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Acta Crystallogr Sect E Struct Rep Online. 2008 March 1; 64(Pt 3): m472.
Published online 2008 February 13. doi:  10.1107/S160053680800319X
PMCID: PMC2960829

μ2-Iodido-bis­{dimeth­yl[methyl­bis(quinolin-8-yl)silanyl-κ3 N,Si,N′]platinum(IV)} tetra­kis(penta­fluoro­phen­yl)borate dichloro­methane 0.66-solvate

Abstract

The title complex, [Pt2(CH3)4(C19H15N2Si)2I][B(C6F5)4]·0.66CH2Cl2, resulted from an attempt to synthesize a stable five-coordinate platinum species via ligand abstraction of a six-coordinate platinum precursor. However, dimerization occurred after ligand abstraction, thereby yielding the compound described in this study. The cation is a dinuclear PtIV organometallic complex, in which the metal centers are bridged by an I anion. Both metal centers display a coordination geometry close to octa­hedral, including cis-arranged quinoline ligands connected by Si atoms, which form Pt—Si bonds, two cis-methyl groups, and the bridging I anion. In the crystal structure, voids between cations and anions are partially filled with an average of 0.66 mol­ecules of dichloro­methane solvent.

Related literature

Five-coordinate platinum compounds have been speculated to be inter­mediates in bond-activation processes (Brown et al., 1974 [triangle]). However, ligand abstraction of a six-coordinate platinum precursor carried out in the present study yielded a dinuclear six-coordinate complex.

An external file that holds a picture, illustration, etc.
Object name is e-64-0m472-scheme1.jpg

Experimental

Crystal data

  • [Pt2(CH3)4(C19H15N2Si)2I](C24F20B)·0.66CH2Cl2
  • M r = 1911.14
  • Triclinic, An external file that holds a picture, illustration, etc.
Object name is e-64-0m472-efi1.jpg
  • a = 13.9051 (10) Å
  • b = 15.3559 (11) Å
  • c = 17.1261 (12) Å
  • α = 71.930 (1)°
  • β = 72.045 (1)°
  • γ = 87.621 (1)°
  • V = 3301.3 (4) Å3
  • Z = 2
  • Mo Kα radiation
  • μ = 4.89 mm−1
  • T = 167 (2) K
  • 0.24 × 0.11 × 0.07 mm

Data collection

  • Bruker APEX CCD diffractometer
  • Absorption correction: multi-scan (SADABS; Bruker, 2002 [triangle]) T min = 0.530, T max = 0.710
  • 30538 measured reflections
  • 13293 independent reflections
  • 11270 reflections with I > 2σ(I)
  • R int = 0.020

Refinement

  • R[F 2 > 2σ(F 2)] = 0.025
  • wR(F 2) = 0.065
  • S = 1.08
  • 13293 reflections
  • 898 parameters
  • H-atom parameters constrained
  • Δρmax = 0.94 e Å−3
  • Δρmin = −0.71 e Å−3

Data collection: SMART (Bruker, 2002 [triangle]); cell refinement: SAINT (Bruker, 2002 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: ORTEP-3 (Farrugia, 1997 [triangle]) and POV-RAY (Cason, 2002 [triangle]); software used to prepare material for publication: SHELXL97.

Table 1
Selected geometric parameters (Å, °)

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S160053680800319X/bh2154sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053680800319X/bh2154Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

We thank Dr Fred Hollander and Michael Pluth for assistance throughout the CHEM 208 course, as well as Professor Kenneth Raymond for teaching the course. We thank Preeyanuch Sangtrirutnugul for providing us with a sample.

supplementary crystallographic information

Comment

Five-coordinate platinum compounds have been speculated as intermediates in bond activation processes (Brown et al., 1974). During an attempt to synthesize such a stable five-coordinate platinum species via ligand abstraction of six-coordinate platinum precursor, we obtained the title complex (I). We assume that dimerization occurred after ligand abstraction, thereby yielding a dinuclear cationic complex. In the cation, both crystallographically independent PtIV ions display a coordination geometry close to octahedral, while Si atoms, as expected, are tetrahedrally bonded to two quinoline ligands, one methyl group, and one PtIV ion (Fig. 1). In the crystal, voids between cations and anions are partially filled with solvent molecules, giving a 0.66 dichloromethane solvate crystal (Fig. 2).

Experimental

Compound (I) was synthesized by addition of lithium tetrakis(perfluorophenyl)borate to a solution of the parent six-coordinate monomer in dichloromethane. X-ray quality single crystals were obtained by vapor diffusion of pentane into dichloromethane.

Refinement

Structure refinement was conducted using least-squares analysis. Thermal parameters for all atoms except H were refined anisotropically. Solvent occupancy was allowed to refine with Uiso fixed and subsequently fixed at 0.66 during anisotropic refinement. H atoms were placed in calculated positions, and refined using a riding approximation, with C—H bond lengths constrained to 0.93 (aromatic CH), 0.97 (methylene CH2) or 0.96 Å (methyl CH3), and Uiso(H) = 1.2 Ueq(carrier C) for aromatic CH and methylene CH2 groups, and Uiso(H) = 1.5 Ueq(carrier C) for methyl groups. In order to get accurate torsion angles, methyl groups were allowed to rotate about their C—C bonds.

Figures

Fig. 1.
ORTEP-3 diagram of compound (I). H atoms are omitted for clarity.
Fig. 2.
Packing diagram with co-crystallized dichloromethane shown as the space-filling model.

Crystal data

[Pt2(CH3)4(C19H15N2Si)2I](C24F20B)·0.66CH2Cl2Z = 2
Mr = 1911.14F000 = 1831.4
Triclinic, P1Dx = 1.921 Mg m3
Hall symbol: -P 1Mo Kα radiation λ = 0.71073 Å
a = 13.9051 (10) ÅCell parameters from 30538 reflections
b = 15.3559 (11) Åθ = 2.1–26.4º
c = 17.1261 (12) ŵ = 4.89 mm1
α = 71.930 (1)ºT = 167 (2) K
β = 72.045 (1)ºPrism, colourless
γ = 87.621 (1)º0.24 × 0.11 × 0.07 mm
V = 3301.3 (4) Å3

Data collection

Bruker APEX CCD diffractometer13293 independent reflections
Monochromator: graphite11270 reflections with I > 2σ(I)
T = 167(2) KRint = 0.020
P = 101(1) kPaθmax = 26.4º
ω scansθmin = 2.1º
Absorption correction: multi-scan(SADABS; Bruker, 2002)h = −11→17
Tmin = 0.530, Tmax = 0.710k = −19→19
30538 measured reflectionsl = −21→21

Refinement

Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.025H-atom parameters constrained
wR(F2) = 0.065  w = 1/[σ2(Fo2) + (0.0365P)2] where P = (Fo2 + 2Fc2)/3
S = 1.08(Δ/σ)max = 0.003
13293 reflectionsΔρmax = 0.95 e Å3
898 parametersΔρmin = −0.71 e Å3
Primary atom site location: structure-invariant direct methodsExtinction correction: none

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/UeqOcc. (<1)
C10.5927 (3)0.8330 (2)0.1569 (2)0.0282 (8)
H1A0.54900.86330.19160.034*
C20.6658 (3)0.8859 (2)0.0819 (3)0.0326 (9)
H2A0.66970.94950.06750.039*
C30.7308 (3)0.8432 (3)0.0304 (2)0.0304 (8)
H3A0.78040.8774−0.01920.036*
C40.7227 (3)0.7460 (2)0.0527 (2)0.0246 (8)
C50.7887 (3)0.6975 (3)0.0026 (3)0.0300 (8)
H5A0.83970.7291−0.04730.036*
C60.7776 (3)0.6041 (3)0.0275 (3)0.0316 (9)
H6A0.82190.5721−0.00500.038*
C70.7005 (3)0.5562 (3)0.1013 (2)0.0296 (8)
H7A0.69350.49260.11610.035*
C80.6344 (3)0.6000 (2)0.1528 (2)0.0250 (8)
C90.6462 (3)0.6969 (2)0.1286 (2)0.0222 (7)
C100.2819 (3)0.7299 (3)0.2598 (3)0.0356 (9)
H10A0.28870.77200.28710.043*
C110.1989 (3)0.7348 (3)0.2287 (3)0.0427 (11)
H11A0.15210.77900.23540.051*
C120.1883 (3)0.6733 (3)0.1885 (3)0.0419 (10)
H12A0.13420.67610.16680.050*
C130.2582 (3)0.6064 (3)0.1796 (3)0.0331 (9)
C140.2521 (4)0.5407 (3)0.1388 (3)0.0450 (11)
H14A0.19920.54100.11630.054*
C150.3226 (4)0.4770 (3)0.1321 (3)0.0472 (12)
H15A0.31810.43480.10430.057*
C160.4021 (3)0.4748 (3)0.1671 (3)0.0363 (9)
H16A0.44880.43000.16290.044*
C170.4129 (3)0.5371 (2)0.2074 (2)0.0293 (8)
C180.3408 (3)0.6045 (2)0.2129 (2)0.0281 (8)
C190.5971 (3)0.6374 (3)0.3545 (3)0.0363 (9)
H19A0.62750.58180.34800.054*
H19B0.57260.63250.41470.054*
H19C0.64650.68810.32410.054*
C200.3865 (3)0.5713 (3)0.4192 (3)0.0419 (10)
H20A0.33390.54270.40850.063*
H20B0.35690.60550.45820.063*
H20C0.42620.52490.44450.063*
C210.5518 (3)0.4274 (3)0.3099 (3)0.0398 (10)
H21A0.57440.39070.27220.060*
H21B0.49190.39810.35580.060*
H21C0.60400.43400.33390.060*
C220.3632 (3)0.9755 (3)0.4990 (2)0.0310 (8)
H22A0.37460.91490.50070.037*
C230.3762 (3)1.0041 (3)0.5660 (3)0.0357 (9)
H23A0.39410.96280.61120.043*
C240.3623 (3)1.0924 (3)0.5636 (3)0.0406 (10)
H24A0.37281.11270.60630.049*
C250.3319 (3)1.1539 (3)0.4965 (3)0.0340 (9)
C260.3132 (3)1.2469 (3)0.4902 (3)0.0479 (12)
H26A0.32211.27020.53180.057*
C270.2829 (4)1.3021 (3)0.4252 (3)0.0551 (13)
H27A0.27301.36340.42130.066*
C280.2659 (3)1.2677 (3)0.3629 (3)0.0419 (10)
H28A0.24391.30650.31880.050*
C290.2817 (3)1.1761 (3)0.3663 (3)0.0306 (9)
C300.3170 (3)1.1201 (3)0.4323 (2)0.0295 (8)
C310.1589 (3)0.8372 (2)0.4373 (2)0.0303 (8)
H31A0.21320.80160.44450.036*
C320.0610 (3)0.7944 (3)0.4749 (3)0.0364 (9)
H32A0.05140.73220.50600.044*
C33−0.0188 (3)0.8446 (3)0.4653 (3)0.0353 (9)
H33A−0.08390.81700.48860.042*
C34−0.0029 (3)0.9392 (2)0.4198 (2)0.0271 (8)
C35−0.0832 (3)0.9962 (3)0.4075 (3)0.0328 (9)
H35A−0.14950.97100.43040.039*
C36−0.0648 (3)1.0870 (3)0.3630 (3)0.0370 (10)
H36A−0.11811.12380.35550.044*
C370.0360 (3)1.1255 (3)0.3280 (3)0.0341 (9)
H37A0.04761.18790.29790.041*
C380.1173 (3)1.0737 (2)0.3371 (2)0.0250 (8)
C390.0981 (3)0.9787 (2)0.3836 (2)0.0228 (7)
C400.4696 (3)1.0604 (3)0.2528 (3)0.0361 (9)
H40A0.47161.11660.26600.054*
H40B0.47911.07410.19220.054*
H40C0.52261.02330.26760.054*
C410.3279 (3)0.9685 (3)0.2114 (2)0.0318 (9)
H41A0.34171.02580.16540.048*
H41B0.26210.94300.22010.048*
H41C0.37820.92660.19650.048*
C420.2777 (4)1.2036 (3)0.1814 (3)0.0450 (11)
H42A0.23191.25200.18280.068*
H42B0.26831.17230.14350.068*
H42C0.34621.22910.16090.068*
C430.7438 (3)0.2082 (2)0.0728 (2)0.0231 (7)
C440.7338 (3)0.1558 (2)0.0219 (2)0.0270 (8)
C450.6554 (3)0.1602 (3)−0.0123 (2)0.0312 (9)
C460.5817 (3)0.2207 (3)0.0014 (3)0.0339 (9)
C470.5896 (3)0.2774 (2)0.0480 (2)0.0299 (8)
C480.6680 (3)0.2697 (2)0.0821 (2)0.0246 (8)
C490.9330 (3)0.2601 (2)0.0168 (2)0.0221 (7)
C501.0032 (3)0.2259 (2)−0.0421 (2)0.0256 (8)
C511.0698 (3)0.2809 (3)−0.1188 (2)0.0266 (8)
C521.0678 (3)0.3745 (3)−0.1411 (2)0.0292 (8)
C530.9984 (3)0.4116 (2)−0.0859 (2)0.0273 (8)
C540.9335 (3)0.3553 (2)−0.0105 (2)0.0245 (8)
C550.8299 (3)0.2420 (2)0.1879 (2)0.0223 (7)
C560.9035 (3)0.2909 (2)0.1992 (2)0.0245 (8)
C570.8893 (3)0.3211 (2)0.2696 (2)0.0284 (8)
C580.7979 (3)0.3032 (2)0.3339 (2)0.0313 (9)
C590.7230 (3)0.2533 (2)0.3277 (2)0.0292 (8)
C600.7413 (3)0.2234 (2)0.2565 (2)0.0254 (8)
C610.8718 (3)0.0923 (2)0.1483 (2)0.0231 (7)
C620.9665 (3)0.0714 (2)0.1555 (2)0.0249 (8)
C630.9933 (3)−0.0154 (3)0.1944 (3)0.0298 (9)
C640.9221 (3)−0.0866 (2)0.2319 (2)0.0305 (9)
C650.8251 (3)−0.0704 (2)0.2285 (2)0.0281 (8)
C660.8022 (3)0.0170 (2)0.1872 (2)0.0248 (8)
C67−0.0752 (11)0.5150 (8)0.4112 (9)0.122 (4)0.66
H67A−0.11260.49090.38230.147*0.66
H67B−0.10820.48960.47300.147*0.66
N10.5823 (2)0.74187 (18)0.18139 (18)0.0220 (6)
N20.3514 (2)0.66832 (19)0.25244 (19)0.0261 (7)
N30.3360 (2)1.0299 (2)0.43409 (19)0.0253 (7)
N40.1783 (2)0.92465 (19)0.39265 (18)0.0232 (6)
B10.8452 (3)0.2007 (3)0.1062 (3)0.0231 (8)
Cl10.0568 (4)0.4763 (3)0.3846 (3)0.1616 (17)0.66
Cl2−0.0800 (3)0.6230 (2)0.3838 (2)0.1332 (14)0.66
F10.80500 (17)0.09582 (14)0.00363 (14)0.0345 (5)
F20.65082 (19)0.10489 (16)−0.05899 (16)0.0464 (6)
F30.50501 (19)0.22623 (18)−0.03129 (17)0.0510 (7)
F40.51852 (18)0.33806 (16)0.06101 (16)0.0429 (6)
F50.66725 (16)0.32833 (13)0.12742 (14)0.0308 (5)
F61.01229 (16)0.13451 (13)−0.02676 (14)0.0329 (5)
F71.13855 (17)0.24295 (16)−0.17102 (14)0.0390 (6)
F81.13372 (18)0.42857 (16)−0.21388 (14)0.0423 (6)
F90.99416 (18)0.50378 (14)−0.10509 (14)0.0404 (6)
F100.86536 (16)0.39738 (13)0.03881 (13)0.0302 (5)
F110.99707 (16)0.31049 (14)0.14062 (13)0.0294 (5)
F120.96573 (18)0.36638 (15)0.27686 (14)0.0392 (6)
F130.7830 (2)0.33331 (15)0.40263 (14)0.0443 (6)
F140.63277 (17)0.23398 (15)0.38999 (13)0.0387 (6)
F150.66365 (16)0.17265 (15)0.25679 (14)0.0328 (5)
F161.04155 (16)0.13871 (14)0.12469 (15)0.0335 (5)
F171.08923 (18)−0.02941 (15)0.19654 (17)0.0445 (6)
F180.9457 (2)−0.17045 (14)0.27213 (16)0.0462 (6)
F190.75214 (17)−0.13898 (14)0.26455 (14)0.0376 (5)
F200.70486 (16)0.02546 (13)0.18756 (14)0.0331 (5)
I10.430471 (19)0.815649 (18)0.374301 (16)0.03229 (7)
Pt10.478070 (11)0.658600 (9)0.304310 (9)0.02414 (4)
Pt20.331383 (10)0.990179 (9)0.322963 (8)0.02269 (4)
Si10.52290 (8)0.54261 (7)0.24778 (7)0.0265 (2)
Si20.25226 (8)1.12171 (7)0.29133 (6)0.0266 (2)

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
C10.030 (2)0.0266 (19)0.033 (2)0.0078 (16)−0.0137 (17)−0.0125 (16)
C20.038 (2)0.0187 (18)0.041 (2)−0.0007 (16)−0.0136 (19)−0.0070 (16)
C30.025 (2)0.032 (2)0.031 (2)−0.0043 (16)−0.0069 (17)−0.0069 (16)
C40.0215 (19)0.0306 (19)0.0257 (19)0.0018 (15)−0.0117 (16)−0.0103 (15)
C50.021 (2)0.039 (2)0.034 (2)0.0022 (16)−0.0084 (17)−0.0172 (17)
C60.025 (2)0.041 (2)0.038 (2)0.0112 (17)−0.0107 (18)−0.0243 (19)
C70.026 (2)0.0279 (19)0.037 (2)0.0045 (16)−0.0079 (17)−0.0150 (17)
C80.023 (2)0.0248 (18)0.030 (2)0.0029 (15)−0.0096 (16)−0.0106 (15)
C90.0219 (19)0.0233 (17)0.0265 (18)0.0042 (14)−0.0135 (15)−0.0091 (14)
C100.028 (2)0.038 (2)0.049 (3)0.0072 (18)−0.0157 (19)−0.0207 (19)
C110.029 (2)0.042 (2)0.062 (3)0.0119 (19)−0.020 (2)−0.017 (2)
C120.030 (2)0.046 (3)0.057 (3)0.0048 (19)−0.024 (2)−0.016 (2)
C130.027 (2)0.033 (2)0.041 (2)−0.0037 (17)−0.0148 (19)−0.0089 (18)
C140.046 (3)0.044 (3)0.056 (3)−0.006 (2)−0.030 (2)−0.017 (2)
C150.056 (3)0.039 (2)0.063 (3)0.000 (2)−0.032 (3)−0.025 (2)
C160.037 (2)0.028 (2)0.047 (3)0.0009 (18)−0.015 (2)−0.0143 (18)
C170.025 (2)0.0246 (18)0.035 (2)−0.0016 (15)−0.0071 (17)−0.0070 (16)
C180.024 (2)0.0255 (18)0.032 (2)−0.0060 (15)−0.0071 (17)−0.0061 (16)
C190.036 (2)0.039 (2)0.041 (2)0.0079 (19)−0.023 (2)−0.0129 (19)
C200.041 (3)0.045 (2)0.033 (2)0.001 (2)−0.006 (2)−0.0075 (19)
C210.043 (3)0.027 (2)0.044 (2)0.0059 (18)−0.014 (2)−0.0039 (18)
C220.025 (2)0.041 (2)0.028 (2)0.0012 (17)−0.0071 (17)−0.0132 (17)
C230.025 (2)0.057 (3)0.026 (2)−0.0005 (19)−0.0082 (17)−0.0142 (19)
C240.023 (2)0.071 (3)0.037 (2)−0.005 (2)−0.0051 (18)−0.032 (2)
C250.023 (2)0.046 (2)0.035 (2)−0.0100 (18)−0.0017 (17)−0.0210 (19)
C260.045 (3)0.051 (3)0.055 (3)−0.011 (2)−0.009 (2)−0.032 (2)
C270.061 (3)0.037 (2)0.070 (4)−0.006 (2)−0.012 (3)−0.029 (2)
C280.044 (3)0.028 (2)0.047 (3)−0.0074 (19)−0.007 (2)−0.0069 (19)
C290.019 (2)0.034 (2)0.035 (2)−0.0111 (16)0.0020 (17)−0.0158 (17)
C300.0191 (19)0.037 (2)0.030 (2)−0.0086 (16)0.0017 (16)−0.0160 (17)
C310.028 (2)0.0264 (19)0.034 (2)0.0035 (16)−0.0057 (17)−0.0099 (16)
C320.028 (2)0.027 (2)0.041 (2)−0.0037 (17)0.0011 (19)−0.0039 (17)
C330.024 (2)0.036 (2)0.037 (2)−0.0094 (17)0.0018 (18)−0.0098 (18)
C340.023 (2)0.033 (2)0.0257 (19)0.0006 (16)−0.0065 (16)−0.0115 (16)
C350.0159 (19)0.047 (2)0.036 (2)0.0026 (17)−0.0062 (17)−0.0152 (19)
C360.026 (2)0.042 (2)0.042 (2)0.0094 (18)−0.0118 (19)−0.0117 (19)
C370.035 (2)0.032 (2)0.035 (2)0.0048 (18)−0.0134 (19)−0.0078 (17)
C380.023 (2)0.0305 (19)0.0222 (18)0.0027 (15)−0.0082 (15)−0.0082 (15)
C390.0232 (19)0.0260 (18)0.0190 (17)0.0010 (15)−0.0055 (15)−0.0076 (14)
C400.023 (2)0.050 (2)0.033 (2)−0.0066 (18)−0.0069 (18)−0.0100 (19)
C410.033 (2)0.040 (2)0.030 (2)0.0048 (18)−0.0141 (18)−0.0167 (17)
C420.051 (3)0.041 (2)0.034 (2)−0.003 (2)−0.011 (2)−0.0003 (19)
C430.0203 (19)0.0215 (17)0.0249 (18)−0.0007 (14)−0.0063 (15)−0.0041 (14)
C440.028 (2)0.0244 (18)0.029 (2)0.0018 (15)−0.0063 (17)−0.0106 (15)
C450.039 (2)0.031 (2)0.029 (2)−0.0019 (17)−0.0135 (18)−0.0128 (16)
C460.032 (2)0.041 (2)0.032 (2)−0.0040 (18)−0.0189 (18)−0.0066 (17)
C470.027 (2)0.031 (2)0.031 (2)0.0049 (16)−0.0101 (17)−0.0070 (16)
C480.027 (2)0.0216 (17)0.0259 (19)−0.0005 (15)−0.0079 (16)−0.0087 (14)
C490.0234 (19)0.0218 (17)0.0244 (18)−0.0006 (14)−0.0113 (15)−0.0079 (14)
C500.027 (2)0.0264 (18)0.030 (2)0.0014 (15)−0.0126 (17)−0.0142 (15)
C510.023 (2)0.036 (2)0.0249 (19)0.0027 (16)−0.0082 (16)−0.0150 (16)
C520.027 (2)0.038 (2)0.0196 (18)−0.0052 (17)−0.0067 (16)−0.0050 (16)
C530.030 (2)0.0235 (18)0.030 (2)0.0014 (16)−0.0147 (17)−0.0064 (15)
C540.024 (2)0.0263 (18)0.0263 (19)0.0054 (15)−0.0099 (16)−0.0111 (15)
C550.0236 (19)0.0178 (16)0.0267 (19)0.0062 (14)−0.0102 (16)−0.0069 (14)
C560.026 (2)0.0209 (17)0.0268 (19)0.0061 (15)−0.0090 (16)−0.0068 (14)
C570.034 (2)0.0236 (18)0.035 (2)0.0036 (16)−0.0185 (18)−0.0124 (16)
C580.050 (3)0.0279 (19)0.0225 (19)0.0107 (18)−0.0155 (19)−0.0140 (16)
C590.037 (2)0.0258 (18)0.0197 (18)0.0090 (17)−0.0048 (17)−0.0047 (15)
C600.026 (2)0.0230 (18)0.0276 (19)0.0065 (15)−0.0106 (16)−0.0066 (15)
C610.027 (2)0.0216 (17)0.0232 (18)0.0035 (15)−0.0068 (15)−0.0109 (14)
C620.024 (2)0.0241 (18)0.0297 (19)0.0009 (15)−0.0084 (16)−0.0131 (15)
C630.029 (2)0.033 (2)0.040 (2)0.0115 (17)−0.0191 (18)−0.0206 (17)
C640.041 (2)0.0207 (18)0.033 (2)0.0080 (17)−0.0154 (19)−0.0089 (15)
C650.031 (2)0.0205 (18)0.029 (2)−0.0015 (15)−0.0021 (17)−0.0092 (15)
C660.022 (2)0.0254 (18)0.0288 (19)0.0053 (15)−0.0064 (16)−0.0134 (15)
C670.143 (13)0.089 (8)0.153 (12)−0.002 (8)−0.070 (10)−0.036 (8)
N10.0207 (16)0.0228 (15)0.0270 (16)0.0059 (12)−0.0123 (13)−0.0095 (12)
N20.0222 (17)0.0270 (16)0.0294 (17)0.0026 (13)−0.0087 (14)−0.0089 (13)
N30.0203 (16)0.0320 (16)0.0239 (16)−0.0031 (13)−0.0038 (13)−0.0114 (13)
N40.0196 (16)0.0273 (15)0.0239 (15)0.0021 (12)−0.0068 (13)−0.0098 (12)
B10.022 (2)0.0231 (19)0.026 (2)0.0051 (16)−0.0076 (18)−0.0109 (16)
Cl10.230 (5)0.125 (3)0.132 (3)−0.012 (3)−0.052 (3)−0.046 (3)
Cl20.227 (4)0.0683 (17)0.109 (2)0.004 (2)−0.059 (3)−0.0270 (17)
F10.0365 (13)0.0351 (12)0.0415 (13)0.0090 (10)−0.0138 (11)−0.0243 (10)
F20.0575 (17)0.0516 (15)0.0496 (15)0.0035 (13)−0.0287 (13)−0.0308 (12)
F30.0483 (16)0.0623 (17)0.0609 (17)0.0088 (13)−0.0394 (14)−0.0230 (14)
F40.0345 (14)0.0459 (14)0.0552 (15)0.0181 (11)−0.0223 (12)−0.0193 (12)
F50.0315 (12)0.0289 (11)0.0412 (13)0.0090 (9)−0.0164 (10)−0.0197 (10)
F60.0344 (13)0.0274 (11)0.0356 (12)0.0053 (10)−0.0037 (10)−0.0156 (9)
F70.0351 (14)0.0508 (14)0.0324 (12)0.0082 (11)−0.0041 (10)−0.0218 (11)
F80.0413 (15)0.0462 (14)0.0259 (12)−0.0078 (11)−0.0004 (11)−0.0015 (10)
F90.0503 (16)0.0245 (11)0.0375 (13)−0.0016 (10)−0.0089 (11)−0.0014 (10)
F100.0314 (12)0.0259 (11)0.0321 (12)0.0082 (9)−0.0054 (10)−0.0125 (9)
F110.0254 (12)0.0312 (11)0.0338 (12)−0.0026 (9)−0.0078 (10)−0.0141 (9)
F120.0512 (16)0.0380 (13)0.0384 (13)−0.0025 (11)−0.0218 (12)−0.0174 (11)
F130.0676 (18)0.0432 (14)0.0308 (13)0.0115 (12)−0.0183 (12)−0.0215 (11)
F140.0389 (14)0.0422 (13)0.0259 (12)0.0090 (11)0.0002 (10)−0.0092 (10)
F150.0253 (12)0.0407 (13)0.0308 (12)−0.0036 (10)−0.0047 (10)−0.0122 (10)
F160.0258 (12)0.0298 (11)0.0483 (14)0.0018 (9)−0.0151 (11)−0.0133 (10)
F170.0377 (14)0.0392 (13)0.0698 (17)0.0144 (11)−0.0332 (13)−0.0204 (12)
F180.0625 (17)0.0247 (12)0.0569 (16)0.0114 (11)−0.0330 (14)−0.0071 (11)
F190.0394 (14)0.0227 (11)0.0410 (13)−0.0037 (10)−0.0002 (11)−0.0082 (10)
F200.0224 (12)0.0244 (11)0.0470 (14)0.0016 (9)−0.0054 (10)−0.0091 (10)
I10.02772 (14)0.04357 (15)0.03540 (14)0.01162 (11)−0.01362 (11)−0.02336 (12)
Pt10.02348 (8)0.02635 (8)0.02421 (8)0.00427 (6)−0.00920 (6)−0.00873 (6)
Pt20.01752 (8)0.03071 (8)0.02077 (7)−0.00020 (6)−0.00455 (6)−0.01054 (6)
Si10.0257 (6)0.0216 (5)0.0317 (6)0.0034 (4)−0.0097 (5)−0.0072 (4)
Si20.0246 (6)0.0280 (5)0.0243 (5)−0.0037 (4)−0.0058 (4)−0.0054 (4)

Geometric parameters (Å, °)

C1—N11.331 (4)C36—H36A0.9300
C1—C21.399 (5)C37—C381.375 (5)
C1—H1A0.9300C37—H37A0.9300
C2—C31.357 (5)C38—C391.419 (5)
C2—H2A0.9300C38—Si21.879 (4)
C3—C41.421 (5)C39—N41.380 (4)
C3—H3A0.9300C40—Pt22.060 (4)
C4—C51.409 (5)C40—H40A0.9600
C4—C91.413 (5)C40—H40B0.9600
C5—C61.364 (5)C40—H40C0.9600
C5—H5A0.9300C41—Pt22.054 (3)
C6—C71.393 (5)C41—H41A0.9600
C6—H6A0.9300C41—H41B0.9600
C7—C81.376 (5)C41—H41C0.9600
C7—H7A0.9300C42—Si21.846 (4)
C8—C91.418 (5)C42—H42A0.9600
C8—Si11.870 (4)C42—H42B0.9600
C9—N11.387 (4)C42—H42C0.9600
C10—N21.328 (5)C43—C481.391 (5)
C10—C111.403 (6)C43—C441.395 (5)
C10—H10A0.9300C43—B11.664 (5)
C11—C121.366 (6)C44—F11.355 (4)
C11—H11A0.9300C44—C451.379 (5)
C12—C131.395 (6)C45—F21.349 (4)
C12—H12A0.9300C45—C461.371 (5)
C13—C141.412 (6)C46—F31.337 (4)
C13—C181.427 (5)C46—C471.378 (5)
C14—C151.360 (6)C47—F41.346 (4)
C14—H14A0.9300C47—C481.373 (5)
C15—C161.406 (6)C48—F51.357 (4)
C15—H15A0.9300C49—C501.387 (5)
C16—C171.380 (5)C49—C541.388 (5)
C16—H16A0.9300C49—B11.656 (5)
C17—C181.414 (5)C50—F61.354 (4)
C17—Si11.877 (4)C50—C511.387 (5)
C18—N21.387 (4)C51—F71.342 (4)
C19—Pt12.059 (4)C51—C521.370 (5)
C19—H19A0.9600C52—F81.342 (4)
C19—H19B0.9600C52—C531.369 (5)
C19—H19C0.9600C53—F91.354 (4)
C20—Pt12.062 (4)C53—C541.372 (5)
C20—H20A0.9600C54—F101.351 (4)
C20—H20B0.9600C55—C601.381 (5)
C20—H20C0.9600C55—C561.387 (5)
C21—Si11.860 (4)C55—B11.663 (5)
C21—H21A0.9600C56—F111.353 (4)
C21—H21B0.9600C56—C571.378 (5)
C21—H21C0.9600C57—F121.350 (4)
C22—N31.316 (5)C57—C581.372 (5)
C22—C231.411 (5)C58—F131.350 (4)
C22—H22A0.9300C58—C591.367 (6)
C23—C241.352 (6)C59—F141.345 (4)
C23—H23A0.9300C59—C601.381 (5)
C24—C251.408 (6)C60—F151.355 (4)
C24—H24A0.9300C61—C621.376 (5)
C25—C261.418 (6)C61—C661.391 (5)
C25—C301.422 (5)C61—B11.673 (5)
C26—C271.346 (7)C62—F161.359 (4)
C26—H26A0.9300C62—C631.385 (5)
C27—C281.410 (6)C63—F171.353 (4)
C27—H27A0.9300C63—C641.361 (5)
C28—C291.400 (5)C64—F181.339 (4)
C28—H28A0.9300C64—C651.376 (5)
C29—C301.402 (6)C65—F191.349 (4)
C29—Si21.879 (4)C65—C661.385 (5)
C30—N31.393 (5)C66—F201.352 (4)
C31—N41.314 (4)C67—Cl21.582 (11)
C31—C321.404 (5)C67—Cl11.869 (14)
C31—H31A0.9300C67—H67A0.9700
C32—C331.347 (5)C67—H67B0.9700
C32—H32A0.9300N1—Pt12.184 (3)
C33—C341.409 (5)N2—Pt12.186 (3)
C33—H33A0.9300N3—Pt22.190 (3)
C34—C351.416 (5)N4—Pt22.199 (3)
C34—C391.424 (5)I1—Pt22.9720 (3)
C35—C361.357 (6)I1—Pt12.9770 (3)
C35—H35A0.9300Pt1—Si12.2591 (10)
C36—C371.415 (6)Pt2—Si22.2556 (10)
N1—C1—C2123.7 (3)H42A—C42—H42C109.5
N1—C1—H1A118.1H42B—C42—H42C109.5
C2—C1—H1A118.1C48—C43—C44112.5 (3)
C3—C2—C1119.2 (3)C48—C43—B1127.1 (3)
C3—C2—H2A120.4C44—C43—B1120.1 (3)
C1—C2—H2A120.4F1—C44—C45116.2 (3)
C2—C3—C4119.6 (4)F1—C44—C43119.2 (3)
C2—C3—H3A120.2C45—C44—C43124.6 (3)
C4—C3—H3A120.2F2—C45—C46119.9 (3)
C5—C4—C9119.4 (3)F2—C45—C44120.3 (3)
C5—C4—C3122.4 (3)C46—C45—C44119.8 (3)
C9—C4—C3118.2 (3)F3—C46—C45120.9 (3)
C6—C5—C4119.7 (4)F3—C46—C47120.6 (4)
C6—C5—H5A120.1C45—C46—C47118.5 (3)
C4—C5—H5A120.1F4—C47—C48121.0 (3)
C5—C6—C7120.7 (3)F4—C47—C46119.2 (3)
C5—C6—H6A119.7C48—C47—C46119.7 (3)
C7—C6—H6A119.7F5—C48—C47114.4 (3)
C8—C7—C6122.0 (3)F5—C48—C43120.7 (3)
C8—C7—H7A119.0C47—C48—C43124.9 (3)
C6—C7—H7A119.0C50—C49—C54113.0 (3)
C7—C8—C9118.0 (3)C50—C49—B1127.2 (3)
C7—C8—Si1125.0 (3)C54—C49—B1119.4 (3)
C9—C8—Si1116.8 (3)F6—C50—C49121.2 (3)
N1—C9—C4121.1 (3)F6—C50—C51115.1 (3)
N1—C9—C8118.7 (3)C49—C50—C51123.7 (3)
C4—C9—C8120.2 (3)F7—C51—C52119.3 (3)
N2—C10—C11123.6 (4)F7—C51—C50120.4 (3)
N2—C10—H10A118.2C52—C51—C50120.3 (3)
C11—C10—H10A118.2F8—C52—C53120.8 (3)
C12—C11—C10118.7 (4)F8—C52—C51121.0 (3)
C12—C11—H11A120.7C53—C52—C51118.2 (3)
C10—C11—H11A120.7F9—C53—C52120.2 (3)
C11—C12—C13120.4 (4)F9—C53—C54119.8 (3)
C11—C12—H12A119.8C52—C53—C54120.0 (3)
C13—C12—H12A119.8F10—C54—C53116.1 (3)
C12—C13—C14123.5 (4)F10—C54—C49119.1 (3)
C12—C13—C18118.4 (4)C53—C54—C49124.7 (3)
C14—C13—C18118.1 (4)C60—C55—C56112.9 (3)
C15—C14—C13120.9 (4)C60—C55—B1121.3 (3)
C15—C14—H14A119.5C56—C55—B1125.6 (3)
C13—C14—H14A119.5F11—C56—C57115.1 (3)
C14—C15—C16120.2 (4)F11—C56—C55120.8 (3)
C14—C15—H15A119.9C57—C56—C55124.0 (3)
C16—C15—H15A119.9F12—C57—C58119.6 (3)
C17—C16—C15121.9 (4)F12—C57—C56120.5 (3)
C17—C16—H16A119.1C58—C57—C56119.9 (3)
C15—C16—H16A119.1F13—C58—C59120.7 (4)
C16—C17—C18117.9 (4)F13—C58—C57120.3 (4)
C16—C17—Si1123.5 (3)C59—C58—C57118.9 (3)
C18—C17—Si1118.4 (3)F14—C59—C58120.3 (3)
N2—C18—C17118.5 (3)F14—C59—C60120.7 (4)
N2—C18—C13120.5 (3)C58—C59—C60119.0 (4)
C17—C18—C13120.9 (3)F15—C60—C59115.0 (3)
Pt1—C19—H19A109.5F15—C60—C55119.9 (3)
Pt1—C19—H19B109.5C59—C60—C55125.1 (4)
H19A—C19—H19B109.5C62—C61—C66113.1 (3)
Pt1—C19—H19C109.5C62—C61—B1121.0 (3)
H19A—C19—H19C109.5C66—C61—B1125.6 (3)
H19B—C19—H19C109.5F16—C62—C61120.1 (3)
Pt1—C20—H20A109.5F16—C62—C63115.1 (3)
Pt1—C20—H20B109.5C61—C62—C63124.8 (3)
H20A—C20—H20B109.5F17—C63—C64119.8 (3)
Pt1—C20—H20C109.5F17—C63—C62120.4 (3)
H20A—C20—H20C109.5C64—C63—C62119.7 (3)
H20B—C20—H20C109.5F18—C64—C63120.6 (4)
Si1—C21—H21A109.5F18—C64—C65120.8 (4)
Si1—C21—H21B109.5C63—C64—C65118.5 (3)
H21A—C21—H21B109.5F19—C65—C64120.6 (3)
Si1—C21—H21C109.5F19—C65—C66119.5 (3)
H21A—C21—H21C109.5C64—C65—C66119.9 (3)
H21B—C21—H21C109.5F20—C66—C65115.1 (3)
N3—C22—C23123.6 (4)F20—C66—C61121.0 (3)
N3—C22—H22A118.2C65—C66—C61123.9 (3)
C23—C22—H22A118.2Cl2—C67—Cl1113.3 (8)
C24—C23—C22119.1 (4)Cl2—C67—H67A108.9
C24—C23—H23A120.5Cl1—C67—H67A108.9
C22—C23—H23A120.5Cl2—C67—H67B108.9
C23—C24—C25120.2 (4)Cl1—C67—H67B108.9
C23—C24—H24A119.9H67A—C67—H67B107.7
C25—C24—H24A119.9C1—N1—C9118.1 (3)
C24—C25—C26123.8 (4)C1—N1—Pt1123.7 (2)
C24—C25—C30118.0 (4)C9—N1—Pt1118.1 (2)
C26—C25—C30118.1 (4)C10—N2—C18118.4 (3)
C27—C26—C25121.2 (4)C10—N2—Pt1123.4 (3)
C27—C26—H26A119.4C18—N2—Pt1118.2 (2)
C25—C26—H26A119.4C22—N3—C30118.3 (3)
C26—C27—C28120.5 (4)C22—N3—Pt2123.7 (2)
C26—C27—H27A119.8C30—N3—Pt2117.8 (2)
C28—C27—H27A119.8C31—N4—C39118.7 (3)
C29—C28—C27121.0 (4)C31—N4—Pt2124.3 (2)
C29—C28—H28A119.5C39—N4—Pt2116.9 (2)
C27—C28—H28A119.5C49—B1—C55113.0 (3)
C28—C29—C30118.1 (4)C49—B1—C43101.6 (3)
C28—C29—Si2124.2 (3)C55—B1—C43113.4 (3)
C30—C29—Si2117.7 (3)C49—B1—C61114.6 (3)
N3—C30—C29118.1 (3)C55—B1—C61101.8 (3)
N3—C30—C25120.8 (4)C43—B1—C61113.0 (3)
C29—C30—C25121.1 (4)Pt2—I1—Pt1133.755 (10)
N4—C31—C32123.8 (4)C19—Pt1—C2089.23 (18)
N4—C31—H31A118.1C19—Pt1—N188.67 (14)
C32—C31—H31A118.1C20—Pt1—N1175.45 (14)
C33—C32—C31119.2 (4)C19—Pt1—N2175.02 (13)
C33—C32—H32A120.4C20—Pt1—N288.42 (15)
C31—C32—H32A120.4N1—Pt1—N293.36 (11)
C32—C33—C34119.6 (4)C19—Pt1—Si190.71 (11)
C32—C33—H33A120.2C20—Pt1—Si192.18 (12)
C34—C33—H33A120.2N1—Pt1—Si183.81 (7)
C33—C34—C35122.7 (4)N2—Pt1—Si184.99 (8)
C33—C34—C39118.6 (3)C19—Pt1—I187.36 (11)
C35—C34—C39118.7 (3)C20—Pt1—I190.20 (12)
C36—C35—C34120.9 (4)N1—Pt1—I193.73 (7)
C36—C35—H35A119.5N2—Pt1—I197.04 (7)
C34—C35—H35A119.5Si1—Pt1—I1176.91 (3)
C35—C36—C37119.7 (4)C41—Pt2—C4087.51 (16)
C35—C36—H36A120.1C41—Pt2—N3173.53 (13)
C37—C36—H36A120.1C40—Pt2—N389.24 (14)
C38—C37—C36122.2 (4)C41—Pt2—N491.29 (14)
C38—C37—H37A118.9C40—Pt2—N4175.47 (14)
C36—C37—H37A118.9N3—Pt2—N491.53 (10)
C37—C38—C39118.2 (3)C41—Pt2—Si290.71 (11)
C37—C38—Si2123.6 (3)C40—Pt2—Si290.25 (12)
C39—C38—Si2118.2 (3)N3—Pt2—Si283.72 (8)
N4—C39—C38119.5 (3)N4—Pt2—Si285.39 (8)
N4—C39—C34120.2 (3)C41—Pt2—I191.84 (11)
C38—C39—C34120.3 (3)C40—Pt2—I191.38 (12)
Pt2—C40—H40A109.5N3—Pt2—I193.82 (8)
Pt2—C40—H40B109.5N4—Pt2—I193.03 (7)
H40A—C40—H40B109.5Si2—Pt2—I1177.03 (3)
Pt2—C40—H40C109.5C21—Si1—C8111.53 (18)
H40A—C40—H40C109.5C21—Si1—C17112.32 (18)
H40B—C40—H40C109.5C8—Si1—C17108.13 (16)
Pt2—C41—H41A109.5C21—Si1—Pt1123.55 (14)
Pt2—C41—H41B109.5C8—Si1—Pt1100.08 (11)
H41A—C41—H41B109.5C17—Si1—Pt199.61 (12)
Pt2—C41—H41C109.5C42—Si2—C38111.40 (19)
H41A—C41—H41C109.5C42—Si2—C29111.50 (19)
H41B—C41—H41C109.5C38—Si2—C29109.66 (16)
Si2—C42—H42A109.5C42—Si2—Pt2124.05 (15)
Si2—C42—H42B109.5C38—Si2—Pt299.38 (11)
H42A—C42—H42B109.5C29—Si2—Pt299.48 (13)
Si2—C42—H42C109.5
N1—C1—C2—C3−0.3 (6)F17—C63—C64—F181.0 (5)
C1—C2—C3—C41.0 (6)C62—C63—C64—F18−178.0 (3)
C2—C3—C4—C5−179.1 (4)F17—C63—C64—C65−179.8 (3)
C2—C3—C4—C90.0 (5)C62—C63—C64—C651.2 (5)
C9—C4—C5—C60.5 (5)F18—C64—C65—F19−1.1 (5)
C3—C4—C5—C6179.6 (3)C63—C64—C65—F19179.8 (3)
C4—C5—C6—C71.1 (6)F18—C64—C65—C66179.5 (3)
C5—C6—C7—C8−1.5 (6)C63—C64—C65—C660.4 (5)
C6—C7—C8—C90.3 (6)F19—C65—C66—F200.6 (5)
C6—C7—C8—Si1175.0 (3)C64—C65—C66—F20180.0 (3)
C5—C4—C9—N1177.5 (3)F19—C65—C66—C61179.8 (3)
C3—C4—C9—N1−1.6 (5)C64—C65—C66—C61−0.8 (5)
C5—C4—C9—C8−1.8 (5)C62—C61—C66—F20178.8 (3)
C3—C4—C9—C8179.1 (3)B1—C61—C66—F205.5 (5)
C7—C8—C9—N1−177.9 (3)C62—C61—C66—C65−0.3 (5)
Si1—C8—C9—N16.9 (4)B1—C61—C66—C65−173.7 (3)
C7—C8—C9—C41.3 (5)C2—C1—N1—C9−1.3 (5)
Si1—C8—C9—C4−173.8 (3)C2—C1—N1—Pt1174.0 (3)
N2—C10—C11—C12−0.1 (7)C4—C9—N1—C12.3 (5)
C10—C11—C12—C130.8 (7)C8—C9—N1—C1−178.5 (3)
C11—C12—C13—C14180.0 (4)C4—C9—N1—Pt1−173.3 (2)
C11—C12—C13—C18−0.5 (7)C8—C9—N1—Pt16.0 (4)
C12—C13—C14—C15−180.0 (4)C11—C10—N2—C18−0.9 (6)
C18—C13—C14—C150.5 (7)C11—C10—N2—Pt1−178.2 (3)
C13—C14—C15—C161.0 (7)C17—C18—N2—C10−178.0 (3)
C14—C15—C16—C17−1.3 (7)C13—C18—N2—C101.2 (5)
C15—C16—C17—C180.0 (6)C17—C18—N2—Pt1−0.6 (4)
C15—C16—C17—Si1−175.3 (3)C13—C18—N2—Pt1178.6 (3)
C16—C17—C18—N2−179.3 (3)C23—C22—N3—C30−1.3 (5)
Si1—C17—C18—N2−3.8 (5)C23—C22—N3—Pt2173.2 (3)
C16—C17—C18—C131.5 (6)C29—C30—N3—C22−175.9 (3)
Si1—C17—C18—C13177.1 (3)C25—C30—N3—C223.2 (5)
C12—C13—C18—N2−0.5 (6)C29—C30—N3—Pt29.2 (4)
C14—C13—C18—N2179.0 (4)C25—C30—N3—Pt2−171.6 (3)
C12—C13—C18—C17178.7 (4)C32—C31—N4—C391.8 (5)
C14—C13—C18—C17−1.8 (6)C32—C31—N4—Pt2−173.9 (3)
N3—C22—C23—C24−1.5 (6)C38—C39—N4—C31178.7 (3)
C22—C23—C24—C252.1 (6)C34—C39—N4—C31−2.1 (5)
C23—C24—C25—C26178.4 (4)C38—C39—N4—Pt2−5.3 (4)
C23—C24—C25—C30−0.2 (6)C34—C39—N4—Pt2173.9 (2)
C24—C25—C26—C27−179.0 (4)C50—C49—B1—C55141.1 (3)
C30—C25—C26—C27−0.4 (7)C54—C49—B1—C55−46.3 (4)
C25—C26—C27—C281.9 (7)C50—C49—B1—C43−97.1 (4)
C26—C27—C28—C29−1.0 (7)C54—C49—B1—C4375.6 (4)
C27—C28—C29—C30−1.4 (6)C50—C49—B1—C6125.0 (5)
C27—C28—C29—Si2175.3 (3)C54—C49—B1—C61−162.4 (3)
C28—C29—C30—N3−177.9 (3)C60—C55—B1—C49158.0 (3)
Si2—C29—C30—N35.1 (5)C56—C55—B1—C49−27.3 (5)
C28—C29—C30—C253.0 (6)C60—C55—B1—C4343.1 (4)
Si2—C29—C30—C25−174.0 (3)C56—C55—B1—C43−142.3 (3)
C24—C25—C30—N3−2.5 (6)C60—C55—B1—C61−78.6 (4)
C26—C25—C30—N3178.8 (4)C56—C55—B1—C6196.1 (4)
C24—C25—C30—C29176.6 (4)C48—C43—B1—C49−97.3 (4)
C26—C25—C30—C29−2.1 (6)C44—C43—B1—C4975.6 (4)
N4—C31—C32—C330.0 (6)C48—C43—B1—C5524.3 (5)
C31—C32—C33—C34−1.5 (6)C44—C43—B1—C55−162.8 (3)
C32—C33—C34—C35−179.7 (4)C48—C43—B1—C61139.5 (3)
C32—C33—C34—C391.1 (6)C44—C43—B1—C61−47.6 (4)
C33—C34—C35—C36−179.8 (4)C62—C61—B1—C4944.8 (4)
C39—C34—C35—C36−0.6 (6)C66—C61—B1—C49−142.4 (3)
C34—C35—C36—C370.1 (6)C62—C61—B1—C55−77.6 (4)
C35—C36—C37—C380.3 (6)C66—C61—B1—C5595.3 (4)
C36—C37—C38—C39−0.3 (6)C62—C61—B1—C43160.4 (3)
C36—C37—C38—Si2179.6 (3)C66—C61—B1—C43−26.7 (5)
C37—C38—C39—N4178.9 (3)C1—N1—Pt1—C19−97.0 (3)
Si2—C38—C39—N4−1.0 (4)C9—N1—Pt1—C1978.3 (3)
C37—C38—C39—C34−0.2 (5)C1—N1—Pt1—N287.6 (3)
Si2—C38—C39—C34179.9 (3)C9—N1—Pt1—N2−97.1 (2)
C33—C34—C39—N40.7 (5)C1—N1—Pt1—Si1172.2 (3)
C35—C34—C39—N4−178.5 (3)C9—N1—Pt1—Si1−12.5 (2)
C33—C34—C39—C38179.9 (3)C1—N1—Pt1—I1−9.7 (3)
C35—C34—C39—C380.7 (5)C9—N1—Pt1—I1165.6 (2)
C48—C43—C44—F1176.9 (3)C10—N2—Pt1—C2088.5 (3)
B1—C43—C44—F13.1 (5)C18—N2—Pt1—C20−88.9 (3)
C48—C43—C44—C45−3.0 (5)C10—N2—Pt1—N1−95.7 (3)
B1—C43—C44—C45−176.8 (3)C18—N2—Pt1—N187.0 (3)
F1—C44—C45—F21.9 (5)C10—N2—Pt1—Si1−179.2 (3)
C43—C44—C45—F2−178.3 (3)C18—N2—Pt1—Si13.5 (3)
F1—C44—C45—C46−178.4 (3)C10—N2—Pt1—I1−1.5 (3)
C43—C44—C45—C461.5 (6)C18—N2—Pt1—I1−178.9 (2)
F2—C45—C46—F3−0.3 (6)Pt2—I1—Pt1—C19152.31 (12)
C44—C45—C46—F3179.9 (4)Pt2—I1—Pt1—C20−118.47 (13)
F2—C45—C46—C47−178.8 (3)Pt2—I1—Pt1—N163.82 (7)
C44—C45—C46—C471.4 (6)Pt2—I1—Pt1—N2−30.04 (8)
F3—C46—C47—F40.6 (6)C22—N3—Pt2—C40−99.6 (3)
C45—C46—C47—F4179.1 (3)C30—N3—Pt2—C4075.0 (3)
F3—C46—C47—C48179.0 (3)C22—N3—Pt2—N484.9 (3)
C45—C46—C47—C48−2.5 (6)C30—N3—Pt2—N4−100.6 (3)
F4—C47—C48—F5−1.0 (5)C22—N3—Pt2—Si2170.1 (3)
C46—C47—C48—F5−179.3 (3)C30—N3—Pt2—Si2−15.4 (2)
F4—C47—C48—C43179.1 (3)C22—N3—Pt2—I1−8.2 (3)
C46—C47—C48—C430.8 (6)C30—N3—Pt2—I1166.3 (2)
C44—C43—C48—F5−178.0 (3)C31—N4—Pt2—C4192.5 (3)
B1—C43—C48—F5−4.7 (6)C39—N4—Pt2—C41−83.2 (2)
C44—C43—C48—C471.8 (5)C39—N4—Pt2—N391.0 (2)
B1—C43—C48—C47175.1 (3)C31—N4—Pt2—Si2−176.9 (3)
C54—C49—C50—F6−179.1 (3)C39—N4—Pt2—Si27.4 (2)
B1—C49—C50—F6−6.0 (5)C31—N4—Pt2—I10.6 (3)
C54—C49—C50—C512.2 (5)C39—N4—Pt2—I1−175.1 (2)
B1—C49—C50—C51175.2 (3)Pt1—I1—Pt2—C41−7.74 (12)
F6—C50—C51—F7−1.5 (5)Pt1—I1—Pt2—C40−95.29 (11)
C49—C50—C51—F7177.3 (3)Pt1—I1—Pt2—N3175.38 (8)
F6—C50—C51—C52−179.9 (3)Pt1—I1—Pt2—N483.64 (7)
C49—C50—C51—C52−1.0 (6)C7—C8—Si1—C2138.2 (4)
F7—C51—C52—F8−0.4 (5)C9—C8—Si1—C21−147.0 (3)
C50—C51—C52—F8178.0 (3)C7—C8—Si1—C17−85.8 (3)
F7—C51—C52—C53−178.6 (3)C9—C8—Si1—C1789.0 (3)
C50—C51—C52—C53−0.3 (6)C7—C8—Si1—Pt1170.5 (3)
F8—C52—C53—F91.3 (5)C9—C8—Si1—Pt1−14.7 (3)
C51—C52—C53—F9179.6 (3)C16—C17—Si1—C21−46.6 (4)
F8—C52—C53—C54−178.0 (3)C18—C17—Si1—C21138.1 (3)
C51—C52—C53—C540.3 (6)C16—C17—Si1—C876.9 (4)
F9—C53—C54—F102.8 (5)C18—C17—Si1—C8−98.4 (3)
C52—C53—C54—F10−177.9 (3)C16—C17—Si1—Pt1−179.1 (3)
F9—C53—C54—C49−178.2 (3)C18—C17—Si1—Pt15.6 (3)
C52—C53—C54—C491.1 (6)C19—Pt1—Si1—C2148.3 (2)
C50—C49—C54—F10176.8 (3)C20—Pt1—Si1—C21−41.0 (2)
B1—C49—C54—F103.2 (5)N1—Pt1—Si1—C21136.86 (19)
C50—C49—C54—C53−2.3 (5)N2—Pt1—Si1—C21−129.2 (2)
B1—C49—C54—C53−175.9 (3)C19—Pt1—Si1—C8−76.13 (17)
C60—C55—C56—F11176.2 (3)C20—Pt1—Si1—C8−165.39 (17)
B1—C55—C56—F111.2 (5)N1—Pt1—Si1—C812.45 (14)
C60—C55—C56—C57−2.3 (5)N2—Pt1—Si1—C8106.39 (14)
B1—C55—C56—C57−177.4 (3)C19—Pt1—Si1—C17173.35 (17)
F11—C56—C57—F12−0.3 (5)C20—Pt1—Si1—C1784.08 (17)
C55—C56—C57—F12178.3 (3)N1—Pt1—Si1—C17−98.07 (14)
F11—C56—C57—C58−178.6 (3)N2—Pt1—Si1—C17−4.13 (14)
C55—C56—C57—C580.0 (5)C37—C38—Si2—C42−41.5 (4)
F12—C57—C58—F132.3 (5)C39—C38—Si2—C42138.4 (3)
C56—C57—C58—F13−179.3 (3)C37—C38—Si2—C2982.4 (3)
F12—C57—C58—C59−176.7 (3)C39—C38—Si2—C29−97.7 (3)
C56—C57—C58—C591.6 (5)C37—C38—Si2—Pt2−173.9 (3)
F13—C58—C59—F140.5 (5)C39—C38—Si2—Pt26.0 (3)
C57—C58—C59—F14179.5 (3)C28—C29—Si2—C4235.5 (4)
F13—C58—C59—C60−179.8 (3)C30—C29—Si2—C42−147.7 (3)
C57—C58—C59—C60−0.7 (5)C28—C29—Si2—C38−88.3 (4)
F14—C59—C60—F15−1.8 (5)C30—C29—Si2—C3888.5 (3)
C58—C59—C60—F15178.5 (3)C28—C29—Si2—Pt2168.1 (3)
F14—C59—C60—C55177.8 (3)C30—C29—Si2—Pt2−15.2 (3)
C58—C59—C60—C55−1.9 (5)C41—Pt2—Si2—C42−38.8 (2)
C56—C55—C60—F15−177.1 (3)C40—Pt2—Si2—C4248.7 (2)
B1—C55—C60—F15−1.9 (5)N3—Pt2—Si2—C42137.9 (2)
C56—C55—C60—C593.3 (5)N4—Pt2—Si2—C42−130.0 (2)
B1—C55—C60—C59178.6 (3)C41—Pt2—Si2—C3885.15 (16)
C66—C61—C62—F16−176.6 (3)C40—Pt2—Si2—C38172.66 (16)
B1—C61—C62—F16−2.9 (5)N3—Pt2—Si2—C38−98.14 (13)
C66—C61—C62—C632.0 (5)N4—Pt2—Si2—C38−6.08 (13)
B1—C61—C62—C63175.7 (3)C41—Pt2—Si2—C29−162.93 (16)
F16—C62—C63—F17−2.9 (5)C40—Pt2—Si2—C29−75.42 (16)
C61—C62—C63—F17178.5 (3)N3—Pt2—Si2—C2913.79 (14)
F16—C62—C63—C64176.1 (3)N4—Pt2—Si2—C29105.84 (14)
C61—C62—C63—C64−2.5 (6)

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BH2154).

References

  • Brown, M. P., Puddephatt, R. J. & Upton, C. E. E. (1974). J. Chem. Soc. Dalton Trans. pp. 2457–2465.
  • Bruker (2002). SMART, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
  • Cason, C. J. (2002). POV-RAY for Windows Persistence of Vision Raytracer Pty. Ltd, Victoria, Australia.
  • Farrugia, L. J. (1997). J. Appl. Cryst.30, 565.
  • Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [PubMed]

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