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Acta Crystallogr Sect E Struct Rep Online. 2008 December 1; 64(Pt 12): m1505.
Published online 2008 November 8. doi:  10.1107/S1600536808035514
PMCID: PMC2960134

catena-Poly[[[tetra­quazinc(II)]-μ-2,5-dihydroxy­benzene-1,4-diacetato-κ2 O 1:O 4] dihydrate]

Abstract

The title compound, {[Zn(C10H8O6)(H2O)4]·2H2O}n, is a one-dimensional coordination polymer with 2,5-dihydroxy­benzene-1,4-diacetate acting as bridging ligand. The zigzag chains, extending parallel to [011], are further packed into a three-dimensional network by hydrogen bonds.

Related literature

For related structures, see Ren et al. (2008 [triangle]); Cano et al. (1997 [triangle]); Sun et al. (2001 [triangle]); Zhao et al. (2004 [triangle]).

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Object name is e-64-m1505-scheme1.jpg

Experimental

Crystal data

  • [Zn(C10H8O6)(H2O)4]·2H2O
  • M r = 397.63
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-64-m1505-efi1.jpg
  • a = 11.122 (2) Å
  • b = 7.5176 (15) Å
  • c = 8.6417 (17) Å
  • β = 95.12 (3)°
  • V = 719.7 (2) Å3
  • Z = 2
  • Mo Kα radiation
  • μ = 1.77 mm−1
  • T = 113 (2) K
  • 0.32 × 0.24 × 0.10 mm

Data collection

  • Rigaku Saturn diffractometer
  • Absorption correction: multi-scan (CrystalStructure; Rigaku/MSC, 2005 [triangle]) T min = 0.601, T max = 0.843
  • 6863 measured reflections
  • 1833 independent reflections
  • 1405 reflections with I > 2σ(I)
  • R int = 0.041

Refinement

  • R[F 2 > 2σ(F 2)] = 0.032
  • wR(F 2) = 0.117
  • S = 1.17
  • 1833 reflections
  • 125 parameters
  • 9 restraints
  • H atoms treated by a mixture of independent and constrained refinement
  • Δρmax = 0.60 e Å−3
  • Δρmin = −0.66 e Å−3

Data collection: CrystalStructure (Rigaku/MSC, 2005 [triangle]); cell refinement: CrystalStructure; data reduction: CrystalStructure; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: ORTEP-3 (Farrugia, 1997 [triangle]); software used to prepare material for publication: CrystalStructure.

Table 1
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808035514/bq2094sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808035514/bq2094Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

This work was supported by the National Natural Science Foundation of China (grant No. 50578108) and the Sci and Tec Innovation Foundation of Tianjin (No. 06FZZDSH00900).

supplementary crystallographic information

Comment

Rigid carboxylato ligands, such as benzene-carboxylic acid, pyridine-carboxylic acid, etc. have been widely utilized to synthesize coordination polymers because they can link metal ions via one carboxyl group or via the aroma rings, leading plentiful varieties of structures (Cano et al., 1997; Sun et al., 2001; Zhao, et al., 2004). In contrast, flexible aroma-carboxylic acid and their complexes are less studied comparing to the rigid ones. (Ren et al., 2008)

In this contribution, a flexible ligand, 2,5-dihydroxy-p-benzenediacetic acid (H2dba), was selected to construct coordination polymer, and the title complex was obtained under solvothermal conditions.

The Zn(II) ion in the title compound is coordinated by two oxygen atoms from dba anions in the apical sites and four water molecules in the equatorial plane (Fig. 1). The Zn(II) ions are linked through dba dianion forming one-dimensional chain (Fig. 2). Furthermore, the chains are packed into three-dimensional supermolecular moiety by O—H···O H-bonds (Fig. 3).

Experimental

A mixture of Zn(Ac)22H2O (0.5 mmol, 109.8 mg), H2dba (0.5 mmol, 133.0 mg), 10 ml THF and 10 ml water was put into a 25 ml acid digestion bomb and heated at 80°C for three days. After cooling to room temperature, the title compound (56% yield based on Zn(II) salt) was obtained. Elemental analysis (%) for the title compound C10H20ZnO12: found: C, 29.94; H, 4.96; N, 0. Calc.: C, 30.20; H, 5.07; N, 0.

Refinement

The carboxyl H and aromatic H were placed in calculated positions and refined in riding mode with Uiso(H) = 1.2Ueq(C). Water H atoms were located in a difference Fourier map and refined as riding in as-found relative positions with Uiso(H) = 1.5Ueq(O).

Figures

Fig. 1.
The molecular structure of the title compound with 30% probability displacement ellipsoids. Symmetry code: A - x, -y + 2 - z.
Fig. 2.
One-dimensional chain structure of the title compound. H atoms and lattice water molecules are omitted for clarity. Symmetry code: (A) x, y, z; (B) - x, -y + 2 - z; (C) 1 - x, 1 - y, -z.
Fig. 3.
The packing diagram of the title compound.

Crystal data

[Zn(C10H8O6)(H2O)4]·2H2OF000 = 412
Mr = 397.63Dx = 1.835 Mg m3
Monoclinic, P21/cMo Kα radiation λ = 0.71073 Å
Hall symbol: -P2ybcCell parameters from 1803 reflections
a = 11.122 (2) Åθ = 2.9–28.6º
b = 7.5176 (15) ŵ = 1.77 mm1
c = 8.6417 (17) ÅT = 113 (2) K
β = 95.12 (3)ºPrism, colorless
V = 719.7 (2) Å30.32 × 0.24 × 0.10 mm
Z = 2

Data collection

Rigaku Saturn diffractometer1833 independent reflections
Radiation source: rotating anode1405 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.041
T = 113(2) Kθmax = 28.6º
ω scansθmin = 1.8º
Absorption correction: multi-scan(CrystalStructure; Rigaku/MSC, 2005)h = −14→14
Tmin = 0.601, Tmax = 0.843k = −10→10
6863 measured reflectionsl = −10→11

Refinement

Refinement on F29 restraints
Least-squares matrix: fullH atoms treated by a mixture of independent and constrained refinement
R[F2 > 2σ(F2)] = 0.032  w = 1/[σ2(Fo2) + (0.0565P)2 + 0.7652P] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.117(Δ/σ)max < 0.001
S = 1.17Δρmax = 0.60 e Å3
1833 reflectionsΔρmin = −0.66 e Å3
125 parametersExtinction correction: none

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
Zn10.50000.50000.50000.00908 (16)
O10.33235 (19)0.5544 (3)0.5773 (2)0.0106 (4)
O20.30469 (19)0.8254 (3)0.4764 (3)0.0142 (5)
O30.17185 (19)1.0259 (3)0.7503 (3)0.0124 (5)
H30.18321.13320.77460.019*
O40.4629 (2)0.2263 (3)0.5260 (3)0.0121 (4)
H4A0.5325 (13)0.207 (5)0.494 (4)0.018*
H4B0.4037 (18)0.197 (5)0.460 (3)0.018*
O50.4263 (2)0.5039 (3)0.2703 (3)0.0138 (4)
H5A0.3500 (11)0.517 (4)0.268 (4)0.021*
H5B0.449 (3)0.426 (4)0.207 (4)0.021*
C10.2689 (3)0.6913 (4)0.5470 (3)0.0103 (6)
C20.1445 (3)0.6927 (4)0.6029 (4)0.0107 (6)
H2A0.10140.58380.56470.013*
H2B0.15250.68790.71780.013*
C30.0690 (2)0.8511 (4)0.5524 (3)0.0090 (6)
C4−0.0186 (3)0.8388 (4)0.4269 (3)0.0103 (6)
H4−0.03210.72770.37580.012*
C50.0863 (2)1.0146 (4)0.6249 (3)0.0095 (5)
O60.2650 (2)0.3550 (3)0.8178 (3)0.0133 (4)
H6A0.246 (3)0.426 (4)0.886 (3)0.020*
H6B0.286 (3)0.395 (4)0.733 (2)0.020*

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
Zn10.0073 (2)0.0100 (3)0.0101 (3)0.00122 (18)0.00169 (16)0.00064 (19)
O10.0082 (10)0.0111 (10)0.0125 (10)0.0037 (8)0.0015 (8)0.0024 (8)
O20.0097 (10)0.0127 (10)0.0204 (12)0.0011 (8)0.0035 (9)0.0034 (9)
O30.0108 (10)0.0131 (11)0.0125 (11)−0.0002 (8)−0.0035 (8)−0.0011 (8)
O40.0086 (9)0.0104 (10)0.0177 (11)0.0004 (8)0.0032 (8)0.0010 (8)
O50.0111 (10)0.0182 (11)0.0117 (11)0.0018 (9)−0.0007 (8)−0.0026 (9)
C10.0089 (13)0.0116 (14)0.0104 (14)0.0005 (11)−0.0001 (11)−0.0042 (11)
C20.0080 (13)0.0126 (14)0.0117 (14)0.0043 (10)0.0023 (11)0.0046 (11)
C30.0049 (12)0.0095 (13)0.0132 (14)0.0020 (10)0.0043 (10)0.0031 (11)
C40.0079 (12)0.0156 (14)0.0080 (14)0.0006 (11)0.0039 (10)−0.0018 (11)
C50.0048 (11)0.0159 (14)0.0082 (13)0.0023 (11)0.0027 (9)0.0011 (11)
O60.0159 (11)0.0119 (11)0.0123 (11)−0.0003 (8)0.0028 (9)0.0001 (8)

Geometric parameters (Å, °)

Zn1—O12.077 (2)O5—H5B0.855 (10)
Zn1—O1i2.077 (2)C1—C21.506 (4)
Zn1—O5i2.080 (2)C2—C31.500 (4)
Zn1—O52.080 (2)C2—H2A0.9900
Zn1—O42.115 (2)C2—H2B0.9900
Zn1—O4i2.115 (2)C3—C51.384 (4)
O1—C11.262 (3)C3—C41.395 (4)
O2—C11.261 (4)C4—C5ii1.387 (4)
O3—C51.379 (3)C4—H40.9500
O3—H30.8400C5—C4ii1.387 (4)
O4—H4A0.857 (10)O6—H6A0.836 (10)
O4—H4B0.859 (10)O6—H6B0.843 (10)
O5—H5A0.853 (10)
?···??
O1—Zn1—O1i180.0Zn1—O5—H5B119 (2)
O1—Zn1—O5i89.12 (9)H5A—O5—H5B114.9 (18)
O1i—Zn1—O5i90.88 (9)O2—C1—O1123.9 (3)
O1—Zn1—O590.88 (9)O2—C1—C2119.2 (3)
O1i—Zn1—O589.12 (9)O1—C1—C2116.8 (3)
O5i—Zn1—O5180.0C3—C2—C1114.8 (2)
O1—Zn1—O488.16 (8)C3—C2—H2A108.6
O1i—Zn1—O491.84 (8)C1—C2—H2A108.6
O5i—Zn1—O487.08 (8)C3—C2—H2B108.6
O5—Zn1—O492.92 (9)C1—C2—H2B108.6
O1—Zn1—O4i91.84 (8)H2A—C2—H2B107.6
O1i—Zn1—O4i88.16 (8)C5—C3—C4118.1 (3)
O5i—Zn1—O4i92.92 (9)C5—C3—C2121.4 (3)
O5—Zn1—O4i87.08 (8)C4—C3—C2120.5 (3)
O4—Zn1—O4i180.0C5ii—C4—C3121.3 (3)
C1—O1—Zn1126.52 (19)C5ii—C4—H4119.4
C5—O3—H3109.5C3—C4—H4119.4
Zn1—O4—H4A86 (3)O3—C5—C3117.9 (3)
Zn1—O4—H4B109 (3)O3—C5—C4ii121.4 (3)
H4A—O4—H4B113.9 (17)C3—C5—C4ii120.7 (3)
Zn1—O5—H5A109 (3)H6A—O6—H6B119.8 (19)
O5i—Zn1—O1—C1118.5 (2)C1—C2—C3—C5−77.9 (4)
O5—Zn1—O1—C1−61.5 (2)C1—C2—C3—C4100.0 (3)
O4—Zn1—O1—C1−154.4 (2)C5—C3—C4—C5ii0.2 (5)
O4i—Zn1—O1—C125.6 (2)C2—C3—C4—C5ii−177.7 (3)
Zn1—O1—C1—O2−7.4 (4)C4—C3—C5—O3179.1 (3)
Zn1—O1—C1—C2173.89 (19)C2—C3—C5—O3−2.9 (4)
O2—C1—C2—C36.2 (4)C4—C3—C5—C4ii−0.2 (5)
O1—C1—C2—C3−175.0 (3)C2—C3—C5—C4ii177.7 (3)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x, −y+2, −z+1.

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
O3—H3···O6iii0.841.922.725 (3)160
O4—H4A···O2i0.857 (10)1.823 (15)2.616 (3)153 (3)
O4—H4A···O1i0.857 (10)2.45 (3)3.011 (3)123 (3)
O4—H4B···O6iv0.859 (10)1.925 (10)2.783 (3)176 (3)
O5—H5A···O3v0.853 (10)2.000 (15)2.828 (3)164 (3)
O5—H5B···O4iv0.855 (10)1.956 (15)2.787 (3)164 (3)
O6—H6A···O2vi0.836 (10)2.11 (3)2.781 (3)137 (3)
O6—H6B···O10.843 (10)1.908 (15)2.721 (3)162 (3)

Symmetry codes: (iii) x, y+1, z; (i) −x+1, −y+1, −z+1; (iv) x, −y+1/2, z−1/2; (v) x, −y+3/2, z−1/2; (vi) x, −y+3/2, z+1/2.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BQ2094).

References

  • Cano, J., Munno, G. D., Sanz, J. L., Ruiz, R., Faus, J., Lloret, F., Julve, M. & Caneschi, A. (1997). J. Chem. Soc. Dalton Trans. pp. 1915–1924.
  • Farrugia, L. J. (1997). J. Appl. Cryst.30, 565.
  • Ren, P., Xu, N., Chen, C., Song, H. B., Shi, W. & Cheng, P. (2008). Inorg. Chem. Commun.11, 730–732.
  • Rigaku/MSC (2005). CrystalStructure Rigaku/MSC, The Woodlands, Texas, USA.
  • Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [PubMed]
  • Sun, D. F., Gao, R., Liang, Y. C., Shi, Q., Su, W. P. & Hong, M. C. (2001). J. Chem. Soc. Dalton Trans. pp. 2335–2340.
  • Zhao, B., Cheng, P., Chen, X. Y., Cheng, C., Shi, W., Liao, D. Z., Yan, S. P. & Jiang, Z. H. (2004). J. Am. Chem. Soc.126, 3012–3013. [PubMed]

Articles from Acta Crystallographica Section E: Structure Reports Online are provided here courtesy of International Union of Crystallography