120.1 (4)C56—C61—C60120.6 (5)
C16—C17—H17120.0C56—C61—H61119.7
C18—C17—H17120.0C60—C61—H61119.7
C17—C18—C13120.7 (4)C63—C62—P4113.8 (3)
C17—C18—H18119.6C63—C62—H62A108.8
C13—C18—H18119.6P4—C62—H62A108.8
O2—C19—O1129.8 (4)C63—C62—H62B108.8
O2—C19—C20118.3 (4)P4—C62—H62B108.8
O1—C19—C20111.9 (4)H62A—C62—H62B107.7
F1—C20—F2106.7 (3)C64—C63—C62115.4 (3)
F1—C20—C19111.8 (4)C64—C63—H63A108.4
F2—C20—C19111.0 (3)C62—C63—H63A108.4
F1—C20—Cl1108.0 (3)C64—C63—H63B108.4
F2—C20—Cl1108.2 (3)C62—C63—H63B108.4
C19—C20—Cl1111.0 (3)H63A—C63—H63B107.5
O4—C21—O3130.4 (4)C63—C64—P3115.7 (3)
O4—C21—C22118.8 (4)C63—C64—H64A108.4
O3—C21—C22110.9 (4)P3—C64—H64A108.4
F3—C22—F4107.1 (4)C63—C64—H64B108.4
F3—C22—C21111.6 (4)P3—C64—H64B108.4
F4—C22—C21111.4 (3)H64A—C64—H64B107.4
F3—C22—Cl2107.4 (3)C70—C65—C66118.3 (4)
F4—C22—Cl2108.2 (3)C70—C65—P3119.4 (3)
C21—C22—Cl2110.9 (3)C66—C65—P3122.1 (3)
C24—C23—C28119.4 (4)C65—C66—C67120.6 (4)
C24—C23—P1117.1 (3)C65—C66—H66119.7
C28—C23—P1123.4 (3)C67—C66—H66119.7
C25—C24—C23120.7 (4)C68—C67—C66119.3 (4)
C25—C24—H24119.6C68—C67—H67120.3
C23—C24—H24119.6C66—C67—H67120.3
C24—C25—C26119.8 (4)C67—C68—C69121.1 (4)
C24—C25—H25120.1C67—C68—H68119.5
C26—C25—H25120.1C69—C68—H68119.5
C27—C26—C25120.1 (4)C70—C69—C68119.1 (5)
C27—C26—H26119.9C70—C69—H69120.5
C25—C26—H26119.9C68—C69—H69120.5
C26—C27—C28120.3 (4)C65—C70—C69121.6 (4)
C26—C27—H27119.9C65—C70—H70119.2
C28—C27—H27119.9C69—C70—H70119.2
C27—C28—C23119.6 (4)C76—C71—C72118.9 (4)
C27—C28—H28120.2C76—C71—P3120.1 (3)
C23—C28—H28120.2C72—C71—P3121.0 (4)
C30—C29—C34118.0 (4)C73—C72—C71120.5 (4)
C30—C29—P1122.8 (3)C73—C72—H72119.8
C34—C29—P1119.1 (3)C71—C72—H72119.8
C31—C30—C29120.7 (4)C72—C73—C74120.1 (4)
C31—C30—H30119.7C72—C73—H73119.9
C29—C30—H30119.7C74—C73—H73119.9
C32—C31—C30120.6 (4)C75—C74—C73120.4 (4)
C32—C31—H31119.7C75—C74—H74119.8
C30—C31—H31119.7C73—C74—H74119.8
C31—C32—C33119.7 (4)C74—C75—C76119.7 (5)
C31—C32—H32120.1C74—C75—H75120.2
C33—C32—H32120.1C76—C75—H75120.2
C34—C33—C32119.7 (4)C71—C76—C75120.5 (4)
C34—C33—H33120.2C71—C76—H76119.8
C32—C33—H33120.2C75—C76—H76119.8
P3—Ag1—P1—C2975.36 (15)C26—C27—C28—C231.7 (7)
P4—Ag1—P1—C29−46.32 (16)C24—C23—C28—C27−0.8 (6)
P2—Ag1—P1—C29−158.28 (15)P1—C23—C28—C27−177.8 (3)
P3—Ag1—P1—C23−46.74 (14)C23—P1—C29—C301.2 (4)
P4—Ag1—P1—C23−168.42 (14)C35—P1—C29—C30110.0 (4)
P2—Ag1—P1—C2379.62 (14)Ag1—P1—C29—C30−127.0 (3)
P3—Ag1—P1—C35−164.15 (14)C23—P1—C29—C34176.8 (3)
P4—Ag1—P1—C3574.18 (15)C35—P1—C29—C34−74.3 (4)
P2—Ag1—P1—C35−37.79 (15)Ag1—P1—C29—C3448.6 (4)
P1—Ag1—P2—C44156.14 (18)C34—C29—C30—C31−0.3 (6)
P3—Ag1—P2—C44−77.05 (18)P1—C29—C30—C31175.4 (3)
P4—Ag1—P2—C4430.32 (18)C29—C30—C31—C321.8 (7)
P1—Ag1—P2—C38−79.03 (17)C30—C31—C32—C33−2.2 (7)
P3—Ag1—P2—C3847.78 (17)C31—C32—C33—C341.1 (7)
P4—Ag1—P2—C38155.16 (16)C32—C33—C34—C290.4 (7)
P1—Ag1—P2—C3736.01 (14)C30—C29—C34—C33−0.8 (6)
P3—Ag1—P2—C37162.82 (14)P1—C29—C34—C33−176.7 (4)
P4—Ag1—P2—C37−89.80 (14)C29—P1—C35—C36−172.0 (3)
P1—Ag1—P3—C6581.93 (16)C23—P1—C35—C36−64.8 (3)
P4—Ag1—P3—C65−144.06 (16)Ag1—P1—C35—C3659.0 (3)
P2—Ag1—P3—C65−31.36 (16)P1—C35—C36—C37−78.9 (4)
P1—Ag1—P3—C71−41.11 (14)C35—C36—C37—P277.1 (4)
P4—Ag1—P3—C7192.90 (14)C44—P2—C37—C36173.6 (3)
P2—Ag1—P3—C71−154.41 (13)C38—P2—C37—C3666.4 (3)
P1—Ag1—P3—C64−159.07 (15)Ag1—P2—C37—C36−55.4 (3)
P4—Ag1—P3—C64−25.07 (15)C44—P2—C38—C39145.2 (4)
P2—Ag1—P3—C6487.63 (15)C37—P2—C38—C39−107.6 (4)
P1—Ag1—P4—C56−81.76 (17)Ag1—P2—C38—C3911.0 (4)
P3—Ag1—P4—C56146.44 (17)C44—P2—C38—C43−35.2 (5)
P2—Ag1—P4—C5623.66 (17)C37—P2—C38—C4371.9 (4)
P1—Ag1—P4—C5042.89 (17)Ag1—P2—C38—C43−169.4 (4)
P3—Ag1—P4—C50−88.92 (17)C43—C38—C39—C40−1.0 (7)
P2—Ag1—P4—C50148.30 (17)P2—C38—C39—C40178.6 (4)
P1—Ag1—P4—C62162.07 (14)C38—C39—C40—C411.9 (7)
P3—Ag1—P4—C6230.26 (14)C39—C40—C41—C42−1.1 (7)
P2—Ag1—P4—C62−92.52 (14)C40—C41—C42—C43−0.5 (8)
C13—Sn1—O1—C1950.2 (3)C41—C42—C43—C381.4 (9)
C7—Sn1—O1—C19−67.4 (3)C39—C38—C43—C42−0.7 (8)
C1—Sn1—O1—C19177.8 (3)P2—C38—C43—C42179.8 (4)
C13—Sn1—O3—C2167.1 (3)C38—P2—C44—C45−71.1 (3)
C7—Sn1—O3—C21−175.4 (3)C37—P2—C44—C45−178.3 (3)
C1—Sn1—O3—C21−60.2 (3)Ag1—P2—C44—C4558.6 (3)
C13—Sn1—C1—C242.7 (4)C38—P2—C44—C49108.5 (3)
C7—Sn1—C1—C2−135.7 (3)C37—P2—C44—C491.3 (3)
O3—Sn1—C1—C2137.3 (3)Ag1—P2—C44—C49−121.9 (3)
O1—Sn1—C1—C2−41.7 (3)C49—C44—C45—C460.1 (2)
C13—Sn1—C1—C6−139.8 (3)P2—C44—C45—C46179.7 (3)
C7—Sn1—C1—C641.9 (4)C44—C45—C46—C470.2 (3)
O3—Sn1—C1—C6−45.1 (3)C45—C46—C47—C48−0.3 (5)
O1—Sn1—C1—C6135.8 (3)C46—C47—C48—C490.2 (6)
C6—C1—C2—C30.7 (6)C47—C48—C49—C440.0 (6)
Sn1—C1—C2—C3178.2 (3)C45—C44—C49—C48−0.2 (4)
C1—C2—C3—C4−1.2 (7)P2—C44—C49—C48−179.7 (3)
C2—C3—C4—C50.4 (7)C56—P4—C50—C55−27.5 (4)
C3—C4—C5—C60.8 (7)C62—P4—C50—C5582.5 (4)
C4—C5—C6—C1−1.4 (7)Ag1—P4—C50—C55−155.6 (3)
C2—C1—C6—C50.6 (6)C56—P4—C50—C51154.2 (3)
Sn1—C1—C6—C5−177.0 (3)C62—P4—C50—C51−95.8 (4)
C13—Sn1—C7—C1261.2 (4)Ag1—P4—C50—C5126.1 (4)
C1—Sn1—C7—C12−120.2 (3)C55—C50—C51—C52−1.3 (6)
O3—Sn1—C7—C12−30.8 (3)P4—C50—C51—C52177.1 (3)
O1—Sn1—C7—C12152.7 (3)C50—C51—C52—C530.9 (7)
C13—Sn1—C7—C8−119.6 (3)C51—C52—C53—C54−0.1 (7)
C1—Sn1—C7—C858.9 (4)C52—C53—C54—C55−0.4 (7)
O3—Sn1—C7—C8148.3 (3)C51—C50—C55—C540.8 (6)
O1—Sn1—C7—C8−28.2 (3)P4—C50—C55—C54−177.5 (3)
C12—C7—C8—C91.6 (6)C53—C54—C55—C500.0 (7)
Sn1—C7—C8—C9−177.5 (3)C50—P4—C56—C61112.9 (4)
C7—C8—C9—C10−3.3 (7)C62—P4—C56—C615.9 (4)
C8—C9—C10—C111.8 (7)Ag1—P4—C56—C61−111.5 (3)
C9—C10—C11—C121.2 (7)C50—P4—C56—C57−72.6 (3)
C8—C7—C12—C111.5 (6)C62—P4—C56—C57−179.7 (3)
Sn1—C7—C12—C11−179.4 (3)Ag1—P4—C56—C5762.9 (3)
C10—C11—C12—C7−2.9 (6)C61—C56—C57—C58−1.1 (6)
C7—Sn1—C13—C14168.2 (3)P4—C56—C57—C58−175.9 (3)
C1—Sn1—C13—C14−10.1 (4)C56—C57—C58—C591.5 (7)
O3—Sn1—C13—C14−103.6 (4)C57—C58—C59—C60−1.4 (7)
O1—Sn1—C13—C1472.4 (4)C58—C59—C60—C610.8 (7)
C7—Sn1—C13—C18−8.4 (4)C57—C56—C61—C600.5 (6)
C1—Sn1—C13—C18173.3 (3)P4—C56—C61—C60174.9 (3)
O3—Sn1—C13—C1879.9 (4)C59—C60—C61—C56−0.4 (7)
O1—Sn1—C13—C18−104.2 (4)C56—P4—C62—C63−178.9 (3)
C18—C13—C14—C150.6 (7)C50—P4—C62—C6373.1 (3)
Sn1—C13—C14—C15−176.0 (3)Ag1—P4—C62—C63−59.2 (3)
C13—C14—C15—C160.7 (7)P4—C62—C63—C6487.4 (4)
C14—C15—C16—C17−1.7 (8)C62—C63—C64—P3−77.9 (4)
C15—C16—C17—C181.3 (8)C65—P3—C64—C63172.3 (3)
C16—C17—C18—C130.1 (8)C71—P3—C64—C63−79.7 (3)
C14—C13—C18—C17−1.0 (7)Ag1—P3—C64—C6345.7 (3)
Sn1—C13—C18—C17175.8 (4)C71—P3—C65—C70−159.1 (3)
Sn1—O1—C19—O229.7 (6)C64—P3—C65—C70−51.7 (4)
Sn1—O1—C19—C20−149.2 (2)Ag1—P3—C65—C7071.8 (4)
O2—C19—C20—F16.8 (5)C71—P3—C65—C6626.9 (4)
O1—C19—C20—F1−174.1 (3)C64—P3—C65—C66134.3 (3)
O2—C19—C20—F2125.8 (4)Ag1—P3—C65—C66−102.2 (3)
O1—C19—C20—F2−55.1 (4)C70—C65—C66—C671.6 (6)
O2—C19—C20—Cl1−113.8 (4)P3—C65—C66—C67175.7 (3)
O1—C19—C20—Cl165.3 (4)C65—C66—C67—C68−1.4 (7)
Sn1—O3—C21—O4−9.4 (6)C66—C67—C68—C691.1 (7)
Sn1—O3—C21—C22171.0 (2)C67—C68—C69—C70−1.0 (7)
O4—C21—C22—F3−4.1 (6)C66—C65—C70—C69−1.5 (7)
O3—C21—C22—F3175.5 (3)P3—C65—C70—C69−175.8 (4)
O4—C21—C22—F4−123.8 (4)C68—C69—C70—C651.2 (7)
O3—C21—C22—F455.8 (4)C65—P3—C71—C76−129.0 (3)
O4—C21—C22—Cl2115.6 (4)C64—P3—C71—C76123.3 (3)
O3—C21—C22—Cl2−64.8 (4)Ag1—P3—C71—C760.6 (3)
C29—P1—C23—C24−85.8 (4)C65—P3—C71—C7250.4 (3)
C35—P1—C23—C24165.2 (3)C64—P3—C71—C72−57.3 (4)
Ag1—P1—C23—C2445.0 (4)Ag1—P3—C71—C72180.0 (3)
C29—P1—C23—C2891.3 (4)C76—C71—C72—C730.5 (6)
C35—P1—C23—C28−17.7 (4)P3—C71—C72—C73−178.9 (3)
Ag1—P1—C23—C28−137.9 (3)C71—C72—C73—C74−1.5 (6)
C28—C23—C24—C25−0.5 (7)C72—C73—C74—C751.3 (6)
P1—C23—C24—C25176.7 (3)C73—C74—C75—C76−0.2 (6)
C23—C24—C25—C260.9 (7)C72—C71—C76—C750.6 (6)
C24—C25—C26—C270.0 (7)P3—C71—C76—C75180.0 (3)
C25—C26—C27—C28−1.3 (7)C74—C75—C76—C71−0.8 (6)

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CV2399).

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