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Acta Crystallogr Sect E Struct Rep Online. 2008 January 1; 64(Pt 1): m22–m23.
Published online 2007 December 6. doi:  10.1107/S1600536807061533
PMCID: PMC2914914

Diaqua­bis[2,5-dichloro-N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)benzene­sulfonamidato-κN]zinc(II)

Abstract

In the title compound, [Zn(C17H14Cl2N3O3S)2(H2O)2], the ZnII ion has a tetra­hedral coordination formed by the two N atoms of the sulfonamide groups and the two water mol­ecules. Two inter- and two intra­molecular O—H(...)O hydrogen bonds are observed in the crystal structure.

Related literature

For related literature, see: Burdulene et al. (1999 [triangle]); Hernández-Delgadillo & Cruz (2006 [triangle]); Macías et al. (2003 [triangle]); Nardelli (1999 [triangle]); Prasad & Agarwal (2007 [triangle]); Raman et al. (2003 [triangle]); Xue et al. (2000 [triangle]).

An external file that holds a picture, illustration, etc.
Object name is e-64-00m22-scheme1.jpg

Experimental

Crystal data

  • [Zn(C17H14Cl2N3O3S)2(H2O)2]
  • M r = 923.95
  • Monoclinic, An external file that holds a picture, illustration, etc.
Object name is e-64-00m22-efi1.jpg
  • a = 15.0683 (7) Å
  • b = 12.3009 (5) Å
  • c = 21.8256 (9) Å
  • β = 104.681 (4)°
  • V = 3913.4 (3) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 1.07 mm−1
  • T = 299 (2) K
  • 0.50 × 0.42 × 0.36 mm

Data collection

  • Oxford Diffraction Xcalibur diffractometer with Sapphire CCD detector
  • Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2007 [triangle]) T min = 0.597, T max = 0.698
  • 29052 measured reflections
  • 7987 independent reflections
  • 5392 reflections with I > 2σ(I)
  • R int = 0.023

Refinement

  • R[F 2 > 2σ(F 2)] = 0.038
  • wR(F 2) = 0.118
  • S = 1.09
  • 7987 reflections
  • 512 parameters
  • 6 restraints
  • H atoms treated by a mixture of independent and constrained refinement
  • Δρmax = 0.73 e Å−3
  • Δρmin = −0.56 e Å−3

Data collection: CrysAlis CCD (Oxford Diffraction, 2007 [triangle]); cell refinement: CrysAlis RED (Oxford Diffraction, 2007 [triangle]); data reduction: CrysAlis RED; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997 [triangle]); molecular graphics: PLATON (Spek, 2003 [triangle]); software used to prepare material for publication: SHELXL97.

Table 1
Selected geometric parameters (Å, °)
Table 2
Hydrogen-bond geometry (Å, °)

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536807061533/at2502sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536807061533/at2502Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The authors thank Professor Dr. Hartmut Fuess, Technische Universität Darmstadt, for diffractometer time.

supplementary crystallographic information

Comment

The interest to develop the coordination chemistry of pyrazolone derivatives is because of their biological and medicinal properties. They present a variety of biological activities ranging from anti-tumour, fungicide, bactericide, antiinflamatory and anti-viral activities (Prasad and Agarwal, 2007; Hernández-Delgadillo et al., 2006; Raman et al., 2003; Burdulene et al., 1999). As part of our efforts to investigate transition metal (II) complexes based on 4-aminoantypirine derivatives and sulfonamide pharmacophoric group, we describe the X-ray characterization of the title compound, (I).

The ZnII ion has a tetrahedral coordination formed by the two sulfonamide N atoms and the two water molecules (Table 1). The bond angles around the central Zn atom are close to the 109° angle of an ideal tetrahedral value. Both hydrogen atoms of each water molecule are involved in an intermolecular O—H···O [O—H···O = 2.52 (3) Å, O—H···O = 2.05 (3) Å, respectively] and an intramolecular O—H···O [O—H···O = 2.06 (2) Å, O—H···O = 2.22 (3) Å, respectively] hydrogen bonds (Table 2).

Experimental

The ligand was obtained according to the procedure previously described (Xue et al., 2000). Compound (I) was prepared by a literature procedure (Macías et al., 2003). Single crystals of (I) suitable for X-ray data collection appeared after a few days from a methanol solution.

Refinement

The O-bound H atoms were located in difference map and were refined with restrained geometry (Nardelli, 1999), viz. O—H distances were restrained to 0.85 (2) Å and H···H distances were restrained to 1.365 (2) Å, thus leading to the angle of 107°.

The other H atoms were positioned with idealized geometry using a riding model with C—H = 0.93Å (aromatic), 0.96Å (methyl). All H atoms were refined with isotropic displacement parameters (set to 1.2 or 1.5 times of the Ueq of the parent atom).

Figures

Fig. 1.
Molecular structure of (I), showing the atom labeling and displacement ellipsoids drawn at the 50% probability level.

Crystal data

[Zn(C17H14Cl2N3O3S)2(H2O)2]F(000) = 1888
Mr = 923.95Dx = 1.568 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 8931 reflections
a = 15.0683 (7) Åθ = 1.9–25.0°
b = 12.3009 (5) ŵ = 1.07 mm1
c = 21.8256 (9) ÅT = 299 K
β = 104.681 (4)°Prism, colourless
V = 3913.4 (3) Å30.50 × 0.42 × 0.36 mm
Z = 4

Data collection

Oxford Diffraction Xcalibur diffractometer with Sapphire CCD detector7987 independent reflections
Radiation source: fine-focus sealed tube5392 reflections with I > 2σ(I)
graphiteRint = 0.023
Rotation method data acquisition using ω and phi scans.θmax = 26.4°, θmin = 2.2°
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2007)h = −18→18
Tmin = 0.597, Tmax = 0.698k = −11→15
29052 measured reflectionsl = −27→27

Refinement

Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.038Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.118H atoms treated by a mixture of independent and constrained refinement
S = 1.09w = 1/[σ2(Fo2) + (0.0463P)2 + 4.1837P] where P = (Fo2 + 2Fc2)/3
7987 reflections(Δ/σ)max = 0.001
512 parametersΔρmax = 0.73 e Å3
6 restraintsΔρmin = −0.56 e Å3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

xyzUiso*/Ueq
C10.5603 (2)0.6796 (3)0.28912 (16)0.0409 (7)
C20.5768 (2)0.6727 (3)0.35422 (16)0.0440 (8)
H20.53010.65170.37250.053*
C30.6630 (2)0.6972 (3)0.39213 (17)0.0494 (9)
C40.7332 (2)0.7298 (3)0.36661 (19)0.0527 (9)
H40.79020.74810.39270.063*
C50.7176 (2)0.7347 (3)0.3020 (2)0.0530 (9)
H50.76470.75540.28410.064*
C60.6323 (2)0.7093 (3)0.26338 (17)0.0469 (8)
C70.4364 (2)0.4486 (2)0.24139 (14)0.0333 (7)
C80.5111 (2)0.3709 (3)0.25951 (14)0.0346 (7)
C90.3639 (2)0.4081 (3)0.25942 (15)0.0383 (7)
C100.5135 (2)0.1837 (3)0.30486 (14)0.0389 (7)
C110.6071 (2)0.1694 (3)0.32822 (15)0.0439 (8)
H110.64640.22900.33440.053*
C120.6417 (3)0.0660 (3)0.34219 (17)0.0528 (9)
H120.70460.05600.35760.063*
C130.5844 (3)−0.0222 (3)0.33367 (18)0.0583 (10)
H130.6083−0.09130.34420.070*
C140.4915 (3)−0.0087 (3)0.3095 (2)0.0577 (10)
H140.4527−0.06870.30290.069*
C150.4561 (2)0.0943 (3)0.29522 (17)0.0477 (8)
H150.39320.10360.27900.057*
C160.2069 (2)0.3622 (3)0.00350 (14)0.0396 (7)
C170.1821 (2)0.2601 (3)−0.02154 (16)0.0466 (8)
H170.22090.2220−0.04080.056*
C180.1005 (3)0.2152 (4)−0.0180 (2)0.0654 (11)
C190.0418 (3)0.2701 (5)0.0092 (2)0.0807 (15)
H19−0.01390.23900.01060.097*
C200.0652 (3)0.3710 (5)0.0345 (2)0.0777 (15)
H200.02530.40870.05310.093*
C210.1481 (2)0.4170 (3)0.03238 (17)0.0557 (10)
C220.4052 (2)0.2880 (2)0.08708 (13)0.0334 (7)
C230.4841 (2)0.2373 (3)0.07336 (14)0.0350 (7)
C240.3656 (2)0.2139 (3)0.11794 (14)0.0360 (7)
C250.5654 (2)0.0663 (3)0.11081 (16)0.0399 (7)
C260.6037 (2)0.0348 (3)0.06249 (17)0.0479 (8)
H260.57500.05180.02060.057*
C270.6851 (3)−0.0223 (3)0.0771 (2)0.0608 (10)
H270.7117−0.04340.04490.073*
C280.7271 (3)−0.0482 (3)0.1386 (2)0.0641 (11)
H280.7824−0.08600.14810.077*
C290.6876 (3)−0.0182 (3)0.1860 (2)0.0616 (10)
H290.7156−0.03710.22770.074*
C300.6065 (2)0.0399 (3)0.17273 (17)0.0492 (8)
H300.58020.06090.20510.059*
C310.2695 (2)0.4531 (3)0.25029 (19)0.0547 (9)
H31A0.25630.50150.21460.066*
H31B0.26560.49200.28760.066*
H31C0.22580.39460.24270.066*
C320.3580 (3)0.2902 (4)0.34843 (19)0.0653 (11)
H32A0.38420.22320.36730.078*
H32B0.29240.28650.34010.078*
H32C0.38030.34920.37690.078*
C330.2803 (2)0.2221 (3)0.14020 (16)0.0452 (8)
H33A0.29290.19950.18370.054*
H33B0.23400.17600.11470.054*
H33C0.25920.29600.13660.054*
C340.3762 (3)0.0120 (3)0.1241 (2)0.0578 (10)
H34A0.4233−0.04110.13950.069*
H34B0.3460−0.00360.08080.069*
H34C0.33240.00960.14930.069*
N10.44014 (18)0.5439 (2)0.20587 (12)0.0362 (6)
N20.47815 (17)0.2898 (2)0.29227 (12)0.0380 (6)
N30.38412 (17)0.3080 (2)0.28874 (13)0.0418 (6)
N40.37893 (17)0.3976 (2)0.07149 (11)0.0359 (6)
N50.48516 (17)0.1322 (2)0.09505 (12)0.0382 (6)
N60.41734 (17)0.1203 (2)0.12843 (12)0.0391 (6)
O10.5833 (2)0.4718 (3)0.12585 (15)0.0683 (8)
H11O0.625 (2)0.516 (3)0.118 (2)0.082*
H12O0.582 (3)0.418 (2)0.0979 (17)0.082*
O20.4242 (3)0.6670 (3)0.07039 (15)0.0901 (11)
H21O0.431 (4)0.721 (3)0.0980 (18)0.108*
H22O0.451 (3)0.692 (4)0.0415 (17)0.108*
O30.39205 (16)0.6519 (2)0.28993 (11)0.0501 (6)
O40.42301 (18)0.74189 (19)0.19750 (12)0.0553 (6)
O50.34501 (15)0.3405 (2)−0.04321 (10)0.0480 (6)
O60.30904 (17)0.5236 (2)−0.01506 (11)0.0535 (6)
O70.58658 (14)0.3693 (2)0.24759 (11)0.0461 (6)
O80.54446 (15)0.27471 (18)0.04963 (11)0.0441 (5)
Cl10.68388 (7)0.68768 (11)0.47414 (5)0.0732 (3)
Cl20.62100 (8)0.71621 (9)0.18265 (5)0.0690 (3)
Cl30.07311 (10)0.08467 (13)−0.04885 (9)0.1168 (6)
Cl40.17694 (9)0.54153 (11)0.06876 (6)0.0899 (4)
S10.44404 (6)0.65578 (7)0.24313 (4)0.03951 (19)
S20.31731 (5)0.41072 (7)0.00093 (4)0.03802 (19)
Zn10.45325 (3)0.52527 (3)0.116433 (17)0.03809 (11)

Atomic displacement parameters (Å2)

U11U22U33U12U13U23
C10.0483 (19)0.0283 (16)0.0476 (19)−0.0001 (14)0.0150 (15)−0.0068 (15)
C20.0430 (18)0.0366 (18)0.054 (2)0.0020 (14)0.0149 (16)−0.0062 (16)
C30.052 (2)0.044 (2)0.051 (2)0.0089 (16)0.0104 (17)−0.0064 (17)
C40.0405 (19)0.043 (2)0.072 (3)0.0043 (16)0.0109 (18)−0.0070 (19)
C50.049 (2)0.039 (2)0.077 (3)−0.0023 (16)0.0265 (19)−0.0066 (19)
C60.061 (2)0.0317 (17)0.054 (2)−0.0056 (16)0.0260 (18)−0.0063 (16)
C70.0366 (16)0.0326 (16)0.0326 (15)0.0011 (13)0.0127 (13)0.0015 (13)
C80.0351 (16)0.0368 (17)0.0328 (15)−0.0030 (13)0.0101 (13)−0.0013 (14)
C90.0386 (17)0.0355 (17)0.0437 (17)0.0072 (14)0.0158 (14)0.0043 (15)
C100.0437 (18)0.0388 (18)0.0346 (16)0.0035 (14)0.0108 (14)0.0083 (14)
C110.0434 (18)0.045 (2)0.0407 (17)0.0015 (15)0.0048 (14)0.0002 (16)
C120.048 (2)0.055 (2)0.048 (2)0.0158 (18)0.0000 (16)−0.0009 (18)
C130.072 (3)0.041 (2)0.060 (2)0.013 (2)0.013 (2)0.0081 (19)
C140.061 (2)0.038 (2)0.073 (3)−0.0053 (17)0.015 (2)0.0061 (19)
C150.0412 (18)0.042 (2)0.058 (2)−0.0020 (15)0.0092 (16)0.0106 (17)
C160.0343 (16)0.050 (2)0.0336 (16)0.0065 (14)0.0068 (13)0.0073 (15)
C170.0419 (19)0.052 (2)0.0443 (19)−0.0029 (16)0.0073 (15)0.0061 (17)
C180.048 (2)0.072 (3)0.070 (3)−0.011 (2)0.004 (2)0.015 (2)
C190.040 (2)0.122 (5)0.080 (3)−0.009 (3)0.016 (2)0.019 (3)
C200.043 (2)0.129 (5)0.065 (3)0.027 (3)0.022 (2)0.010 (3)
C210.049 (2)0.073 (3)0.046 (2)0.0192 (19)0.0139 (16)0.0030 (19)
C220.0346 (15)0.0334 (16)0.0321 (15)−0.0023 (13)0.0083 (12)0.0006 (13)
C230.0352 (16)0.0356 (17)0.0349 (16)−0.0033 (13)0.0104 (13)0.0035 (14)
C240.0367 (16)0.0393 (18)0.0327 (15)−0.0031 (14)0.0102 (13)0.0008 (14)
C250.0431 (18)0.0289 (16)0.0489 (19)−0.0004 (14)0.0139 (15)0.0008 (15)
C260.0486 (19)0.045 (2)0.052 (2)0.0025 (16)0.0163 (16)−0.0065 (17)
C270.060 (2)0.048 (2)0.083 (3)0.0109 (19)0.032 (2)−0.007 (2)
C280.052 (2)0.043 (2)0.097 (3)0.0128 (18)0.019 (2)0.010 (2)
C290.067 (3)0.049 (2)0.065 (2)0.005 (2)0.009 (2)0.016 (2)
C300.055 (2)0.043 (2)0.051 (2)0.0042 (17)0.0167 (17)0.0036 (17)
C310.043 (2)0.056 (2)0.071 (2)0.0095 (17)0.0243 (18)0.012 (2)
C320.067 (3)0.073 (3)0.069 (3)0.014 (2)0.041 (2)0.029 (2)
C330.0418 (18)0.052 (2)0.0458 (18)0.0006 (16)0.0184 (15)0.0066 (17)
C340.062 (2)0.046 (2)0.074 (3)−0.0101 (18)0.034 (2)0.002 (2)
N10.0462 (15)0.0300 (14)0.0340 (13)−0.0019 (11)0.0133 (11)0.0005 (11)
N20.0339 (13)0.0354 (15)0.0464 (15)0.0016 (11)0.0133 (12)0.0086 (12)
N30.0370 (14)0.0426 (16)0.0515 (16)0.0043 (12)0.0215 (12)0.0135 (13)
N40.0387 (14)0.0328 (14)0.0356 (13)0.0014 (11)0.0081 (11)0.0045 (12)
N50.0389 (14)0.0349 (15)0.0462 (15)0.0005 (11)0.0206 (12)0.0058 (12)
N60.0411 (14)0.0342 (15)0.0475 (15)0.0002 (12)0.0211 (12)0.0076 (12)
O10.0611 (17)0.072 (2)0.080 (2)−0.0129 (15)0.0329 (15)−0.0137 (16)
O20.156 (3)0.055 (2)0.062 (2)−0.009 (2)0.033 (2)0.0071 (16)
O30.0474 (13)0.0563 (15)0.0507 (13)0.0042 (11)0.0197 (11)−0.0130 (12)
O40.0726 (17)0.0336 (13)0.0566 (15)0.0086 (12)0.0109 (13)0.0037 (12)
O50.0466 (13)0.0632 (16)0.0385 (12)0.0005 (12)0.0187 (10)−0.0028 (12)
O60.0624 (15)0.0448 (14)0.0498 (14)−0.0028 (12)0.0074 (12)0.0156 (12)
O70.0323 (12)0.0529 (15)0.0562 (14)0.0009 (10)0.0170 (10)0.0070 (12)
O80.0415 (12)0.0425 (13)0.0549 (14)−0.0006 (10)0.0244 (11)0.0090 (11)
Cl10.0562 (6)0.1051 (9)0.0530 (6)0.0131 (6)0.0042 (4)−0.0111 (6)
Cl20.0884 (7)0.0679 (7)0.0600 (6)−0.0338 (6)0.0361 (5)−0.0118 (5)
Cl30.0875 (9)0.0850 (10)0.1688 (15)−0.0411 (8)0.0159 (9)−0.0023 (10)
Cl40.0998 (9)0.0860 (9)0.0894 (8)0.0301 (7)0.0343 (7)−0.0232 (7)
S10.0458 (4)0.0321 (4)0.0415 (4)0.0033 (3)0.0126 (3)−0.0032 (3)
S20.0391 (4)0.0404 (5)0.0346 (4)−0.0002 (3)0.0096 (3)0.0048 (4)
Zn10.0460 (2)0.0346 (2)0.0361 (2)−0.00316 (17)0.01467 (16)0.00228 (16)

Geometric parameters (Å, °)

C1—C21.382 (5)C23—O81.243 (3)
C1—C61.391 (5)C23—N51.375 (4)
C1—S11.809 (3)C24—N61.377 (4)
C2—C31.385 (5)C24—C331.487 (4)
C2—H20.9300C25—C301.375 (5)
C3—C41.374 (5)C25—C261.380 (5)
C3—Cl11.741 (4)C25—N51.423 (4)
C4—C51.370 (5)C26—C271.379 (5)
C4—H40.9300C26—H260.9300
C5—C61.383 (5)C27—C281.368 (6)
C5—H50.9300C27—H270.9300
C6—Cl21.729 (4)C28—C291.370 (6)
C7—C91.348 (4)C28—H280.9300
C7—N11.414 (4)C29—C301.381 (5)
C7—C81.452 (4)C29—H290.9300
C8—O71.230 (3)C30—H300.9300
C8—N21.390 (4)C31—H31A0.9600
C9—N31.386 (4)C31—H31B0.9600
C9—C311.492 (4)C31—H31C0.9600
C10—C151.383 (5)C32—N31.470 (4)
C10—C111.384 (4)C32—H32A0.9600
C10—N21.410 (4)C32—H32B0.9600
C11—C121.379 (5)C32—H32C0.9600
C11—H110.9300C33—H33A0.9600
C12—C131.370 (5)C33—H33B0.9600
C12—H120.9300C33—H33C0.9600
C13—C141.375 (5)C34—N61.462 (4)
C13—H130.9300C34—H34A0.9600
C14—C151.380 (5)C34—H34B0.9600
C14—H140.9300C34—H34C0.9600
C15—H150.9300N1—S11.592 (3)
C16—C171.382 (5)N1—Zn12.024 (2)
C16—C211.386 (5)N2—N31.417 (3)
C16—S21.781 (3)N4—S21.592 (3)
C17—C181.369 (5)N4—Zn12.031 (3)
C17—H170.9300N5—N61.405 (3)
C18—C191.362 (7)O1—Zn12.028 (3)
C18—Cl31.750 (5)O1—H11O0.884 (18)
C19—C201.367 (7)O1—H12O0.896 (18)
C19—H190.9300O2—Zn12.004 (3)
C20—C211.384 (6)O2—H21O0.883 (19)
C20—H200.9300O2—H22O0.881 (19)
C21—Cl41.729 (4)O3—S11.437 (2)
C22—C241.358 (4)O4—S11.433 (2)
C22—N41.422 (4)O5—S21.433 (2)
C22—C231.440 (4)O6—S21.430 (3)
C2—C1—C6118.5 (3)C28—C27—C26120.6 (4)
C2—C1—S1117.2 (2)C28—C27—H27119.7
C6—C1—S1124.3 (3)C26—C27—H27119.7
C1—C2—C3119.8 (3)C27—C28—C29119.8 (4)
C1—C2—H2120.1C27—C28—H28120.1
C3—C2—H2120.1C29—C28—H28120.1
C4—C3—C2121.6 (3)C28—C29—C30120.8 (4)
C4—C3—Cl1118.6 (3)C28—C29—H29119.6
C2—C3—Cl1119.8 (3)C30—C29—H29119.6
C5—C4—C3118.7 (3)C25—C30—C29118.9 (3)
C5—C4—H4120.6C25—C30—H30120.6
C3—C4—H4120.6C29—C30—H30120.6
C4—C5—C6120.6 (3)C9—C31—H31A109.5
C4—C5—H5119.7C9—C31—H31B109.5
C6—C5—H5119.7H31A—C31—H31B109.5
C5—C6—C1120.8 (3)C9—C31—H31C109.5
C5—C6—Cl2116.6 (3)H31A—C31—H31C109.5
C1—C6—Cl2122.6 (3)H31B—C31—H31C109.5
C9—C7—N1127.9 (3)N3—C32—H32A109.5
C9—C7—C8107.8 (3)N3—C32—H32B109.5
N1—C7—C8124.0 (3)H32A—C32—H32B109.5
O7—C8—N2124.6 (3)N3—C32—H32C109.5
O7—C8—C7130.3 (3)H32A—C32—H32C109.5
N2—C8—C7105.0 (2)H32B—C32—H32C109.5
C7—C9—N3111.3 (3)C24—C33—H33A109.5
C7—C9—C31129.8 (3)C24—C33—H33B109.5
N3—C9—C31118.8 (3)H33A—C33—H33B109.5
C15—C10—C11119.7 (3)C24—C33—H33C109.5
C15—C10—N2121.0 (3)H33A—C33—H33C109.5
C11—C10—N2119.3 (3)H33B—C33—H33C109.5
C12—C11—C10119.5 (3)N6—C34—H34A109.5
C12—C11—H11120.3N6—C34—H34B109.5
C10—C11—H11120.3H34A—C34—H34B109.5
C13—C12—C11120.7 (3)N6—C34—H34C109.5
C13—C12—H12119.7H34A—C34—H34C109.5
C11—C12—H12119.7H34B—C34—H34C109.5
C12—C13—C14120.2 (4)C7—N1—S1116.0 (2)
C12—C13—H13119.9C7—N1—Zn1117.49 (19)
C14—C13—H13119.9S1—N1—Zn1126.19 (14)
C13—C14—C15119.7 (4)C8—N2—C10126.7 (3)
C13—C14—H14120.2C8—N2—N3110.0 (2)
C15—C14—H14120.2C10—N2—N3118.7 (2)
C14—C15—C10120.3 (3)C9—N3—N2105.4 (2)
C14—C15—H15119.8C9—N3—C32117.7 (3)
C10—C15—H15119.8N2—N3—C32114.7 (3)
C17—C16—C21118.8 (3)C22—N4—S2112.7 (2)
C17—C16—S2117.0 (2)C22—N4—Zn1122.10 (19)
C21—C16—S2124.1 (3)S2—N4—Zn1120.23 (14)
C18—C17—C16120.1 (4)C23—N5—N6109.3 (2)
C18—C17—H17120.0C23—N5—C25123.6 (2)
C16—C17—H17120.0N6—N5—C25120.0 (2)
C19—C18—C17121.1 (4)C24—N6—N5106.4 (2)
C19—C18—Cl3120.5 (4)C24—N6—C34122.6 (3)
C17—C18—Cl3118.4 (4)N5—N6—C34114.4 (3)
C18—C19—C20119.7 (4)Zn1—O1—H11O120 (3)
C18—C19—H19120.1Zn1—O1—H12O108 (3)
C20—C19—H19120.1H11O—O1—H12O102 (2)
C19—C20—C21120.0 (4)Zn1—O2—H21O110 (3)
C19—C20—H20120.0Zn1—O2—H22O126 (4)
C21—C20—H20120.0H21O—O2—H22O103 (3)
C20—C21—C16120.2 (4)O4—S1—O3117.03 (15)
C20—C21—Cl4118.1 (3)O4—S1—N1108.11 (14)
C16—C21—Cl4121.6 (3)O3—S1—N1112.20 (14)
C24—C22—N4128.6 (3)O4—S1—C1106.15 (16)
C24—C22—C23107.6 (3)O3—S1—C1103.70 (15)
N4—C22—C23123.8 (3)N1—S1—C1109.20 (14)
O8—C23—N5123.1 (3)O6—S2—O5116.33 (15)
O8—C23—C22131.0 (3)O6—S2—N4109.16 (14)
N5—C23—C22105.9 (2)O5—S2—N4113.04 (14)
C22—C24—N6110.0 (3)O6—S2—C16107.99 (15)
C22—C24—C33129.9 (3)O5—S2—C16104.64 (15)
N6—C24—C33120.1 (3)N4—S2—C16104.83 (14)
C30—C25—C26120.9 (3)O2—Zn1—N1108.83 (12)
C30—C25—N5121.0 (3)O2—Zn1—O1114.56 (15)
C26—C25—N5118.0 (3)N1—Zn1—O1105.49 (11)
C27—C26—C25119.1 (4)O2—Zn1—N4114.00 (13)
C27—C26—H26120.4N1—Zn1—N4112.12 (10)
C25—C26—H26120.4O1—Zn1—N4101.44 (11)
C6—C1—C2—C31.3 (5)C11—C10—N2—C847.2 (5)
S1—C1—C2—C3−175.7 (3)C15—C10—N2—N319.4 (4)
C1—C2—C3—C40.8 (5)C11—C10—N2—N3−159.5 (3)
C1—C2—C3—Cl1−179.6 (3)C7—C9—N3—N23.9 (4)
C2—C3—C4—C5−2.0 (5)C31—C9—N3—N2−178.1 (3)
Cl1—C3—C4—C5178.4 (3)C7—C9—N3—C32133.2 (3)
C3—C4—C5—C61.2 (5)C31—C9—N3—C32−48.8 (5)
C4—C5—C6—C10.9 (5)C8—N2—N3—C9−6.6 (3)
C4—C5—C6—Cl2−179.0 (3)C10—N2—N3—C9−164.0 (3)
C2—C1—C6—C5−2.1 (5)C8—N2—N3—C32−137.7 (3)
S1—C1—C6—C5174.7 (3)C10—N2—N3—C3265.0 (4)
C2—C1—C6—Cl2177.8 (3)C24—C22—N4—S2−96.7 (3)
S1—C1—C6—Cl2−5.4 (4)C23—C22—N4—S285.3 (3)
C9—C7—C8—O7172.7 (3)C24—C22—N4—Zn1108.1 (3)
N1—C7—C8—O7−2.0 (5)C23—C22—N4—Zn1−69.8 (3)
C9—C7—C8—N2−4.2 (3)O8—C23—N5—N6170.1 (3)
N1—C7—C8—N2−178.8 (3)C22—C23—N5—N6−7.3 (3)
N1—C7—C9—N3174.5 (3)O8—C23—N5—C2519.9 (5)
C8—C7—C9—N30.1 (4)C22—C23—N5—C25−157.6 (3)
N1—C7—C9—C31−3.2 (6)C30—C25—N5—C23109.5 (4)
C8—C7—C9—C31−177.7 (3)C26—C25—N5—C23−67.0 (4)
C15—C10—C11—C12−0.7 (5)C30—C25—N5—N6−37.8 (4)
N2—C10—C11—C12178.3 (3)C26—C25—N5—N6145.8 (3)
C10—C11—C12—C13−0.5 (5)C22—C24—N6—N5−8.0 (3)
C11—C12—C13—C141.6 (6)C33—C24—N6—N5172.4 (3)
C12—C13—C14—C15−1.4 (6)C22—C24—N6—C34−142.5 (3)
C13—C14—C15—C100.2 (6)C33—C24—N6—C3438.0 (4)
C11—C10—C15—C140.9 (5)C23—N5—N6—C249.5 (3)
N2—C10—C15—C14−178.1 (3)C25—N5—N6—C24161.0 (3)
C21—C16—C17—C180.5 (5)C23—N5—N6—C34148.1 (3)
S2—C16—C17—C18176.4 (3)C25—N5—N6—C34−60.4 (4)
C16—C17—C18—C190.9 (6)C7—N1—S1—O4−164.9 (2)
C16—C17—C18—Cl3−178.7 (3)Zn1—N1—S1—O421.9 (2)
C17—C18—C19—C20−1.1 (7)C7—N1—S1—O3−34.3 (3)
Cl3—C18—C19—C20178.4 (4)Zn1—N1—S1—O3152.46 (17)
C18—C19—C20—C21−0.1 (7)C7—N1—S1—C180.1 (2)
C19—C20—C21—C161.5 (6)Zn1—N1—S1—C1−93.1 (2)
C19—C20—C21—Cl4−176.6 (4)C2—C1—S1—O4133.1 (3)
C17—C16—C21—C20−1.6 (5)C6—C1—S1—O4−43.7 (3)
S2—C16—C21—C20−177.2 (3)C2—C1—S1—O39.2 (3)
C17—C16—C21—Cl4176.3 (3)C6—C1—S1—O3−167.6 (3)
S2—C16—C21—Cl40.8 (4)C2—C1—S1—N1−110.6 (3)
C24—C22—C23—O8−174.8 (3)C6—C1—S1—N172.6 (3)
N4—C22—C23—O83.5 (5)C22—N4—S2—O6−168.7 (2)
C24—C22—C23—N52.3 (3)Zn1—N4—S2—O6−13.0 (2)
N4—C22—C23—N5−179.4 (3)C22—N4—S2—O5−37.5 (2)
N4—C22—C24—N6−174.6 (3)Zn1—N4—S2—O5118.13 (17)
C23—C22—C24—N63.6 (3)C22—N4—S2—C1675.8 (2)
N4—C22—C24—C335.0 (5)Zn1—N4—S2—C16−128.50 (17)
C23—C22—C24—C33−176.9 (3)C17—C16—S2—O6139.8 (2)
C30—C25—C26—C27−1.1 (5)C21—C16—S2—O6−44.6 (3)
N5—C25—C26—C27175.3 (3)C17—C16—S2—O515.3 (3)
C25—C26—C27—C280.5 (6)C21—C16—S2—O5−169.1 (3)
C26—C27—C28—C290.7 (6)C17—C16—S2—N4−103.9 (3)
C27—C28—C29—C30−1.3 (6)C21—C16—S2—N471.7 (3)
C26—C25—C30—C290.5 (5)C7—N1—Zn1—O2165.5 (2)
N5—C25—C30—C29−175.8 (3)S1—N1—Zn1—O2−21.4 (2)
C28—C29—C30—C250.7 (6)C7—N1—Zn1—O1−71.1 (2)
C9—C7—N1—S176.1 (4)S1—N1—Zn1—O1101.98 (19)
C8—C7—N1—S1−110.3 (3)C7—N1—Zn1—N438.4 (2)
C9—C7—N1—Zn1−110.1 (3)S1—N1—Zn1—N4−148.45 (17)
C8—C7—N1—Zn163.5 (3)C22—N4—Zn1—O2163.1 (2)
O7—C8—N2—C10−15.3 (5)S2—N4—Zn1—O29.8 (2)
C7—C8—N2—C10161.8 (3)C22—N4—Zn1—N1−72.6 (2)
O7—C8—N2—N3−170.4 (3)S2—N4—Zn1—N1134.01 (15)
C7—C8—N2—N36.6 (3)C22—N4—Zn1—O139.5 (2)
C15—C10—N2—C8−133.8 (3)S2—N4—Zn1—O1−113.89 (17)

Hydrogen-bond geometry (Å, °)

D—H···AD—HH···AD···AD—H···A
O1—H11O···O5i0.88 (2)2.52 (3)3.277 (4)145 (4)
O1—H12O···O80.90 (2)2.06 (2)2.914 (4)160 (4)
O2—H21O···O40.88 (2)2.22 (3)2.928 (4)137 (4)
O2—H22O···O8i0.88 (2)2.05 (3)2.868 (4)154 (5)

Symmetry codes: (i) −x+1, −y+1, −z.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: AT2502).

References

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