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Acta Crystallogr Sect E Struct Rep Online. 2008 September 1; 64(Pt 9): m1215–m1216.
Published online 2008 August 30. doi:  10.1107/S1600536808027177
PMCID: PMC2960716

catena-Poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ2 N 8,N 9)cobalt(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ3 N 1 O 2:O 3]

Abstract

In the title compound, [Co(C6H2N2O4)(C14H8N4)(H2O)]n, the Co atom is bonded to one N,N′-bidentate pyrazino[2,3-f][1,10]phenanthroline (Pyphen) ligand, one N,O-bidentate pyrazine-2,3-dicarboxyl­ate (PZDC) dianion and one water mol­ecule in a distorted octa­hedral mer-CoN3O3 geometry. The CoII atoms are bridged by the PZDC dianions, forming an infinite one-dimensional chain running along the b axis. Adjacent chains pack together through π–π stacking inter­actions [centroid–centroid separations = 3.498 (4) and 3.528 (4) Å], and O—H(...)O and O—H(...)N hydrogen bonds involving the water mol­ecule complete the structure.

Related literature

For related structures, see: Che et al. (2008 [triangle]); Liu et al. (2008 [triangle]). For the synthesis of the ligand, see: Che et al. (2006 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-64-m1215-scheme1.jpg

Experimental

Crystal data

  • [Co(C6H2N2O4)(C14H8N4)(H2O)]
  • M r = 475.29
  • Triclinic, An external file that holds a picture, illustration, etc.
Object name is e-64-m1215-efi1.jpg
  • a = 6.8430 (14) Å
  • b = 7.4455 (15) Å
  • c = 17.454 (4) Å
  • α = 93.64 (3)°
  • β = 95.99 (3)°
  • γ = 97.61 (3)°
  • V = 873.9 (3) Å3
  • Z = 2
  • Mo Kα radiation
  • μ = 1.04 mm−1
  • T = 292 (2) K
  • 0.41 × 0.33 × 0.19 mm

Data collection

  • Bruker SMART CCD diffractometer
  • Absorption correction: multi-scan (SADABS; Bruker, 2002 [triangle]) T min = 0.672, T max = 0.823
  • 7576 measured reflections
  • 3434 independent reflections
  • 1541 reflections with I > 2σ(I)
  • R int = 0.114

Refinement

  • R[F 2 > 2σ(F 2)] = 0.070
  • wR(F 2) = 0.161
  • S = 0.92
  • 3434 reflections
  • 297 parameters
  • H atoms treated by a mixture of independent and constrained refinement
  • Δρmax = 0.45 e Å−3
  • Δρmin = −0.65 e Å−3

Data collection: SMART (Bruker, 2002 [triangle]); cell refinement: SAINT (Bruker, 2002 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: SHELXTL (Sheldrick, 2008 [triangle]); software used to prepare material for publication: SHELXTL.

Table 1
Selected bond lengths (Å)
Table 2
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808027177/hb2775sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808027177/hb2775Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The authors thank the Doctoral Foundation of Jilin Normal University (Nos. 2006006 and 2007009) and the Subject and Base Construction Foundation of Jilin Normal University (No. 2006041).

supplementary crystallographic information

Comment

As part of our ongoing studies of supramolecular architectures containing pyrazino[2,3-f][1,10]phenanthroline (Pyphen) (Che, Liu et al., 2008; Liu et al., 2008), we selected pyrazine-2,3-dicarboxylic acid (H2PZDC) as a linker and Pyphen as a secondary ligandin combination with Co2+ ions, forming the title compound, (I), a new coordination polymer, which is reported here.

In compound (I), each Co atom is six-coordinated by three N atoms from one Pyphen ligand and one PZDC2- ligand, and three O atoms from two PZDC2- ligands and one water molecule in a slightly distorted octahedral geometry (Fig. 1) with O1W, N1, N2 and N5 forming the equatorial plane, and O1 and O3 in the axial positions (Table 1). One carboxylate oxygen atom and pyrazine nitrogen atom of PZDC2- chelate one Co(II) ion, while the other carboxylate oxygen atom is coordinated to another Co(II) ion in a monodentate fashion, forming an infinite one-dimensional chain running along the b axis (Fig. 2).

Adjacent chains pack together through π-π stacking interactions between the Pyphen ligands at a centroid separation of 3.498 (4) Å and between the PZDC2- ligands from adjacent one-dimensional chains at centroid separation 3.528 (4)Å, resulting in a three-dimensional supramolecular structure (Fig. 3).

Finally, O—H···O and O—H···N hydrogen bonds involving the water molecules and the O4 and N6 atoms of the PZDC2- dianion acceptors complete the structure of (I) (Table 2).

Experimental

The Pyphen ligand was synthesized according to the literature method (Che et al., 2006). A mixture of Pyphen, H2PZDC, Co(NO3)2 and water in a molar ratio of 1:1:1:5000 was sealed in a Teflon-lined autoclave and heated to 433 K for 3 d. Upon cooling and opening the bomb, yellow blocks of (I) were obtained (76% yield based on Co).

Refinement

All H atoms on C atoms were positioned geometrically (C—H = 0.93 Å) and refined as riding, with Uiso(H)= 1.2Ueq(C). The hydrogen atoms of water molecules were located from difference Fourier maps and their positions and Uiso values were refined freely.

Figures

Fig. 1.
The asymmetric unit of (I), expanded to show the metal coordination sphere. Displacement ellipsoids are drawn at the 30% probability level (arbitrary spheres for the H atoms). [Symmetry code: (i) x, y - 1, z.]
Fig. 2.
View of one-dimensional chain structure of (I). H atoms have been omitted.
Fig. 3.
View of three-dimensional superamolecular structure of (I) built up viaπ-π interactions. H atoms have been omitted.

Crystal data

[Co(C6H2N2O4)(C14H8N4)(H2O)]Z = 2
Mr = 475.29F000 = 482
Triclinic, P1Dx = 1.806 Mg m3
Hall symbol: -P 1Mo Kα radiation λ = 0.71073 Å
a = 6.8430 (14) ÅCell parameters from 2411 reflections
b = 7.4455 (15) Åθ = 2.4–26.0º
c = 17.454 (4) ŵ = 1.04 mm1
α = 93.64 (3)ºT = 292 (2) K
β = 95.99 (3)ºBlock, yellow
γ = 97.61 (3)º0.41 × 0.33 × 0.19 mm
V = 873.9 (3) Å3

Data collection

Bruker SMART CCD diffractometer3434 independent reflections
Radiation source: fine-focus sealed tube1541 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.114
T = 292(2) Kθmax = 26.1º
ω scansθmin = 2.4º
Absorption correction: multi-scan(SADABS; Bruker, 2002)h = −8→8
Tmin = 0.672, Tmax = 0.823k = −9→9
7576 measured reflectionsl = −20→21

Refinement

Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: difmap and geom
R[F2 > 2σ(F2)] = 0.070H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.161  w = 1/[σ2(Fo2) + (0.0488P)2] where P = (Fo2 + 2Fc2)/3
S = 0.92(Δ/σ)max < 0.001
3434 reflectionsΔρmax = 0.45 e Å3
297 parametersΔρmin = −0.65 e Å3
Primary atom site location: structure-invariant direct methodsExtinction correction: none

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
C10.1297 (9)−0.2248 (9)0.7468 (4)0.0382 (19)
H10.0668−0.21190.79120.046*
C20.0341 (10)−0.3449 (9)0.6867 (4)0.042 (2)
H2−0.0854−0.41600.69180.050*
C30.1202 (10)−0.3567 (9)0.6187 (4)0.0378 (18)
H30.0554−0.43050.57610.045*
C40.3067 (10)−0.2560 (9)0.6148 (4)0.0334 (17)
C50.4113 (10)−0.2614 (9)0.5466 (4)0.0309 (17)
C60.4200 (11)−0.3667 (10)0.4217 (4)0.047 (2)
H60.3620−0.43520.37670.057*
C70.6080 (12)−0.2729 (10)0.4227 (4)0.046 (2)
H70.6723−0.28170.37850.056*
C80.6015 (10)−0.1635 (9)0.5474 (4)0.0377 (19)
C90.6942 (9)−0.0530 (9)0.6161 (4)0.0307 (17)
C100.8851 (10)0.0455 (9)0.6205 (4)0.0368 (18)
H100.95840.04320.57850.044*
C110.9615 (10)0.1464 (9)0.6892 (4)0.0383 (19)
H111.08590.21620.69390.046*
C120.8503 (10)0.1414 (9)0.7502 (4)0.0390 (19)
H120.90550.20660.79630.047*
C130.5930 (9)−0.0467 (8)0.6809 (4)0.0306 (17)
C140.3934 (9)−0.1466 (8)0.6793 (4)0.0283 (16)
C150.6273 (9)0.4436 (8)0.8808 (3)0.0243 (15)
C160.7009 (9)0.6013 (9)0.9285 (4)0.0287 (16)
C170.7670 (9)0.4280 (10)1.0288 (4)0.0352 (18)
H170.81130.41791.08040.042*
C180.7034 (9)0.2695 (9)0.9810 (4)0.0314 (17)
H180.71190.15681.00020.038*
C190.5404 (10)0.4446 (10)0.7980 (4)0.0346 (18)
C200.7100 (11)0.7927 (9)0.9014 (4)0.0329 (17)
N10.3064 (8)−0.1266 (7)0.7451 (3)0.0311 (14)
N20.6678 (8)0.0493 (7)0.7479 (3)0.0328 (14)
N30.3191 (8)−0.3632 (7)0.4820 (3)0.0376 (15)
N40.7025 (8)−0.1691 (8)0.4849 (3)0.0386 (15)
N50.6314 (7)0.2789 (7)0.9087 (3)0.0292 (14)
N60.7668 (7)0.5927 (7)1.0039 (3)0.0321 (14)
O10.4150 (7)0.3020 (6)0.7750 (2)0.0389 (12)
O20.5959 (7)0.5679 (7)0.7600 (3)0.0494 (14)
O1W0.2264 (8)0.0860 (8)0.8973 (3)0.0411 (14)
O30.5474 (7)0.8538 (6)0.8915 (3)0.0368 (12)
O40.8788 (7)0.8715 (7)0.8956 (3)0.0536 (15)
Co0.46559 (14)0.06529 (13)0.83165 (5)0.0332 (3)
HW1A0.113 (11)0.005 (10)0.905 (4)0.06 (3)*
HW1B0.200 (10)0.182 (10)0.910 (4)0.05 (3)*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
C10.029 (4)0.047 (5)0.037 (5)−0.004 (4)0.011 (3)0.000 (4)
C20.040 (4)0.046 (5)0.034 (5)−0.016 (4)0.010 (4)−0.001 (4)
C30.038 (4)0.037 (5)0.034 (5)−0.001 (4)−0.004 (4)−0.006 (4)
C40.034 (4)0.027 (4)0.038 (4)−0.001 (3)0.004 (3)−0.002 (3)
C50.040 (4)0.032 (4)0.021 (4)0.008 (3)0.001 (3)0.004 (3)
C60.051 (5)0.064 (6)0.025 (4)0.002 (4)0.009 (4)−0.008 (4)
C70.059 (6)0.051 (6)0.032 (5)0.014 (4)0.012 (4)0.001 (4)
C80.036 (4)0.030 (4)0.053 (5)0.008 (4)0.024 (4)0.011 (4)
C90.031 (4)0.036 (5)0.024 (4)0.003 (3)0.004 (3)−0.001 (3)
C100.032 (4)0.034 (5)0.046 (5)0.006 (3)0.009 (4)0.005 (4)
C110.032 (4)0.039 (5)0.044 (5)−0.003 (3)0.016 (4)0.008 (4)
C120.039 (5)0.038 (5)0.040 (5)0.003 (4)0.002 (4)0.011 (4)
C130.038 (4)0.022 (4)0.030 (4)0.001 (3)−0.003 (3)0.000 (3)
C140.034 (4)0.015 (4)0.034 (4)−0.001 (3)0.000 (3)0.002 (3)
C150.030 (4)0.020 (4)0.025 (4)0.007 (3)0.004 (3)0.005 (3)
C160.025 (4)0.030 (4)0.031 (4)0.001 (3)0.008 (3)0.003 (3)
C170.039 (4)0.039 (5)0.027 (4)0.004 (4)0.001 (3)0.005 (4)
C180.033 (4)0.026 (4)0.038 (5)0.004 (3)0.012 (3)0.012 (3)
C190.039 (4)0.032 (5)0.035 (5)0.006 (4)0.013 (4)−0.001 (4)
C200.036 (4)0.030 (5)0.031 (4)−0.005 (4)0.010 (4)−0.001 (3)
N10.030 (3)0.026 (3)0.037 (4)0.002 (3)0.006 (3)0.000 (3)
N20.035 (3)0.030 (3)0.032 (4)−0.006 (3)0.009 (3)0.000 (3)
N30.044 (4)0.038 (4)0.029 (4)0.004 (3)0.003 (3)0.001 (3)
N40.041 (4)0.045 (4)0.032 (4)0.006 (3)0.013 (3)0.004 (3)
N50.026 (3)0.035 (4)0.030 (4)0.007 (3)0.009 (3)0.011 (3)
N60.028 (3)0.029 (4)0.038 (4)−0.003 (3)0.011 (3)0.002 (3)
O10.050 (3)0.032 (3)0.030 (3)−0.003 (2)−0.003 (2)0.001 (2)
O20.063 (4)0.041 (4)0.043 (3)−0.002 (3)0.008 (3)0.007 (3)
O1W0.035 (3)0.030 (4)0.055 (4)−0.009 (3)0.015 (3)−0.009 (3)
O30.036 (3)0.033 (3)0.045 (3)0.006 (2)0.014 (2)0.009 (2)
O40.042 (3)0.050 (4)0.064 (4)−0.017 (3)0.009 (3)0.009 (3)
Co0.0347 (6)0.0307 (6)0.0323 (6)−0.0037 (4)0.0069 (4)0.0004 (4)

Geometric parameters (Å, °)

C1—N11.332 (7)C13—N21.345 (8)
C1—C21.383 (9)C13—C141.463 (9)
C1—H10.9300C14—N11.357 (7)
C2—C31.381 (8)C15—N51.351 (7)
C2—H20.9300C15—C161.399 (8)
C3—C41.403 (9)C15—C191.504 (9)
C3—H30.9300C16—N61.353 (8)
C4—C141.378 (8)C16—C201.525 (9)
C4—C51.453 (9)C17—N61.328 (8)
C5—N31.364 (8)C17—C181.393 (8)
C5—C81.403 (9)C17—H170.9300
C6—N31.318 (8)C18—N51.315 (8)
C6—C71.378 (9)C18—H180.9300
C6—H60.9300C19—O21.211 (7)
C7—N41.345 (8)C19—O11.288 (7)
C7—H70.9300C20—O41.242 (7)
C8—N41.353 (8)C20—O31.257 (8)
C8—C91.446 (9)Co—N12.116 (5)
C9—C131.389 (8)Co—N22.124 (5)
C9—C101.403 (9)Co—N52.135 (5)
C10—C111.389 (9)Co—O3i2.050 (5)
C10—H100.9300Co—O1W2.110 (5)
C11—C121.370 (8)Co—O12.125 (5)
C11—H110.9300O1W—HW1A0.95 (7)
C12—N21.338 (8)O1W—HW1B0.78 (7)
C12—H120.9300O3—Coii2.050 (5)
N1—C1—C2124.0 (7)N6—C16—C20115.1 (6)
N1—C1—H1118.0C15—C16—C20123.7 (6)
C2—C1—H1118.0N6—C17—C18122.7 (6)
C3—C2—C1118.5 (6)N6—C17—H17118.6
C3—C2—H2120.7C18—C17—H17118.6
C1—C2—H2120.7N5—C18—C17120.2 (6)
C2—C3—C4119.1 (6)N5—C18—H18119.9
C2—C3—H3120.5C17—C18—H18119.9
C4—C3—H3120.5O2—C19—O1127.2 (7)
C14—C4—C3117.7 (6)O2—C19—C15120.0 (7)
C14—C4—C5119.0 (6)O1—C19—C15112.7 (6)
C3—C4—C5123.4 (6)O4—C20—O3128.2 (7)
N3—C5—C8121.2 (6)O4—C20—C16115.6 (7)
N3—C5—C4118.2 (6)O3—C20—C16116.1 (6)
C8—C5—C4120.6 (6)C1—N1—C14116.6 (6)
N3—C6—C7122.6 (7)C1—N1—Co127.8 (5)
N3—C6—H6118.7C14—N1—Co115.5 (4)
C7—C6—H6118.7C12—N2—C13116.6 (6)
N4—C7—C6122.8 (7)C12—N2—Co127.5 (5)
N4—C7—H7118.6C13—N2—Co115.3 (4)
C6—C7—H7118.6C6—N3—C5116.3 (6)
N4—C8—C5121.5 (7)C7—N4—C8115.6 (6)
N4—C8—C9118.3 (6)C18—N5—C15119.2 (6)
C5—C8—C9120.2 (6)C18—N5—Co127.6 (5)
C13—C9—C10118.4 (6)C15—N5—Co112.2 (4)
C13—C9—C8119.1 (6)C17—N6—C16116.7 (6)
C10—C9—C8122.6 (6)C19—O1—Co114.9 (4)
C11—C10—C9118.1 (6)Co—O1W—HW1A134 (4)
C11—C10—H10121.0Co—O1W—HW1B120 (6)
C9—C10—H10121.0HW1A—O1W—HW1B104 (7)
C12—C11—C10118.9 (7)C20—O3—Coii131.4 (4)
C12—C11—H11120.6O3i—Co—O1W91.3 (2)
C10—C11—H11120.6O3i—Co—N188.77 (19)
N2—C12—C11124.5 (7)O1W—Co—N196.0 (2)
N2—C12—H12117.7O3i—Co—N296.21 (19)
C11—C12—H12117.7O1W—Co—N2169.4 (2)
N2—C13—C9123.6 (6)N1—Co—N276.8 (2)
N2—C13—C14115.9 (6)O3i—Co—O1173.06 (19)
C9—C13—C14120.5 (6)O1W—Co—O191.9 (2)
N1—C14—C4123.9 (6)N1—Co—O196.98 (19)
N1—C14—C13115.5 (6)N2—Co—O181.41 (19)
C4—C14—C13120.6 (6)O3i—Co—N596.8 (2)
N5—C15—C16119.9 (6)O1W—Co—N587.2 (2)
N5—C15—C19116.4 (6)N1—Co—N5173.5 (2)
C16—C15—C19123.7 (6)N2—Co—N599.2 (2)
N6—C16—C15121.2 (6)O1—Co—N577.22 (19)

Symmetry codes: (i) x, y−1, z; (ii) x, y+1, z.

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
O1W—HW1A···O4iii0.95 (7)1.76 (7)2.680 (7)164 (6)
O1W—HW1B···N6iv0.78 (7)2.15 (7)2.851 (8)149 (7)

Symmetry codes: (iii) x−1, y−1, z; (iv) −x+1, −y+1, −z+2.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HB2775).

References

  • Bruker (2002). SMART, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
  • Che, G.-B., Li, W.-L., Kong, Z.-G., Su, Z.-S., Chu, B., Li, B., Zhang, Z.-Q., Hu, Z.-Z. & Chi, H.-J. (2006). Synth. Commun.36, 2519–2524.
  • Che, G.-B., Liu, C.-B., Liu, B., Wang, Q.-W. & Xu, Z.-L. (2008). CrystEngComm, 10, 184–191.
  • Liu, C.-B., Che, G.-B., Wang, Q.-W. & Xu, Z.-L. (2008). Chin. J. Inorg. Chem.24, 835–838.
  • Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [PubMed]

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