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Acta Crystallogr Sect E Struct Rep Online. 2008 January 1; 64(Pt 1): m179–m180.
Published online 2007 December 12. doi:  10.1107/S1600536807065877
PMCID: PMC2915114

trans-Carbonyl­chloridobis(ethyl­diphenyl­phosphine-κP)rhodium(I)

Abstract

The title compound, [RhCl(C14H15P)2(CO)], crystallizes with two almost identical mol­ecules in the asymmetric unit. The mol­ecules have the RhI atom in a square-planar geometry. The crystal structure involves intermolecular C—H(...)O hydrogen bonds.

Related literature

For related literature, see: Beck et al. (1999 [triangle]); Higham et al. (2004 [triangle]); Hoye et al. (1993 [triangle]); Lorenzini et al. (2007a [triangle],b [triangle],c [triangle]); O’Connor & Wilkinson (1969 [triangle]); Vallarino (1957 [triangle]); Vaska & Di Luzio (1961 [triangle], 1962 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-64-0m179-scheme1.jpg

Experimental

Crystal data

  • [RhCl(C14H15P)2(CO)]
  • M r = 594.83
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-64-0m179-efi1.jpg
  • a = 9.8557 (14) Å
  • b = 16.385 (2) Å
  • c = 16.381 (2) Å
  • β = 90.216 (6)°
  • V = 2645.3 (6) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 0.89 mm−1
  • T = 173.0 (1) K
  • 0.15 × 0.15 × 0.07 mm

Data collection

  • Bruker X8 APEXII diffractometer
  • Absorption correction: multi-scan (SADABS; Bruker, 2003 [triangle]) T min = 0.701, T max = 0.940
  • 41680 measured reflections
  • 12665 independent reflections
  • 8610 reflections with I > 2σ(I)
  • R int = 0.049

Refinement

  • R[F 2 > 2σ(F 2)] = 0.037
  • wR(F 2) = 0.080
  • S = 0.98
  • 12665 reflections
  • 668 parameters
  • 1 restraint
  • H-atom parameters constrained
  • Δρmax = 0.45 e Å−3
  • Δρmin = −0.36 e Å−3
  • Absolute structure: Flack (1983 [triangle]), 6047 Friedel pairs
  • Flack parameter: 0.04 (4)

Data collection: SAINT (Bruker, 1997 [triangle]); cell refinement: SAINT; data reduction: SAINT; program(s) used to solve structure: SIR97 (Altomare et al., 1999 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997 [triangle]); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 [triangle]); software used to prepare material for publication: WinGX (Farrugia, 1999 [triangle]).

Table 1
Selected geometric parameters (Å, °)
Table 2
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536807065877/ng2391sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536807065877/ng2391Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The authors thank the Natural Sciences and Engineering Research Council of Canada for financial support via a Discovery Grant.

supplementary crystallographic information

Comment

We have recently reported the syntheses of water-soluble RhI—THP complexes (THP is tris(hydroxymethyl)phosphine, P(CH2OH)3) (Lorenzini et al., 2007a). During a subsequent study of the general reactivity of such complexes with other potential ligands, we discovered a remarkable reaction of RhCl(cod)(THP), where cod = 1,5-cyclooctadiene, with several PRR'2 phosphines (R = or ≠ R'), that generates, concomitantly with R'H, the phosphine-phosphinite derivatives RhCl(PRR'2)[P,PR'(R)POCH2P(CH2OH)2] in two isomeric cis- and trans-forms (cis and trans refer to the disposition of the P-atoms with the R and R' substituents) (Lorenzini et al., 2007b). Such reactions, when investigated under a hydrogen atmosphere, led to the serendipitous isolation of the dihydrido complexes cis,mer-Rh(H)2Cl(PRR'2)3, where R = Me, R' = Ph, or R = Cy, R' = Ph (Lorenzini et al., 2007c). 31P{1H} NMR data suggested the presence of traces of trans-RhCl(CO)(PRR'2)2 in some of the isolated RhCl(PRR'2)[P,PR'(R)POCH2P(CH2OH)2] complexes and in the in situ preparative solutions of the phosphine-phosphinite and dihydrido species (Lorenzini et al., 2007b). The carbonyl ligand is thought to arise via decarbonylation of formaldehyde which can be readily formed from transition metal-THP species (Higham et al., 2004; Hoye et al., 1993); the Wilkinson-type complex such as RhCl(PPh3)3 is well known to decarbonylate aldehydes with formation of trans-RhCl(CO)(PPh3)2 (Beck et al., 1999). The suggested formation of trans-RhCl(CO)(PRR'2)2 has now been confirmed by X-ray structural analysis of a single-crystal of trans-RhCl(CO)(PEtPh2)2 that was precipitated in trace yield during the reaction of RhCl(cod)(THP) with PEtPh2, under a hydrogen atmosphere.

The complex trans-RhCl(CO)(PPh3)2 was first reported 50 years ago (Vallarino, 1957), but it was not until the Ir analogue (Vaska's compound) was synthesized (Vaska & Di Luzio, 1961) and shown to oxidatively add H2 and other small molecules (Vaska & Di Luzio, 1962) that interest in such d8 square-planar molecules intensified. According to the Cambridge Crystallography Data Base, there have been 125 crystallographically characterized complexes of the type trans-RhCl(CO)(P-phosphine)2, where (P-phosphine)2 represents two monodentate ligands or one bidentate phosphine ligand but there are none containing PEtPh2. Indeed, in spite of the vast literature on the chemistry of Rh-phosphine complexes, we can find no other example of any isolated Rh-complex containing PEtPh2, although an in situ RhCl/PEtPh2 species has been noted (O'Connor & Wilkinson, 1969).

Experimental

General. The RhCl(cod)(THP) complex was synthesized by our recently reported method; (Lorenzini et al., 2007a) and PEtPh2 was used as received from Strem Chemicals. The Rh-phosphine reaction was carried out under Ar or H2 using standard Schlenk techniques. Acetone-d6 and CD3OD (Cambridge Isotope Laboratory) were used as received. 31P{1H}-NMR spectra were measured in acetone-d6 and CD3OD at room temperature (~300 K) on a Bruker AV400 spectrometer. External 85% aq H3PO4 were used as references (d = doublet, m = multiplet).

Trans-RhCl(CO)(PEtPh2)2. Addition of PEtPh2 (12 µL, 0.057 mmol) in acetone-d6 (0.3 ml) to a yellow CD3OD solution (0.3 ml) of RhCl(cod)(THP) (10 mg, 0.026 mmol) at room temperature under Ar results in the immediate formation of a brown solution. The Ar is then replaced by H2 and the vessel shaken, this resulting in a yellow solution. Over 12 h, a minute quantity of X-ray quality, yellow prism crystals of trans-RhCl(CO)(PEtPh2)2 deposit from the solution; the 31P{1H} of the yellow solution shows the doublet resonance of the title compound (δ 27.49, d, JPRh = 123.4 Hz) and also resonances at δ 36.64 (dd, 2P, JPRh = 112.0, JPP = 21.0 Hz, trans-P), and 18.29 (m, 1P, P-trans to Cl) thought to be due to RhCl(PEtPh2)3.

Refinement

The material crystallizes with two molecules in the asymmetric unit. In each molecule the Cl and CO ligands are positionally disordered. Each was modelled such that the sum of the ligands at each coordination site was 1.

Figures

Crystal data

[RhCl(C14H15P)2(CO)]F000 = 1216
Mr = 594.83Dx = 1.494 Mg m3
Monoclinic, P21Mo Kα radiation λ = 0.71073 Å
a = 9.8557 (14) ÅCell parameters from 6687 reflections
b = 16.385 (2) Åθ = 2.4–27.8º
c = 16.381 (2) ŵ = 0.89 mm1
β = 90.216 (6)ºT = 173.0 (1) K
V = 2645.3 (6) Å3Prism, yellow
Z = 40.15 × 0.15 × 0.07 mm

Data collection

Bruker X8 APEXII diffractometer8610 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.049
T = 173.0(1) Kθmax = 28.0º
area–detector scansθmin = 1.8º
Absorption correction: multi-scan(SADABS; Bruker, 2003)h = −12→12
Tmin = 0.701, Tmax = 0.940k = −21→21
41680 measured reflectionsl = −21→21
12665 independent reflections

Refinement

Refinement on F2Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: fullH-atom parameters constrained
R[F2 > 2σ(F2)] = 0.037  w = 1/[σ2(Fo2) + (0.0297P)2] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.080(Δ/σ)max = 0.001
S = 0.98Δρmax = 0.45 e Å3
12665 reflectionsΔρmin = −0.36 e Å3
668 parametersExtinction correction: none
1 restraintAbsolute structure: Flack (1983), 6047 Friedel pairs
Primary atom site location: structure-invariant direct methodsFlack parameter: 0.04 (4)
Secondary atom site location: difference Fourier map

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/UeqOcc. (<1)
C10.9538 (4)0.4119 (3)0.9327 (3)0.0217 (10)
C20.9587 (4)0.4211 (3)0.8491 (3)0.0229 (10)
H20.97770.47290.82580.027*
C30.9356 (4)0.3539 (3)0.7992 (3)0.0286 (10)
H30.93710.36070.74170.034*
C40.9107 (5)0.2785 (3)0.8311 (3)0.0337 (13)
H40.89690.23310.79610.040*
C50.9058 (5)0.2687 (3)0.9160 (4)0.0306 (13)
H50.88860.21670.93920.037*
C60.9264 (5)0.3359 (3)0.9653 (3)0.0288 (11)
H60.92160.32981.02280.035*
C70.9578 (5)0.5884 (3)0.9429 (3)0.0201 (11)
C80.8304 (5)0.6227 (3)0.9481 (3)0.0318 (13)
H80.76390.59880.98240.038*
C90.7990 (5)0.6921 (3)0.9032 (3)0.0381 (13)
H90.71060.71500.90620.046*
C100.8947 (6)0.7274 (3)0.8551 (4)0.0306 (14)
H100.87390.77590.82580.037*
C111.0193 (5)0.6935 (3)0.8489 (3)0.0327 (12)
H111.08470.71770.81390.039*
C121.0527 (5)0.6247 (3)0.8924 (3)0.0285 (10)
H121.14110.60200.88790.034*
C131.1777 (4)0.4925 (3)1.0074 (2)0.0253 (9)
H13A1.21410.49290.95120.030*
H13B1.21080.54231.03530.030*
C141.2332 (5)0.4181 (3)1.0520 (3)0.0389 (12)
H14A1.19820.41711.10780.058*
H14B1.33250.42081.05340.058*
H14C1.20480.36841.02330.058*
C150.8052 (5)0.4018 (3)1.3072 (3)0.0229 (11)
C160.9351 (5)0.3710 (3)1.3029 (3)0.0318 (13)
H161.00030.39821.27020.038*
C170.9731 (5)0.3013 (3)1.3452 (3)0.0377 (13)
H171.06360.28171.34230.045*
C180.8783 (6)0.2608 (4)1.3914 (4)0.0361 (14)
H180.90260.21231.41960.043*
C190.7478 (5)0.2909 (3)1.3967 (3)0.0430 (14)
H190.68260.26321.42900.052*
C200.7116 (5)0.3606 (3)1.3554 (3)0.0379 (12)
H200.62160.38081.35970.045*
C210.7961 (4)0.5771 (3)1.3191 (3)0.0225 (10)
C220.7836 (4)0.5671 (3)1.4027 (3)0.0261 (10)
H220.76220.51501.42450.031*
C230.8021 (5)0.6328 (3)1.4547 (3)0.0333 (12)
H230.79330.62541.51190.040*
C240.8332 (5)0.7093 (3)1.4237 (3)0.0349 (13)
H240.84780.75401.45960.042*
C250.8427 (5)0.7200 (3)1.3417 (4)0.0361 (14)
H250.86140.77271.32040.043*
C260.8254 (5)0.6549 (3)1.2888 (3)0.0296 (11)
H260.83340.66311.23160.036*
C270.5785 (4)0.4937 (3)1.2440 (3)0.0316 (10)
H27A0.54770.44401.21500.038*
H27B0.54230.49141.30020.038*
C280.5200 (5)0.5684 (3)1.2010 (3)0.0428 (13)
H28A0.54910.61791.22970.064*
H28B0.42080.56521.20100.064*
H28C0.55270.57001.14450.064*
C290.5462 (5)0.9084 (3)0.1954 (3)0.0207 (11)
C300.4458 (5)0.8558 (3)0.1673 (3)0.0323 (11)
H300.35280.86930.17460.039*
C310.4809 (5)0.7846 (3)0.1291 (3)0.0377 (13)
H310.41160.74790.11240.045*
C320.6137 (6)0.7653 (4)0.1143 (4)0.0317 (14)
H320.63650.71660.08600.038*
C330.7145 (5)0.8179 (3)0.1414 (3)0.0317 (11)
H330.80720.80520.13200.038*
C340.6804 (5)0.8888 (3)0.1821 (3)0.0249 (11)
H340.74990.92440.20090.030*
C350.5486 (4)1.0840 (3)0.1819 (3)0.0228 (10)
C360.5895 (5)1.1597 (3)0.2134 (3)0.0290 (11)
H360.60071.16680.27060.035*
C370.6134 (5)1.2244 (3)0.1605 (4)0.0308 (13)
H370.64091.27570.18190.037*
C380.5980 (5)1.2152 (3)0.0787 (3)0.0335 (13)
H380.61411.26010.04340.040*
C390.5591 (5)1.1409 (3)0.0463 (3)0.0316 (11)
H390.55001.1345−0.01110.038*
C400.5333 (4)1.0753 (3)0.0982 (3)0.0259 (10)
H400.50511.02440.07620.031*
C410.3228 (4)1.0043 (3)0.2550 (2)0.0264 (9)
H41A0.28721.00060.19850.032*
H41B0.28940.95620.28550.032*
C420.2677 (5)1.0820 (3)0.2950 (3)0.0372 (12)
H42A0.30081.08540.35140.056*
H42B0.16831.08050.29490.056*
H42C0.29871.12980.26440.056*
C430.6994 (4)0.9272 (3)0.5727 (3)0.0225 (10)
C440.6515 (4)0.8529 (3)0.5463 (3)0.0265 (11)
H440.63560.84410.48980.032*
C450.6264 (5)0.7911 (3)0.6014 (4)0.0368 (15)
H450.59370.73980.58280.044*
C460.6488 (5)0.8042 (3)0.6836 (3)0.0356 (13)
H460.63120.76190.72180.043*
C470.6962 (5)0.8777 (3)0.7100 (3)0.0334 (12)
H470.71060.88660.76660.040*
C480.7234 (4)0.9395 (3)0.6551 (3)0.0254 (10)
H480.75840.99020.67380.030*
C490.7068 (5)1.1020 (3)0.5537 (3)0.0213 (11)
C500.5730 (5)1.1252 (3)0.5646 (3)0.0305 (13)
H500.50211.09160.54400.037*
C510.5414 (5)1.1965 (3)0.6052 (3)0.0397 (13)
H510.44921.21080.61400.048*
C520.6422 (6)1.2462 (4)0.6325 (4)0.0405 (16)
H520.62021.29580.65950.049*
C530.7755 (5)1.2252 (3)0.6212 (3)0.0404 (13)
H530.84571.26040.63980.049*
C540.8080 (5)1.1519 (3)0.5823 (3)0.0321 (11)
H540.90031.13660.57580.039*
C550.9249 (4)1.0010 (3)0.4947 (2)0.0272 (9)
H55A0.95941.04810.46310.033*
H55B0.96121.00570.55090.033*
C560.9788 (5)0.9231 (3)0.4568 (3)0.0389 (13)
H56A0.95350.87650.49100.058*
H56B1.07790.92630.45300.058*
H56C0.93990.91630.40210.058*
O10.6403 (12)0.4282 (9)1.0455 (9)0.042 (3)0.690 (16)
C570.7319 (13)0.4523 (8)1.0755 (8)0.026 (2)0.690 (16)
Cl11.0740 (4)0.5520 (2)1.1907 (2)0.0325 (13)0.690 (16)
O20.3780 (16)0.9494 (11)0.4549 (11)0.046 (4)0.505 (16)
C580.4754 (16)0.9675 (10)0.4244 (9)0.029 (3)0.505 (16)
Cl20.8281 (4)1.0452 (3)0.3070 (3)0.0330 (16)0.505 (16)
O1B1.118 (2)0.5677 (18)1.2021 (16)0.036 (6)0.310 (16)
C57B1.017 (3)0.5407 (15)1.1698 (14)0.024 (5)0.310 (16)
Cl1B0.6789 (8)0.4422 (6)1.0585 (5)0.029 (2)0.310 (16)
O2B0.8740 (14)1.0596 (10)0.2968 (9)0.044 (3)0.495 (16)
C58B0.7709 (15)1.0374 (7)0.3261 (8)0.028 (3)*0.495 (16)
Cl2B0.4212 (5)0.9610 (3)0.4431 (3)0.0271 (16)0.495 (16)
P10.99277 (10)0.49628 (8)1.00219 (6)0.0213 (2)
P20.76358 (10)0.49333 (8)1.24884 (6)0.0232 (2)
P30.50860 (10)1.00148 (8)0.25227 (6)0.0206 (2)
P40.74016 (10)1.00706 (8)0.49855 (6)0.0207 (2)
Rh10.87809 (4)0.49622 (3)1.12535 (3)0.02214 (9)
Rh20.62381 (4)1.00347 (3)0.37570 (3)0.02055 (8)

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
C10.020 (2)0.023 (2)0.022 (2)0.0041 (18)0.0033 (18)−0.0033 (19)
C20.021 (2)0.023 (2)0.024 (2)0.0045 (18)0.0029 (18)0.0027 (18)
C30.028 (2)0.033 (3)0.025 (3)0.006 (2)−0.0021 (19)−0.007 (2)
C40.032 (3)0.028 (3)0.041 (3)0.005 (2)−0.001 (2)−0.011 (2)
C50.031 (3)0.021 (3)0.040 (3)0.002 (2)0.002 (2)0.007 (2)
C60.035 (3)0.026 (3)0.025 (3)0.003 (2)0.002 (2)0.005 (2)
C70.022 (2)0.018 (2)0.021 (3)0.0014 (18)0.0001 (19)−0.0026 (19)
C80.031 (3)0.031 (3)0.034 (3)−0.003 (2)0.009 (2)0.008 (2)
C90.026 (3)0.037 (3)0.051 (4)0.010 (2)0.005 (2)0.000 (3)
C100.038 (3)0.022 (3)0.032 (3)0.001 (2)0.001 (2)0.000 (2)
C110.035 (3)0.029 (3)0.034 (3)−0.002 (2)0.005 (2)0.007 (2)
C120.026 (2)0.030 (2)0.029 (3)0.002 (2)0.007 (2)0.007 (2)
C130.023 (2)0.029 (2)0.024 (2)−0.002 (2)0.0001 (16)0.004 (2)
C140.036 (3)0.044 (3)0.036 (3)0.007 (2)−0.003 (2)0.011 (2)
C150.028 (3)0.020 (2)0.021 (3)−0.0035 (19)0.0034 (19)−0.0016 (19)
C160.032 (3)0.030 (3)0.034 (3)0.003 (2)0.007 (2)0.003 (2)
C170.039 (3)0.038 (3)0.036 (3)0.009 (2)0.008 (2)0.015 (2)
C180.054 (4)0.025 (3)0.029 (3)0.000 (2)−0.009 (3)0.009 (2)
C190.043 (3)0.045 (3)0.041 (3)−0.013 (3)0.002 (2)0.023 (3)
C200.030 (3)0.039 (3)0.045 (3)−0.007 (2)0.005 (2)0.011 (2)
C210.019 (2)0.024 (2)0.024 (2)−0.0016 (18)0.0049 (18)0.0018 (18)
C220.022 (2)0.029 (2)0.027 (2)0.0041 (19)0.0048 (18)0.002 (2)
C230.031 (3)0.045 (3)0.024 (3)0.006 (2)0.003 (2)−0.005 (2)
C240.031 (3)0.032 (3)0.042 (3)0.001 (2)0.006 (2)−0.014 (2)
C250.034 (3)0.025 (3)0.049 (4)−0.006 (2)0.014 (3)−0.004 (2)
C260.031 (3)0.029 (3)0.029 (3)−0.005 (2)0.004 (2)0.002 (2)
C270.025 (2)0.039 (3)0.030 (2)−0.005 (2)0.0068 (17)0.002 (2)
C280.031 (3)0.050 (3)0.048 (3)0.007 (2)0.004 (2)0.003 (3)
C290.022 (3)0.024 (3)0.016 (3)−0.005 (2)−0.0011 (19)0.000 (2)
C300.024 (2)0.033 (3)0.039 (3)−0.002 (2)0.001 (2)−0.015 (2)
C310.033 (3)0.031 (3)0.049 (4)−0.010 (2)0.004 (2)−0.014 (2)
C320.039 (3)0.029 (3)0.028 (3)−0.001 (2)−0.002 (2)−0.007 (2)
C330.025 (3)0.037 (3)0.034 (3)0.000 (2)0.002 (2)−0.004 (2)
C340.022 (2)0.026 (3)0.026 (3)−0.004 (2)−0.004 (2)−0.002 (2)
C350.020 (2)0.027 (2)0.021 (2)0.0020 (19)0.0016 (18)0.0037 (19)
C360.034 (3)0.024 (2)0.029 (3)−0.004 (2)0.002 (2)−0.006 (2)
C370.028 (3)0.024 (3)0.040 (3)0.000 (2)−0.001 (2)−0.001 (2)
C380.040 (3)0.026 (3)0.034 (3)0.005 (2)0.008 (2)0.010 (2)
C390.034 (3)0.041 (3)0.020 (2)0.005 (2)0.0040 (19)0.009 (2)
C400.025 (2)0.026 (2)0.026 (2)0.0012 (18)−0.0019 (18)−0.0007 (19)
C410.021 (2)0.031 (3)0.027 (2)−0.004 (2)−0.0003 (16)−0.001 (2)
C420.032 (3)0.037 (3)0.042 (3)0.007 (2)0.003 (2)−0.007 (2)
C430.021 (2)0.022 (2)0.024 (2)0.0003 (18)−0.0012 (18)0.0003 (18)
C440.028 (3)0.026 (2)0.025 (3)0.005 (2)−0.001 (2)0.001 (2)
C450.033 (3)0.025 (3)0.053 (4)−0.003 (2)0.005 (3)0.007 (3)
C460.033 (3)0.035 (3)0.039 (3)0.004 (2)0.010 (2)0.019 (2)
C470.032 (3)0.047 (3)0.022 (3)0.013 (2)0.004 (2)0.008 (2)
C480.028 (2)0.027 (2)0.021 (2)0.0058 (19)−0.0035 (18)−0.0013 (19)
C490.029 (3)0.018 (2)0.017 (3)−0.0006 (19)−0.0038 (19)−0.0008 (18)
C500.032 (3)0.023 (3)0.036 (3)−0.002 (2)−0.003 (2)−0.005 (2)
C510.039 (3)0.040 (3)0.040 (3)0.010 (2)0.002 (3)−0.008 (3)
C520.057 (4)0.026 (3)0.038 (4)0.008 (3)0.003 (3)−0.009 (3)
C530.049 (3)0.034 (3)0.038 (3)−0.008 (3)−0.006 (3)−0.012 (2)
C540.029 (3)0.034 (3)0.034 (3)−0.005 (2)−0.003 (2)−0.003 (2)
C550.025 (2)0.031 (3)0.026 (2)−0.004 (2)−0.0040 (16)−0.001 (2)
C560.031 (3)0.041 (3)0.045 (3)0.006 (2)0.003 (2)−0.005 (3)
O10.033 (7)0.056 (6)0.038 (6)−0.015 (5)−0.003 (4)−0.009 (4)
C570.025 (7)0.031 (5)0.021 (5)−0.007 (5)0.003 (5)−0.001 (4)
Cl10.032 (3)0.037 (2)0.028 (2)−0.004 (2)0.0013 (19)−0.0021 (15)
O20.040 (9)0.064 (8)0.033 (7)−0.009 (6)0.011 (6)0.001 (5)
C580.025 (8)0.040 (7)0.020 (6)0.012 (6)0.009 (5)0.000 (5)
Cl20.027 (4)0.045 (2)0.027 (2)−0.0107 (19)−0.001 (2)0.0060 (14)
O1B0.022 (12)0.041 (13)0.046 (11)−0.005 (8)−0.015 (8)0.002 (8)
C57B0.032 (14)0.027 (10)0.014 (10)0.006 (10)0.003 (9)−0.007 (8)
Cl1B0.017 (6)0.045 (4)0.026 (5)−0.016 (4)−0.006 (4)−0.008 (3)
O2B0.024 (7)0.060 (7)0.048 (7)−0.019 (5)0.004 (5)0.005 (5)
Cl2B0.022 (4)0.038 (2)0.022 (3)−0.003 (2)0.004 (2)0.0006 (17)
P10.0240 (5)0.0224 (6)0.0175 (5)0.0000 (5)0.0027 (4)0.0026 (5)
P20.0233 (5)0.0245 (6)0.0219 (6)−0.0033 (5)0.0042 (4)0.0027 (5)
P30.0218 (5)0.0226 (6)0.0175 (5)−0.0030 (5)−0.0024 (4)−0.0018 (5)
P40.0224 (5)0.0219 (6)0.0179 (5)−0.0024 (5)−0.0023 (4)−0.0016 (5)
Rh10.02361 (14)0.0258 (2)0.01709 (13)−0.00473 (15)0.00288 (10)0.00149 (14)
Rh20.02122 (13)0.0247 (2)0.01573 (12)−0.00439 (14)−0.00130 (9)−0.00039 (13)

Geometric parameters (Å, °)

C1—C21.379 (6)C32—H320.9500
C1—C61.381 (6)C33—C341.382 (7)
C1—P11.831 (4)C33—H330.9500
C2—C31.388 (6)C34—H340.9500
C2—H20.9500C35—C401.385 (6)
C3—C41.363 (6)C35—C361.403 (6)
C3—H30.9500C35—P31.821 (4)
C4—C51.400 (8)C36—C371.390 (7)
C4—H40.9500C36—H360.9500
C5—C61.380 (7)C37—C381.357 (8)
C5—H50.9500C37—H370.9500
C6—H60.9500C38—C391.381 (7)
C7—C81.379 (6)C38—H380.9500
C7—C121.385 (6)C39—C401.395 (6)
C7—P11.827 (5)C39—H390.9500
C8—C91.388 (7)C40—H400.9500
C8—H80.9500C41—C421.533 (6)
C9—C101.360 (7)C41—P31.832 (4)
C9—H90.9500C41—H41A0.9900
C10—C111.352 (7)C41—H41B0.9900
C10—H100.9500C42—H42A0.9800
C11—C121.374 (6)C42—H42B0.9800
C11—H110.9500C42—H42C0.9800
C12—H120.9500C43—C441.374 (6)
C13—C141.521 (6)C43—C481.384 (6)
C13—P11.825 (4)C43—P41.831 (4)
C13—H13A0.9900C44—C451.379 (7)
C13—H13B0.9900C44—H440.9500
C14—H14A0.9800C45—C461.381 (8)
C14—H14B0.9800C45—H450.9500
C14—H14C0.9800C46—C471.362 (7)
C15—C161.378 (7)C46—H460.9500
C15—C201.392 (7)C47—C481.381 (6)
C15—P21.824 (5)C47—H470.9500
C16—C171.387 (7)C48—H480.9500
C16—H160.9500C49—C541.371 (6)
C17—C181.375 (7)C49—C501.385 (7)
C17—H170.9500C49—P41.829 (5)
C18—C191.380 (7)C50—C511.380 (6)
C18—H180.9500C50—H500.9500
C19—C201.374 (7)C51—C521.359 (8)
C19—H190.9500C51—H510.9500
C20—H200.9500C52—C531.372 (7)
C21—C221.385 (6)C52—H520.9500
C21—C261.399 (6)C53—C541.397 (6)
C21—P21.818 (4)C53—H530.9500
C22—C231.383 (6)C54—H540.9500
C22—H220.9500C55—C561.516 (6)
C23—C241.387 (7)C55—P41.825 (4)
C23—H230.9500C55—H55A0.9900
C24—C251.358 (8)C55—H55B0.9900
C24—H240.9500C56—H56A0.9800
C25—C261.385 (7)C56—H56B0.9800
C25—H250.9500C56—H56C0.9800
C26—H260.9500O1—C571.10 (2)
C27—C281.524 (6)C57—Rh11.803 (13)
C27—P21.825 (4)Cl1—Rh12.386 (3)
C27—H27A0.9900O2—C581.12 (3)
C27—H27B0.9900C58—Rh21.770 (17)
C28—H28A0.9800Cl2—Rh22.409 (4)
C28—H28B0.9800O1B—C57B1.21 (4)
C28—H28C0.9800C57B—Rh11.71 (3)
C29—C341.379 (6)Cl1B—Rh12.412 (6)
C29—C301.390 (6)O2B—C58B1.18 (3)
C29—P31.826 (5)C58B—Rh21.755 (17)
C30—C311.369 (6)Cl2B—Rh22.389 (4)
C30—H300.9500P1—Rh12.3161 (11)
C31—C321.370 (7)P2—Rh12.3207 (11)
C31—H310.9500P3—Rh22.3154 (11)
C32—C331.388 (7)P4—Rh22.3132 (11)
C2—C1—C6119.3 (4)C39—C38—H38119.8
C2—C1—P1121.8 (3)C38—C39—C40119.7 (4)
C6—C1—P1118.8 (3)C38—C39—H39120.1
C1—C2—C3119.4 (4)C40—C39—H39120.1
C1—C2—H2120.3C35—C40—C39120.3 (4)
C3—C2—H2120.3C35—C40—H40119.8
C4—C3—C2121.5 (5)C39—C40—H40119.8
C4—C3—H3119.3C42—C41—P3112.7 (3)
C2—C3—H3119.3C42—C41—H41A109.0
C3—C4—C5119.4 (5)P3—C41—H41A109.0
C3—C4—H4120.3C42—C41—H41B109.0
C5—C4—H4120.3P3—C41—H41B109.0
C6—C5—C4118.9 (5)H41A—C41—H41B107.8
C6—C5—H5120.5C41—C42—H42A109.5
C4—C5—H5120.5C41—C42—H42B109.5
C5—C6—C1121.4 (4)H42A—C42—H42B109.5
C5—C6—H6119.3C41—C42—H42C109.5
C1—C6—H6119.3H42A—C42—H42C109.5
C8—C7—C12118.6 (4)H42B—C42—H42C109.5
C8—C7—P1118.3 (4)C44—C43—C48119.5 (4)
C12—C7—P1123.1 (4)C44—C43—P4120.0 (3)
C7—C8—C9120.2 (4)C48—C43—P4120.3 (3)
C7—C8—H8119.9C43—C44—C45120.5 (5)
C9—C8—H8119.9C43—C44—H44119.8
C10—C9—C8120.1 (5)C45—C44—H44119.8
C10—C9—H9120.0C44—C45—C46119.7 (5)
C8—C9—H9120.0C44—C45—H45120.2
C11—C10—C9120.0 (5)C46—C45—H45120.2
C11—C10—H10120.0C47—C46—C45120.0 (5)
C9—C10—H10120.0C47—C46—H46120.0
C10—C11—C12121.0 (5)C45—C46—H46120.0
C10—C11—H11119.5C46—C47—C48120.6 (5)
C12—C11—H11119.5C46—C47—H47119.7
C11—C12—C7120.1 (4)C48—C47—H47119.7
C11—C12—H12120.0C47—C48—C43119.7 (4)
C7—C12—H12120.0C47—C48—H48120.2
C14—C13—P1114.0 (3)C43—C48—H48120.2
C14—C13—H13A108.7C54—C49—C50118.9 (4)
P1—C13—H13A108.7C54—C49—P4123.0 (4)
C14—C13—H13B108.7C50—C49—P4118.0 (4)
P1—C13—H13B108.7C51—C50—C49120.8 (5)
H13A—C13—H13B107.6C51—C50—H50119.6
C13—C14—H14A109.5C49—C50—H50119.6
C13—C14—H14B109.5C52—C51—C50120.0 (5)
H14A—C14—H14B109.5C52—C51—H51120.0
C13—C14—H14C109.5C50—C51—H51120.0
H14A—C14—H14C109.5C51—C52—C53120.3 (5)
H14B—C14—H14C109.5C51—C52—H52119.9
C16—C15—C20118.0 (5)C53—C52—H52119.9
C16—C15—P2118.8 (4)C52—C53—C54119.9 (5)
C20—C15—P2123.2 (4)C52—C53—H53120.0
C15—C16—C17121.7 (5)C54—C53—H53120.0
C15—C16—H16119.1C49—C54—C53120.1 (5)
C17—C16—H16119.1C49—C54—H54120.0
C18—C17—C16119.3 (5)C53—C54—H54120.0
C18—C17—H17120.3C56—C55—P4114.3 (3)
C16—C17—H17120.3C56—C55—H55A108.7
C17—C18—C19119.9 (5)P4—C55—H55A108.7
C17—C18—H18120.1C56—C55—H55B108.7
C19—C18—H18120.1P4—C55—H55B108.7
C20—C19—C18120.4 (5)H55A—C55—H55B107.6
C20—C19—H19119.8C55—C56—H56A109.5
C18—C19—H19119.8C55—C56—H56B109.5
C19—C20—C15120.8 (5)H56A—C56—H56B109.5
C19—C20—H20119.6C55—C56—H56C109.5
C15—C20—H20119.6H56A—C56—H56C109.5
C22—C21—C26118.5 (4)H56B—C56—H56C109.5
C22—C21—P2121.4 (3)O1—C57—Rh1177.3 (16)
C26—C21—P2119.9 (4)O2—C58—Rh2175.7 (19)
C23—C22—C21120.3 (4)O1B—C57B—Rh1176 (3)
C23—C22—H22119.8O2B—C58B—Rh2176.1 (14)
C21—C22—H22119.8C13—P1—C7103.8 (2)
C22—C23—C24120.5 (4)C13—P1—C1102.2 (2)
C22—C23—H23119.8C7—P1—C1104.76 (19)
C24—C23—H23119.8C13—P1—Rh1116.71 (13)
C25—C24—C23119.6 (5)C7—P1—Rh1111.83 (16)
C25—C24—H24120.2C1—P1—Rh1116.06 (15)
C23—C24—H24120.2C21—P2—C15104.4 (2)
C24—C25—C26120.7 (5)C21—P2—C27101.5 (2)
C24—C25—H25119.6C15—P2—C27104.4 (2)
C26—C25—H25119.6C21—P2—Rh1116.82 (14)
C25—C26—C21120.3 (5)C15—P2—Rh1111.38 (17)
C25—C26—H26119.8C27—P2—Rh1116.82 (14)
C21—C26—H26119.8C35—P3—C29104.62 (19)
C28—C27—P2113.5 (3)C35—P3—C41102.4 (2)
C28—C27—H27A108.9C29—P3—C41103.8 (2)
P2—C27—H27A108.9C35—P3—Rh2115.85 (15)
C28—C27—H27B108.9C29—P3—Rh2110.93 (16)
P2—C27—H27B108.9C41—P3—Rh2117.74 (13)
H27A—C27—H27B107.7C55—P4—C49104.2 (2)
C27—C28—H28A109.5C55—P4—C43101.9 (2)
C27—C28—H28B109.5C49—P4—C43103.9 (2)
H28A—C28—H28B109.5C55—P4—Rh2117.37 (13)
C27—C28—H28C109.5C49—P4—Rh2111.21 (17)
H28A—C28—H28C109.5C43—P4—Rh2116.70 (15)
H28B—C28—H28C109.5C57B—Rh1—C57177.8 (11)
C34—C29—C30119.1 (4)C57B—Rh1—P188.7 (8)
C34—C29—P3118.2 (3)C57—Rh1—P189.8 (4)
C30—C29—P3122.7 (4)C57B—Rh1—P291.7 (8)
C31—C30—C29119.9 (5)C57—Rh1—P289.8 (4)
C31—C30—H30120.0P1—Rh1—P2178.85 (7)
C29—C30—H30120.0C57B—Rh1—Cl12.8 (8)
C30—C31—C32121.4 (5)C57—Rh1—Cl1178.9 (4)
C30—C31—H31119.3P1—Rh1—Cl189.65 (9)
C32—C31—H31119.3P2—Rh1—Cl190.70 (9)
C31—C32—C33118.9 (5)C57B—Rh1—Cl1B176.2 (9)
C31—C32—H32120.6C57—Rh1—Cl1B2.0 (4)
C33—C32—H32120.6P1—Rh1—Cl1B90.2 (2)
C34—C33—C32120.1 (5)P2—Rh1—Cl1B89.5 (2)
C34—C33—H33119.9Cl1—Rh1—Cl1B179.0 (3)
C32—C33—H33119.9C58B—Rh2—C58178.8 (7)
C29—C34—C33120.5 (4)C58B—Rh2—P489.3 (4)
C29—C34—H34119.8C58—Rh2—P491.4 (5)
C33—C34—H34119.8C58B—Rh2—P390.2 (4)
C40—C35—C36119.0 (4)C58—Rh2—P389.2 (5)
C40—C35—P3121.8 (3)P4—Rh2—P3179.25 (7)
C36—C35—P3119.1 (3)C58B—Rh2—Cl2B178.4 (4)
C37—C36—C35119.6 (5)C58—Rh2—Cl2B2.5 (5)
C37—C36—H36120.2P4—Rh2—Cl2B91.03 (13)
C35—C36—H36120.2P3—Rh2—Cl2B89.50 (13)
C38—C37—C36120.8 (5)C58B—Rh2—Cl22.0 (4)
C38—C37—H37119.6C58—Rh2—Cl2177.0 (5)
C36—C37—H37119.6P4—Rh2—Cl289.25 (12)
C37—C38—C39120.5 (5)P3—Rh2—Cl290.22 (11)
C37—C38—H38119.8Cl2B—Rh2—Cl2179.5 (2)
C6—C1—C2—C30.2 (6)C16—C15—P2—C21−91.8 (5)
P1—C1—C2—C3176.4 (3)C20—C15—P2—C2189.1 (5)
C1—C2—C3—C4−1.3 (7)C16—C15—P2—C27162.0 (4)
C2—C3—C4—C51.2 (7)C20—C15—P2—C27−17.0 (5)
C3—C4—C5—C60.0 (7)C16—C15—P2—Rh135.1 (5)
C4—C5—C6—C1−1.1 (7)C20—C15—P2—Rh1−144.0 (4)
C2—C1—C6—C51.0 (7)C28—C27—P2—C2168.7 (4)
P1—C1—C6—C5−175.3 (4)C28—C27—P2—C15177.0 (3)
C12—C7—C8—C90.1 (8)C28—C27—P2—Rh1−59.5 (4)
P1—C7—C8—C9−179.2 (4)C40—C35—P3—C2931.4 (4)
C7—C8—C9—C10−1.2 (8)C36—C35—P3—C29−151.8 (4)
C8—C9—C10—C112.0 (9)C40—C35—P3—C41−76.6 (4)
C9—C10—C11—C12−1.8 (9)C36—C35—P3—C41100.1 (4)
C10—C11—C12—C70.7 (8)C40—C35—P3—Rh2153.9 (3)
C8—C7—C12—C110.1 (7)C36—C35—P3—Rh2−29.4 (4)
P1—C7—C12—C11179.4 (4)C34—C29—P3—C3572.5 (4)
C20—C15—C16—C17−0.3 (8)C30—C29—P3—C35−109.3 (4)
P2—C15—C16—C17−179.4 (4)C34—C29—P3—C41179.5 (4)
C15—C16—C17—C181.3 (9)C30—C29—P3—C41−2.3 (5)
C16—C17—C18—C19−1.4 (9)C34—C29—P3—Rh2−53.1 (4)
C17—C18—C19—C200.6 (9)C30—C29—P3—Rh2125.1 (4)
C18—C19—C20—C150.4 (9)C42—C41—P3—C35−67.0 (3)
C16—C15—C20—C19−0.5 (8)C42—C41—P3—C29−175.7 (3)
P2—C15—C20—C19178.6 (4)C42—C41—P3—Rh261.3 (3)
C26—C21—C22—C23−1.1 (6)C56—C55—P4—C49175.6 (3)
P2—C21—C22—C23−176.7 (3)C56—C55—P4—C4367.8 (4)
C21—C22—C23—C240.1 (7)C56—C55—P4—Rh2−61.0 (4)
C22—C23—C24—C251.4 (7)C54—C49—P4—C550.0 (5)
C23—C24—C25—C26−1.8 (8)C50—C49—P4—C55178.2 (4)
C24—C25—C26—C210.8 (8)C54—C49—P4—C43106.3 (4)
C22—C21—C26—C250.7 (7)C50—C49—P4—C43−75.5 (4)
P2—C21—C26—C25176.3 (4)C54—C49—P4—Rh2−127.3 (4)
C34—C29—C30—C311.9 (7)C50—C49—P4—Rh250.9 (4)
P3—C29—C30—C31−176.3 (4)C44—C43—P4—C55−102.2 (4)
C29—C30—C31—C32−3.0 (8)C48—C43—P4—C5574.3 (4)
C30—C31—C32—C332.3 (9)C44—C43—P4—C49149.8 (4)
C31—C32—C33—C34−0.5 (8)C48—C43—P4—C49−33.8 (4)
C30—C29—C34—C33−0.1 (7)C44—C43—P4—Rh227.0 (4)
P3—C29—C34—C33178.2 (4)C48—C43—P4—Rh2−156.6 (3)
C32—C33—C34—C29−0.6 (8)C13—P1—Rh1—C57B27.4 (8)
C40—C35—C36—C370.2 (7)C7—P1—Rh1—C57B−91.9 (8)
P3—C35—C36—C37−176.7 (3)C1—P1—Rh1—C57B148.0 (8)
C35—C36—C37—C38−0.1 (7)C13—P1—Rh1—C57−154.3 (4)
C36—C37—C38—C39−0.5 (8)C7—P1—Rh1—C5786.4 (4)
C37—C38—C39—C401.1 (7)C1—P1—Rh1—C57−33.7 (4)
C36—C35—C40—C390.4 (6)C13—P1—Rh1—Cl124.7 (2)
P3—C35—C40—C39177.2 (3)C7—P1—Rh1—Cl1−94.6 (2)
C38—C39—C40—C35−1.0 (7)C1—P1—Rh1—Cl1145.30 (19)
C48—C43—C44—C450.5 (7)C13—P1—Rh1—Cl1B−156.3 (3)
P4—C43—C44—C45177.0 (4)C7—P1—Rh1—Cl1B84.4 (3)
C43—C44—C45—C460.3 (8)C1—P1—Rh1—Cl1B−35.7 (3)
C44—C45—C46—C47−0.3 (8)C21—P2—Rh1—C57B33.7 (8)
C45—C46—C47—C48−0.6 (7)C15—P2—Rh1—C57B−86.2 (8)
C46—C47—C48—C431.5 (7)C27—P2—Rh1—C57B154.0 (8)
C44—C43—C48—C47−1.4 (6)C21—P2—Rh1—C57−144.7 (4)
P4—C43—C48—C47−177.9 (3)C15—P2—Rh1—C5795.5 (4)
C54—C49—C50—C51−1.3 (8)C27—P2—Rh1—C57−24.3 (4)
P4—C49—C50—C51−179.5 (4)C21—P2—Rh1—Cl136.3 (2)
C49—C50—C51—C522.2 (8)C15—P2—Rh1—Cl1−83.5 (2)
C50—C51—C52—C53−1.2 (9)C27—P2—Rh1—Cl1156.7 (2)
C51—C52—C53—C54−0.7 (9)C21—P2—Rh1—Cl1B−142.7 (3)
C50—C49—C54—C53−0.7 (7)C15—P2—Rh1—Cl1B97.5 (3)
P4—C49—C54—C53177.5 (4)C27—P2—Rh1—Cl1B−22.3 (3)
C52—C53—C54—C491.7 (8)C43—P4—Rh2—C58B−144.0 (4)
C14—C13—P1—C7−177.9 (3)C55—P4—Rh2—C58156.3 (5)
C14—C13—P1—C1−69.1 (4)C49—P4—Rh2—C58−84.0 (5)
C14—C13—P1—Rh158.6 (4)C43—P4—Rh2—C5835.0 (5)
C8—C7—P1—C13−160.7 (4)C55—P4—Rh2—Cl2B158.8 (2)
C12—C7—P1—C1320.0 (5)C49—P4—Rh2—Cl2B−81.4 (2)
C8—C7—P1—C192.4 (4)C43—P4—Rh2—Cl2B37.5 (2)
C12—C7—P1—C1−86.8 (4)C55—P4—Rh2—Cl2−20.8 (2)
C8—C7—P1—Rh1−34.1 (5)C49—P4—Rh2—Cl299.0 (2)
C12—C7—P1—Rh1146.7 (4)C43—P4—Rh2—Cl2−142.1 (2)
C2—C1—P1—C13−83.1 (4)C35—P3—Rh2—C58B−37.8 (4)
C6—C1—P1—C1393.1 (4)C29—P3—Rh2—C58B81.2 (4)
C2—C1—P1—C724.9 (4)C41—P3—Rh2—C58B−159.5 (4)
C6—C1—P1—C7−158.9 (4)C35—P3—Rh2—C58143.2 (5)
C2—C1—P1—Rh1148.8 (3)C29—P3—Rh2—C58−97.8 (5)
C6—C1—P1—Rh1−35.0 (4)C41—P3—Rh2—C5821.5 (5)
C22—C21—P2—C15−28.8 (4)C35—P3—Rh2—Cl2B140.6 (2)
C26—C21—P2—C15155.6 (4)C29—P3—Rh2—Cl2B−100.3 (2)
C22—C21—P2—C2779.5 (4)C41—P3—Rh2—Cl2B19.0 (2)
C26—C21—P2—C27−96.1 (4)C35—P3—Rh2—Cl2−39.8 (2)
C22—C21—P2—Rh1−152.3 (3)C29—P3—Rh2—Cl279.2 (2)
C26—C21—P2—Rh132.1 (4)C41—P3—Rh2—Cl2−161.5 (2)

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
C22—H22···O2i0.952.643.424 (18)140
C48—H48···O1Bii0.952.683.51 (3)145
C4—H4···O1Biii0.952.713.51 (3)142

Symmetry codes: (i) −x+1, y−1/2, −z+2; (ii) −x+2, y+1/2, −z+2; (iii) −x+2, y−1/2, −z+2.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: NG2391).

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