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Acta Crystallogr C. Mar 15, 2010; 66(Pt 3): i22–i24.
Published online Feb 3, 2010. doi:  10.1107/S0108270110001393
PMCID: PMC2855588
Ba5Cl4(H2O)8(VPO5)8: a novel three-dimensional framework solid
Ai-Yun Zhang,a* Juan Zheng,a and Qiu-Fen Wanga
aDepartment of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000, People’s Republic of China
Correspondence e-mail: zay/at/hpu.edu.cn
Received November 2, 2009; Accepted January 11, 2010.
The novel hydro­thermally synthesized title compound, penta­barium tetra­chloride octa­hydrate octa­kis(oxovanadium phosphate), Ba5Cl4(H2O)8(VPO5)8, crystallizes in the ortho­­rhom­bic space group Cmca with a unit cell containing four formula units. Two Ba2+ cations, two Cl anions and the O atoms of four water mol­ecules are situated on the (100) mirror plane, while the third independent Ba2+ cation is on the inter­section of the (100) plane and the twofold axis parallel to a. Two phosphate P atoms are on twofold axes, while the remaining independent P atom and both V atoms are in general positions. The structure is characterized by two kinds of layers, namely anionic oxovanadium phosphate (VPO5), composed of corner-sharing VO5 square pyramids and PO4 tetra­hedra, and cationic barium chloride hydrate clusters, Ba5Cl4(H2O)8, composed of three Ba2+ cations linked by bridging chloride anions. The layers are connected by Ba—O bonds to generate a three-dimensional structure.
The V–P–O system has received considerable attention, not only because of its application to catalysis, but also due to its rich and impressive structural chemistry associated with the ability of vanadium to have tetra­hedral, square-pyramidal and octa­hedral coordination environments in various oxidation states. The introduction of pyridinium cations into the V–P–O system leads to rather complicated structures (Huang et al., 2001 [triangle]; Luan et al., 2001 [triangle]). Several structures have also been reported with the introduction of organic ammonium cations into the V–P–O system (Zhang et al., 1995 [triangle]; Soghomonian et al., 1996 [triangle]; Luan et al., 2003 [triangle]). A few structures with introduction of inorganic cations into the P—V—O system have also been reported (Soghomonian et al., 1998 [triangle]; Khan et al., 1996 [triangle]; Tian & Wu, 2002 [triangle]). In the present paper, we report a new compound, Ba5Cl4(H2O)8(PVO5)8, in which the oxovanadium phosphate framework is templated by an unusual cationic barium chloride hydrate cluster of composition Ba5Cl4(H2O)8.
Ba5Cl4(H2O)8(VPO5)8 crystallizes in the ortho­rhom­bic space group Cmca with a unit cell consisting of four asymmetric units. The coordination environments of the V, P and Ba atoms are shown in Fig. 1 [triangle]. Each of the two independent V sites in the asymmetric unit exhibits a distorted square-pyramidal [VO5] geometry. The basal positions are defined by O-atom donors from four adjacent phosphate groups and the apical O atoms (O1 and O2) are coordinated to adjacent Ba2+ cations. Based on the stoichiometry of the compound and assuming normal oxidation states for Ba, Cl, P and O, the oxidation states of vanadium are VIV and VV in a ratio of 3:1, i.e. two of the eight V atoms are VV and six are VIV. Bond-valence sum calculations (Brese & O’Keeffe, 1991 [triangle]) for V1 and V2 give values of 4.42 and 4.35, respectively. The mean valence, 4.385, is reasonably close to 4.25 for VIV:VV = 3:1. Similar mixed bond-valence sums for V atoms have been reported in other oxovanadium phosphates (Zhang et al., 1999 [triangle]; Le Fur et al., 2001 [triangle]). Atoms Ba1, Ba2, Cl1, Cl2 and O11–O14 are situated on the (100) mirror plane, while atom Ba3 is on the inter­section of the (100) plane and the twofold axis parallel to a. Atom P1 is on the twofold axis parallel to b and atom P3 is on the twofold axis parallel to a. All other atoms, i.e. V1, V2, P2 and O1–O10, are on general positions.
Figure 1
Figure 1
The asymmetric unit and the complete coordination environments of the V, Ba and P atoms in the structure of Ba5Cl4(H2O)8(VPO5)8. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry codes: (i) −x, −An external file that holds a picture, illustration, etc.
Object name is c-66-00i22-efi2.jpg +  (more ...)
Atoms Ba1 and Ba2 are both 11-coordinate, with four phosphate O atoms, two vanadyl oxide atoms, three water mol­ecules and two bridging chloride anions. Atom Ba3 is ten-coordinate, with four phosphate O atoms, four water mol­ecules and two bridging chloride anions. The Ba—O bond lengths range from 2.725 (4) to 3.086 (7) Å, while the O—Ba—O angles span the range 46.77 (10)–180°. The Ba—Cl bond lengths vary from 3.225 (2) to 3.362 (2) Å, with the Cl—Ba—Cl angles in the range 131.61 (5)–180°.
There are two kinds of layer in the structure, namely anionic oxovanadium phosphate (VPO5) and cationic barium chloride hydrate, Ba5Cl4(H2O)8. The VPO5 layers consist of a checker­board pattern of corner-sharing VO5 square pyramids and PO4 tetra­hedra in the bc plane, and are similar to those found in Na3V2O2F(PO4)2 (Massa et al., 2002 [triangle]) (Fig. 2 [triangle]). In the layers of barium chloride hydrate, clusters of three Ba2+ cations are linked via additional bridging of the chloride anions and water mol­ecules to form a two-dimensional network in the bc plane (Fig. 3 [triangle]). To our knowledge, this barium chloride hydrate structural unit is unprecedented. Adjacent VPO5 and Ba5Cl4(H2O)8 layers are connected by Ba—O bonds involving both phosphate and vanadyl O atoms of the anionic layers, and the layers alternate along the a axis to generate the three-dimensional structure (Fig. 4 [triangle]).
Figure 2
Figure 2
A view of the VPO5 layers along the a axis. The VO5 square pyramids are larger and the PO4 tetra­hedra are smaller.
Figure 3
Figure 3
A view of the Ba5Cl4(H2O)8 layers along the a axis.
Figure 4
Figure 4
The three-dimensional structure of Ba5Cl4(H2O)8(VPO5)8, viewed along the b axis. The layers parallel to the bc plane can be seen to stack along the a axis.
Single crystals of the title compound were prepared from a mixture of NH4VO3 (2 mmol, 0.234 g), BaCl2 (2 mmol, 0.4886 g), H3BO3 (2.5 mmol, 0.1758 g), H3PO4 (2 ml) and H2O (2 ml). The mixture was sealed in a 30 ml Teflon-lined stainless steel vessel and heated at 443 K for 6 d under autogenous pressure, then cooled to room temperature. The resulting dark-green crystals were collected and dried in air at ambient temperature.
Crystal data
  • Ba5Cl4(H2O)8(VPO5)8
  • M r = 2267.91
  • Orthorhombic, An external file that holds a picture, illustration, etc.
Object name is c-66-00i22-efi1.jpg
  • a = 13.5073 (8) Å
  • b = 8.8803 (5) Å
  • c = 35.482 (2) Å
  • V = 4256.1 (4) Å3
  • Z = 4
  • Mo Kα radiation
  • μ = 6.90 mm−1
  • T = 295 K
  • 0.20 × 0.12 × 0.12 mm
Data collection
  • Bruker APEXII CCD area-detector diffractometer
  • Absorption correction: multi-scan (SADABS; Bruker, 2007 [triangle]) T min = 0.339, T max = 0.492
  • 10601 measured reflections
  • 1993 independent reflections
  • 1614 reflections with I > 2σ(I)
  • R int = 0.046
Refinement
  • R[F 2 > 2σ(F 2)] = 0.031
  • wR(F 2) = 0.078
  • S = 1.04
  • 1993 reflections
  • 180 parameters
  • H-atom parameters constrained
  • Δρmax = 1.63 e Å−3
  • Δρmin = −1.20 e Å−3
The H atoms were located in a difference map and included in the model with O—H distances constrained to 0.85 Å and with U iso(H) = 1.2U eq(O). The highest peak in the difference map is 1.82 Å from atom H11 and the deepest hole is 0.66 Å from atom Ba1.
Data collection: APEX2 (Bruker, 2007 [triangle]); cell refinement: SAINT (Bruker, 2007 [triangle]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 [triangle]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 [triangle]); molecular graphics: SHELXTL (Sheldrick, 2008 [triangle]); software used to prepare material for publication: SHELXTL.
Supplementary Material
Crystal structure: contains datablocks I, global. DOI: 10.1107/S0108270110001393/sq3227sup1.cif
Structure factors: contains datablocks I. DOI: 10.1107/S0108270110001393/sq3227Isup2.hkl
Acknowledgments
We thank the Universities and Colleges Natural Science Foundation of Henan (grant No. 2009A150011) and the Natural Science Foundation of China (grant No. 200903036) for financial support.
Footnotes
Supplementary data for this paper are available from the IUCr electronic archives (Reference: SQ3227). Services for accessing these data are described at the back of the journal.
  • Bruker (2007). APEX2 (Version 2.1-4) and SADABS (Version 2007/4). Bruker AXS Inc., Madison, Wisconsin, USA.
  • Brese, N. E. & O’Keeffe, M. (1991). Acta Cryst. B47, 192–197.
  • Huang, C.-H., Huang, L.-H. & Lii, K.-H. (2001). Inorg. Chem.40, 2625–2627. [PubMed]
  • Khan, M. I., Meyer, L. M., Haushalter, R. C., Schweitzer, A. L., Zubieta, J. & Dye, J. L. (1996). Chem. Mater.8, 43–53.
  • Le Fur, E., Villars, B.-D., Tortelier, J. & Pivan, J.-Y. (2001). Int. J. Inorg. Mater.3, 9–15.
  • Luan, G.-Y., Wang, M.-H., Wang, E.-B., Han, Z.-B. & Hu, C.-W. (2001). J. Mol. Sci.17, 121–123.
  • Luan, G.-Y., Wang, M.-H., Wang, E.-B., Liu, W.-C., Li, Y.-G. & Xu, L. (2003). J. Mol. Sci.19, 115–118.
  • Massa, W., Yakubovich, O.-V. & Dimitrova, O. V. (2002). Solid State Sci.4, 495–501.
  • Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [PubMed]
  • Soghomonian, V., Haushalter, R. C., Zubieta, J. & O’Connor, C. J. (1996). Inorg. Chem.35, 2826–2830.
  • Soghomonian, V., Meyer, L. A., Haushaker, R. C. & Zubieta, J. (1998). Inorg. Chim. Acta, 275–276, 122–129.
  • Tian, J.-L. & Wu, J.-G. (2002). Chin. Rare Earths, 23, 24–26.
  • Zhang, L.-R., Shi, Z., Yang, G.-Y., Chen, X.-M. & Feng, S.-H. (1999). J. Solid State Chem.148, 450–454.
  • Zhang, Y.-P., Clearfield, J. A. & Haushalter, R. C. (1995). Chem. Mater.7, 1221–1225.
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