Search tips
Search criteria 


Logo of ijmsMDPIhomeThis articleThis journalInstructions for authorsSubscribeIJMS
Int J Mol Sci. 2010; 11(7): 2770–2779.
Published online 2010 July 23. doi:  10.3390/ijms11072770
PMCID: PMC2920566

Reactivity of Heteropolytungstate and Heteropolymolybdate Metal Transition Salts in the Synthesis of Dimethyl Carbonate from Methanol and CO2


A series of Keggin-type heteropoly compounds (HPC) having different countercations (Co, Fe) and different addenda atoms (W, Mo) were synthesized and characterized by means of Fourier-Transform Infrared Spectrometer (FT-IR) and X-ray powder diffraction (XRD). The catalytic properties of the prepared catalysts for the dimethyl carbonate (DMC) synthesis from CO2 and CH3OH were investigated. The experimental results showed that the catalytic activity is significantly influenced by the type of the countercation and addenda atoms transition metal. Among the catalysts examined, Co1.5PW12O40 is the most active for the DMC synthesis, owing to the synergetic effect between Co and W. Investigating the effect of the support showed that the least acidic one (Al2O3) enhanced the conversion but decreased the DMC selectivity in favor of that of methyl formate (MF), while that of dimethoxy methane remained stable.

Keywords: heteropoly compounds, dimethyl carbonate, Keggin structure, carbon dioxide

1. Introduction

The limited fossil fuel resources and the problems of global warming caused by an increase of atmospheric carbon dioxide concentrations have stimulated research in the utilization of CO2. One of the remedies for these problems is the development of processes that could economically convert CO2 into fuels or useful chemicals. The efficient transformation of carbon dioxide into useful chemical compounds is very attractive because it is a potentially inexpensive and abundant C1 building block, and it is environmentally benign (nontoxic, noncorrosive, and nonflammable) [1,2]. In recent years, various chemical processes have been tried to convert CO2 into valuable chemical compounds [35]. An increased use of CO2 would only be possible if the relatively inert CO2 molecule could be activated. Among the chemical compounds that can be obtained by using CO2, dimethyl carbonate (DMC) is considered as one of the most important. It can be synthesized by reaction of methanol and CO2. Therefore, it is required to find highly reactive metal catalysts that can activate the relatively inert CO2 molecule. Various catalysts have been reported to catalyze this reaction [616]. It is worth noting that DMC is an important raw material in organic synthesis and has drawn much attention of researchers. It has been paid more and more attention due to its low toxicity and wide applications [17]. It can be used as an environment-friendly intermediate and starting material for organic synthesis via carbonylation and methylation, replacing poisonous phosgene and dimethyl sulfate [18]. It is also considered an option for meeting the oxygenate specifications on gasoline [17]. Although the direct synthesis of DMC from methanol and CO2 is a promising route, nevertheless, DMC yield is relatively low due to the fact that CO2 is highly thermodynamically stable and kinetically inert and due to the deactivation of catalysts by in situ produced water. The problems associated with liquid phase processes can be solved by the development of an effective heterogeneous catalyst that can facilitate the CO2 activation. For that purpose, various catalysts have been tested in the activation of CO2 [1922]. Among them, cobalt-based and iron-based catalysts have been reported effective for the activation of CO2 [19,23,24]. In this work, a series of cobalt and iron heteropolyoxometalate catalysts were prepared and tested for the direct synthesis of DMC in liquid-phase. The influence of the cobalt and iron as a countercation in the Keggin type heteropolytungstate and hetropolymolybdate was investigated. It is well known that the acidity and redox properties of 12-heteropoly compounds depend on both the constituent elements of polyanions and countercations.

2. Results and Discussion

2.1. Characterization of Catalysts

IR spectra of the heteropoly compounds are shown in Table 1. The IR spectra have been assigned according to Ref [25]. The main characteristic features of the Keggin structure are observed at 1080−1060 cm−1, 990−960 cm−1, 900−870 cm−1, and 810−760 cm−1 assigned to the stretching vibration νas (P-Oa), νas (M-Od), νas (M-Ob-M), and νas (M-Oc-M), respectively (M = W or Mo). The result of X-ray powder diffraction (XRD) of the product is shown in Figure 1. In each of the four ranges of 2θ, 7°–10°, 16°–23°, 25°–30°, and 31°–38°, the compound shows a characteristic peak of heteropolyanions (HPA) having Keggin structure [2628]. Therefore, the presence of the primary Keggin structure in the synthesized phases was confirmed by FT-IR and XRD.

Figure 1.
X-ray powder diffraction (XRD) patterns of PW12O40 and PMo12O40 having cobalt and iron as countercations.
Table 1.
The relevant frequencies (cm−1) of PW12O40 and PMo12O40 having cobalt and iron as countercations.

2.2. Catalytic Activity of the Series of Heteropoly Compounds

The catalytic properties of the prepared series of catalysts in which the cobalt and iron were tested as countercation of the Keggin 12-heteropolytungstate (Co1.5PW12O40, Fe1.5PW12O40) and 12-heteropolymolybdate (Co1.5PMo12O40, and Fe1.5PMo12O40) were investigated. The conversion of methanol (Xc) and the selectivity of the products are listed in Table 2. The results show that the conversion and the DMC selectivity obtained over the Fe1.5PMo12O40 catalyst were 24.18% and 0.18%, respectively. When the iron cation was replaced by cobalt cation, Xc raised to 0.51% and the DMC selectivity to 54.12%.

Table 2.
Conversion of methanol (Xc) and product selectivities obtained from the reaction of methanol with CO2. Reaction conditions: catalytic mass = 0.1 g; reaction temperature 80 °C; pressure of CO2 = 2.5 bar.

When the molybdenum addenda atom of the Fe1.5PMo12O40 catalyst was substituted by tungsten addenda atom, the conversion (0.51%) remained stable, whereas a remarkable increase in DMC selectivity (61.87%) was observed. Finally, when the iron cation of the tungstate metal salt was replaced by the cobalt cation, only a slight increase in the DMC selectivity (69.00%) was observed, whereas a remarkable increase in Xc (1.53%) was observed. It can be seen from these results that the conversion and the selectivity of DMC showed dependence on the type of metal constituting the counteraction and the polyanions. Co1.5PW12O40 was the most active and the most selective for the DMC formation of the series of catalysts, probably due to the remarkable synergistic effect between Co and W. Taking into account the above results, we can conclude that designing a catalyst system constituting of Co and W is suitable for the conversion of methanol and CO2 into dimethyl carbonate.

2.3. Catalytic Activity of Co1.5PW12O40

2.3.1. Effect of Reaction Time

Since the 12- tungstphosphate cobalt salt was found to be the best catalyst of the prepared series, it was chosen as the catalyst for the further study. In order to examine the variation of the conversion and the products formation during the reaction time, the reaction was carried out for 7 h at 80 °C and 2.5 bar using 0.1 g of Co1.5PW12O40 catalyst. Figure 2 shows the variation of the conversion and the yields as a function of reaction time. From this figure, it can be seen that the conversion and the yield for DMC production increased significantly in the initial 4 h. In fact, the conversion increased from 0.06% to 1.53% when the time increased from 1 h to 5 h. This increase corresponds to 96.08%. For further reaction time the conversion increased slightly. In fact, the conversion increased from 1.53% to 1.90% when the reaction time increased from 5 h to 7 h, which corresponds to an increase of 19.47%. As for the yield of DMC, it can be seen that in the first five hours, an increase of 96.23% was observed. Longer reaction times result in a formal decrease at about 6 h, and then the DMC yield remains stable. With longer reaction times (after 6 h), the continuous increase of the conversion along with the yield of dimethoxy methane (DMM) and methyl formate (MF), while a decrease of that of DMC was observed means that the system appears to approach an equilibrium state between DMC production and DMC hydrolysis. A kinetic study of the DMC decomposition is required to explain the decrease of the DMC yield in favor of DMM and MF.

Figure 2.
Conversion and DMC yield versus reaction time. Reaction conditions: m (catalyst) = 0.1 g; PCO2 = 2.5 bar.

As for the selectivities of the products (Figure 3), the change trend of the DMC selectivity was the same as that of DMC yield. The maximum of the DMC selectivity observed at 5 h was to the detriment to that of DMM and MF.

Figure 3.
The effect of reaction time on product selectivity. Reaction conditions: m (catalyst) = 0.1 g; PCO2 = 2.5 bar.

2.3.2. Effect of the Support

The activity of Co1.5PW12O40 in the synthesis of DMC from methanol and CO2 on the different supports, Al2O3 SiO2 and TiO2, was examined at 80 °C and at a pressure of CO2 equal to 5 bar. The results are summarized in Table 3. From these results, it can be concluded that the support significantly affects the conversion. When Al2O3 was used as a support, the activity (mol%/g of HPC) of the Co1.5PW12O40 changed from 3.73% (for the unsupported) to 39.33% (for the Al2O3-supported). Relatively high methanol conversion activity was obtained when the Al2O3 support was used. As for the products distribution (Figure 4), it can be seen that the DMC selectivity decreased when the Co1.5PW12O40 was supported on the kind of supports characterized as weakly basic. The decrease of DMC selectivity was in favor of that of MF, while the DMM selectivity remained almost unchanged (≈23%). The SiO2 and TiO2 (≈42–45%) support formed more MF than Al2O3 (≈36%). This indicates that the properties of the supports can influence the performance of the catalysts considerably. According to Ref. [29], the formation of MF on supported heteropoly compound catalysts requires the presence of both isolated oxo-metal sites and methoxy groups on the support, which can be formed from the interaction of methanol with hydroxyl groups of titania. Damyanova et al. [30] mentioned that the free titania surface could induce an increased methoxy group concentration and hence the formation of MF. This hints that a weak basic character of the support is more advantageous for this reaction. The enhanced Xc and DMC selectivity was probably due to the fact that Al2O3 is less acidic than SiO2 and TiO2. In fact, it was reported that the acidity of Al2O3 support can be increased by the addition of SiO2 and TiO2 in the preparation of Al2O3 support [31,32].

Figure 4.
The effect of the support on the product selectivity. Reaction conditions: catalytic mass = 0.1 g; reaction temperature 80 °C; pressure of CO2 = 5 bar.
Table 3.
The effect of the support on the conversion and DMC yield. Reaction conditions: catalytic mass = 0.1 g; reaction temperature 80 °C; pressure of CO2 = 5 bar.

3. Experimental Section

3.1. Catalyst Preparation

The heteropolytungstate (Co1.5PW12O40; Fe1.5PW12O40) and the heteropolymolybdate transition metal salts (Co1.5PMo12O40; Fe1.5PW12O40) were prepared from 12-tungstophosphoric acid H3PW12O40, and 12-molybdophosphoric acid H3PMo12O40, respectively. These two heteropolyacids were prepared according to the methods of Deltcheff et al. [33]. The salt forms were obtained from their counterpart heteropolyacids, as precipitate by adding slowly the required amount of Ba(OH)2.8H2O (to neutralize the three protons) to the aqueous solution of the heteropolyacid, and then the required amount of MSO4.xH2O was added (M = Co; Fe). After eliminating the formed BaSO4 precipitate, the obtained solution was allowed to stand for few days at 4 °C. The salt was recovered from the solution by filtration. The series of supported catalysts (Co1.5PW12O40/Al2O3, Co1.5PW12O40/SiO2 and Co1.5PW12O40/TiO2) with a composition HPC/support = 30/70 was prepared by incipient-wetness impregnation. The support (Al2O3, SiO2, or TiO2) was impregnated with aqueous solutions of Co1.5PW12O40 with concentrations high enough to avoid its degradation [34]. The slurry of support and impregnation solution was constantly stirred at 50 °C until dryness evaporation. The catalyst was then dried over night at 120 °C.

3.2. Physicochemical Techniques

The purity and the Keggin structure of the samples were characterized by means of IR and XRD. IR spectra were recorded with an infrared spectrometer GENESIS II-FT-IR (4000−400 cm−1) as KBr pellets. The XRD powder patterns were recorded on a Rigaku diffractometer Ultima IV using CuKα radiation.

3.3. Reaction Procedure

Catalytic performance was tested in a stainless steel 250 mL autoclave equipped with a magnetic stirrer. The temperature of the autoclave was adjusted by a heating jacket. In a typical procedure, 20 mL of methanol and 0.1 g of catalyst were charged into the autoclave. CO2 was injected in to a low pressure, and then released, which was repeated two or three times in order to remove the air from the reactor. Following this, CO2 was injected to 2.5 bars. The system was stirred and heated at 80 °C for 5 h. After the reaction, the reactor was cooled down to less than 5 °C with a circulator and depressurized. The resulting solution was analyzed with a gas phase chromatograph (Agilent 6890N) equipped with a flame ionization detector, a thermal conductivity detector and a capillary column (HP-PLOT Q length 30 m ID 0.53 mm).

4. Conclusion

The catalytic properties of the prepared 12-heteropolytungstates (Co1.5PW12O40, Fe1.5PW12O40) and 12-heteropolymolybdates (Co1.5PMo12O40, and Fe1.5PMo12O40) were investigated. It was found that Co1.5PW12O40 was the most active and selective catalyst for the direct synthesis of DMC from methanol and CO2. Its high catalytic activity can be attributed to the synergetic effect between Co and Fe.

The methanol conversion activity was drastically increased whereas the DMC selectivity was decreased if Co1.5PW12O40 was supported on an acidic or a weak basic support. Thus, the direct conversion of the methanol in DMC can be enhanced if the 12-tungstophosphate cobalt salt is supported on a support that is adequately basic.


1. Centi G, Perathoner S. Opportunities and prospects in the chemical recycling of carbon dioxide to fuels. Catal. Today. 2009;148:191–205.
2. Yin X, Moss JR. Recent developments in the activation of carbon dioxide by metal complexes. Coordinat. Chem. Rev. 1999;181:27–59.
3. Zhag K, Kogelschatz U, Eliasson B. Conversion of greenhouse gases to synthesis gas and higher hydrocarbons. Energy Fuel. 2001;15:395–401.
4. Inui T, Yamamoto T. Effective synthesis of ethanol from CO2 on polyfunctional composite catalysts. Catal. Today. 1998;45:209–221.
5. Zevenhoven R, Eloneva S, Teir S. Chemical fixation of CO2 in carbonates: Routes to valuable products and long-term storage. Catal. Today. 2006;115:73–79.
6. Aouissi A, Al-Othman ZA, Al-Amro A. Gas-phase synthesis of dimethyl carbonate from methanol and carbon dioxide over Co1.5PW12O40 keggin-type heteropolyanion. Int. J. Mol. Sci. 2010;11:1343–1351. [PMC free article] [PubMed]
7. Aouissi A, Allaoui LA, Aldhayan D. Catalytic reactivity of 12-molybdophosphoric acid and its Copper and Zinc salts in CO2 methanol reforming. Asian J. Chem. 2006;18:3009–3016.
8. Aouissi A, Allaoui LA. Effect of the Brønsted acidity on the behavior of CO2 methanol reaction. J. Mol. Catal. A: Chem. 2006;259:281.
9. Guo XC, Qin ZF, Wang GF. Wang, J.G. Critical temperatures and pressures of reacting mixture in synthesis of dimethyl carbonate with methanol and carbon dioxide. Chin. Chem. Lett. 2008;19:249–252.
10. Jiang C, Guo Y, Wang C, Hua C, Wuc Y, Wang E. Synthesis of dimethyl carbonate from methanol and carbon dioxide in the presence of polyoxometalates under mild conditions. Appl. Catal. A: Gen. 2003;256:203–212.
11. Bian J, Xiao M, Wang S, Lu Y, Meng Y. Direct synthesis of DMC from CH3OH and CO2 over V-doped Cu–Ni/AC catalysts. Catal. Commun. 2009;10:1142–1145.
12. Bian J, Xiao M, Wang S, Lu Y, Meng Y. Novel application of thermally expanded graphite as the support of catalysts for direct synthesis of DMC from CH3OH and CO2. J. Colloid Interf. Sci. 2009;334:50–57. [PubMed]
13. Wu XL, Xiao M, Meng YZ, Lu YX. Direct synthesis of dimethyl carbonate (DMC) using Cu-Ni/VSO as catalyst. J. Mol. Catal. A: Chem. 2006;249:93–97.
14. Jiang C, Guo Y, Wang C, Hu C, Wu Y, Wang E. Synthesis of dimethyl carbonate from methanol and carbon dioxide in the presence of polyoxometalates under mild conditions. Appl. Catal. A: Gen. 2003;256:203–212.
15. Kizlink J, Pastucha I. Preparation of dimethyl carbonate from methanol and carbon dioxide in the presence of Sn(IV) and Ti(IV) alkoxides and metal acetates. Collect. Czech. Chem. Commun. 1995;60:687.
16. Jung KT, Bell AT. Effects of catalyst phase structure on the elementary processes involved in the synthesis of dimethyl carbonate from methanol and carbon dioxide over zirconia. Topics Catal. 2002;20:97–105.
16. Pacheco MA, Marshall CL. Review on Dimethyl carbonate manufacture and its characteristics as a fuel additive. Energ. Fuel. 1997;11:2–29.
18. Ono Y. Catalysis in the production and reactions of dimethyl carbonate, an environmentally benign building block. Appl. Catal. A: Gen. 1997;155:133–166.
19. Niemelä M, Nokkosmäki M. Activation of carbon dioxide on Fe-catalysts. Catal. Today. 2005;100:269–274.
20. Kim BJ, Cho KS, Park SJ. Copper oxide-decorated porous carbons for carbon dioxide adsorption behaviors. J. Colloid Interf. Sci. 2010;342:575–578. [PubMed]
21. Walther D, Ruben M, Rau S. Carbon dioxide and metal centres: from reactions inspired by nature to reactions in compressed carbon dioxide as solvent. Coord. Chem. Rev. 1999;182:67–100.
22. Yin X, Moss JR. Recent developments in the activation of carbon dioxide by metal complexes. Coord. Chem. Rev. 1999;181:27–59.
23. Wang D, Zhang X, Gao Y, Xiao F, Wei W, Sun Y. Zn/Fe mixed oxide: Heterogeneous catalyst for the synthesis of dimethyl carbonate from methyl carbamate and methanol. Catal. Commun. 2010;11:430–433.
24. Montilla F, Clara E, Avile’s T, Casimiro T, Ricardo AA, Nunes da Ponte M. Transition-metal-mediated activation of arylisocyanates in supercritical carbon dioxide. J. Organomet. Chem. 2001;626:227–232.
25. Rocchiccioli-Deltcheff C, Fournier M. Catalysis by polyoxometalates. Part 3,–influence of Vanadium (V) on the thermal stability of 12-metallophosphoric acids from in situ infrared studies. J. Chem. Soc. Faraday Trans. 1991;87:3913–3920.
26. Fournier M, Feumi-Jantou C, Rabia C, Herve G, Launay S. Polyoxometalates catalyst materials: X-Ray thermal stability study of phosphorus-containing heteropolyacids H3+xPM12−xVxO40.13–14H2O (M=Mo, W; x=0–1) J. Mater. Chem. 1992;2:971–978.
27. Gao R, Chen H, Le Y, Dai W-L, Fan K. Highly active and selective Cs2.5H0.5PW12O40/SBA- 15 composite material in the oxidation of cyclopentane-1,2-diol to glutaric acid by aqueous H2O2. Appl. Catal. A: Gen. 2009;352:61–65.
28. Fuchs VM, Pizzio LR, Blanco MN. Synthesis and characterization of aluminum or copper tungstophosphate and tungstosilicate immobilized in a polymeric blend. Eur. Polym. J. 2008;44:801–807.
29. Louis C, Tatibouët JM, Che M. Catalytic properties of silica-supported molybdenum catalysts in methanol oxidation: The influence of molybdenum dispersion. J. Catal. 1988;109:354–366.
30. Damyanova S, Cubeiro ML, Fierro JLG. Acid-redox properties of titania-supported 12-molybdophosphates for methanol oxidation. J. Mol. Catal. A: Chem. 1999;142:85–100.
31. Venezia AM, Parola VL, Pawelec B, Fierro JLG. Hydrogenation of aromatics over Au–Pd/SiO2–Al2O3 catalysts; support acidity effect. Appl. Catal. A: Gen. 2004;264:43–51.
32. Borque MP, Lopez-Agudo A, Olguin E. Catalytic activities of Co(Ni) Mo/TiO2–Al2O3 catalysts in gasoil and thiophene HDS and pyridine HDN: Effect of the TiO2–Al2O3 composition. Appl. Catal. A: Gen. 1999;180:53–61.
33. Rocchiccioli-Deltcheff C, Fournier M, Franck R, Thouvenot R. Vibrational investigations of polyoxometalates. Evidence for anion-anion interactions in molybdenum(VI) and tungsten(VI) compounds related to the Keggin structure. Inorg. Chem. 1983;22:207–216.
34. Rocchiccioli-Deltcheff C, Aouissi A, Launay S, Fournier M. Silica-supported 12-molybdophosphoric acid catalysts: Influence of the thermal treatments and of the Mo contents on their behavior, from IR, Raman, X-ray diffraction studies, and catalytic reactivity in the methanol oxidation. J. Mol. Catal. A: Chem. 1996;114:331–342.

Articles from International Journal of Molecular Sciences are provided here courtesy of Multidisciplinary Digital Publishing Institute (MDPI)