3.1. Response of the Pt electrode
In are presented data obtained during a steady voltammetric cycle for the EQCM bare Pt electrode: (a) the CV data at 50 mV/s; (b) the corresponding EQCM mass data; and (c) the derivative of the EQCM mass data, or the massogram
]. Each voltammetric cycle begins at 0 V, ramps anodically to +0.8 V, then cathodically from +0.8 V to -0.7 V, and then completes the cycle anodically from -0.7 V to 0 V. The data shown are for the fifth cycle, except for the anodic portion from -0.7 to 0 V, which is the end of the fourth cycle. (The voltammograms are steady by about the third cycle.) are discussed immediately below, and subsequently.
As shown in , without arsenic the voltammogram exhibits the characteristic features expected for a platinum electrode. The region between −0.7V and −0.55V corresponds to the so-called hydrogen adsorption-desorption zone. During the anodic sweep, OH-
adsorption is first observed at about -0.26 V, beginning the formation of platinum surface oxide. During the cathodic sweep, the reduction peak (B) of the platinum surface oxides, located at about −0.28V, is also observed [15
]. It is noted that all the potentials reported here are vs. Ag/AgCl (Satd KCl), and they are shifted to significantly lower values than in acidic media, in accordance with the well-known dependence of reaction potential on pH.
As shown in , the addition of arsenic results in the appearance of a large peak (A) in the steady voltammograms, located at about +0.38V, and another cathodic peak (C) located at about -0.56V. Peak A has been attributed to the catalytic oxidation of As(III) to As(V) on Pt by a number of authors [3
]. Cabelka et al.
] observed this peak in an acidic medium at +0.85V (vs SCE) and attributed it “to the simultaneous processes of (i) oxide formation, (ii) oxidation of adsorbed As(III), and (iii) oxidation of As(III) transported to the electrode surface…” The data in exhibit a linear increase in the peak current of peak A of 0.15 A/cm-2
, while the data of Cabelka et al.
] in an acidic medium on a Pt RDE also show a linear, but larger current increase of about 1.3 A/cm-2
. The data of Dai and Compton [3
], also in an acidic medium on a Pt “macro electrode,” exhibit the same behavior, but with 0.6 A/cm-2
. These observed differences are attributed to the available amount of As(III) in acidic vs. alkaline media, and/or perhaps the number of catalytic Pt sites available for arsenic oxidation from solution in the case of each electrode. In alkaline solutions, almost all the arsenic in the bulk solution is As(V). Consequently, the contribution of As(III) from solution to the oxidation peak is limited to what is formed and present on the surface and available in solution in the vicinity of the surface during the CV. Peak C in is attributed to the formation of As(0)/As(III) on the Pt surface [17
]. The anodic current observed from -0.5 to 0 V during the anodic sweep is attributed to the oxidation of As(0) as subsequently discussed below.
In are presented the corresponding mass data for the Pt electrode versus the potential, as recorded by the EQCM for the same cycle as in . As shown, the data without arsenic exhibit completely reversible mass gain and loss and zero net change in mass per cycle. Most of the mass is gained relatively evenly during the anodic sweep, corresponding to platinum oxidation, and most of it is lost more precipitously in the reduction of platinum oxides during the cathodic sweep. The mass data with arsenic in solution are quite different. Almost all of the mass gain occurs at the end of the cathodic sweep, which coincides with the reduction peak attributed primarily to the formation of As(0)/As(III) (peak C). The mass loss occurs in two stages – during the anodic sweep at positive potentials (peak A) from approximately 0.3V, and another coincident with the negative cathodic peak (peak B), which is attributed primarily to the reduction of the Pt surface.
From , the mass loss over peak A during the anodic sweep from about 0V to the end of the sweep is the same value of about 10.5 ng for the 100, 75, and 50 ppm solutions. (The 25 ppm solution data are discussed further below). However, it is also noted that the electrode mass in the absence of arsenic increases by about 13.5 ng over this same potential range due to Pt oxidation. Consequently, the latter behavior considerably “masks” the actual mass loss due to arsenic oxidation/desorption. During the anodic sweep over the potential region of peak A it is quite likely that almost all the active Pt sites, whether originally containing adsorbed arsenic or not, end up oxidized by the end of the sweep (as evidenced by the relatively flat mass curve during the return cathodic sweep for Pt in the absence of arsenic), then it is reasonable to assume that the total mass gain due to Pt oxidation will be roughly similar in the presence of arsenic as well. This assumption means that the actual mass loss due to oxidation/desorption of adsorbed arsenic for the three highest concentration arsenic solutions was actually about 24 ng. This approximation is supported by the behavior of the “loop” in the mass record evident at the highest anodic potentials for all the arsenic-containing solutions upon switching from the anodic to the cathodic sweep, which is invariant with arsenic concentration. Examination of these data indicate that this “loop” is caused by the mass increase due to Pt oxidation, occurring simultaneously with the mass loss due to oxidation/desorption of arsenic from the surface. Correction of the mass behavior due to Pt oxidation eliminates this “loop” for all the arsenic solutions, consistent with the preceding assumption.
Shibata et al. [19
] have determined that arsenic deposited as As(0) under cathodic conditions (in peak C) becomes oxidized to As(III) as (As2n
complexes on Pt and Au surfaces, where the Asad
are adsorbed arsenic atoms, or “ad-atoms.” The subsequent oxidation/hydrolysis/desorption of these complexes to As(V) in alkaline solution occurs according to the stoichiometry:
which corresponds to a net mass loss from the electrode of 99 g/mol Asad.
Since the mass loss in peak A is the same for the three highest arsenic concentrations, this means that the adsorbed arsenic sites at the inception of peak A are saturated for the three highest concentrations (but not for the lowest concentration of 25 ppm, from which only a net mass loss of about 17 ng occurs). However, as can be seen from , the total charge comprising the peak increases monotonically with arsenic concentration. Consequently, there must be an additional process occurring than oxidation of just the adsorbed arsenic to produce the significant observed change in current.
It has been well established that Pt sites can participate catalytically in the oxidation of As(III) from solution in accordance with a process that has been demonstrated for arsenic in acidic solutions [3
]. In this process, OH-
and As(III) are adsorbed on a Pt site from solution. Transfer of the oxygen atom from the adsorbed OH to arsenic then oxidizes As(III) to As(V), which then desorbs from the catalytic site to complete the process. In alkaline solution at elevated pH, As(O)2
(aq) is the most stable form of As(III) [21
], and the corresponding anodic electrocatalytic process is:
with no attendant change in the electrode mass.
From the preceding, it is concluded the peak A current is the result of at least two processes: (1) oxidation of (As2n)adO3n surface complexes that originate from the reduction of As(V) from solution in peak C; and (2) electrocatalytic oxidation of As(III) from solution in the immediate vicinity of the electrode.
In are summarized the results obtained from the analysis of peak A, in accordance with the preceding observations. It is noted that the total charge in peak A (corrected for the double layer charge) is almost perfectly linear with the bulk As concentration at 0.025 nmol electrons/ppm As. As shown, the contribution to the total charge from the oxidation/desorption of the pre-existing As(III) surface complexes produced by As(0) oxidation is less than that from the electrocatalytic oxidation of As(III) from solution, ranging from about 27% for the 25 ppm solution to 15% of the total for the 100 ppm solution. In the case of the 25 ppm solution, it is apparent that there was insufficient arsenic deposited on the Pt electrode prior to peak A to populate all the available contiguous sites, as occurred for the three higher concentrations. However, as shown in , the amount of As(III) oxidized from solution remains linear in the bulk arsenic concentration.
Results of the analysis of peak A
The amount of Pt active sites calculated from the total corrected charge in reduction peak B for the non-arsenic containing electrolyte in is 0.9 nmol. Based on this value, from it is noted that the “Pt-catalyzed” oxidation of As(III) to As(V) becomes truly catalytic (i.e., exhibiting a turnover number greater than unity) for the two highest As concentrations of 75 and 100 ppm.
Under alkaline conditions, practically all the arsenic in the bulk solution is As(V). Consequently, the contribution of As(III) from solution to the oxidation peak is limited to what is available in the immediate vicinity of the surface during the CV. In , at the inception of the return cathodic sweep following peak A, it is noted that the mass of the electrode following peak A continues to decrease slowly. (The mass loss is also “masked” by the increase in mass of the Pt electrode over in this region.) Thus, there is still some arsenic left on the electrode after peak A.
It is well known that stable Pt oxides “passivate” the Pt surface with respect to “detection,” or oxidation of As(III) [18
]. Cabelka et al.
] have postulated As(III) adsorption onto PtO, as well as PtOH sites. Those adsorbed on PtO sites will be stable, since the oxygen atom is bonded to Pt and will not oxidize As(III). These PtOAs(III) complexes will survive anodic oxidation until Pt is reduced. The latter begins at about -0.1V to become peak B (i.e., “peak D” in the work of Cabelka et al.
]). As shown in , in the presence of arsenic the amplitude of this peak decreases and shifts to more negative potentials with increasing arsenic concentration. This process occurs simultaneously with the reduction of Pt surface oxides (peak B). In the vicinity of peak B it is expected that the PtO in the stable arsenic sites will also be reduced; e.g., in alkaline solution:
The oxygen atom in the adsorbed OH in PtOH sites has been identified as primarily responsible for the oxidation of As(III) from solution to As(V) in anodic peak A [3
]. Consequently, As(III) in the resultant complex can then be oxidized by transfer of the oxygen from the adsorbed OH to arsenic:
In the total current data in , reactions (4
) and (5
) represent a redox process (i.e., Pt reduction and arsenic oxidation) that produces no net charge. Consequently, it appears as an “inhibition” or diminution of peak B in terms of total current, since the Pt sites involved do not consume an electron as they would have in the absence of the stable arsenic complexes.
In it is noted that there is almost zero anodic current for all the arsenic solutions during the return cathodic sweep from about 0.7 to 0.1V. However, the data of Cabelka et al.
] and Dai and Compton [3
] in acidic media, both exhibit considerable anodic current over this range of potential, proportional to the bulk concentration of arsenic in their solutions. Under acidic conditions, where As(III) is the predominant arsenic form in the bulk solution, the anodic current during the return cathodic sweep is most probably a continuation of the electrocatalytic oxidation of As(III) from solution. However, in the present case under alkaline conditions, where all the available As(III) in solution in the immediate vicinity of the electrode appears to be exhausted in peak A, there should be little or no anodic current over this same potential range, just as shown by the data.
Immediately following peak B in the cathodic sweep appears peak C, that is attributed to the adsorption and reduction of As(V) from solution. Since the potential stability region for As(III) at high pH is very narrow [21
], the reduction of As(V) to As(III) will be immediately followed by reduction to As(0), resulting in elemental arsenic deposition, contributing to the observed precipitous mass increase over a small potential range (). This is the primary source of the arsenic that is subsequently oxidized back to As(V) and desorbed in peak A. Once deposited, the As(0) undergoes rapid oxidation to form an “oxy-arsenic surface polymer” of As(III) with a planar structure [19
]. As discussed above, Shibata et al.
] proposed that As(ad)
(0) ad-atoms are deposited on the Pt surface by rapid reduction of As(V) from solution. As(ad)
(0) is then oxidized to a +1 valence state, OH-As(ad)
, and then rapidly to As(ad)
(III), forming As2n
. The initial mechanistic step proposed by Shibata et al. [19
] exhibits a mass change per electron, M/n = 17. Subsequent steps in their mechanism to produce As(ad)2n
exhibit M/n = 8. It is noted, however, that their data are also consistent with the electrocatalytic mechanism discussed above. That is, in alkaline media, OH-
adsorbs onto As(0) sites:
with M/n = 17. Subsequent transfer of the oxygen atom from the adsorbed OH to arsenic will then oxidize As(0) to As(III):
with M/n = 8. Condensation reactions between contiguous oxidized arsenic sites will then produce As(ad)2O3:
etc., to continue to grow the surface oxide as As(ad)2nO3n. In alkaline media, the overall stoichiometry is:
with M/n = 8. From the current data and that which exists in the literature, it is not possible to determine which mechanism is more correct – that of Shibata et al. [19
] involving arsenic oxidation to a +1 valence state, or the electrocatalytic oxygen transfer reaction. However, this mechanistic difference does not affect the present data analysis and conclusions.
The apparent mass gain in peak C for the three highest concentration arsenic solutions is about the same at 18.4 ng. However, from it is noted that the Pt electrode in the absence of arsenic loses about 4.3 ng over the same potential range, which “masks” the actual mass gain due to arsenic. If it is assumed that the latter remains about the same in the presence of arsenic, this means that approximately 22.7 ng are gained from arsenic deposition. The charge, corrected, for the double layer charge over this same range, is about 0.71 electron nmol, or M/n = 32 g/electron mol. The process of adsorption and reduction of As(V) (as AsO43-) from solution to As(0) yields M/n = 75/5 = 15 g/electron mol, while the overall process of adsorption and reduction of As(V) to adsorbed As(III) (as AsO1.5) is 99/2 = 49.5 g/electron mol. Since the experimental value lies between these two limits, it is concluded that about 76% of the As(V) from solution is reduced to AsO1.5 in peak C. The remaining 24% of the arsenic as As(0) becomes oxidized during the return anodic sweep following peak C, which gives rise to the anodic current during the anodic sweep from about -0.5 to 0 V, and the concomitant mass increases evident in over this same range.
Mass loss in successive CV cycles is apparent for all the arsenic solutions at the lowest potentials, which repeats from cycle to cycle after the voltammograms become steady (i.e., after about the third cycle). From , these mass “deficits” are about 2.3, 4.9, 5.4, and 8.8 ng for the 25, 50, 75, and 100 ppm solutions. Since no corresponding mass deficit occurs in the absence of arsenic, these must be due to arsenic redox processes. The mass increase due to arsenic reduction in peak C is roughly the same as the mass loss due to oxidation in peak A. However, the mass remaining on the electrode following peak A is of the same order of magnitude as the mass deficit between cycles. As discussed above, the arsenic mass remaining on the electrode at the end of peak A is attributed to stable As(III) complexes formed from solution on deactivated PtO sites that are slowly oxidized and desorb as As(V) during the return cathodic sweep following peak A.
In is presented a plot of the derivative of the electrode mass with respect to time (dM/dt) versus the applied potential, known as a massogram
]. This type of data representation can be particularly useful in cases where the current behavior is coupled to adsorption/desorption of species, and where capacitative current effects predominate such that the CV is relatively featureless, as is the case with arsenic redox on the carbon electrode (CE) (see below). In the absence of arsenic, clearly shows the large mass loss peak during the cathodic sweep, corresponding to the reduction of Pt surface oxides (peak B) [3
]. It also shows the more gradual and steady mass gain during the anodic sweep due to platinum oxidation. In the presence of arsenic, the maximum of the cathodic mass loss corresponding to reduction of platinum surface oxides (peak B) appears to shift slightly to more positive potentials, similar to what is evident in the behavior of the charge in . also clearly shows the anodic mass loss peak (peak A) and the cathodic mass gain peak (peak C).
3.2. EQCM response of the carbon electrode (CE) in the electrolyte
In are presented cyclic voltammograms (CV) for the carbon electrode (CE) in the sodium chloride electrolyte for five consecutive cycles, starting from 0V. As shown, in comparison to , the CV is featureless, reflecting an essentially capacitative process, in agreement with the large contribution of the double layer to the total charge. This also indicates that the process is dominated by the CE, and that the effects of the underlying Pt surface are negligible in the presence of the carbon layer.
(a) Voltammogram; (b) electrode mass behavior; and (c) massogram (dM/dt vs E) of the carbon electrode at a solution pH of 12 at 50 mV/s in the NaCl electrolyte for five voltammetric cycles with no arsenic in solution.
In are presented the corresponding mass data for the CE versus potential, as recorded with the EQCM for five consecutive cycles. As shown, the CE mass decreases continuously, but steadily, with cycling by about 14-18 ng/cycle. Once steady cyclic conditions are attained, the largest mass loss occurs during the cathodic sweep from 0V to more negative potentials. This is followed by a smaller mass increase during the anodic sweep. Experiments were also conducted continuously under similar conditions for up to 30 cycles, while exhibiting very similar steady mass losses. This behavior differs significantly from that in in the absence of arsenic for the bare Pt electrode, for which the mass record was completely reversible and reproducible from cycle to cycle. Consequently, the behavior in must be due to a net mass loss of carbon from redox processes under these experimental conditions. Similar redox processes have also been observed during the investigation of capacitance changes with pH of a high specific surface area carbon cloth [26
]. Under alkaline conditions (pH values from 13.6 to 10), a cathodic process was identified at potentials below 0.6V vs RHE (i.e., at about -0.3 V vs Ag/AgCl) that was related to an unidentified base active surface functionality [26
]. This is consistent with the observed mass loss being due to a reduction process associated with carbon-oxygen surface groups, most probably formed on the carbon surface during the anodic sweep.
The corresponding massogram for the five consecutive cycles is presented in . In this figure, the large, broad mass loss peak during the cathodic sweep is clearly evident with a maximum at approximately -0.4V, as well as the much broader, but smaller mass gain peak centered at approximately -0.1V during the anodic sweep.
Under anodic conditions in alkaline solution, carbon oxidation can occur via adsorption of hydroxide and oxidation of carbon in an fashion analogous to what occurs on Pt, as discussed above; i.e.,
where C( ) is a reactive carbon site, and C(O) and C(O2
) are carbon-oxygen surface complexes. Under alkaline conditions, these can be various types of complexes like semiquinones, carboxyls, phenols, esters, etc. Therefore, as used here, C(O) and C(O2
) are simply intended to be representative of the various types of CO and CO2
-producing carbon-oxygen surface complexes that may participate in the carbon redox processes. The broad mass gain peak in during the anodic sweep is attributed to oxidation processes like reactions (10
) and (11
) that produce carbon-oxygen surface complexes.
Under cathodic conditions in alkaline solution, carbon-oxygen surface complexes can also be reduced according to reactions like:
to produce gaseous oxides of carbon, and, possibly, H2. These are electrogasification steps that cause mass loss from the carbon electrode as CO and CO2, as well as create additional carbon active sites from the broken bonds created when the solid carbon atom leaves the surface as a carbon oxide.
Addition of the two half-cell reactions (10
) and (12
), and (11
) and (13
which are electrochemical analogs in alkaline solution of the well-known thermal steam gasification reaction.
Electrochemical carbon gasification, or electrogasification
, also sometimes referred to by the more generic term of “carbon corrosion,” which includes oxidation, has been reported by a number of authors in various electrochemical contexts [27
]. Such redox cycles involving net carbon loss account for at least some of the mass loss observed during the cathodic sweep, as well as the mass increase during the anodic sweep by forming carbon-oxygen surface complexes. Electrogasification is the background against which the arsenic redox reactions occur on the CE, as discussed below.
Although the gasification products are CO, CO2
, and H2
, it is important to note that no gas bubbles were ever observed on the surface or in the vicinity of the electrode. This is understandable in terms of the very small amounts of gas generated per cycle. For example, assuming an upper limit of gas generation of about 18 ng of CO, this is about 0.6 nmol, which is a total gas volume of 0.015 μl per cycle. This entire amount would form one gas bubble 300 μm in diameter. However, since gas generation is distributed over the entire electrode surface, it is much more likely that the generated gases dissolve in solution. Under these conditions, the saturation level of dissolved CO in water in contact with CO gas is 990 nmol/ml [30
], which far exceeds the electrogasification generation capacity in the present experiments. H2
bubbles would not be observed either for the same reason since the value of the Henry's law constant for H2
is similar to that for CO [30
bubbles would not be observed either, for similar reasons, especially since CO2
is even more soluble in water than CO (i.e., the Henry's law constant for CO2
in water is two orders of magnitude greater than that for CO [30
]). Consequently, the cathodic mass loss peak in is attributed to electrogasification processes like reactions (12
) and (13
The formation of C(H) complexes on the carbon surface is also likely. Indeed, hydrogen chemisorption on carbon active sites has recently been detected in electrochemical experiments by in situ
Raman spectroscopy [31
]. It is also well known that gas phase hydrogen dissociatively chemisorbs on carbon active sites, and can also recombine to release H2
, , , 35
]. In alkaline solution, active carbon sites can also be generated anodically from C(H) sites via
adsorption and hydrogen abstraction:
The C( ) sites could then be further oxidized to C(O) or C(O2). However, since more than one active site can be produced for every cathodic gasification step (exactly how many depends on the nature of the oxygen surface complex decomposed, as well as the nature of the carbon (for example, whether it is ordered or disordered), the important point is that carbon electrogasification produces additional carbon sites that are available for arsenic redox as well.
3.3. EQCM response of the CE in arsenic-containing electrolyte
In are presented the steady CV data for the CE as a function of arsenic concentration in the electrolyte solution. A comparison of and show considerable changes with increasing arsenic concentration. In particular, the current decreases appreciably over the entire cycle. This decrease of the double layer charge may be at least partially attributable to the effect of substitution of the much larger As(V) anions (AsO43-) for chlorine ions, even though they are less concentrated.
Figure 3 (a) Voltammogram; and (b) mass behavior of the carbon electrode at a solution pH of 12 at 50 mV/s in NaCl electrolyte as a function of arsenic concentration. The data all correspond to the fifth voltammetric cycle beginning with a positive potential sweep (more ...)
In are presented the corresponding mass data for the CE. Qualitatively, these data are remarkably similar to those for the bare Pt electrode in arsenic solutions in , except that the mass variations are considerably larger (attributed to the larger number of active sites in the CE than on the bare Pt electrode). The similarity is due to the fact that the redox mechanisms for the Pt and C( ) sites are mechanistically similar. However, as noted previously, the arsenic-free data on the bare Pt electrode in show no net mass change upon cycling, whereas the corresponding data for the CE electrode in exhibit a relatively large net mass loss on the order of 18 ng per cycle due to carbon electrogasification. But, the net electrode mass data for the arsenic-containing solutions in all still show relatively small net mass losses per cycle, just as in .
Even though arsenic and oxygen may compete for similar active carbon sites in the CE electrode, even at 100 ppm the arsenic concentration is still an order of magnitude less than that of OH-, and thus there should be relatively little difference in the carbon electrogasification rate in the presence of arsenic. Consequently, the large net mass loss of the CE due to carbon electrogasification at the end of the cathodic sweep “masks” the cathodic mass gain due to arsenic in peak C. Instead of a mass loss, on the CE electrode there is clearly a significant mass gain due to arsenic reduction over successive cycles for all the arsenic concentrations. It is also noted that the behavior of the mass loss in peak A is very similar to what was found on the bare Pt electrode. That is, following the peak there is still a relatively large residual mass of arsenic left on the electrode which gradually decreases with decreasing potential during the cathodic sweep. This suggests a similar arsenic oxidation process occurring in peak A as that for the bare Pt electrode; that is, oxidation of surface AsO1.5 and As(III) from solution. However, a similar analysis cannot be performed for the CE as for the Pt electrode because the faradaic current data are obscured by the relatively large capacitative current.
The behavior of the total mass of the CE for five successive cycles as a function of arsenic concentration is shown in . Correcting these data for the effect of carbon electrogasification by subtracting the CE mass loss data in the absence of arsenic yields . As expected from the preceding discussion, the net mass loss per cycle observed in “masks” the mass gain due to arsenic reduction on additional active sites created by carbon electrogasification during the cyclic process. After the first cycle, the net mass loss observed in and the arsenic mass gain in become relatively linear with cycle or time. From , the electrogasification rate in the absence of arsenic is about 18 ng/cycle. For a 0.25 mg carbon electrode, this corresponds to a gasification rate of 72 μg/g/cycle, or about 72 μg/g/min. From , the net mass gain per cycle for the 100 ppm arsenic solution data is about 18 − 7 = 11 ng/cycle. Assuming that the mass gain is mostly as AsO1.5, this suggests that the increase in net cathodic arsenic removal is about 0.11 nmol/cycle, or, for an estimated 0.25 mg of carbon in the CE, 444 nmol As/gC/cycle, or 444 nmol As/gC/min.
(a) Total mass behavior of the carbon electrode, and (b) “corrected” mass behavior due just to arsenic at a solution pH of 12 at 50 mV/s in the NaCl electrolyte for five CV cycles as a function of arsenic concentration.
The corresponding massograms for the 100 ppm arsenic solution on the CE for five cycles in are presented in . As shown, they appear qualitatively similar to those in for the bare Pt electrode in the presence of arsenic. However, peaks A and C are considerably larger, and peak B, although comparable, is slightly smaller. The maximum of the cathodic mass loss peak B is located at about -0.2V, rather than about -0.4V as in , and the cathodic mass gain peak C is larger and broader and located at about -0.5V. However, the arsenic oxidation peak A, although larger, is still located at about +0.4V. The differences in peaks B are consistent with the difference in electrode materials. That is, peak B in most probably involves reduction of carbon-oxygen surface complexes, as well as oxy-arsenic surface complexes. The oxidation of carbon sites evident in , appears to be suppressed in , most probably as a result of competition with arsenic.
Massogram (dM/dt versus E) of the carbon electrode mass behavior at a solution pH of 12 at 50 mV/s with 100 ppm arsenic in the NaCl electrolyte solution for five CV cycles.
The large cathodic mass gain peak appears to be analogous to, although much greater than that observed on the bare Pt electrode (peak C). This is attributed primarily to the uptake of As(V) on carbon active sites, some of which are created by electrogasification, followed by reduction to As(0) and AsO1.5, analogous to the overall stoichiometry of the reactions on Pt; i.e.,
followed by reaction (9
) to produce As2n
. surface complexes. Correspondingly, the large mass loss peak at positive potentials (peak A) is attributed to the oxidation of As(III), both from As2n
surface complex species, as well as from solution, and their desorption as As(V).